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Results for “VACUUM ULTRAVIOLET”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Vacuum ultraviolet light source utilizing rare gas scintillation amplification sustained by photon positive feedback

A source of light in the vacuum ultraviolet (VUV) spectral region includes a reflective UV-sensitive photocathode supported in spaced parallel relationship with a mesh electrode within a rare gas at low pressure. A high positive potential applied to the mesh electrode creates an electric field which causes drifting of free electrons occurring between the electrodes and producing continuous VUV light output by electric field-driven scintillation amplification sustained by positive photon feedback mediated by photoemission from the photocathode. In one embodiment the lamp emits a narrow-band continuum peaked at 175 nm.

Aprile, Elena↗
NASA NTRS1979

Vacuum ultraviolet reflectance spectra of group H chondrites

The spectral reflectances of seventeen group H chondrites have been measured in the vacuum ultraviolet region, from 5 to 14 eV photon energy (250 to 90 nm, wavelength), as part of a survey of all meteorite types. Olivines, ortho-, and clino- pyroxenes are the three most important silicate minerals in these meteorites, and the spectrum of each mineral contains a distinct peak caused by a transition believed to be excitonic in nature and involving the valence-conduction bandgap. The energy at which this peak occurs varies as a function of mineral composition, and this variation has been determined from the spectra of a number of mineral standards. The observed positions of the olivine and pyroxene peaks in the meteorite spectra are compared to predicted positions based on the standard minerals.

Wagner, J. K.↗
NASA NTRS1995

Evaluation of Thermal Control Coatings and Polymeric Materials Exposed to Ground Simulated Atomic Oxygen and Vacuum Ultraviolet Radiation

Numerous thermal control and polymeric samples with potential International Space Station applications were evaluated for atomic oxygen and vacuum ultraviolet radiation effects in the Princeton Plasma Physics Laboratory 5 eV Neutral Atomic Oxygen Facility and in the MSFC Atomic Oxygen Drift Tube System. Included in this study were samples of various anodized aluminum samples, ceramic paints, polymeric materials, and beta cloth, a Teflon-impregnated fiberglass cloth. Aluminum anodizations tested were black duranodic, chromic acid anodize, and sulfuric acid anodize. Paint samples consisted of an inorganic glassy black paint and Z-93 white paint made with the original PS7 binder and the new K2130 binder. Polymeric samples evaluated included bulk Halar, bulk PEEK, and silverized FEP Teflon. Aluminized and nonaluminized Chemfab 250 beta cloth were also exposed. Samples were evaluated for changes in mass, thickness, solar absorptance, and infrared emittance. In addition to material effects, an investigation was made comparing diffuse reflectance/solar absorptance measurements made using a Beckman DK2 spectroreflectometer and like measurements made using an AZ Technology-developed laboratory portable spectroreflectometer.

Kamenetzky, R. R.↗
NASA NTRS1974

Possibility of using sources of vacuum ultraviolet irradiation to solve problems of space material science

An urgent problem in space materials science is simulating the interaction of vacuum ultraviolet (VUV) of solar emission with solids in space conditions, that is, producing a light source with a distribution that approximates the distribution of solar energy. Information is presented on the distribution of the energy flux of VUV of solar radiation. Requirements that must be satisfied by the VUV source used for space materials science are formulated, and a critical evaluation is given of the possibilities of using existing sources for space materials science. From this evaluation it was established that none of the sources of VUV satisfies the specific requirements imposed on the simulator of solar radiation. A solution to the problem was found to be in the development of a new type of source based on exciting a supersonic gas jet flowing into vacuum with a sense electron beam. A description of this gas-jet source, along with its spectral and operation characteristics, is presented.

Verkhoutseva, E. T.↗
NASA NTRS1972

Molecular branching ratio method for intensity calibration of optical systems in the vacuum ultraviolet

A state-of-the-art review is given of the molecular branching ratio method for intensity calibration in the vacuum ultraviolet. Ways are described for determining both relative and quantitative responses in the wavelength range 1000 A to 3000 A. The molecular band systems which are discussed are the following: H2(B 1 Sigma u +)-(X 1 Sigma g +), H2(C 1 Pi u)-(X 1 Sigma g +), N2(A 1 Pi g)-(X 1 Sigma g +), CO(A 1 Pi)-(X 1 Sigma +), NO(A 2 Sigma +)-(X 2 Pi r), and NO(+) (A 1 Pi)-(X 1 Sigma +).

Mumma, M. J.↗
NASA NTRS2003

Luminescence from Vacuum-Ultraviolet-Irradiated Cosmic Ice Analogs and Residue

Here we report a study of the optical luminescent properties for a variety of vacuum-ultraviolet (VUV)-irradiated cosmic ice analogs and the complex organic residues produced. Detailed results are presented for the irradiated, mixed molecular ice: H2O: CH3OH:NH3:CO(100:50:1:1), a realistic representation for an interstellar/precometary ice that reproduces all the salient infrared spectral features associated with interstellar ices. The irradiated ices and the room-temperature residues resulting from this energetic processing have remarkable photoluminescent properties in the visible (520-570 nm). The luminescence dependence on temperature, thermal cycling, and VUV exposure is described. It is suggested that this type of luminescent behavior might be applicable to solar system and interstellar observations and processes for various astronomical objects with an ice heritage. Some examples include grain temperature determination and vaporization rates, nebula radiation balance, albedo values, color analysis, and biomarker identification.

Gudipati, Murthy S.↗
NASA NTRS2003

Luminescence from Vacuum-Ultraviolet-Irradiated Cosmic Ice Analogs and Residues

Here we report a study of the optical luminescent properties for a variety of vacuum-ultraviolet (VUV)- irradiated cosmic ice analogs and the complex organic residues produced. Detailed results are presented for the irradiated, mixed molecular ice: H2O:CH3OH:NH3:CO (100:50:1:1), a realistic representation for an interstellar/precometary ice that reproduces all the salient infrared spectral features associated with interstellar ices. The irradiated ices and the room-temperature residues resulting from this energetic processing have remarkable photoluminescent properties in the visible (520-570 nm). The luminescence dependence on temperature, thermal cycling, and VUV exposure is described. It is suggested that this type of luminescent behavior might be applicable to solar system and interstellar observations and processes for various astronomical objects with an ice heritage. Some examples include grain temperature determination and vaporization rates, nebula radiation balance, albedo values, color analysis, and biomarker identification.

Gudipati, Murthy S.↗
DOE OSTI2025

Time-resolved vacuum-ultraviolet photoelectron spectroscopy of the à 1 A u state of acetylene

Ultrafast time-resolved photoelectron spectra are reported for the vacuum-ultraviolet (VUV) photoionization of acetylene following excitation to the à 1 A u state via UV absorption at 200 nm. The excitation energy lies above the lowest dissociation threshold to C 2 H X̃ 2 Σ + + H, as well as above the threshold for adiabatic dissociation of the à 1 A u state to form C 2 H (à 2 Π) + H. The time-dependent mass spectra and photoelectron spectra provide insight into the intramolecular decay processes of the à 1 A u state. In addition, photoelectron spectra of the à 1 A u state with VUV light access both the X̃ 2 Π u and à 2 Σ g + states of the ion, as well as the predicted, but previously unobserved, 1 2 Π g state, which corresponds to a two-hole, one-particle configuration that lies in close proximity to the à 2 Σ g + state. The 1 2 Π g state is split into 2 A 2 + 2 B 2 and 2 A g + 2 B g states in the cis and trans configurations, respectively. In conclusion, electronic structure calculations, along with trajectory calculations, reproduce the principal features of the experimental data and confirm the assignment of the 1 2 Π g state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

Cross sections and band strengths for the N2O/+/ /A 2Sigma+ to X 2Pi/ system produced by vacuum ultraviolet radiation

Analysis of cross sections that have been obtained for the production of the N2O(+) (A 2Sigma+ to X 2Pi) fluorescence, using vacuum ultraviolet radiation between 462 and 755 A. The fluorescence spectra produced using incident photons of 715.6- and 754.9-A wavelengths are presented, as well as the relative fluorescence cross sections for the individual observed bands of the above-mentioned N2O(+) system. Finally, absolute cross sections for the production of the N2O(+) (A 2Sigma+ to X 2Pi) system are presented, as well as band strengths for the A 2Sigma+(0,0,0) to X 2Pi(n1,n2,0) fluorescence.

Lee, L. C.↗
NASA NTRS1980

Vacuum ultraviolet reflectance spectra of groups L, LL, and E chondrites and of achondrites

The reflectance spectra of individual meteorites of all classes are being measured in the vacuum ultraviolet (VUV) spectral wavelength region from 89 to 248 nm to evaluate the potential of VUV spectroscopy as a remote sensing method for planetary studies. In the present investigation, specimens of 15 group L chondrites, 13 group LL chondrites, 7 group E chondrites, and 18 achondrites were studied. Spectra were measured of both polished thin sections and powders of the meteorites, where both were available. Attention is given to measurements of mineral standards, shock effects, and meteorite data. It is concluded that the VUV spectra of meteorites should provide a useful basis for comparisons with spectra of asteroids and comet nuclei taken from spacecraft. VUV spectroscopy should make it possible to identify the major minerals present in a meteorite or asteroid.

Wagner, J. K.↗
NASA NTRS1990

In situ measurements of scattering from contaminated optics in the Vacuum Ultraviolet

NASA's In Situ Contamination Effects Facility has been used to measure the time dependence of the angular reflectance from molecularly contaminated optical surfaces in the vacuum ultraviolet. The light scattering measurements are accomplished in situ on optical surfaces in real time during deposition of molecular contaminants. The measurements are taken using noncoherent VUV sources with the predominant wavelengths being the krypton resonance lines at 1236 and 1600 angstroms. Detection of the scattered light is accomplished using a set of three solar blind VUV photomultipliers. An in-plane VUV BRDF (bidirectional reflectance distribution function) experiment is described and details of the on-going program to characterize optical materials exposed to the space environment is reported.

Herren, Kenneth A.↗
NASA NTRS1972

The molecular branching ratio method for calibration of optical systems in the vacuum ultraviolet

The intensity distribution of bands belonging to six molecular band systems is discussed with special emphasis on their usefulness for intensity calibration of optical systems in the vacuum ultraviolet (1000A Lambda 3000A). The theory of molecular band intensities is outlined and the technique of measuring the spectral response curve is described. Several methods for establishing an absolute intensity calibration are discussed.

Mumma, M. J.↗
NASA NTRS2001

International Test Program for Synergistic Atomic Oxygen and Vacuum Ultraviolet Radiation Exposure of Spacecraft Materials

The components and materials of spacecraft in low Earth orbit can degrade in thermal and optical performance through interaction with atomic oxygen and vacuum ultraviolet (VUV) radiation, which are predominant in low Earth orbit. Because of the importance of low Earth orbit durability and performance to manufacturers and users, an international test program for assessing the durability of spacecraft materials and components was initiated. Initial tests at the NASA Glenn Research Center consisted of exposure of samples representing a variety of thermal control paints, multilayer insulation materials, and Sun sensors that have been used in space. Materials donated from various international sources were tested alongside materials whose performance is well known, such as Teflon FEP, Kapton H, or Z-93-P white paint. The optical, thermal, or mass loss data generated during the tests were then provided to the participating material suppliers. Data were not published unless the participant donating the material consented to publication. The test program is intended to give spacecraft builders and users a better understanding of degradation processes and effects so that they can improve their predictions of spacecraft performance.

Miller, Sharon K.↗