Search NASA⌕ Search

SEARCH · Search NASA

Results for “Thermodynamic limit”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

On the limitations of General Circulation Climate Models

General Circulation Models (GCMs) by definition calculate large-scale dynamical and thermodynamical processes and their associated feedbacks from first principles. This aspect of GCMs is widely believed to give them an advantage in simulating global scale climate changes as compared to simpler models which do not calculate the large-scale processes from first principles. However, it is pointed out that the meridional transports of heat simulated GCMs used in climate change experiments differ from observational analyses and from other GCMs by as much as a factor of two. It is also demonstrated that GCM simulations of the large scale transports of heat are sensitive to the (uncertain) subgrid scale parameterizations. This leads to the question whether current GCMs are in fact superior to simpler models for simulating temperature changes associated with global scale climate change.

Stone, Peter H.↗
NASA NTRS1986

A progress report on bolometers operating at 0.1 K using adiabatic demagnetization refrigeration

Bolometers are still the detectors of choice for low background infrared observations at wavelengths longer than 200 microns. In the low background limit, bolometers become more sensitive as their operating temperature decreases, due to fundamental thermodynamic laws. The adiabatic demagnetization technique was evaluated by building a bolometer detection system operating at a wavelength of 1 millimeter for use at a ground based telescope. The system was fit checked at the telescope and is expected to take its first data in November, 1985.

Roellig, T.↗
NASA NTRS2008

Improving the Optical Quality Factor of the WGM Resonator

Resonators usually are characterized with two partially dependent values: finesse (F) and quality factor (Q). The finesse of an empty Fabry-Perot (FP) resonator is defined solely by the quality of its mirrors and is calculated as F=piR(exp 1/2)/(1-R). The maximum up-to-date value of reflectivity R approximately equal to 1 - 1.6 x 10(exp -6) is achieved with dielectric mirrors. An FP resonator made with the mirrors has finesse F=1.9 x 10(exp 6). Further practical increase of the finesse of FP resonators is problematic because of the absorption and the scattering of light in the mirror material through fundamental limit on the reflection losses given by the internal material losses and by thermodynamic density fluctuations on the order of parts in 109. The quality factor of a resonator depends on both its finesse and its geometrical size. A one-dimensional FP resonator has Q=2 F L/lambda, where L is the distance between the mirrors and lambda is the wavelength. It is easy to see that the quality factor of the resonator is unlimited because L is unlimited. F and Q are equally important. In some cases, finesse is technically more valuable than the quality factor. For instance, buildup of the optical power inside the resonator, as well as the Purcell factor, is proportional to finesse. Sometimes, however, the quality factor is more valuable. For example, inverse threshold power of intracavity hyperparametric oscillation is proportional to Q(exp 2) and efficiency of parametric frequency mixing is proportional to Q(exp 3). Therefore, it is important to know both the maximally achievable finesse and quality factor values of a resonator. Whispering gallery mode (WGM) resonators are capable of achieving larger finesse compared to FP resonators. For instance, fused silica resonators with finesse 2.3 x 10(exp 6) and 2.8 x 10(exp 6) have been demonstrated. Crystalline WGM resonators reveal even larger finesse values, F=6.3 x 10(exp 6), because of low attenuation of light in the transparent optical crystals. The larger values of F and Q result in the enhancement of various nonlinear processes. Low-threshold Raman lasing, optomechanical oscillations, frequency doubling, and hyperparametric oscillations based on these resonators have been recently demonstrated. Theory predicts a possibility of nearly 10(exp 14) room-temperature optical Q-factors of optical crystalline WGM resonators, which correspond to finesse levels higher than 10(exp 9). Experiments have shown numbers a thousand times lower than that. The difference occurs due to media imperfections. To substantially reduce the optical losses caused by the imperfections, a specific, multi-step, asymptotic processing of the resonator is implemented. The technique has been initially developed to reduce microwave absorption in dielectric resonators. One step of the process consists of mechanical polishing performed after high temperature annealing. Several steps repeat one after another to lead to significant reduction in optical attenuation and, as a result, to the increase of Q-factor as well as finesse of the resonator which demonstrates a CaF2 WGM resonator with F greater than 10(exp 7) and Q greater than 10(exp 11).

Savchenkov, Anatoliy↗
NASA NTRSDate not supplied

Pumping Wavelength Related Population Inversion in Nd:doped Laser

Pumping wavelength related population inversion in Nd:doped laser has been investigated, where the laser is regarded as two thermodynamic equilibrium systems, upper state one and lower state one. The population inversion limits at various pumping wavelengths and temperatures are compared. The effective metastable life time has been derived, where both pump and laser fields within Nd:doped laser medium reduce the lifetime. The saturation of lifetime is discussed. As a result, in-band pumping of Nd: doped laser is good for improving the efficiency and achieving narrow-linewidth of laser wavelength due to less population inversion; off-band pumping is benefit for extracting high pulse energy thanks of large population inversion.

optical Parametric Oscillator↗
NASA NTRS2023

Observed Changes in Hydroclimate Attributed to Human Forcing

Observational and modeling studies indicate significant changes in the global hydroclimate in the twentieth and early twenty-first centuries due to anthropogenic climate change. In this review, we analyze the recent literature on the observed changes in hydroclimate attributable to anthropogenic forcing, the physical and biological mechanisms underlying those changes, and the advantages and limitations of current detection and attribution methods. Changes in the magnitude and spatial patterns of precipitation minus evaporation ( P–E ) are consistent with increased water vapor content driven by higher temperatures. While thermodynamics explains most of the observed changes, the contribution of dynamics is not yet well constrained, especially at regional and local scales, due to limitations in observations and climate models. Anthropogenic climate change has also increased the severity and likelihood of contemporaneous droughts in southwestern North America, southwestern South America, the Mediterranean, and the Caribbean. An increased frequency of extreme precipitation events and shifts in phenology has also been attributed to anthropogenic climate change. While considerable uncertainties persist on the role of plant physiology in modulating hydroclimate and vice versa, emerging evidence indicates that increased canopy water demand and longer growing seasons negate the water-saving effects from increased water-use efficiency.

Drought↗
NASA NTRS1971

Laser power transmission.

Description of studies which have led to the design of a conceptual device in which the limitation of transforming heat into coherent radiation can be examined. By exploring the basic thermodynamic relationships controlling the operation of this device, it is concluded that a closed-cycle gasdynamic laser is possible in which all of the shaft energy supplied can be turned into laser radiation. Hence, it is possible in principle to convert heat into coherent radiation with approximately the same efficiency with which heat may be converted into electricity. By modifying the closed-cycle-gasdynamic-laser system, this system can be operated in reverse and the incoming radiation may be used to pump the gas in the loop so that shaft power can be extracted. By carefully controlling the temperature distribution in this machine, laser energy can be converted into useful shaft energy with an efficiency approaching 1 .

Ahlstrom, H. G.↗
NASA NTRS2003

From Oxygen Generation to Metals Production: In Situ Resource Utilization by Molten Oxide Electrolysis

For the exploration of other bodies in the solar system, electrochemical processing is arguably the most versatile technology for conversion of local resources into usable commodities: by electrolysis one can, in principle, produce (1) breathable oxygen, (2) silicon for the fabrication of solar cells, (3) various reactive metals for use as electrodes in advanced storage batteries, and (4) structural metals such as steel and aluminum. Even so, to date there has been no sustained effort to develop such processes, in part due to the inadequacy of the database. The objective here is to identify chemistries capable of sustaining molten oxide electrolysis in the cited applications and to examine the behavior of laboratory-scale cells designed to generate oxygen and to produce metal. The basic research includes the study of the underlying high-temperature physical chemistry of oxide melts representative of lunar regolith and of Martian soil. To move beyond empirical approaches to process development, the thermodynamic and transport properties of oxide melts are being studied to help set the limits of composition and temperature for the processing trials conducted in laboratory-scale electrolysis cells. The goal of this investigation is to deliver a working prototype cell that can use lunar regolith and Martian soil to produce breathable oxygen along with metal by-product. Additionally, the process can be generalized to permit adaptation to accommodate different feedstock chemistries, such as those that will be encountered on other bodies in the solar system. The expected results of this research include: (1) the identification of appropriate electrolyte chemistries; (2) the selection of candidate anode and cathode materials compatible with electrolytes named above; and (3) performance data from a laboratory-scale cell producing oxygen and metal. On the strength of these results it should be possible to assess the technical viability of molten oxide electrolysis for in situ resource utilization on the Moon and Mars. In parallel, there may be commercial applications here on earth, such as new green technologies for metals extraction and for treatment of hazardous waste, e.g., fixing heavy metals.

Khetpal, Deepak↗
NASA NTRS2004

Notes on Interface Growth Kinetics 50 Years after Burton, Cabrera and Frank

This overview is devoted to some unresolved basic problems in crystal growth kinetics. The density wave approach to propagation of a spatially diffuse interface between a growing crystal and its simple (e.g., metallic) melt is discussed is Section 2. This approach allows for the calculation of kinetic coefficients and is an alternative to the localized interface concept in which each atom belongs to either a solid or a liquid. Sections 3 and 4 deals mainly with layer growth from solution. Mutual retardation of the growth steps via their bulk and d a c e diffusion fields is the major subject. The influence of solution flow on step bunching (Section 4) suggests the essential influence of bulk diffusion on the surface morphology. The flow within the solution boundary layer enhances step-step interaction, influences the step bunching process and the resulting step pattern morphology on the growing surface. Recent experiments on the rates at which strongly polygonized steps on protein and small molecule crystals propagate during growth from solution are analyzed in Section 5 . We have shown that the step segments may be "singular" and that "one-dimensional nucleation" may be the rate limiting stage for the segments that are shorter or comparable in length to the thermodynamically equilibrium interlink distance. In this case, the reciprocal dependence of the segment propagation rate on the segment length that follow from the Gibbs-Thompson law, should be replaced by an abrupt switch from zero to a finite constant velocity. Until recently, the Kossel crystal remained the only model used in crystal growth theory. In such Kossel Gibbs-Thomson law, should be replaced by an abrupt switch &om zero to a finite constant velocity. crystals, all kinks at the steps are identical and the kink rate is a linear function of the supersaturation. In the non-Kossel crystals, there may be several kink configurations characterized by different geometries and energies. These configurations should appear in a specific sequence when each new lattice unit cell is filled. As a result of such a cooperative interaction within the unit cell, a non-linear dependence of the kink rate on the vapor pressure or solution concentration in excess over the equilibrium value should be expected.

Chernov, A. A.↗
NASA NTRS1986

Adiabaticity and viscosity in deep mantle convection

A study has been conducted of steady convection with adiabatic and viscous heating for variable viscosity in the Boussinesq limit using the mean-field theory. A strong nonlinear coupling is found between the thermodynamic constants governing adiabatic heating and the rheological parameters. The range of rheological values for which adiabaticity would occur throughout the mantle has been established. Too large an activation volume, greater than 6 cu cm/mol for the cases examined, would produce unreasonably high temperature at the bottom of the mantle (greater than 6000 K) and superadiabatic gradients, especially in the lower mantle. Radiogenic heating plays a profound role in controlling dynamically mantle temperatures. Present values for the averaged mantle heat production would yield objectionably high temperatures in the lower mantle.

Quareni, F.↗
NASA NTRS1986

The solar nebula redox state as recorded by the most reduced chondrules of five primitive chondrites

Mafic minerals in the most reduced chondrules of five primitive meteorites were analyzed with an electron microprobe to determine the lower limit on their FeO contents. The accuracy obtained was + or - 0.01 weight percent FeO. The thermodynamic relationship between mole fraction FeSiO3 and pO2 of the ambient nebular gas at the time of mineral equilibration was established, and was used to infer the local O/H ratio of the nebular gas during chondrule formation. The lowest ferrosilite compositions reflected equilibration at 1500 K with a gas 2-18 times more oxidizing than a gas of solar composition. Olivines in low-FeO unequilibrated ordinary chondrites (UOC) chondrules are uniformly more FeO-rich than coexisting pyroxenes. This discrepancy suggests that a significant change in the O/H ratio of the nebular gas occurred between the time of olivine and pyroxene crystallization in the region of the nebula where UOCs formed. Mineral compositions in the chondrules of two C2 chondrites studied suggest they formed in a more homogeneous region of the nebula than the UOCs.

Johnson, M. C.↗
NASA NTRS1987

Magnetic field morphology in the upper layers

Some basic properties of emerged magnetic flux concentrations are examined with emphasis on the interplay between the magnetic and thermodynamic structure in the region between the photosphere and the transition zone. The discussion is limited to the gross behavior of those phenomena that may be reasonably regarded as quasi-static, such as the longer-lived sunspots, pores, and some smaller magnetic flux tubes. Substructure and dynamic phenomena are not considered.

Pizzo, V. J.↗
NASA NTRS1976

Interior models of Jupiter

Understanding the interior of Jupiter depends upon our knowledge of the thermodynamics and transport properties of hydrogen-helium mixtures at high pressures and temperatures. The current status of this knowledge is reviewed, and attention is given to the metallic-molecular hydrogen transition and the limited solubility of helium in hydrogen. Models of Jupiter are constructed which are consistent with all the observations to date, but which make various assumptions about the thermodynamics and composition of the interior. These models typically consist of a rocky core surrounded by a nearly-solar fluid mixture. In contrast to the models of Podolak and Cameron, a large enhancement of water or helium is not found to be essential. It is concluded that further progress in constructing interior models requires a better understanding of the thermodynamics of dense molecular hydrogen.

Stevenson, D. J.↗
NASA NTRS1975

Thermochemical production of hydrogen via multistage water splitting processes

This paper presents and reviews the fundamental thermodynamic principles underlying thermochemical water splitting processes. The overall system is considered first and the temperature limitation in process thermal efficiency is developed. The relationship to an ideal water electrolysis cell is described and the nature of efficient multistage reaction processes is discussed. The importance of the reaction entropy change and the relation of the reaction free energy change to the work of separation is described. A procedure for analyzing thermochemical water splitting processes is presented and its use to calculate individual stage efficiency is demonstrated. A number of processes are used to illustrate the concepts and procedures.

Funk, J. E.↗
NASA NTRS1993

Microgravity combustion of dust suspensions

Unlike the combustion of homogeneous gas mixtures, there are practically no reliable fundamental data (i.e., laminar burning velocity, flammability limits, quenching distance, minimum ignition energy) for the combustion of heterogeneous dust suspensions. Even the equilibrium thermodynamic data such as the constant pressure volume combustion pressure and the constant pressure adiabatic flame temperature are not accurately known for dust mixtures. This is mainly due to the problem of gravity sedimentation. In normal gravity, turbulence, convective flow, electric and acoustic fields are required to maintain a dust in suspension. These external influences have a dominating effect on the combustion processes. Microgravity offers a unique environment where a quiescent dust cloud can in principle be maintained for a sufficiently long duration for almost all combustion experiments (dust suspensions are inherently unstable due to Brownian motion and particle aggregation). Thus, the microgravity duration provided by drop towers, parabolic flights, and the space shuttle, can all be exploited for different kinds of dust combustion experiments. The present paper describes some recent studies on microgravity combustion of dust suspension carried out on the KC-135 and the Caravelle aircraft. The results reported are obtained from three parabolic flight campaigns.

Lee, John H. S.↗
NASA NTRS1998

Mechanisms Regulating Deep Moist Convection and Sea-Surface Temperatures of the Tropics

Despite numerous previous studies, two relationships between deep convection and the sea-surface temperature (SST) of the tropics remain unclear. The first is the cause for the sudden emergence of deep convection at about 28 deg SST, and the second is its proximity to the highest observed SST of about 30 C. Our analysis provides a rational explanation for both by utilizing the Improved Meteorological (IMET) buoy data together with radar rainfall retrievals and atmospheric soundings provided by the Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA-COARE). The explanation relies on the basic principles of moist convection as enunciated in the Arakawa-Schubert cumulus parameterization. Our analysis shows that an SST range of 28-29 C is necessary for "charging" the atmospheric boundary layer with sufficient moist static energy that can enable the towering convection to reach up to the 200 hPa level. In the IMET buoy data, the changes in surface energy fluxes associated with different rainfall amounts show that the deep convection not only reduces the solar flux into the ocean with a thick cloud cover, but it also generates downdrafts which bring significantly cooler and drier air into the boundary-layer thereby augmenting oceanic cooling by increased sensible and latent heat fluxes. In this way, the ocean seasaws between a net energy absorber for non-raining and a net energy supplier for deep-convective raining conditions. These processes produce a thermostat-like control of the SST. The data also shows that convection over the warm pool is modulated by dynamical influences of large-scale circulation embodying tropical easterly waves (with a 5-day period) and MJOs (with 40-day period); however, the quasi-permanent feature of the vertical profile of moist static energy, which is primarily maintained by the large-scale circulation and thermodynamical forcings, is vital for both the 28 C SST for deep convection and its upper limit at about 30 C.

Sud, Y. C.↗
NASA NTRS2004

Assessing the Role of Anhydrite in the KT Mass Extinction: Hints from Shock-loading Experiments

Various killing mechanisms have been suggested to contribute to the mass extinctions at the KT boundary, including severe, global deterioration of the atmosphere and hydrosphere due to SO(x) released from heavily shocked, sulfate-bearing target rocks. The devolatilization of anhydrite is predominantly inferred from thermodynamic considerations and lacks experimental confirmation. To date, the experimentally determined shock behavior of anhydrite is limited to solid-state effects employing X-ray diffraction methods. The present report employs additional methods to characterize experimentally shocked anhydrite.

Skala, R.↗
NASA NTRS2012

From Extremophiles to Star Trek, The Use of Synthetic Biology in Astrobiology

Synthetic biology – the design and construction of new biological parts and systems and the redesign of existing ones for useful purposes – has the potential to transform fields from pharmaceuticals to fuels. Our lab has focused on the potential of synthetic biology to revolutionize all three major parts of astrobiology: Where do we come from? Where are we going? and Are we alone? For the first and third, synthetic biology is allowing us to answer whether the evolutionary narrative that has played out on planet earth is likely to have been unique or universal. For example, in our lab we are re-evolving biotic functions using only the most thermodynamically stable amino acids in order to understand potential capabilities of an early organism with a limited repertoire of amino acids. In the future synthetic biology will play an increasing role in human activities both on earth, in fields as diverse as bio-mining, human health and the industrial production of novel bio-composites. Beyond earth, we will rely increasingly on biologically-provided life support, as we have throughout our evolutionary history. In order to do this, the field will build on two of the great contributions of astrobiology: studies of the origin of life and life in extreme environments.

Life in Extreme Environments↗
NASA NTRS1981

Low-thrust chemical rocket engine study

An analytical study evaluating thrust chamber cooling engine cycles and preliminary engine design for low thrust chemical rocket engines for orbit transfer vehicles is described. Oxygen/hydrogen, oxygen/methane, and oxygen/RP-1 engines with thrust levels from 444.8 N to 13345 N, and chamber pressures from 13.8 N/sq cm to 689.5 N/sq cm were evaluated. The physical and thermodynamic properties of the propellant theoretical performance data, and transport properties are documented. The thrust chamber cooling limits for regenerative/radiation and film/radiation cooling are defined and parametric heat transfer data presented. A conceptual evaluation of a number of engine cycles was performed and a 2224.1 N oxygen/hydrogen engine cycle configuration and a 2224.1 N oxygen/methane configuration chosen for preliminary engine design. Updated parametric engine data, engine design drawings, and an assessment of technology required are presented.

Shoji, J. M.↗