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NASA NTRS1993

Possible Near-IR Channels for Remote Sensing Precipitable Water Vapor from Geostationary Satellite Platforms

Remote sensing of tropospheric water vapor profiles from current geostationary weather satellites are made using a few broadband infrared (IR) channels in the 6 to 13- micrometers region. Uncertainties greater than 20 percent exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micrometer water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micrometer. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor...

Green, R. O.↗

NASA NTRS1991

Airborne water vapor DIAL system and measurements of water and aerosol profiles

The Lidar Applications Group at NASA Langley Research Center has developed a differential absorption lidar (DIAL) system for the remote measurement of atmospheric water vapor (H2O) and aerosols from an aircraft. The airborne H2O DIAL system is designed for extended flights to perform mesoscale investigations of H2O and aerosol distributions. This DIAL system utilizes a Nd:YAG-laser-pumped dye laser as the off-line transmitter and a narrowband, tunable Alexandrite laser as the on-line transmitter. The dye laser has an oscillator/amplifier configuration which incorporates a grating and prism in the oscillator cavity to narrow the output linewidth to approximately 15 pm. This linewidth can be maintained over the wavelength range of 725 to 730 nm, and it is sufficiently narrow to satisfy the off-line spectral requirements. In the Alexandrite laser, three intracavity tuning elements combine to produce an output linewidth of 1.1 pm. These spectral devices include a five-plate birefringent tuner, a 1-mm thick solid etalon and a 1-cm air-spaced etalon. A wavelength stability of +/- 0.35 pm is achieved by active feedback control of the two Fabry-Perot etalons using a frequency stabilized He-Ne laser as a wavelength reference. The three tuning elements can be synchronously scanned over a 150 pm range with microprocessor-based scanning electronics. Other aspects of the DIAL system are discussed.

Higdon, Noah S.↗

NASA NTRS2002

High Temperature Corrosion of Silicon Carbide and Silicon Nitride in Water Vapor

Silicon carbide (SiC) and silicon nitride (Si3N4) are proposed for applications in high temperature combustion environments containing water vapor. Both SiC and Si3N4 react with water vapor to form a silica (SiO2) scale. It is therefore important to understand the durability of SiC, Si3N4 and SiO2 in water vapor. Thermogravimetric analyses, furnace exposures and burner rig results were obtained for these materials in water vapor at temperatures between 1100 and 1450 C and water vapor partial pressures ranging from 0.1 to 3.1 atm. First, the oxidation of SiC and Si3N4 in water vapor is considered. The parabolic kinetic rate law, rate dependence on water vapor partial pressure, and oxidation mechanism are discussed. Second, the volatilization of silica to form Si(OH)4(g) is examined. Mass spectrometric results, the linear kinetic rate law and a volatilization model based on diffusion through a gas boundary layer are discussed. Finally, the combined oxidation and volatilization reactions, which occur when SiC or Si3N4 are exposed in a water vapor-containing environment, are presented. Both experimental evidence and a model for the paralinear kinetic rate law are shown for these simultaneous oxidation and volatilization reactions.

Opila, E. J.↗

NASA NTRS2008

Seasonal Trends in Stratospheric Water Vapor as Derived from SAGE II Data

Published analysis of HALOE and Boulder balloon measurements of water vapor have shown conflicting trends in stratospheric water vapor for the periods of 1981 through 2005. Analysis of the SAGE II monthly mean water vapor data filtered for large aerosol events for time periods from 1985-1991, 1995-1999, and 2000-2005 have shown a globally decreasing water vapor trend at 17.5km. Seasonal analysis for these three time periods show a decreasing trend in water vapor at 17.5km for the winter and spring seasons. The summer and autumn seasonal analysis show a decreasing trend from 1985-2005, however, there is a increasing trend in water vapor at 17.5km for these seasons during 1995-2005. Latitude vs height seasonal analysis show a decreasing trend in the lower stratosphere between 20S - 20N for the autumn season, while at the latitudes of 30-50S and 30-50N there is an increasing trend in water vapor at heights up to 15km for that season. Comparison with regions of monsoon activity (Asian and North American) show that the Asian monsoon region had some effect on the lower stratospheric moistening in 1995-1999, however, for the time period of 2000-2005, there was no change in the global trend analysis due to either monsoon region. This may be due to the limitations of the SAGE II data from 2000-2005.

Roell, Marilee M.↗

NASA NTRS1995

First lidar measurements of water vapor and aerosols from a high-altitude aircraft

Water vapor plays an important role in many atmospheric processes related to radiation, climate change, atmospheric dynamics, meteorology, the global hydrologic cycle, and atmospheric chemistry, and yet our knowledge of the global distribution of water vapor is very limited. The differential absorption lidar (DIAL) technique has the potential of providing needed high resolution water vapor measurements from aircraft and from space, and the Lidar Atmospheric Sensing Experiment (LASE) is a key step in the development of this capability. The LASE instrument is the first fully engineered, autonomous DIAL system, and it is designed to operate from a high-altitude aircraft (ER-2) and to make water vapor and aerosol profile measurements across the troposphere. The LASE system was flown from the NASA Wallops Flight Facility in a series of engineering flights during September 1994. This paper discusses the characteristics of the LASE system and presents the first LASE measurements of water vapor and aerosol profiles.

Browell, Edward V.↗

NASA NTRS2017

Retrieval of Water Vapor Column Abundance and Aerosol Properties from ChemCam Passive Sky Spectroscopy

We derive water vapor column abundances and aerosol properties from Mars Science Laboratory (MSL) ChemCam passive mode observations of scattered sky light. This paper covers the methodology and initial results for water vapor and also provides preliminary results for aerosols. The data set presented here includes the results of 113 observations spanning from Mars Year 31 L(s) = 291 deg (March 30, 2013) to Mars Year 33 L(s) = 127 deg (March 24, 2016). Each ChemCam passive sky observation acquires spectra at two different elevation angles. We fit these spectra with a discrete-ordinates multiple scattering radiative transfer model, using the correlated-k approximation for gas absorption bands. The retrieval proceeds by first fitting the continuum of the ratio of the two elevation angles to solve for aerosol properties, and then fitting the continuum-removed ratio to solve for gas abundances. The final step of the retrieval makes use of the observed CO 2 absorptions and the known CO 2 abundance to correct the retrieved water vapor abundance for the effects of the vertical distribution of scattering aerosols and to derive an aerosol scale height parameter. Our water vapor results give water vapor column abundance with a precision of +/-0.6 precipitable microns and systematic errors no larger than +/-0.3 precipitable microns, assuming uniform vertical mixing. The ChemCam-retrieved water abundances show, with only a few exceptions, the same seasonal behavior and the same timing of seasonal minima and maxima as the TES, CRISM, and REMS-H data sets that we compare them to. However ChemCam-retrieved water abundances are generally lower than zonal and regional scale from-orbit water vapor data, while at the same time being significantly larger than pre-dawn REMS-H abundances. Pending further analysis of REMS-H volume mixing ratio uncertainties, the differences between ChemCam and REMS-H pre-dawn mixing ratios appear to be much too large to be explained by large scale circulations and thus they tend to support the hypothesis of substantial diurnal interactions of water vapor with the surface. Our preliminary aerosol results, meanwhile, show the expected seasonal pattern in dust particle size but also indicate a surprising interannual increase in water-ice cloud opacities.

Mcconnochie, Timothy H.↗

NASA NTRS2016

A Multi-Sensor Water Vapor, Temperature and Cloud Climate Data Record: Status of Our MEaSUREs 2012 Project

- Our primary objectives: Incorporate all A-Train water vapor, including small-scale, horizontal and vertical water vapor structure from MODIS (Moderate Resolution Imaging Spectroradiometer) and GPS (Global Positioning System); Use MODIS cloud classification that is collocated at the pixel-scale over the full AIRS/AMSU (Atmospheric Infrared Sounder/Advanced Microwave Sounding Unit) swath; Extend summaries to PDFs (Probability Distribution Functions)/higher order moments of water vapor sorted by cloud classes; Establish robust, scale-dependent statistical relationships between cloud, temperature, and water vapor PDFs for the climate modeling community. - We will also: Update our current data record to new CloudSat/CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) cloud classification; Provide merged AIRS and MLS (Microwave Limb Sounder) water vapor profiles using averaging kernels; Include temperature and water vapor from models (ECMWF - European Centre for Medium-Range Weather Forecasts) and re-analyses (MERRA - Modern Era-Retrospective Analysis for Research and Applications); Classify METOP-A (Meteorological Operational Satellite-A) and NOAA (National Oceanic and Atmospheric Administration) satellite water vapor with AVHRR (Advanced Very High Resolution Radiometer) during SNOs (Solar Neutrino Oscillations); Compare with the NVAP-M (re-analysis and extension of the NASA Water Vapor Project (NVAP)) water vapor climatologies; Use existing data sources and mature algorithms, and document processing algorithms.

Fetzer, Eric↗

NASA NTRS1999

Water Vapor Feedbacks to Climate Change

The response of water vapor to climate change is investigated through a series of model studies with varying latitudinal temperature gradients, mean temperatures, and ultimately, actual climate change configurations. Questions to be addressed include: what role does varying convection have in water vapor feedback; do Hadley Circulation differences result in differences in water vapor in the upper troposphere; and, does increased eddy energy result in greater eddy vertical transport of water vapor in varying climate regimes?

Rind, David↗

NASA NTRS1990

An interim reference model for the variability of the middle atmosphere water vapor distribution

A reference model for the middle atmosphere water vapor distribution for some latitudes and seasons was developed using two data sets. One is the seven months of Nimbus LIMS data obtained during November 1978 to May 1979 over the range 64 deg S - 84 deg N latitude and from about 100-mb to 1-mb altitude, and the other is represented by water vapor profiles from 0.2 mb to 0.01 mb in the mid-mesosphere, measured on ground at several fixed mid-latitude sites in the Northern Hemisphere, using microwave-emission techniques. This model provides an interim water vapor profile for the entire vertical range of the middle atmosphere, with accuracies of better than 25 percent. The daily variability of stratospheric water vapor profiles about the monthly mean is demonstrated, and information is provided on the longitudinal variability of LIMS water vapor profiles about the daily, weekly, and monthly zonal means.

Remsberg, E. E.↗

DOE OSTI2025

Effects of Water Vapor on the Reactivity of Aluminosilicates in Vapor-Phase Propanal Aldol Condensation

Aluminosilicate materials have been extensively studied as efficient aldol catalysts for C-C coupling reactions due to their acidic nature, high surface area, thermal stability, and porous structure. This work investigated the impact of water vapor pressure on the catalytic reactivity of aluminosilicates for the aldol condensation of propanal to 2-methyl-2-pentenal (MP). The catalytic performance of amorphous SiO2-Al2O3 (A-Si-Al) and aluminated MCM-41 (Al-MCM-41) for the vapor-phase aldol condensation of propanal was evaluated at 200 degrees C as a function of vapor-phase water content at atmospheric pressure. Our findings demonstrate that co-feeding low water vapor pressures (1-18 kPa) with propanal enhances the rates of MP production at 200 degrees C on A-Si-Al. Conversely, water vapor pressures of 25 kPa result in a decrease in aldol dimer formation rates. The rate of MP production evaluated on Al-MCM-41 also increased in the presence of 5 kPa water compared to anhydrous conditions. Propylamine temperature-programmed desorption analyses revealed an increase in Bronsted acid site density when both catalysts were exposed to water, which likely accounts for the observed enhancement in aldol condensation reactivity under hydrous conditions. Reversibility testing of the water vapor effect under reaction conditions, combined with X-ray diffraction analysis of fresh, spent, and regenerated catalysts, revealed no structural changes in either aluminosilicate upon exposure to water or reaction conditions. The rates of aldol condensation and the impact of water vapor were highly consistent across both materials, suggesting that zeolite crystallinity has minimal influence on the catalytic performance.

acid catalysts↗

DOE OSTI2020

The Incredible Lightness of Water Vapor

The molar mass of water vapor is much less than that of dry air. This makes a moist parcel lighter than a dry parcel of the same temperature and pressure. This effect is referred to as the vapor buoyancy effect and has often been overlooked in climate studies. We propose that the vapor buoyancy effect increases Earth’s outgoing longwave radiation (OLR) and that this negative radiative effect increases with warming, stabilizing Earth’s climate. We illustrate this mechanism in an idealized tropical atmosphere, where there is no horizontal buoyancy gradient in the free troposphere. Temperature increases toward dry atmosphere columns to compensate the reduced vapor buoyancy, increasing OLR by O(1 W m −2 ) at the reference climate. In warmer climates, the temperature difference between moist and dry columns would increase as a result of increasing atmospheric water vapor, leading to enhanced radiative effect and thereby stabilizing Earth’s climate. We estimate that this feedback strength is about O(0.2 W m −2 K −1 ) in the idealized atmosphere, which compares to cloud feedback and surface albedo feedback in the current climate. We further show evidence from observations and real-gas radiative transfer calculations for a significant radiative effect of vapor buoyancy in the tropical atmosphere.

Yang, Da↗

NASA NTRS2000

Advanced Atmospheric Water Vapor DIAL Detection System

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface. This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto a small Printed Circuit Board (PCB) with minimal weight and power consumption. Comparing its measurements to an existing DIAL system for aerosol and water vapor profiling validated the detection system.

Refaat, Tamer F.↗

NASA NTRS2004

Comparison of Upper Tropospheric Water Vapor from AIRS and Cryogenic Frostpoint Hygrometers

Upper tropospheric water vapor (UTWV) from the Atmospheric Infrared Sounder (AIRS) experiment on NASA's Aqua spacecraft has the potential of addressing several important climate questions. The specified AIRS system measurement uncertainty for water vapor is 20 percent absolute averaged over 2 km layers. Cryogenic frostpoint hygrometers (CFH) are balloon-borne water vapor sensors responsive from the surface into the lower stratosphere. Several dozen coincident, collocated CFH profiles have been obtained for AlRS validation. The combination of CFH sensitivity and sample size offers a statistically compelling picture of AIRS UTWV measurement capability. We present a comparison between CFH observations and AlRS retrievals. We focus on the altitude range from the middle troposphere up to heights at the limits of AlRS sensitivity to water vapor, believed to be around 100-1 50 hPa.

validation↗

NASA NTRS1981

Airborne differential absorption lidar system for water vapor investigations

Range-resolved water vapor measurements using the differential-absorption lidar (DIAL) technique is described in detail. The system uses two independently tunable optically pumped lasers operating in the near infrared with laser pulses of less than 100 microseconds separation, to minimize concentration errors caused by atmospheric scattering. Water vapor concentration profiles are calculated for each measurement by a minicomputer, in real time. The work is needed in the study of atmospheric motion and thermodynamics as well as in forestry and agriculture problems.

Browell, E. V.↗

NASA NTRS1998

A Satellite-Derived Upper-Tropospheric Water Vapor Transport Index for Climate Studies

A new approach is presented to quantify upper-level moisture transport from geostationary satellite data. Daily time sequences of GOES-7 water vapor imagery were used to produce estimates of winds and water vapor mixing ratio in the upper-troposphere sensed by the 6.7-microns water vapor channel. The winds and mixing ratio values were gridded and then combined to produce a parameter called the Water Vapor Transport Index (WVTI) which represents the magnitude of the two dimensional transport of water vapor in the upper troposphere. Daily grids of WVTI, meridional moisture transport, mixing ratio, pressure and other associated parameters were averaged to produce monthly fields for June, July and August of 1987 and 1988 over the Americas and surrounding oceanic regions. The WVTI was used to compare upper-tropospheric moisture transport between the summers of 1987 and 1988, contrasting the latter part of the 1986/87 El Nino event and the La Nina period of 1988. A similar product derived from the NCEP reanalysis was used to help validate the index and understand interannual variability of moisture transport from the modeling perspective. Both datasets showed large upper-level water vapor transport associated with synoptic features over the Americas and with outflow from tropical convective systems. Minimal transport occurred over tropical and subtropical high pressure regions where winds were light. Index values from NCEP were 2-3 times larger than that determined from the GOES satellite This difference resulted from an over estimate of the zonal winds and upper-tropospheric moisture in the reanalysis model. A comparison of the satellite-derived monthly values between the summers of 1987 and 1988 provided some insight into the impact of the ENSO event on upper-level moisture and its transport during the period. During July 1987, a large portion of the tropics in the eastern Pacific Ocean and Caribbean Sea was dominated by strong vapor transport in excess of 5 g/kg/ms with relatively small amounts in the other months. In contrast, JJA 1988 showed an opposite trend with July 1988 being less dominated by tropical water vapor transport. The meridional transport of upper-level water vapor indicated significant poleward transport from the tropics to the higher latitudes. This transport favored the Southern Hemisphere with large transport occurring south of the ITCZ which extended across the eastern Pacific and northern South America. Zonally-averaged monthly transport values were shown to provide a simple way to quantify the monthly and interannual changes in water vapor transport. Zonally-averaged WVTI values peaked in the Southern Hemisphere subtropics during both Austral winters. In the tropics a single more pronounced peak located over the equator and south latitudes occurred in 1988 as opposed to a dual peak in 1987. The second peak around 20 deg.N latitude is consistent with findings of others where upper-tropospheric winds were noted to be stronger in this region during warm ENSO events. Zonally-averaged meridional transport was southward for all summer months and stronger in 1988. The asymmetric nature of the zonally-averaged meridional transport (more southerly water vapor transport) was enhanced during JJA 1998 thus indicating a stronger upper-level branch of the Hadley circulation during this notable strong La Nina period.

Jedlovec, Gary J.↗

NASA NTRS1981

Fatigue crack growth in 7475-T651 aluminum alloy plate in hard vacuum and water vapor

Compact specimens of 25 mm thick aluminum alloy plate were subjected to constant amplitude fatigue testing at a load ratio of 0.2. Crack growth rates were determined at frequencies of 1 Hz and 10 Hz in hard vacuum and laboratory air, and in mixtures of water vapor and nitrogen at water vapor partial pressures ranging from 94 Pa to 3.8 kPa. A significant effect of water vapor on fatigue crack growth rates was observed at the lowest water vapor pressure tested. Crack rates changed little for pressures up to 1.03 kPa, but abruptly accelerated at higher pressures. At low stress intensity factor ranges, cracking rates at the lowest and highest water vapor pressure tested were, respectively, two and five times higher than rates in vacuum. Although a frequency was observed in laboratory air, cracking rates in water vapor and vacuum are insensitive to a ten-fold change in frequency. Surfaces of specimens tested in water vapor and vacuum exhibited different amounts of residual deformation. Reduced deformation on the fracture surfaces of the specimens tested in water vapor suggests embrittlement of the plastic zone ahead of the crack tip as a result of environmental interaction.

Dicus, D. L.↗

NASA NTRS1993

Tracking motions from satellite water vapor imagery: Quantitative applications to hurricane track forecasting

Water vapor imagery from GOES satellites has been available for over a decade. These data are used extensively, mainly in a qualitative mode, by forecasters in the United States (Weldon and Holmes, 1991). Some attempts have been made at quantifying the data by tracking features in time sequences of the imagery (Stewart et al., 1985; Hayden and Stewart, 1987). For a variety of reasons, applications of this approach have produced marginal results (Velden, 1990). Recently, METEOSAT-3 (M-3) was repositioned at 50W by the European Space Agency, in order to provide complete coverage of the Atlantic Ocean. Data from this satellite are being transmitted to the U.S. for operational use. Compared with the GOES satellite, the M-3 has a superior resolution and signal-to-noise ratio in its water vapor channel, which translates into improved automated tracking capabilities. During a period in 1992 which included the Atlantic hurricane season, water vapor tracking algorithms were applied to the M-3 data in order to evaluate the coverage, accuracy and model impact of the derived vectors. Data sets were produced during several tropical cyclone cases, including Hurricane Andrew. In this paper, the M-3 water vapor wind sets are assessed, and their impact on a hurricane track forecast model is examined.

Velden, Christopher↗

NASA NTRS2010

Observed Seasonal to Decadal-Scale Responses in Mesospheric Water Vapor

The 14-yr (1991-2005) time series of mesospheric water vapor from the Halogen Occultation Experiment (HALOE) are analyzed using multiple linear regression (MLR) techniques for their6 seasonal and longer-period terms from 45S to 45N. The distribution of annual average water vapor shows a decrease from a maximum of 6.5 ppmv at 0.2 hPa to about 3.2 ppmv at 0.01 hPa, in accord with the effects of the photolysis of water vapor due to the Lyman-flux. The distribution of the semi-annual cycle amplitudes is nearly hemispherically symmetric at the low latitudes, while that of the annual cycles show larger amplitudes in the northern hemisphere. The diagnosed 11-yr, or solar cycle, max minus min, water vapor values are of the order of several percent at 0.2 hPa to about 23% at 0.01 hPa. The solar cycle terms have larger values in the northern than in the southern hemisphere, particularly in the middle mesosphere, and the associated linear trend terms are anomalously large in the same region. Those anomalies are due, at least in part, to the fact that the amplitudes of the seasonal cycles were varying at northern mid latitudes during 1991-2005, while the corresponding seasonal terms of the MLR model do not allow for that possibility. Although the 11-yr variation in water vapor is essentially hemispherically-symmetric and anti-phased with the solar cycle flux near 0.01 hPa, the concurrent temperature variations produce slightly colder conditions at the northern high latitudes at solar minimum. It is concluded that this temperature difference is most likely the reason for the greater occurrence of polar mesospheric clouds at the northern versus the southern high latitudes at solar minimum during the HALOE time period.

Remsberg, Ellis↗