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At least 109 records · Page 6

LADEE UVS Observations of Atoms and Dust in the Lunar Tail

The Lunar Atmosphere and Dust Environment Explorer (LADEE) was a lunar orbiter launched in September 2013 that investigated the composition and temporal variation of the tenuous lunar exosphere and dust environment. A major goal of the mission was to characterize the dust exosphere prior to future lunar exploration activities, which may alter the lunar environment. The Ultraviolet/Visible Spectrometer (UVS) onboard LADEE addresses this goal, utilizing two sets of optics: a limbviewing telescope, and a solar-viewing telescope. We report on spectroscopic (approximately 280 - 820 nm) observations viewing down the lunar wake or along the 'lunar tail' from lunar orbit. Prior groundbased studies have observed the emission from neutral sodium atoms extended along the lunar tail, so often this region is referred to as the lunar sodium tail. UVS measurements were made on the dark side of the moon, with the UVS limb-viewing telescope pointed outward in the direction of the Moon's wake (almost anti-sun), during different lunar phases. These UVS observation activities sample a long column and allow the characterization of scattered light from dust and emission lines from atoms in the lunar tail. Observations in this UVS configuration show the largest excess of scattered blue light in our data set, indicative of the presence of small dust grains in the tail. Once lofted, nanoparticles may become charged and picked up by the solar wind, similar to the phenomena witnessed above Enceladus's northern hemisphere or by the STEREO/WAVES instrument while close to Earth's orbit. The UVS data show that small dust grains as well as atoms become entrained in the lunar tail.

Dust and Solar Wind↗

Formation of the UV Spectrum of Molecular Hydrogen in the Sun

Ultraviolet (UV) lines of molecular hydrogen have been observed in solar spectra for almost four decades, but the behavior of the molecular spectrum and its implications for solar atmospheric structure are not fully understood. Data from the High-Resolution Telescope Spectrometer (HRTS) instrument revealed that H2 emission forms in particular regions, selectively excited by a bright UV transition region and chromospheric lines. We test the conditions under which H2 emission can originate by studying non-LTE models, sampling a broad range of temperature stratifications and radiation conditions. Stratification plays the dominant role in determining the population densities of H2, which forms in greatest abundance near the continuum photosphere. However, opacity due to the photoionization of Si and other neutrals determines the depth to which UV radiation can penetrate to excite the H2. Thus the majority of H2 emission forms in a narrow region, at about 650 km in standard one dimensional (1D) models of the quiet Sun, near the tau = 1 opacity surface for the exciting UV radiation, generally coming from above. When irradiated from above using observed intensities of bright UV emission lines, detailed non-LTE calculations show that the spectrum of H2 seen in the quiet-Sun Solar Ultraviolet Measurement of Emitted Radiation atlas spectrum and HRTS light-bridge spectrum can be satisfactorily reproduced in 1D stratified atmospheres, without including three-dimensional or time-dependent thermal structures. A detailed comparison to observations from 1205 to 1550 Angstroms is presented, and the success of this 1D approach to modeling solar UV H2 emission is illustrated by the identification of previously unidentified lines and upper levels in HRTS spectra.

Jaeggli, S. A.↗

Effect of shadowing on survival of bacteria under conditions simulating the Martian atmosphere and UV radiation

Spacecraft-associated spores and four non-spore-forming bacterial isolates were prepared in Atacama Desert soil suspensions and tested both in solution and in a desiccated state to elucidate the shadowing effect of soil particulates on bacterial survival under simulated Martian atmospheric and UV irradiation conditions. All non-spore-forming cells that were prepared in nutrient-depleted, 0.2-μm-filtered desert soil (DSE) microcosms and desiccated for 75 days on aluminum died, whereas cells prepared similarly in 60-μm-filtered desert soil (DS) microcosms survived such conditions. Among the bacterial cells tested, Microbacterium schleiferi and Arthrobacter sp. exhibited elevated resistance to 254-nm UV irradiation (low-pressure Hg lamp), and their survival indices were comparable to those of DS- and DSE-associated Bacillus pumilus spores. Desiccated DSE-associated spores survived exposure to full Martian UV irradiation (200 to 400 nm) for 5 min and were only slightly affected by Martian atmospheric conditions in the absence of UV irradiation. Although prolonged UV irradiation (5 min to 12 h) killed substantial portions of the spores in DSE microcosms (~5- to 6-log reduction with Martian UV irradiation), dramatic survival of spores was apparent in DS-spore microcosms. The survival of soil-associated wild-type spores under Martian conditions could have repercussions for forward contamination of extraterrestrial environments, especially Mars.

Venkateswaran, Kasthuri↗

PACE UV-VIS Polarimetric Remote Sensing of Atmosphere-Ocean Systems: Sensitivity to Variations in Brown Carbon

The NASA Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) mission, scheduled for launch in 2024, will carry two instruments that measure ultraviolet (UV) radiance emerging from the top of the atmosphere: the Ocean Color Instrument (OCI) and the Spectro-Polarimeter for Planetary Exploration (SPEXone) instrument. OCI will provide single-view, hyperspectral radiometric data, whereas SPEXone will provide multi-angle, multispectral polarimetric data. Together, these instruments will be the most advanced in NASA’s history for the combined observation of ocean color and atmospheric aerosols in the UV, and they will therefore provide unprecedented research opportunities for the ocean color and atmospheric aerosol communities. In particular, UV observations are best suited to retrieve properties of Colored Dissolved Organic Matter (CDOM) in the ocean, and of Brown Carbon (BrC) aerosols in the atmosphere. However, both CDOM and BrC exhibit very similar absorption spectra in the UV and the visible (VIS) spectrum; hence, care must be taken in accurately modeling these spectra for analyses of OCI and SPEXone measurements. In this presentation, we summarize a simple but highly accurate three-parameter model for complex refractive index spectra of BrC in the UV and VIS. We apply this model to simulations of PACE-like total and polarized multiangle radiance in the UV, and demonstrate that the impact of BrC and CDOM variations can be similar in total radiance, but is easy to distinguish in polarized radiance.

PACE↗

HAZMAT. IX. An Analysis of the UV and X-Ray Evolution of Low-mass Stars in the Era of Gaia

Low-mass stars (≤1 M⊙) are some of the best candidates for hosting planets with detectable life because of these stars' long lifetimes and relative ratios of planet to star mass and radius. An important aspect of these stars to consider is the amount of ultraviolet (UV) and X-ray radiation incident on planets in the habitable zones due to the ability of UV and X-ray radiation to alter the chemistry and evolution of planetary atmospheres. In this work, we build on the results of the HAZMAT I and HAZMAT III M-star studies to determine the intrinsic UV and X-ray flux evolution with age for M stars using Gaia parallactic distances. We then compare these results to the intrinsic fluxes of K stars adapted from HAZMAT V. We find that although the intrinsic M-star UV flux is 10–100 times lower than that of K stars, the UV fluxes in their respective habitable zone are similar. However, the habitable zone X-ray flux evolutions are slightly more distinguishable with a factor of 3–15 times larger X-ray flux for late M stars than for K stars. These results suggest that there may not be a K-dwarf advantage compared to M stars in the UV, but one may still exist in the X-ray.

stars↗

Success of Montreal Protocol Demonstrated by Comparing High-Quality UV Measurements with “World Avoided” Calculations from Two Chemistry-Climate Models

The Montreal protocol on Substances that Deplete the ozone Layer has been hailed as the most successful environmental treaty ever (https://www.unenvironment.org/news-and-stories/story/montreal-protocol-triumph-treaty). Yet, although our main concern about ozone depletion is the subsequent increase in harmful solar UV radiation at the earth’s surface, no studies to date have demonstrated its effectiveness in that regard. Here we use long-term UV Index (UVI) data derived from high-quality UV spectroradiometer measurements to demonstrate its success in curbing increases in UV radiation. Without this landmark agreement, UVi values would have increased at mid-latitude locations by approximately 20% between the early 1990s and today and would approximately quadruple at mid-latitudes by 2100. In contrast, an analysis of UVI data from multiple clean-air sites shows that maximum daily UVI values have remained essentially constant over the last ~20 years in all seasons, and may even have decreased slightly in the southern hemisphere, especially in Antarctica, where effects of ozone depletion were larger. Reconstructions of the UVi from total ozone data show evidence of increasing UVI levels in the 1980s, but unfortunately, there are no high-quality UV measurements available prior to the early 1990s to confirm these increases with direct observations.

UV Index (UVI) data derived from high-quality UV s↗

Enhancing lifetime, forecasting, and economic benefits of photovoltaic technologies undergoing UV-induced degradation with optical filtering

Ultraviolet-induced degradation (UV-ID) of various PV cell types was analyzed under optical UV filters with different cutoff wavelengths. Cell types studied included interdigitated back contact (IBC), passivated emitter and rear totally diffused (PERT), and heterojunction technology (HJT) based on crystalline Si (c-Si), and metal halide perovskite (MHP) cells. Analyzing degradation rates in two distinct regimes proved beneficial for all cell types. We used empirical linearizing functions ln(t) for c-Si technologies and 2 √t for MHP samples where t is time. These were applied to extrapolate UV-induced degradation over the lifetime of PV modules under various levels of optical UV filtering and used to predict the relative economic benefits for PV power plants. Degradation rates for all technologies were generally faster under the long pass optical filters having shorter cutoff wavelengths transmitting more UV irradiation and at elevated temperatures when testing MHP samples in the range between 60 °C and 90 °C.

14 SOLAR ENERGY↗

Development of High Performance Detector Technology for UV and Near IR Applications

Sensing and imaging for ultraviolet (UV) and nearinfrared (NIR) bands has many applications forNASA, defense, and commercial systems. Recentwork has involved developing UV avalanchephotodiode (UV-APD) arrays with high gain for highresolution imaging. Various GaN/AlGaN p-i-n (PIN)UV-APDs have been fabricated from epitaxialstructures grown by MOCVD on GaN substrates withavalanche gains higher than 5 x 10(exp 5), and significantlyhigher responsivities. Likewise, the SiGe materialsystem allows the demonstration of high-performancedetector array technology that covers the 0.5 to 1.7 mwavelength range for visible and NIR bands ofinterest. We have utilized SiGe fabrication technologyto develop Ge based PIN detector devices on 300 mmSi wafers. We will discuss the theoretical andexperimental results from electrical and opticalcharacterization of the detector devices with variousn+ region doping concentrations to demonstrate low dark currents below 1 uA at -1 V and high photocurrent. Recent results from these detectorarrays for UV and NIR detection will be presented.

IR↗

Lunar-surface UV Photometric Investigation of Exospheres (LUPINE): Thermal Modeling of Payload in a Relevant Daylit Environment

Direct upward remote sensing of the moon’s exosphere from a surface vantage can address production of water-related lunar volatiles as well as their exospheric loss, ballistic transport, and ultimate adsorption in permanently shadowed regions (PSRs). Far UV (FUV) dayside measurements of atomic oxygen, liberated from regolith by energetic solar protons and micrometeorite impact, can provide critical insight into the endogenic lunar water cycle by constraining total column density [O] at site of production. A notional Lunar-surface UV Photometric Investigation of Exospheres (LUPINE) instrument is designed to exploit solar-pumped atomic oxygen fluorescence at 130.4-nm, in a manner similar to the Apollo 17 UV Spectrometer (UVS) experiment [Fastie 1973; Feldman and Morrison, 1991] and the LRO Lyman-alpha Mapping Project (LAMP) spectrograph [Cook et al., 2013], by implementing a zenith-directed FUV photometer from the lunar surface at low (± 10°) selenographic latitude during the lunar day. Atomic oxygen production from solar energetic particle impact sources is thought to maximize in near solar noon [Sarantos et al., 2012], and the lander-embedded zenith-directed LUPINE photometer, in contrast to UVS and LAMP twilight measurements from orbit, can potentially capture the full column abundance of lunar regolith liberated oxygen. Herein we describe adaptation of FUV reflective optics, pulse-counting electronics, and scattered-light-suppression technologies developed for LEO FUV photometry for the challenging thermal environment of the daylit lunar surface. Preliminary thermal modeling and TVAC measurements of heritage FUV photometer components suggests that, if allowed to shed ~8W of waste heat into the bus of a reference Commercial Lunar Payload Services (CLPS) lander, the LUPINE photometer will be kept sufficiently cool to limit dark current to less than 20 counts/s. This level of dark signal enables an OI 130.4-nm 3-sigma detection threshold of ~1 mR for assumed 2-hour integrations.

Lunar UV Photometer↗

UV Spectropolarimetry with Polstar: Massive Star Binary Colliding Winds

The winds of massive stars are important for their direct impact on the interstellar medium, and for their influence on the final state of a star prior to it exploding as a supernova. However, the dynamics of these winds is understood primarily via their illumination from a single central source. The Doppler shift seen in resonance lines is a useful tool for inferring these dynamics, but the mapping from that Doppler shift to the radial distance from the source is ambiguous. Binary systems can reduce this ambiguity by providing a second light source at a known radius in the wind, seen from orbitally modulated directions. From the nature of the collision between the winds, a massive companion also provides unique additional information about wind momentum fluxes. Since massive stars are strong ultraviolet (UV) sources, and UV resonance line opacity in the wind is strong, UV instruments with a high resolution spectroscopic capability are essential for extracting this dynamical information. Polarimetric capability also helps to further resolve ambiguities in aspects of the wind geometry that are not axisymmetric about the line of sight, because of its unique access to scattering direction information. We review how the proposed MIDEX-scale mission Polstar can use UV spectropolarimetric observations to critically constrain the physics of colliding winds, and hence radiatively-driven winds in general. We propose a sample of 20 binary targets, capitalizing on this unique combination of illumination by companion starlight, and collision with a companion wind, to probe wind attributes over a range in wind strengths. Of particular interest is the hypothesis that the radial distribution of the wind acceleration is altered significantly, when the radiative transfer within the winds becomes optically thick to resonance scattering in multiple overlapping UV lines.

Ultraviolet Astronomy↗

Aging of UV curable PDMS developed for large-scale, high viscosity stereolithography

Polydimethylsiloxane (PDMS) elastomers are silicone rubbers that find widespread application in both academic and industrial settings. This study investigates the use of photosensitive platinum catalysts for UV-activated hydrosilylation of PDMS, which enables the additive manufacturing of PDMS objects through techniques such as stereolithography. Specifically, this study focuses on understanding the aging behavior of Pt-catalyzed, UV-curable PDMS samples, including their mechanical behavior under thermal and UV-accelerated aging conditions. The results show that the Pt-catalyzed, UV-curable PDMS introduced in this research is ‘under-cured’ after being printed and will slowly evolve over time resulting in increased stiffness and decreased elongation, likely due to the formation of additional crosslinks. FTIR spectroscopy indicates that no new chemical bonds or functional groups are generated through the aging process, suggesting that no thermal degradation or polymer chain scissions occur in the polymer matrix. Overall, this PDMS formulation exhibits greater mechanical strength and significantly less reduction in strength with aging, compared with the commonly used, UV-curable thiol-ene PDMS.

36 MATERIALS SCIENCE↗

UV photodissociation dynamics of the acetone oxide Criegee intermediate: experiment and theory

Here, the photodissociation dynamics of the dimethyl-substituted acetone oxide Criegee intermediate [(CH 3 ) 2 COO] is characterized following electronic excitation to the bright 1 ππ* state, which leads to O ( 1 D) + acetone [(CH 3 ) 2 CO, S 0 ] products. The UV action spectrum of (CH 3 ) 2 COO recorded with O ( 1 D) detection under jet-cooled conditions is broad, unstructured, and essentially unchanged from the corresponding electronic absorption spectrum obtained using a UV-induced depletion method. This indicates that UV excitation of (CH 3 ) 2 COO leads predominantly to the O ( 1 D) product channel. A higher energy O ( 3 P) + (CH 3 ) 2 CO (T 1 ) product channel is not observed, although it is energetically accessible. In addition, complementary MS-CASPT2 trajectory surface-hopping (TSH) simulations indicate minimal population leading to the O ( 3 P) channel and non-unity overall probability for dissociation (within 100 fs). Velocity map imaging of the O ( 1 D) products is utilized to reveal the total kinetic energy release (TKER) distribution upon photodissociation of (CH 3 ) 2 COO at various UV excitation energies. Simulation of the TKER distributions is performed using a hybrid model that combines an impulsive model with a statistical component, the latter reflecting the longer-lived (>100 fs) trajectories identified in the TSH calculations. The impulsive model accounts for vibrational activation of (CH 3 ) 2 CO arising from geometrical changes between the Criegee intermediate and the carbonyl product, indicating the importance of CO stretch, CCO bend, and CC stretch along with activation of hindered rotation and rock of the methyl groups in the (CH 3 ) 2 CO product. Detailed comparison is also made with the TKER distribution arising from photodissociation dynamics of CH 2 OO upon UV excitation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation of UV filaments and their applications

UV laser pulses at 266 nm with 170 ps duration and up to 300 mJ energy create UV filaments. The effects of different beam preparation scenarios on UV filamentation are discussed. Beam preparation by focusing in vacuum and launching into the atmosphere through an aerodynamic window establishes the existence of filaments as self-guided non-diffracting entities. In addition, focusing through the aerodynamic window converts the initial super-Gaussian into a parabolic beam profile at the edge of the nonlinear medium (air). The shock-wave generated by the UV filament is investigated via shadowgraphy techniques. The shock-wave is cylindrically symmetric, leaving a low density channel behind, which is well-sustained for 1 ms, as it propagates outward. This low density channel is a waveguide that can be used for guiding purposes. Applications of UV filaments including guiding, remote sensing, and drag reduction for supersonic aircrafts are discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

What controls the UV-to-X-ray continuum shape in quasars?

ABSTRACT We present an investigation of the interdependence of the optical-to-X-ray spectral slope (αox), the He ii equivalent-width (EW), and the monochromatic luminosity at 2500 Å (L2500). The values of αox and He ii EW are indicators of the strength/shape of the quasar ionizing continuum, from the ultraviolet (UV; 1500–2500 Å), through the extreme ultraviolet (EUV; 300–50 Å), to the X-ray (2 keV) regime. For this investigation, we measure the He ii EW of 206 radioquiet quasars devoid of broad absorption lines that have high-quality spectral observations of the UV and 2 keV X-rays. The sample spans wide redshift (≈0.13–3.5) and luminosity (log(L2500) ≈ 29.2–32.5 erg s−1 Hz−1) ranges. We recover the well-known αox–L2500 and He ii EW–L2500 anticorrelations, and we find a similarly strong correlation between αox and He ii EW, and thus the overall spectral shape from the UV, through the EUV, to the X-ray regime is largely set by luminosity. A significant αox– He ii EW correlation remains after removing the contribution of L2500 from each quantity, and thus the emission in the EUV and the X-rays are also directly tied. This set of relations is surprising, since the UV, EUV, and X-ray emission are expected to be formed in three physically distinct regions. Our results indicate the presence of a redshift-independent physical mechanism that couples the continuum emission from these three different regions, and thus controls the overall continuum shape from the UV to the X-ray regime.

Timlin III, John D.↗

Far-UV Fe emission as proxy of Eddington ratios

ABSTRACT The Eddington ratio is a key parameter that governs the diversity of quasar properties. It can be scaled with a strong anticorrelation between optical Fe iiopt and [O iii] emission. In search of such indicators in the far-UV band, the Hubble Space Telescope far-UV spectra of 150 low-redshift quasars are analysed in combination with their optical SDSS counterparts. The strength of Fe ii+Fe iii λ1123 emission is significantly correlated with that of Fe iiopt. A moderate correlation may also exist between Fe ii λ1071 and Fe iiopt. The finding opens the possibility that far-UV Fe ii emission may serve as a new gauge of the Eddington ratios. The high- and low-ionization lines in the far-UV band display different patterns: for the quasars with higher Eddington ratios, the low-ionization UV lines are stronger, and the high-ionization lines are broader and weaker.

Zheng, Wei↗

Probing UV-sensitive Pathways for CN and HCN Formation in Protoplanetary Disks with the Hubble Space Telescope

The UV radiation field is a critical regulator of gas-phase chemistry in surface layers of disks around young stars. In an effort to understand the relationship between photocatalyzing UV radiation fields and gas emission observed at infrared and submillimeter wavelengths, we present an analysis of new and archival Hubble Space Telescope (HST), Spitzer, ALMA, IRAM, and SMA data for five targets in the Lupus cloud complex and 14 systems in Taurus-Auriga. The HST spectra were used to measure Lyα and far-UV (FUV) continuum fluxes reaching the disk surface, which are responsible for dissociating relevant molecular species (e.g., HCN, N{sub 2}). Semi-forbidden C ii] λ2325 and UV-fluorescent H{sub 2} emission were also measured to constrain inner disk populations of C{sup +} and vibrationally excited H{sub 2}. We find a significant positive correlation between 14 μm HCN emission and fluxes from the FUV continuum and C ii] λ2325, consistent with model predictions requiring N{sub 2} photodissociation and carbon ionization to trigger the main CN/HCN formation pathways. We also report significant negative correlations between submillimeter CN emission and both C ii] and FUV continuum fluxes, implying that CN is also more readily dissociated in disks with stronger FUV irradiation. No clear relationships are detected between either CN or HCN and Lyα or UV-H{sub 2} emission. This is attributed to the spatial stratification of the various molecular species, which span several vertical layers and radii across the inner and outer disk. We expect that future observations with the James Webb Space Telescope will build on this work by enabling more sensitive IR surveys than were possible with Spitzer.

79 ASTRONOMY AND ASTROPHYSICS↗

Far UV camera/spectrograph

In March 1610, Galileo Galilei reported the first use of a telescope to view mountains and maria on the Moon. On April 21, 1972, the Apollo 16 commander pointed a somewhat more complex optical instrument at the Earth from the Moon and obtained several remarkable photographs showing atmospheric rather than surface features. The optical part of the far UV camera (aperture, 7.5 cm) was not much larger than Galileo's telescope. Like his, this instrument was also pointed at other celestial objects that Galileo viewed, including the Milky Way and Jupiter, and the Large Magellanic Cloud (LMC), which is not visible from Italy. More important, the far UV camera/spectrograph recorded light in the invisible band of wavelengths between 50 and 160 nm, approximately one-third the wavelength that can penetrate the atmosphere of the Earth to ground-based telescopes. As described in more detail in this section, these UV observations from the Moon allow study of the entire atmosphere of the Earth and the geocorona. The photographs show hydrogen and other gases in the solar wind and interplanetary media, and they provide new data on stars, nebulae, and galaxies much farther away. When used as a spectrograph, the instrument distributes the light it receives according to wavelength, and the resulting spectrum shows bright lines or gaps known to be characteristic of various gases, such as hydrogen (H), helium (He), oxygen (O), nitrogen (N), and neon (Ne). If a gas cloud is hot, the atoms are excited and the spectrum shows bright emission lines; if it is cool, the atoms absorb light, leaving gaps or absorption lines. The far UV camera is blind to ordinary visible light; for that reason, the photographs show very few of the stars mapped by ground-based telescopes. Only the very-high-temperature (blue) stars of spectral classes O, B, and possibly A (temperatures from 50000 ° down to 10000°K) are expected to be recorded. Image blackness or density on the negatives also depends on the brightness of the star, which astronomers measure in an inverted logarithmic scale of magnitudes. A star of 6 magnitudes (mag.) can barely be seen with the unaided eye. An 11-mag. star is 100 times fainter, and a 12-mag. star is 2.5 times fainter yet. The faintest star recorded by the far UV camera is at least 11 mag., which is called the limiting magnitude.

George R. Carruthers↗

Total ozone derived from UV spectrophotometer measurements on the NASA CV-990 aircraft for the fall 1976 latitude survey flights

An ultraviolet interference filter spectrophotometer was modified to use a photodiode and was flown on latitude survey flights in the fall of 1976. Comparison with Dobson station total ozone values shows agreement between UVS and Dobson total ozone of + or - 2 percent. The procedure used to convert UVS measured ozone above the aircraft altitude to total ozone above ground level introduces an additional 2 percent deviation for very high altitude UVS ozone data. Under stable aircraft operating conditions, the UVS derived ozone values have a variability, or reproducibility, of better than + or -1 percent. The UVS data from the latitude survey flights yield a detailed latitude profile of total ozone over the Pacific Ocean during November 1976. Significant latitudinal structure in total ozone is found at the middle latitudes (30 deg to 40 deg N and S).

Hanser, F. A.↗