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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Thermal Conductivity of Polyimide/Carbon Nanofiller Blends

Ultem(TM) was mixed with three different carbon-based nanofillers in efforts to increase the thermal conductivity of the polymer. After initial mixing, the nanocomposites were extruded or processed via the Laboratory Mixing Molder (LMM) process. High resolution scanning electron microscopy (HRSEM) revealed significant alignment of the nanofillers in the extruded samples. Thermal conductivity measurements were made both in the direction and perpendicular to the direction of alignment of nanofillers as well as for unaligned samples. It was found that the largest improvement in thermal conductivity was achieved in the case of aligned samples when the measurement was performed in the direction of alignment. Unaligned samples also showed a significant improvement in thermal conductivity and may be useful in applications when it is not possible to align the nanofiller. However the improvements in thermal conductivity did not approach those expected based on a rule of mixtures. This is likely due to poor phonon transfer through the matrix.

Delozier, D. M.↗

Chemical differentiation of a convecting planetary interior: Consequences for a one-plate planet such as Venus

Chemically depleted mantle forming a buoyant, refractory layer at the top of the mantle can have important implications for the evolution of the interior and surface. On Venus, the large apparent depths of compensation for surface topographic features might be explained if surface topography were supported by variations in the thickness of a 100-200 km thick chemically buoyant mantle layer or by partial melting in the mantle at the base of such a layer. Long volcanic flows seen on the surface may be explained by deep melting that generates low-viscosity MgO-rich magmas. The presence of a shallow refractory mantle layer may also explain the lack of volcanism associated with rifting. As the depleted layer thickens and cools, it becomes denser than the convecting interior and the portion of it that is hot enough to flow can mix with the convecting mantle. Time dependence of the thickness of a depleted layer may create episodic resurfacing events as needed to explain the observed distribution of impact craters on the venusian surface. We consider a planetary structure consisting of a crust, depleted mantle layer, and a thermally and chemically well-mixed convecting mantle. The thermal evolution of the convecting spherical planetary interior is calculated using energy conservation: the time rate of change of thermal energy in the interior is equated to the difference in the rate of radioactive heat production and the rate of heat transfer across the thermal boundary layer. Heat transfer across the thermal boundary layer is parameterized using a standard Nusselt number-Rayleigh number relationship. The radioactive heat production decreases with time corresponding to decay times for the U, Th, and K. The planetary interior cools by the advection of hot mantle at temperature T interior into the thermal boundary layer where it cools conductively. The crust and depleted mantle layers do not convect in our model so that a linear conductive equilibrium temperature distribution is assumed. The rate of melt production is calculated as the product of the volume flux of mantle into the thermal boundary layer and the degree of melting that this mantle undergoes. The volume flux of mantle into the thermal boundary layer is simply the heat flux divided by amount of heat lost in cooling mantle to the average temperature in the thermal boundary layer. The degree of melting is calculated as the temperature difference above the solidus, divided by the latent heat of melting. A maximum degree of melting is prescribed corresponding to the maximum amount of basaltic melt that the mantle can initially generate. As the crust thickens, the pressure at the base of the crust becomes high enough and the temperature remains low enough for basalt to transform to dense eclogite.

Parmentier, E. M.↗

Direct simulations of chemically reacting turbulent mixing layers, part 2

The results of direct numerical simulations of chemically reacting turbulent mixing layers are presented. This is an extension of earlier work to a more detailed study of previous three dimensional simulations of cold reacting flows plus the development, validation, and use of codes to simulate chemically reacting shear layers with heat release. Additional analysis of earlier simulations showed good agreement with self similarity theory and laboratory data. Simulations with a two dimensional code including the effects of heat release showed that the rate of chemical product formation, the thickness of the mixing layer, and the amount of mass entrained into the layer all decrease with increasing rates of heat release. Subsequent three dimensional simulations showed similar behavior, in agreement with laboratory observations. Baroclinic torques and thermal expansion in the mixing layer were found to produce changes in the flame vortex structure that act to diffuse the pairing vortices, resulting in a net reduction in vorticity. Previously unexplained anomalies observed in the mean velocity profiles of reacting jets and mixing layers were shown to result from vorticity generation by baroclinic torques.

Metcalfe, Ralph W.↗

Directional solidification of Bi-Mn alloys using an applied magnetic field

Off-eutectic compositions of Bi-Mn were directionally solidified in applied transverse magnetic fields up to 3 kG, to determine the effects on thermal and solutal convection. Plane front directional solidification of eutectic and near-eutectic Bi-Mn results in a two-phase rodlike morphology consisting of ferromagnetic MnBi rods in a Bi solid solution matrix. Compositions of either side of the eutectic were studied in growth orientations vertically up and down. Temperature gradient was monitored during growth by means of an in-situ thermocouple. For Bi-rich compositions, the magnetic field appeared to increase mixing as determined from thermal, morphological, chemical, and magnetic analyses. For Mn-rich compositions, morphological and chemical analyses suggest some reduction in mixing due to application of the magnetic force. The capability for carrying out directional solidification of Bi-Mn in high longitudinal magnetic fields was established.

Decarlo, J. L.↗

A study of tornadic thunderstorm interactions with thermal boundaries

A study of tornadic thunderstorm interactions with thermal boundaries using a model of subcloud wind profiles is presented. Within a hot, moist, and conditionally unstable air mass, warm thermal advection and surface friction cause the winds to veer and increase with height, while within a cool, moist air mass cool thermal advection and friction combine to produce a wind profile that has maximum speeds near the surface and veers little with height. The spatial distribution of different wind profiles and moisture contents within the boundary layer may act together to maximize mesoscale moisture contents, convergence, and cyclonic vorticity within a narrow mixing zone along the thermal boundary.

Maddox, R. A.↗

On the Fast Evaluation Method of Temperature and Gas Mixing Ratio Weighting Functions for Remote Sensing of Planetary Atmospheres in Thermal IR and Microwave

Evaluation of weighting functions in the atmospheric remote sensing is usually the most computer-intensive part of the inversion algorithms. We present an analytic approach to computations of temperature and mixing ratio weighting functions that is based on our previous results but the resulting expressions use the intermediate variables that are generated in computations of observable radiances themselves. Upwelling radiances at the given level in the atmosphere and atmospheric transmittances from space to the given level are combined with local values of the total absorption coefficient and its components due to absorption of atmospheric constituents under study. This makes it possible to evaluate the temperature and mixing ratio weighting functions in parallel with evaluation of radiances. This substantially decreases the computer time required for evaluation of weighting functions. Implications for the nadir and limb viewing geometries are discussed.

Ustinov, E. A.↗

Mg and Ti isotopes in presolar Al2O3

Oxygen isotopic compositions and initial Al-26/Al-27 ratios were reported for two presolar Al2O3 grains, Orgueil B and Bishunpur B39. In Orgueil B, O-17/O-16 is about twice the solar value but O-18/O-16 is normal. In B39, O-17/O-16 is approximately 7x higher than solar and O-18/O-16 is 0.6x the solar value. Spectroscopic observations of red giant stars show similar O compositions, which result when material that has experienced partial H burning is mixed into the stellar envelope by the first dredge-up. The O-17/O-16 ratios indicate that Orgueil B originated around a star of approximately 1.5 solar mass, while B39 formed around either a approximately 2 solar mass or 4-7 solar mass star. Both grains formed with Al-26/Al-27 ratios of approximately 10(exp -3). Aluminum-26 is produced in the H shell after core H burning has ceased and first dredge-up has occurred. It is spread through the envelope by the third dredge-up, which occurs in low- and intermediate-mass stars as a series of mixing events driven by thermal pulses in the He shell. In intermediate-mass stars (3-8 solar mass), Al-26 can also be brought to the surface by the second dredge-up, which occurs at the end of core He burning. We have measured Ti isotopes by ion probe in Orgueil B and Bishunpur B39, looking for evidence of He-shell nucleosynthesis. Stars of approximately 1.5 solar mass do not experience second dredge-up, so the Al-26 in Orgueil B must have been mixed outward during third dredge-up, which also supplies He-shell material to the envelope. The size of the isotopic shifts in Ti and Mg suggest that Orgueil B contains approximately 5-10x more material from the He-shell than from the H-shell. In contrast, the lack of measurable Mg and Ti anomalies in B39 imply little or no He-shell contribution. This indicates that Al-26 in B39 was supplied by second dredge-up prior to He-shell ignition and points to a parent star of 4-7 solar mass.

Huss, G. R.↗

A numerical solution of the Navier-Stokes equations for supercritical fluid thermodynamic analysis

An explicit numerical solution of the compressible Navier-Stokes equations is applied to the thermodynamic analysis of supercritical oxygen in the Apollo cryogenic storage system. The wave character is retained in the conservation equations which are written in the basic fluid variables for a two-dimensional Cartesian coordinate system. Control-volume cells are employed to simplify imposition of boundary conditions and to ensure strict observance of local and global conservation principles. Non-linear real-gas thermodynamic properties responsible for the pressure collapse phenomonon in supercritical fluids are represented by tabular and empirical functions relating pressure and temperature to density and internal energy. Wall boundary conditions are adjusted at one cell face to emit a prescribed mass flowrate. Scaling principles are invoked to achieve acceptable computer execution times for very low Mach number convection problems. Detailed simulations of thermal stratification and fluid mixing occurring under low acceleration in the Apollo 12 supercritical oxygen tank are presented which model the pressure decay associated with de-stratification induced by an ordinary vehicle maneuver and heater cycle operation.

Heinmiller, P. J.↗

Implications of the VEGA balloon results for Venus atmospheric dynamics

Both VEGA balloons encountered vertical winds with typical velocities of 1 to 2 meters per second. These values are consistent with those estimated from mixing length theory of thermal convection. However, small-scale temperature fluctuations for each balloon were sometimes larger than predicted. The approximate 6.5-kelvin difference in temperature consistently seen between VEGA-1 and VEGA-2 is probably due to synoptic or planetary-scale nonaxisymmetric disturbances that propagate westward with respect to the planet. There is also evidence from Doppler data for the existence of solar-fixed nonaxisymmetric motions that may be thermal tides. Surface topography may influence atmospheric motions experienced by the VEGA-2 balloon.

Blamont, J. E.↗

Spectral reflectance (0.4 - 5.0 microns) of sulfur related compounds and mixtures

Studied and quantified were: (1) the spectral properties of sulfur related compounds and materials; (2) the effects of thermal history, temperature and mixing ratios on the spectral properties of these materials; and (3) the application of these results to the Jovian system, in particular, the surfaces of Io, Europa, and Amalthea, and the chromophores in the Jovian atmosphere. Major results of the study include: (1) a study of how sulfur deposition affects the band strengths in various silicates; (2) a study of how the ultraviolet absorption band of sulfur is affected by dilution in ice; (3) the application of these two sets of experimental studies to Io, in the case of silicate band strengths, and Europa, as in the case of sulfur dilution in ices.

Gradie, Jonathan C.↗

Design of A CVD Reactor for the Deposition of Diamond in A Microgravity Environment

There is a growing body of theoretical and experimental evidence suggesting that the uniformity, rate, adhesion, quality, and other key properties of Chemical Vapor Deposition (CVD) diamond coatings are influenced by the gas mixing kinetics in the thermal plasma environment of the reaction chamber. The implementation of, for example, Microwave Plasma Enhanced Chemical Vapor Deposition (MPECVD) process in microgravity has, thus, been suggested. Such a diamond deposition system, which overcomes the limitations of present systems and which is distiguishable from them by the use of high pressure MPECVD and recirculation of the would be effluent hydrogen and carbon, is described. Given the key fact that there is nothing in the effluent of the MPECVD process that is truly a byproduct or 'waste', the system can, at least in principle, lend itself to being closed loop yet dynamic. The exhaust contains hydrogen and carbon species which can be recirculated to the plasma reactor, that is, since there are no unusable reaction byproducts, the effluent can be fed back to the reaction chamber with no detriment, thus allowing deployment in a microgravity environment.

M L Languell↗

Vacuum/Zero Net-Gravity Application for On-Orbit TPS Tile Repair

The Orbiter Columbia catastrophically failed during reentry February 1, 2003. All space Shuttle flights were suspended, including logistics support for the International Space Station. NASA LaRC s Structures and Materials Competency is performing characterizations of candidate materials for on-orbit repair of orbiter Thermal Protection System (TPS) tiles to support Return-to-Flight activities led by JSC. At least ten materials properties or attributes (adhesion to damage site, thermal protection, char/ash strength, thermal expansion, blistering, flaming, mixing ease, application in vacuum and zero gravity, cure time, shelf or storage life, and short-term outgassing and foaming) of candidate materials are of interest for on-orbit repair. This paper reports application in vacuum and zero net-gravity (for viscous flow repair materials). A description of the test apparatus and preliminary results of several candidate materials are presented. The filling of damage cavities is different for some candidate repair materials in combined vacuum and zero net-gravity than in either vacuum or zero net- gravity alone.

Harvey, Gale A.↗

Vacuum/Zero Net-Gravity Application for On-Orbit TPS Tile Repair

The Orbiter Columbia catastrophically failed during reentry February 1, 2003. All Space Shuttle flights were suspended, including logistics support for the International Space Station. NASA Langley Research Center s (LaRC) Structures and Materials Competency is performing characterizations of candidate materials for on-orbit repair of orbiter Thermal Protection System (TPS) tiles to support Return-to-Flight activities led by Johnson Space Center (JSC). At least ten materials properties or attributes (adhesion to damage site, thermal protection, char/ash strength, thermal expansion, blistering, flaming, mixing ease, application in vacuum and zero gravity, cure time, shelf or storage life, and short-term outgassing and foaming) of candidate materials are of interest for on-orbit repair. This paper reports application in vacuum and zero net-gravity (for viscous flow repair materials). A description of the test apparatus and preliminary results of several candidate materials are presented. The filling of damage cavities is different for some candidate repair materials in combined vacuum and zero net-gravity than in either vacuum or zero net-gravity alone.

Harvey, Gale A.↗

Thermal Modeling of Zero Boil Off Tank Experiment

Understanding fluid behavior in microgravity environments is essential to further development of cryogenic storage in space environments. The Zero Boil Off Tank (ZBOT) experiment was designed to investigate two-phase pressurization and depressurization of a tank in a microgravity environment. The test fluid was the refrigerant Perfluoro-normal-Pentane (PNP). Thermal modeling for the ZBOT model was conducted using Thermal Desktop and SINDA/FLUINT. The temperature distribution within the fluid of the tank is of particular interest. This particular work is centered on ascertaining the thermal behavior of the refrigerant in order to build more complete models of fluid in microgravity. Separate cases were run modeling experiments that were conducted both on the ground and on the International Space Station (ISS) to compare 1g and microgravity environments. The microgravity modeling cases consisted of a fluid lump representing the vapor ullage suspended in a solid to represent the liquid. Mass flow between the liquid and vapor was modeled using the Schrage equation for mass flow. Initial results indicate that the pressure rise and temperature increase within the fluid closely align with the experimental data by matching initial conditions of the experiment. This work is ongoing and will yield further insights into the thermal behavior of fluid mixing in microgravity.

low-gravity fluid modeling↗

Chip Scale Package Issues

Availability of board solder joint reliability information is critical to the wider implementation of Chip Scale Packages (CSPs).

solder↗

Modulation of the Seasonal Cycle of the Antarctic Sea Ice Extent By Sea Ice Processes and Feedbacks With the Ocean and the Atmosphere

The seasonal cycle of the Antarctic sea ice extent is strongly asymmetric, with a relatively slow increase after the summer minimum followed by a more rapid decrease after the winter maximum. This cycle is intimately linked to the seasonal cycle of the insolation received at the top of the atmosphere, but sea ice processes as well as the exchanges with the atmosphere and ocean may also play a role. To quantify these contributions, a series of idealized sensitivity experiments have been performed with an eddy-permitting (∘) NEMO-LIM3 (Nucleus for European Modelling of the Ocean–Louvain-la-Neuve sea ice model version 3) Southern Ocean configuration, including a representation of ice shelf cavities, in which the model was either driven by an atmospheric reanalysis or coupled to the COSMO-CLM2 regional atmospheric model. In those experiments, sea ice thermodynamics and dynamics as well as the exchanges with the ocean and atmosphere are strongly perturbed. This perturbation is achieved by modifying snow and ice thermal conductivities, the vertical mixing in the ocean top layers, the effect of freshwater uptake and release upon sea ice growth and melt, ice dynamics, and surface albedo. We find that the evolution of sea ice extent during the ice advance season is largely independent of the direct effect of the perturbation and appears thus mainly controlled by initial state in summer and subsequent insolation changes. In contrast, the melting rate varies strongly between the experiments during the retreat, in particular if the surface albedo or sea ice transport are modified, demonstrating a strong contribution of those elements to the evolution of ice coverage through spring and summer. As with the advance phase, the retreat is also influenced by conditions at the beginning of the melt season in September. Atmospheric feedbacks enhance the model winter ice extent response to any of the perturbed processes, and the enhancement is strongest when the albedo is modified. The response of sea ice volume and extent to changes in entrainment of subsurface warm waters to the ocean surface is also greatly amplified by the coupling with the atmosphere.

regional atmosphere ocean sea ice model↗

Importance of Atmospheric Feedbacks in Simulating the Seasonal Cycle of the Antarctic Sea Ice and Its Response to Perturbations

The seasonal cycle of the Antarctic sea ice extent is largely controlled by the evolution of the insolation received at the top of the atmosphere. However, sea ice processes and feedbacks with the ocean and the atmosphere can modulate this seasonal cycle. Here, the atmospheric feedbacks are quantified in a series of idealized sensitivity experiments performed with an eddy-permitting (1/4°) NEMO-LIM3 Southern Ocean configuration, including a representation of ice shelf cavities, in which the model was either driven by an atmospheric reanalysis or coupled to the COSMO-CLM 2 regional atmospheric model. In these experiments, sea ice thermodynamics and dynamics as well as the exchanges with the ocean and atmosphere are strongly perturbed. This perturbation is achieved by modifying snow and ice thermal conductivities, the vertical mixing in the ocean top layers, the effect of freshwater uptake/release upon sea ice growth/melt, ice dynamics and surface albedo. We show that the changes in surface heat fluxes are very different between the configurations driven by the reanalysis and those coupled to the atmosphere. Atmospheric feedbacks enhance the response of the modelled winter ice extent to any of the perturbed processes, and the enhancement is strongest when the albedo is modified. The response of sea ice volume and extent to changes in entrainment of subsurface warm waters to the ocean surface is also greatly amplified by the coupling with the atmosphere. By contrast, the atmospheric feedbacks can damp the impact of the perturbations affecting the heat conductivity through sea ice.

Atmospheric feedbacks↗