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At least 109 records · Page 6

Vibrational Spectroscopic Monitoring of the Gelation Transition in Nafion Ionomer Dispersions

Infrared and Raman spectroscopy techniques were applied to investigate the drying and aggregation behavior of Nafion ionomer particles dispersed in aqueous solution. Gravimetric measurements aided the identification of gel-phase development within a series of time-resolved spectra that tracked transformations of a dispersion sample during solvent evaporation. A spectral band characteristic of ionomer sidechain end group vibration provided a quantitative probe of the dispersion-to-gel change. For sets of attenuated total reflection Fourier transform infrared (ATR FT-IR) spectra, adherence to Beer's law was attributed to the relatively constant refractive index in the frequency region of hydrated –SO$^{–}_{3}$ group vibrations as fluorocarbon-rich ionomer regions aggregate in forming the structural framework of membranes and thin films. Although vibrational bands associated with ionomer backbone CF 2 stretching vibrations were affected by distortion characteristic of wavelength-dependent refractive index change within a sample, the onset of band distortion signaled gel formation and coincided with ionomer mass % values just below the critical gelation point for Nafion aqueous dispersions. Similar temporal behavior was observed in confocal Raman microscopy experiments that monitored the formation of a thin ionomer film from an individual dispersion droplet. For the ATR FT-IR spectroscopy and confocal Raman microscopy techniques, intensity in the water H–O–H bending vibrational band dropped sharply at the ionomer critical gelation point and displayed a time dependence consistent with changes in water content derived from gravimetric measurements. The reported studies lay groundwork for examining the impact of dispersing solvents and above-ambient temperatures on fluorinated ionomer transformations that influence structural properties of dispersion-cast membranes and thin films.

36 MATERIALS SCIENCE↗

Study on Intelligent Compaction-Equipment Logistics Scheduling and Propagation Characteristics of Vibration Wave in Nonlinear Systems with Multistability Based on Field Test

The equipment scheduling and propagation characteristics of vibration wave from vibratory roller ⟶ filling material nonlinear systems with multistability are the core problems of subgrade intelligent construction technology, and the logistics scheduling of the equipment is directly related to the construction efficiency. Aiming at the shortages, one typical subgrade located at the Gu’an station of Beijing-Xiong’an city railway is selected to research and finish the field tests; some findings are shown as follows: first, some valuable suggestions about the logistics scheduling of intelligent equipment are proposed, which can break the barriers between the organizations and improve construction efficiency; second, when the vibration wave propagates from the vibratory roller ⟶ surface of filling material ⟶ different buried depths of filling material, the peak acceleration of vibration wave gradually decreases and is hyperbolic distribution approximately. At the same time, the sensitive of attenuation is shown as follows: Z R 2 >0.9), and the concrete functional relationship among different amplitudes of harmonics can be summarized as y = Ae −BX ; fourth, the vibration energy is mainly concentrated near 10–30 Hz in the vibratory roller, but when the vibration wave propagates from vibratory roller⟶filling material, the vibration energy gradually decreases with the increase in depth, and the marginal spectrum gradually changes from one peak to two peaks, that is, 30–50 Hz and 50–100 Hz; fifth, the vibration energy in the vibrational wheel is distributed averagely in the compaction process, and the effective compaction time is two seconds, which will be helpful for revealing the propagation characteristics of vibration wave, optimizing the compaction quality control models and providing some support for the development of intelligent compaction theory of railway subgrade.

Han, Yixuan↗

Optical vibrational spectra of β -U 3 O 8

Technogenic uranium oxides are ubiquitous in the nuclear fuel cycle. Identifying the chemical composition of these oxides is frequently done with optical vibrational spectroscopy (infrared and Raman spectroscopy). The α phase of U 3 O 8 is the most stable and common uranium oxide, but a β phase of U 3 O 8 can be produced via very slow cooling of the α phase from elevated temperatures or the application of small shear forces. However, optical spectra of this compound have not been reported. In this work, we use high-resolution attenuated total reflection infrared spectroscopy and Raman spectroscopy to collect the optical vibrational spectra. Despite similarities in the crystal structure of α and β – U 3 O 8 , the optical spectra of these compounds differ substantially, with additional Raman active modes in β – U 3 O 8 that are likely originating from differences in the U–O coordination units. Measurements presented here provide spectral characterization that can be used for chemical identification in future studies of uranium oxides.

36 MATERIALS SCIENCE↗

Vibration damping of elastic waves in electrically conducting media subjected to high magnetic fields

The propagation of vibrational energy in bulk, torsional, and flexural modes, in electrically conducting media can undergo strong attenuation if subjected to high magnetic fields in certain spatial arrangements. The reasons for this are induced Eddy currents which are generated by the volume elements in the media moving transversally to the magnetic field at acoustic velocities. In magnetic fields achievable with superconductors, the non-conservative (dissipative) forces are compared to the elastic and inertial forces for most metals. Strong dissipation of vibrational energy in the form of heat takes place as a result. A simplified theory is presented based on engineering representations of electrodynamics, attenuation values for representative metals are calculated, and problems encountered in formulating a generalized theory based on electrodynamics of moving media are discussed. General applications as well as applications specific to maglev are discussed.

Horwath, T. G.↗

Magnetoelastic effects in the hyperhoneycomb Kitaev spin liquid

In recent years, several magnetic Mott insulators with strong spin-orbit coupling were suggested to be proximate to the Kitaev quantum spin liquid, whose one of the most exciting features is the fractionalization of spin excitations into itinerant Majorana fermions and static Z 2 fluxes. Unfortunately, the ground states of these systems cannot be easily captured by experiment, remaining featureless to conventional local probes. Here, we propose to study the signatures of fractionalized excitations by exploiting their coupling to the lattice vibrations, dubbed magnetoelastic coupling, which arises from the fact that the interaction between spins depends on the relative distance between them. We argue that the magnetoelastic coupling can lead to the distinct modification of the phonon dynamics, which can be observed by measuring renormalized phonon spectrum, the sound attenuation, and the phonon Hall viscosity. This makes the phonon dynamics a promising tool for the characterization and identification of quantum spin liquid phases. In this work, we focus on the magnetoelastic effects in the three-dimensional Kitaev model realized on the hyperhoneycomb lattice. Here, the hyperhoneycomb Kitaev spin liquid is particularly interesting since the strong Kitaev interaction was observed in the Kitaev magnet β-Li 2 IrO 3 , for which the spin-orbit entangled J eff = 1/2 moments of iridium ions form precisely the hyperhoneycomb lattice.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Improved active vibration isolator

Active vibration isolator simultaneously isolates a flexible structure or payload from disturbances, attenuates the response of a flexible structure to transient disturbances, and maintains the equilibrium position of the payload within predetermined limits over a wide range of steady loads and accelerators.

Dixon, G. V.↗

Survey of Active Vibration Isolation Systems for Microgravity Applications

In view of the utility of space vehicles as orbiting science laboratories, the need for vibration isolation systems for acceleration-sensitive experiments has gained increasing visibility. To date, three active microgravity vibration isolation systems have successfully been demonstrated in flight. A tutorial discussion of the microgravity vibration isolation problem, including a description of the acceleration environment of the International Space Station and attenuation requirements, as well as a comparison or the dynamics of passive isolation, active rack-level isolation, and active payload-level isolation is provided. The flight test results of the three demonstrated systems: suppression of transient accelerations by levitation, the microgravity vibration isolation mount, and the active rack isolation system are surveyed.

Grodsinsky, Carlos M.↗

National Transonic Facility model and model support vibration problems

Vibrations of models and model support system were encountered during testing in the National Transonic Facility. Model support system yaw plane vibrations have resulted in model strain gage balance design load limits being reached. These high levels of vibrations resulted in limited aerodynamic testing for several wind tunnel models. The yaw vibration problem was the subject of an intensive experimental and analytical investigation which identified the primary source of the yaw excitation and resulted in attenuation of the yaw oscillations to acceptable levels. This paper presents the principal results of analyses and experimental investigation of the yaw plane vibration problems. Also, an overview of plans for development and installation of a permanent model system dynamic and aeroelastic response measurement and monitoring system for the National Transonic Facility is presented.

Young, Clarence P., Jr.↗

A Survey of Active Vibration Isolation Systems for Microgravity Applications

In view of the utility of space vehicles as orbiting science laboratories, the need for vibration isolation systems for acceleration sensitive experiments has gained increasing visibility. To date, three active microgravity vibration isolation systems have successfully been demonstrated in flight. This paper provides a tutorial discussion of the microgravity vibration isolation problem including a description of the acceleration environment of the International Space Station and attenuation requirements as well as a comparison of the dynamics of passive isolation, active rack-level isolation, and active payload-level isolation. This paper also surveys the flight test results of the three demonstrated systems: Suppression of Transient Accelerations By Levitation (STABLE); the Microgravity Vibration Isolation Mount (MIM); and the Active Rack Isolation System (ARIS).

Grodsinsky, Carlos M.↗

The Microgravity Vibration Isolation Mount: A Dynamic Model for Optimal Controller Design

Vibration acceleration levels on large space platforms exceed the requirements of many space experiments. The Microgravity Vibration Isolation Mount (MIM) was built by the Canadian Space Agency to attenuate these disturbances to acceptable levels, and has been operational on the Russian Space Station Mir since May 1996. It has demonstrated good isolation performance and has supported several materials science experiments. The MIM uses Lorentz (voice-coil) magnetic actuators to levitate and isolate payloads at the individual experiment/sub-experiment (versus rack) level. Payload acceleration, relative position, and relative orientation (Euler-parameter) measurements are fed to a state-space controller. The controller, in turn, determines the actuator currents needed for effective experiment isolation. This paper presents the development of an algebraic, state-space model of the MIM, in a form suitable for optimal controller design.

Hampton, R. David↗

The Microgravity Isolation Mount: A Linearized State-Space Model a la Newton and Kane

Vibration acceleration levels on large space platforms exceed the requirements of many space experiments. The Microgravity Vibration Isolation Mount (MIM) was built by the Canadian Space Agency to attenuate these disturbances to acceptable levels, and has been operational on the Russian Space Station Mir since May 1996. It has demonstrated good isolation performance and has supported several materials science experiments. The MIM uses Lorentz (voice-coil) magnetic actuators to levitate and isolate payloads at the individual experiment/sub-experiment (versus rack) level. Payload acceleration, relative position, and relative orientation (Euler-parameter) measurements are fed to a state-space controller. The controller, in turn, determines the actuator currents needed for effective experiment isolation. This paper presents the development of an algebraic, state-space model of the MIM, in a form suitable for optimal controller design. The equations are first derived using Newton's Second Law directly; then a second derivation (i.e., validation) of the same equations is provided, using Kane's approach.

Hampton, R. David↗

Design and evaluation of a state-feedback vibration controller

The effectiveness and practicality of the state-feedback vibration controller is demonstrated by computer simulations. It is shown that: (1) the required measurements can be reduced to fuselage accelerations; (2) the system is stable over a wide range of flight conditions; (3) a discrete design for the controller provides effective digital implementation at 80-Hz sampling; (4) attenuation produced by the actuators does not create a problem, and a simple lead compensator provides vibration reduction; and (5) a design based on a hover model worked well at five knots. At 40 and 120 knots, vibrations in all but the vertical acceleration were effectively suppressed. The state-feedback vibration controller has a rapid convergence time and implementation is easier than with multicyclic control since no on-line harmonic analysis or identification algorithms are required.

Du Val, R. W.↗

Active Suppression Of Vibrations On Elastic Beams

Pairs of colocated piezoelectric transducers, independently controlled by multichannel adaptive controller, employed as actuators and sensors to achieve simultaneous attenuation of both extensional and flexural motion. Single pair used to provide simultaneous control of flexural and extensional waves, or two pairs used to control torsional motion also. Capability due to nature of piezoelectric transducers, when bonded to surfaces of structures and activated by oscillating voltages, generate corresponding oscillating distributions of stresses in structures. Phases and amplitudes of actuator voltages adjusted by controller to impede flow of vibrational energy simultaneously, in waves of various forms, beyond locations of actuators. Concept applies equally to harmonic or random response of structure and to multiple responses of structure to transverse bending, torsion, and compression within structural element. System has potential for many situations in which predominant vibration transmission path through framelike structure.

Silcox, Richard J.↗

A Vibrational Probe of Electrical Doping in N2200 and Fermi-Level Alignment at Polymer Cathode/Metal Cocatalyst/Electrolyte Junctions

Hybrid (photo)­cathodes consisting of conjugated polymer and hydrogen evolution reaction (HER) cocatalysts are an emerging platform for low-cost solar fuel generation. Poly­{[N,N′-bis­(2-octyldodecyl)-naphthalene-1,4,5,8-bis­(dicarboximide)-2,6-diyl]-alt-5,5′-(2,2′-bithiophene)}, known as P­(NDI2OD-T2) or N2200, is a promising electron accepting material for bulk heterojunction photocathodes. Unlike inorganic (photo)­electrodes, much less is known about the energetic alignment of conjugated polymer electrode/metal/electrolyte junctions. Here, in this work, we investigate the electrical doping behavior in an N2200 cathode and its Fermi-level alignment with gold nanoparticles, which is used here as a model for the hydrogen evolution metal cocatalyst. Through UV/visible, Raman, and attenuated total-reflectance infrared spectroelectrochemistry, we observe the impact of electrical doping on the vibrational frequencies of neutral, anion, and dianion species in N2200, which suggests that electron density changes within the corresponding naphthalene-diimide (NDI) units. Upon one-electron reduction, the $C=O$ stretching frequency of the NDI anion unit (polaron) shows a red shift by ∼ 68 cm –1 . Additionally, the $C=O$ stretching frequency of neutral units in the doped N2200 shows a minor red shift of ∼ 5 cm –1 , suggesting charge transfer from neighboring polaron units. Surface-enhanced Raman spectroscopy measurements of a gold nanoparticle-functionalized N2200 electrode revealed that the Au Fermi level only shifts with that of N2200 upon polaron formation; thus, the formal potential of polymer polaron formation determines the behavior of the catalyst Fermi level, which we posit will modulate reaction capability. This mechanistic study provides a new approach for understanding the nanometer-scale energetics at the conjugated polymer/cocatalyst junction and provides critical insights for the future design of HER (photo)­cathodes.

charge transfer↗

Robust Control for The G-Limit Microgravity Vibration Isolation System

Many microgravity science experiments need an active isolation system to provide a sufficiently quiescent acceleration environment. The g-LIMIT vibration isolation system will provide isolation for Microgravity Science Glovebox experiments in the International Space Station. While standard control system technologies have been demonstrated for these applications, modern control methods have the potential for meeting performance requirements while providing robust stability in the presence of parametric uncertainties that are characteristic of microgravity vibration isolation systems. While H2 and H infinity methods are well established, neither provides the levels of attenuation performance and robust stability in a compensator with low order. Mixed H2/mu controllers provide a means for maximizing robust stability for a given level of mean-square nominal performance while directly optimizing for controller order constraints. This paper demonstrates the benefit of mixed norm design from the perspective of robustness to parametric uncertainties and controller order for microgravity vibration isolation. A nominal performance metric analogous to the mu measure for robust stability assessment is also introduced in order to define an acceptable trade space from which different control methodologies can be compared.

Whorton, Mark S.↗

Robust Control for Microgravity Vibration Isolation using Fixed Order, Mixed H2/Mu Design

Many space-science experiments need an active isolation system to provide a sufficiently quiescent microgravity environment. Modern control methods provide the potential for both high-performance and robust stability in the presence of parametric uncertainties that are characteristic of microgravity vibration isolation systems. While H2 and H(infinity) methods are well established, neither provides the levels of attenuation performance and robust stability in a compensator with low order. Mixed H2/H(infinity), controllers provide a means for maximizing robust stability for a given level of mean-square nominal performance while directly optimizing for controller order constraints. This paper demonstrates the benefit of mixed norm design from the perspective of robustness to parametric uncertainties and controller order for microgravity vibration isolation. A nominal performance metric analogous to the mu measure, for robust stability assessment is also introduced in order to define an acceptable trade space from which different control methodologies can be compared.

Whorton, Mark↗

Space Shuttle Crawler Transporter Sound Attenuation Study

The crawler transporter (CT) is the world's largest tracked vehicle known, weighing 6 million pounds with a length of 131 feet and a width of 113 feet. The Kennedy Space Center (KSC) has two CTs that were designed and built for the Apollo program in the 1960's, maintained and retrofitted for use in the Space Shuttle program. As a key element of the Space Shuttle ground systems, the crawler transports the entire 12-million-pound stack comprising the orbiter, the mobile launch platform (MLP), the external tank (ET), and the solid rocket boosters (SRB) from the Vehicle Assembly Building (VAB) to the launch pad. This rollout, constituting a 3.5-5.0-mile journey at a top speed of 0.9 miles-per-hour, requires over 8 hours to reach either Launch Complex 39A or B. This activity is only a prelude to the spectacle of sound and fury of the Space Shuttle launch to orbit in less than 10 minutes and traveling at orbital velocities of Mach 24. This paper summarizes preliminary results from the Crawler Transporter Sound Attenuation Study, encompassing test and engineering analysis of significant sound sources to measure and record full frequency spectrum and intensity of the various noise sources and to analyze the conditions of vibration. Additionally, data such as ventilation criteria, plus operational procedures were considered to provide a comprehensive noise suppression design for implementation. To date, sound attenuation study and results on Crawler 2 have shown significant noise reductions ranging from 5 to 24 dBA.

Margasahayam, Ravi N.↗

Monodomain Liquid‐Crystal Elastomer Lattices for Broad Strain‐Rate Mechanical Damping

Designing structures that effectively dissipate energy across a broad range of mechanical loading rates, including those from compression, shock, and vibration, poses a significant engineering challenge. In this study, liquid‐crystal elastomers (LCEs), which possess anisotropic properties due to the alignment of their polymer backbone, are explored. As a result, LCEs exhibit a soft elastic response under mechanical loading, making them ideal for energy dissipation. Advances in additive manufacturing (AM) enable simple fabrication of foamlike dissipative structures with complex lattice geometries. Herein, direct ink write 3D printing, an extrusion AM method, is used to fabricate aligned, monodomain LCE lattice structures for broad strain‐rate mechanical damping. In this work, it is shown that these structures can dissipate strain energy in quasi‐static environments, comparable to traditional elastomeric lattices, and provide improved damping under high strain‐rate drop testing due to LCE soft elasticity. Additionally, under dynamic mechanical vibration, monodomain LCE lattices enhance damping at structural natural frequencies and provide high‐frequency attenuation. Finally, in these findings, a promising method is presented for fabricating mechanical damping devices that effectively dissipate energy across a broad range of loading rates.

3D printings↗