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At least 109 records · Page 6

Influence of Solutocapillary Convection on Macrovoid Defect Formation in Polymeric Membranes

Macrovoids (MVs) are large (10-50 micrometers) pores often found in polymeric membranes prepared via phase-inversion techniques. They are generally considered undesirable, as they adversely affect the permeability properties and performance of polymeric membranes for microfiltration, ultrafiltration, and reverse osmosis. However, MVs can be useful in certain thin-film applications in which vapor transmission is necessary, or for use as reservoirs for enzymes or liquid membrane material. If more could be learned about the nature and causes of MV formation, it might be possible to devise techniques to control and/or prevent MV formation that are more effective than those currently employed. Two hypotheses for the MV growth mechanism have been advanced. Reuvers proposed that once initiated, MV growth can be attributed to diffusion of (primarily) solvent to the MV nuclei. Because this mechanism does not involve gross movement of the MV, the presence or absence of body forces such as buoyancy should not significantly affect MV growth. On the other hand, Shojaie et al. proposed that solutocapillary convection induced by a steep surface-tension gradient along the MV/bulk solution interface enhances mass transfer to the growing MV. This interfacial convection exerts a force that pulls the growing MV downward into the casting solution. Both buoyancy and viscous drag hinder MV growth by inhibiting this motion. Thus, removing the buoyancy force by casting in microgravity should augment MV growth according to this hypothesis. Whereas neither surface tension nor gravity has a significant effect on MV growth according to the first hypothesis, buoyancy forces should be important if the second hypothesis is correct. The overall goal of this research is to test these two hypotheses in order to improve our understanding of the MV growth processing solvent-cast polymeric membranes. Studying MV growth in low-gravity conditions is pivotal to our ability to discriminate between these two hypotheses.

Pekny, M. R.↗

Development of a New Membrane Casting Apparatus for Studying Macrovoid Defects in Low-G

A new membrane-casting apparatus is developed for studying macrovoid defects in polymeric membranes made by the wet- and dry-casting process in low-gravity. Macrovoids are large (10-50 micron), open cavities interspersed among the smaller pores in the substructure under the gelled skin surface layer of the cast membrane. Although their occurrence is considered endemic to the wet- and dry-casting process since they can lead to compaction or skin rupture in the membrane process, recent studies suggest several useful applications such as transdermal and osmotic drug delivery systems, miniature bioreactors, etc. However, lack of knowledge about the macrovoid formation mechanism is an obstacle to further development of applications using them. An on-going debate is the role of the surface-tension-driven solutocapillary convection during macrovoid formation. The rapid growth of macrovoids within 1-5 seconds and the high polymer concentration in and near macrovoids make it difficult to explain the mechanism of macrovoid growth by diffusion alone, which is the widely accepted hypothesis proposed by Reuvers et al. The hypothesis advanced by our research group can explain this rapid growth via a mechanism that involves diffusion from the casting solution in the meta-stable region to the macrovoid enhanced by solutocapillary convection induced by the steep nonsolvent concentration gradient in the vicinity of the macrovoid. Since macrovoid growth is hypothesized to be the interplay of a solutocapillary-induced driving force counteracted by viscous drag and buoyancy, eliminate the latter provides a means for testing this hypothesis. Moreover, free convection mass transfer in the nonsolvent immersion bath used to cause phase-separation in membrane casting complicates developing a model for both the wet-casting process and macrovoid growth. The low-g environment minimizes gravitationally induced free convection thereby permitting a tractable solution to the ternary diffusion equations that characterize membrane formation. NASA's Parabolic Flight Research Aircraft provides a small window of low-g (approximately 25 s) that can be used to study macrovoid development in both wet- and dry-cast membranes if an appropriate casting apparatus is used. This casting apparatus should be able to cast the membrane in both low- and high-g in a manner so that essential one-dimensional mass transfer conditions are achieved to insure lateral uniformity in the membrane. The apparatus used in previous research on membrane casting in low-gravity was operated with the plunger driven mechanism. The spring-loaded plunger pushes the bottom block containing the polymer casting solution well directly under the absorbent chamber located in the upper stationary block. However, membranes made via this casting apparatus often displayed lateral nonuniformities that precluded obtaining quantitative information on the macrovoid growth process. Thus, it was necessary to determine the reason for these structural irregularities observed in the low-g casting apparatus. Both experimental as well as computer simulation studies of the low-g casting apparatus established that the impulsive action of the plunger caused the undesired structural nonuniformities. The simulation results showed that the width-to-depth aspect ratio of the shallow well that contains the casting solution in this apparatus was not an important factor in minimizing this problem. Even for a 40:1 (width : depth) aspect ratio, any convection induced by the horizontal motion of the interface of the casting solution will be damped out within 6.25x10(exp 4) seconds. However, the experimental studies revealed that the impulsive motion of the plunger caused a 'sloshing' of the casting solution that had to be eliminated. Therefore, the plungerdriven mechanism was changed to a cam-driven mechanism that did not cause any impulsive motion of the casting solution. Other refinements to this new membrane-casting apparatus include provision for removing the membranes from the casting wells in a less destructive manner. This was accomplished by using a slit geometry for the casting well that permitted disassembly for removal of the cast membrane. The materials used in the construction of this casting apparatus were chosen to insure wetting at the side walls and to maintain precise control of the thickness of the polymer solution in the casting well. An additional provision in this new casting apparatus is the ability to carry out both wet- as well as dry-casting. As such, this apparatus permitted the first studies of the wet-casting of polymeric membranes in low-g. Both wet- and dry-casting experiments on NASA's KC-135 research aircraft employing this new membrane-casting apparatus are scheduled in July 2002. The morphology of the resulting membranes will be characterized using an environmental scanning electron microscope (ESEM). The results of these low-g studies will be reported later.

Lee, Hanyong↗

Macrovoid Defect Growth during Evaporative Casting of Polymeric Membranes

Macrovoid (MV) formation is a significant problem in evaporatively cast polymeric membranes. MVs are large, elongated or teardrop-shaped pores (~10-50 micron) that can impair membrane structural integrity. Although MVs have been extensively studied, there is no general agreement on the mechanisms governing MV growth. Recently, our research group has formulated the solutocapillary convection (SC) hypothesis, which contends that MV growth involves three principal forces: a Marangoni force generated by surface tension gradients within the MV interface, a viscous drag force, and a gravitationally induced body force. Two sets of complementary experiments were conducted to test the SC hypothesis. Ground-based videomicroscopy flow-visualization (VMFV) was utilized to measure the flow velocities at the MV-casting solution interface and deep within the casting solution. The measurements were performed with casting solutions containing 10 wt% cellulose acetate (CA), 30 wt% H2O, 60 wt% acetone, and 200- ppm TiO2 particles for flow visualization, and the surface tension was controlled by surfactant addition. Qualitatively, the experiments indicated that MV growth occurs in three distinct phases: (1) a very rapid initial growth period, (2) a much slower growth phase, and (3) absorption of selected MVs into the expanding demixed region. The presence of tracer particles inside the MVs suggests the presence of a convective flow, which transfers the particles from the bulk solution to the MV interior. Although the VMFV experiments did not establish any surfactant effect on the interfacial velocities, a statistically significant effect on the MV number density was observed. In the second set of experiments, membranes were cast aboard a KC-135 aircraft under 0-g and 2-g conditions. Despite careful attention to the design and fabrication of the membrane casting apparatus (MCA), several problems were encountered, the most significant of which was the contamination of the casting solution by the activated carbon particles used for solvent absorption.

Greenberg, A. R.↗

Design and Preparation of a Particle Dynamics Space Flight Experiment, SHIVA

ABSTRACT This paper describes the flight experiment, supporting ground science, and the design rationale for project SHIVA (Spaceflight Holography Investigation in a Virtual Apparatus). SHIVA is a fundamental study of particle dynamics in fluids in microgravity. Gravity often dominates the equations of motion of a particle in a fluid, so microgravity provides an ideal environment to study the other forces, such as the pressure and viscous drag and especially the Basset history force. We have developed diagnostic recording methods using holography to save all of the particle field optical characteristics, essentially allowing the experiment to be transferred from space back to earth in what we call the "virtual apparatus" for on-earth microgravity experimentation. We can quantify precisely the three-dimensional motion of sets of particles, allowing us to test and apply new analytical solutions developed by members of the team as reported in the 2001 Conference (Banff, Canada). In addition to employing microgravity to augment the fundamental study of these forces, the resulting data will allow us to quantify and understand the ISS environment with great accuracy. This paper shows how we used both experiment and theory to identify and resolve critical issues and produce an optimal the study. We examined the response of particles of specific gravity from 0.1 to 20, with radii from 0.2 to 2mm. to fluid oscillation at frequencies up to 80 Hz with amplitudes up to 200 microns. To observe some of the interesting effects predicted by the new solutions requires the precise location of the position of a particle in three dimensions. To this end we have developed digital holography algorithms that enable particle position location to a small fraction of a pixel in a CCD array. The spaceflight system will record holograms both on film and electronically. The electronic holograms can be downlinked providing real time data, essentially acting like a remote window into the ISS experimental chamber. Ground experiments have provided input to a flight system design that can meet the requirements for a successful experiment on ISS. Moreover the ground experiments have provided a definitive, quantitative observation of the Basset History force over a wide range of conditions. Results of the ground experiments, the flight experiment design, preliminary flight hardware design, and data analysis procedures are reported.

Trolinger, James↗

Limits to Open Class Performance?

This presentation discusses open or unlimited class aircraft performance limitations and design solutions. Limitations in this class of aircraft include slow climbing flight which requires low wing loading, high cruise speed which requires high wing loading, gains in induced or viscous drag alone which result in only half the gain overall and other structural problems (yaw inertia and spins, flutter and static loads integrity). Design solutions include introducing minimum induced drag for a given span (elliptical span load or winglets) and introducing minimum induced drag for a bell shaped span load. It is concluded that open class performance limits (under current rules and technologies) is very close to absolute limits, though some gains remain to be made from unexplored areas and new technologies.

Bowers, Albion H.↗

Turbulence Model Implementation and Verification in the SENSEI CFD Code

This paper outlines the implementation and verification of the negative Spalart-Allmaras turbulence model into the SENSEI CFD code. The SA-neg turbulence model is implemented in a flexible, object-oriented framework where additional turbulence models can be easily added. In addition to outlining the new turbulence modeling framework in SENSEI, an overview of the other general improvements to SENSEI is provided. The results for four 2D test cases are compared to results from CFL3D and FUN3D to verify that the turbulence models are implemented properly. Several differences in the results from SENSEI, CFL3D, and FUN3D are identified and are attributed to differences in the implementation and discretization order of the boundary conditions as well as the order of discretization of the turbulence model. When a solid surface is located near or intersects an inflow or outflow boundary, higher order boundary conditions should be used to limit their effect on the forces on the surface. When the turbulence equations are discretized using second order spatial accuracy, the edge of the eddy viscosity profile seems to be sharper than when a first order discretization is used. However, the discretization order of the turbulence equation does not have a significant impact on output quantities of interest, such as pressure and viscous drag, for the cases studied.

Jackson, Charles W.↗

Reduction of Base Drag on Launch Vehicles

Current reentry vehicle designs exhibit large amounts of base drag due to large base areas. These large base areas can arise from the integration of the propulsion system (X-33) or control surface placement (X-38). Large base drag limits the vehicle's cross-range capability and causes a large glide-slope angle. Fortunately, there appears to be a possible means of lowering the base drag on these vehicles. Based on early work on the subsonic aerodynamics of lifting bodies, it appears that the addition of small amounts of viscous fore-body drag can produce a significant reduction in base drag. Recent work suggests that this phenomenon also occurs in the transonic and supersonic flight regimes. This report summarizes a study designed to demonstrate the reduction of base drag through the addition of fore-body viscous drag. The present study has focused on the measurement of viscous fore-body drag and the demonstration of the relationship between fore-body viscous drag and base drag at Reynolds Numbers up to 2.5 x 10(exp 6). The results of the present work do not conclusively demonstrate that viscous fore-body drag reduces base drag. The apparent contradictory results of the present study are attributed to the different geometry used in the present study. However, the results suggest that the increased boundary layer thickness at separation caused by larger fore-body viscous drag somehow affects the vortex structure in the wake thereby reducing the base drag. More research is required to confirm this postulated mechanism.

Naughton, Jonathan W.↗

A unified viscous theory of lift and drag of 2-D thin airfoils and 3-D thin wings

A unified viscous theory of 2-D thin airfoils and 3-D thin wings is developed with numerical examples. The viscous theory of the load distribution is unique and tends to the classical inviscid result with Kutta condition in the high Reynolds number limit. A new theory of 2-D section induced drag is introduced with specific applications to three cases of interest: (1) constant angle of attack; (2) parabolic camber; and (3) a flapped airfoil. The first case is also extended to a profiled leading edge foil. The well-known drag due to absence of leading edge suction is derived from the viscous theory. It is independent of Reynolds number for zero thickness and varies inversely with the square root of the Reynolds number based on the leading edge radius for profiled sections. The role of turbulence in the section induced drag problem is discussed. A theory of minimum section induced drag is derived and applied. For low Reynolds number the minimum drag load tends to the constant angle of attack solution and for high Reynolds number to an approximation of the parabolic camber solution. The parabolic camber section induced drag is about 4 percent greater than the ideal minimum at high Reynolds number. Two new concepts, the viscous induced drag angle and the viscous induced separation potential are introduced. The separation potential is calculated for three 2-D cases and for a 3-D rectangular wing. The potential is calculated with input from a standard doublet lattice wing code without recourse to any boundary layer calculations. Separation is indicated in regions where it is observed experimentally. The classical induced drag is recovered in the 3-D high Reynolds number limit with an additional contribution that is Reynold number dependent. The 3-D viscous theory of minimum induced drag yields an equation for the optimal spanwise and chordwise load distribution. The design of optimal wing tip planforms and camber distributions is possible with the viscous 3-D wing theory.

Yates, John E.↗

An improved analytical model of the separation region on boattail nozzles at subsonic speeds

A practical engineering calculation was developed to model the viscous effects of a separated, reverse flow region on afterbody pressures and drag. This viscous calculation was iteratively coupled with an inviscid flow calculation by means of an aerodynamic interface. A standard boundary layer displacement thickness was used to modify the afterbody shape where the flow was attached. A discriminating streamline calculation was developed to account for displacement effects of the reverse flow in separated regions with and without a flowing jet. The viscous flow calculation was coupled with a potential flow calculation. The analysis accurately predicted afterbody pressures and drag with variations in Reynolds number, Mach number, and afterbody shape.

Presz, W. M., Jr.↗

Aircraft drag prediction and reduction. Addendum 1: Computational drag analyses and minimization; mission impossible?

The Special Course on Aircraft Drag Prediction was sponsored by the AGARD Fluid Dynamics Panel and the von Karman Institute and presented at the von Karman Institute, Rhode-Saint-Genese, Belgium, on 20 to 23 May 1985 and at the NASA Langley Research Center, Hampton, Virginia, USA, 5 to 6 August 1985. The course began with a general review of drag reduction technology. Then the possibility of reduction of skin friction through control of laminar flow and through modification of the structure of the turbulence in the boundary layer were discussed. Methods for predicting and reducing the drag of external stores, of nacelles, of fuselage protuberances, and of fuselage afterbodies were then presented followed by discussion of transonic drag rise. The prediction of viscous and wave drag by a method matching inviscid flow calculations and boundary layer integral calculations, and the reduction of transonic drag through boundary layer control are also discussed. This volume comprises Paper No. 9 Computational Drag Analyses and Minimization: Mission Impossible, which was not included in AGARD Report 723 (main volume).

Slooff, J. W.↗

The Effectiveness of Shrouding on Reducing Meshed Spur Gear Power Loss - Test Results

Gearbox efficiency is reduced at high rotational speeds due to windage drag and viscous effects on rotating, meshed gear components. A goal of NASA aeronautics rotorcraft research is aimed at propulsion technologies that improve efficiency while minimizing vehicle weight. Specifically, reducing power losses to rotorcraft gearboxes would allow gains in areas such as vehicle payload, range, mission type, and fuel consumption. To that end, a gear windage rig has been commissioned at NASA Glenn Research Center to measure windage drag on gears and to test methodologies to mitigate windage power losses. One method used in rotorcraft gearbox design attempts to reduce gear windage power loss by utilizing close clearance walls to enclose the gears in both the axial and radial directions. The close clearance shrouds result in reduced drag on the gear teeth, and reduced power loss. For meshed spur gears, the shrouding takes the form of metal side plates and circumferential metal sectors. Variably positioned axial and radial shrouds are incorporated in the NASA rig to study the effect of shroud clearance on gearbox power loss. A number of researchers have given experimental and analytical results for single spur gears, with and without shrouding. Shrouded meshed spur gear test results are sparse in the literature. Windage tests were run at NASA Glenn using meshed spur gears at four shroud configurations: unshrouded, shrouded (max. axial, max radial), and two intermediate shrouding conditions. Results are compared to available meshed spur gear power loss data analyses as well as single spur gear data/analyses. Recommendations are made for future work.

power loss↗

The Effectiveness of Shrouding on Reducing Meshed Spur Gear Power Loss Test Results

Gearbox efficiency is reduced at high rotational speeds due to windage drag and viscous effects on rotating, meshed gear components. A goal of NASA aeronautics rotorcraft research is aimed at propulsion technologies that improve efficiency while minimizing vehicle weight. Specifically, reducing power losses to rotorcraft gearboxes would allow gains in areas such as vehicle payload, range, mission type, and fuel consumption. To that end, a gear windage rig has been commissioned at NASA Glenn Research Center to measure windage drag on gears and to test methodologies to mitigate windage power losses. One method used in rotorcraft gearbox design attempts to reduce gear windage power loss by utilizing close clearance walls to enclose the gears in both the axial and radial directions. The close clearance shrouds result in reduced drag on the gear teeth and reduced power loss. For meshed spur gears, the shrouding takes the form of metal side plates and circumferential metal sectors. Variably positioned axial and radial shrouds are incorporated in the NASA rig to study the effect of shroud clearance on gearbox power loss. A number of researchers have given experimental and analytical results for single spur gears, with and without shrouding. Shrouded meshed spur gear test results are sparse in the literature. Windage tests were run at NASA Glenn using meshed spur gears at four shroud configurations: unshrouded, shrouded (max. axial, max. radial), and two intermediate shrouding conditions. Results are compared to available meshed spur gear power loss data analyses as well as single spur gear data analyses.

windage↗

DONBOL: A computer program for predicting axisymmetric nozzle afterbody pressure distributions and drag at subsonic speeds

A Neumann solution for inviscid external flow was coupled to a modified Reshotko-Tucker integral boundary-layer technique, the control volume method of Presz for calculating flow in the separated region, and an inviscid one-dimensional solution for the jet exhaust flow in order to predict axisymmetric nozzle afterbody pressure distributions and drag. The viscous and inviscid flows are solved iteratively until convergence is obtained. A computer algorithm of this procedure was written and is called DONBOL. A description of the computer program and a guide to its use is given. Comparisons of the predictions of this method with experiments show that the method accurately predicts the pressure distributions of boattail afterbodies which have the jet exhaust flow simulated by solid bodies. For nozzle configurations which have the jet exhaust simulated by high-pressure air, the present method significantly underpredicts the magnitude of nozzle pressure drag. This deficiency results because the method neglects the effects of jet plume entrainment. This method is limited to subsonic free-stream Mach numbers below that for which the flow over the body of revolution becomes sonic.

Putnam, L. E.↗