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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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106 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Optical Characterization and 2,525 micron Lasing of Cr(2+):Cd(0.85)Mn(0.15)Te

Transition metal doped solids are of significant current interest for the development of tunable solid-state lasers for the near and mid-infrared (1-4 pm) spectral region. Applications of these lasers include basic research in atomic, molecular, and solid-state physics, optical communication, medicine, and environmental studies of the atmosphere. In transition metal based laser materials, absorption and emission of light arises from electronic transitions between crystal field split energy levels of 3d transition metal ions. The optical spectra generally exhibit broad bands due to the strong interaction between dopant and host (electron-phonon coupling). Broad emission bands offer the prospect of tunable laser activity over a wide wavelength range, e.g. the tuning range of Ti:Sapphire extends from 700-1100 run. The only current transition metal laser operating in the mid-infrared wavelength region (1.8-2.4 micro-m) is CO(2+):MgF2, but its performance is severely limited due to strong nonradiative decay at room temperature. Based on lifetime data, the quantum efficiency is estimated to be less than 3 deg/0 11,21. In general, the probability for non-radiative decay via multi-phonon relaxation increases with decreasing energy gap between ground and excited state. Therefore, efficient transition metal lasers beyond -1.6 micro-m are rare. Recently, tunable laser activity around 2.3 micro-m was observed from Cr doped ZnS and ZnSe. The new lasing center in these materials was identified as Cr(2+) occupying the tetrahedral Zn site. Tetrahedrally coordinated optical centers are rather unusual among transition metal lasers. Their potential usefulness, however, has been demonstrated by the recent development of near infrared laser materials such as Cr:forsterite and Cr:YAG, which are based on tetrahedrally coordinated Cr(4+) ions. According to the Laporte selection rule, electric-dipole transition within the optically active 3d-electron shells are parity forbidden. However, a static acentric electric crystal field or the coupling of asymmetric phonons can force electric-dipole transitions by the admixture of wave functions with opposite parity. Tetrahedral sites lack inversion symmetry which provides the odd-parity field necessary to relax the parity selection rule. Therefore, high absorption and emission cross sections are observed. An enhanced radiative emission rate is also expected to reduce the detrimental effect of non-radiative decay. Motivated by the initial results on Cr doped ZnS and ZnSe, we have started a comprehensive effort to study Cr(2+) doped II-VI semiconductors for solid-state laser applications. In this paper we present the optical properties and the demonstration of mid-infrared lasing from Cr doped Cd(0.85)Mn(0.15)Te.

Davis, V. R.↗
NASA NTRS2002

Penning Ionization Electron Spectroscopy in Glow Discharge: A New Dimension for Gas Chromatography Detectors

Admixtures to helium of 100 ppm and 5 ppm of nitrogen, and 100 ppm and 10 ppm of carbon monoxide were identified and measured in the helium discharge afterglow using an electrical probe placed into the plasma. For nitrogen and carbon monoxide gases, the measured electron energy spectra display distinct characteristic peaks (fingerprints). Location of the peaks on the energy scale is determined by the ionization energies of the analyte molecules. Nitrogen and carbon monoxide fingerprints were also observed in a binary mixture of these gases in helium, and the relative concentration analytes has been predicted. The technically simple and durable method is considered a good candidate for a number of analytical applications, and in particular, in GC and for analytical flight instrumentation.

Sheverev, V. A.↗
NASA NTRS1998

Intestinal transport of gentamicin with a novel, glycosteroid drug transport agent

PURPOSE: The objective was to investigate the ability of a glycosteroid (TC002) to increase the oral bioavailability of gentamicin. METHODS: Admixtures of gentamicin and TC002 were administered to the rat ileum by injection and to dogs by ileal or jejunal externalized ports, or PO. Bioavailability of gentamicin was determined by HPLC. 3H-TC002 was injected via externalized cannulas into rat ileum or jejunum, or PO and its distribution and elimination was determined. The metabolism of TC002 in rats was evaluated by solid phase extraction and HPLC analysis of plasma, urine and feces following oral or intestinal administration. RESULTS: The bioavailability of gentamicin was substantially increased in the presence of TC002 in both rats and dogs. The level of absorption was dependent on the concentration of TC002 and site of administration. Greatest absorption occurred following ileal orjejunal administration. TC002 was significantly more efficacious than sodium taurocholate, but similar in cytotoxicity. TC002 remained primarily in the GI tract following oral or intestinal administration and cleared rapidly from the body. It was only partly metabolized in the GI tract, but was rapidly and completely converted to its metabolite in plasma and urine. CONCLUSIONS: TC002 shows promise as a new drug transport agent for promoting intestinal absorption of polar molecules such as gentamicin.

Non-NASA Center↗
NASA NTRS1949

Investigation of Conditions of Titanium Carbonization - IV

In a previous paper, results are presented of accurate investigations of the processes of titanium carbonization and the succeeding titanium carbide decarbonization as related to the phenomenon of the graphitization of soot by heating at a constant temperature in atmospheres of pure hydrogen and carbon monoxide. These tests showed that the processes of titanium carbonization-decarbonization in an atmosphere of pure gases without nitrogen proceed in the same direction as the analogous processes under the conditions of the production furnace. In this case, however, the presence of admixtures of nitrogen changes the quantitative results of the decarbonization process. Thermodynamic computations confirming the results of previous tests conducted at atmospheric pressure and additional tests of titanium carbonization at lowered pressures are presented herein.

Meerson, G. A.↗
NASA NTRS2005

Polyimide Foams

A fully imidized, solvent-free polyimide foam having excellent mechanical, acoustic, thermal, and flame resistant properties is produced. A first solution is provided, which includes one or more aromatic dianhydrides or derivatives of aromatic dianhydrides, and may include one or more aromatic diamines, dissolved in one or more polar solvents, along with an effective amount of one or more blowing agents. This first solution may also advantageously include effective amounts respectively of one or mores catalysts, one or more surfactants, and one or more fire retardants. A second solution is also provided which includes one or more isocyanates. The first and second solutions are rapidly and thoroughly mixed to produce an admixture, which is allowed to foam-in an open container, or in a closed mold-under ambient conditions to completion produce a foamed product. This foamed product is then cured by high frequency electromagnetic radiation, thermal energy, or a combination thereof. Alternatively, the process is adapted for spraying or extrusion.

Juan M Vazquez↗
NASA NTRS2006

Global Aspects of Heliosphere-Geosphere Coupling

The magnetosphere serves both to hold off the solar wind and to couple it selectively to the Earth through the auroral zones. It has long been understood that the plasmasphere consists of geogenic plasmas that expand out of the sunlit low latitude ionosphere, but it was initially assumed that the hot low density plasma beyond the plasmasphere is largely of solar wind origin with a minor admixture of ionospheric plasmas, discovered via mass spectrometric observations in the early 70's. Since then, elaborate simulation models have been developed that have taken us from an era of cartoon physics to a new era of quantitative global comparisons between observations and theory. In most current global circulation models of the magnetosphere, the ionospheric load on the system is taken to lie exclusively in the thin F layer of the ionosphere. This layer is coupled with solar wind and magnetospheric plasmas via Maxwell stresses communicated by field aligned current systems, and with the thermosphere via ion-neutral charge exchange and Coulomb collisions. However, recent observations have shown us that ionospheric plasmas flow sporadically in various forms into the plasmasphere and up into the high latitude circulation cells of the outer magnetosphere, as driven by the solar wind and its variable intensity and magnetic field. Under some conditions, ionospheric material is observed to be the principal component of plasmas at the dayside magnetopause and in the plasma sheet and ring current regions. Given a global model of magnetospheric circulation, it is relatively straightforward to investigate the behaviors of ionospheric plasmas in response to solar wind drivers, and we report the results of such efforts here. We find that ionospheric plasmas dominate the plasma pressure in the magnetosphere in some regions, particularly when the solar wind is especially intense and-or southward directed. This result violates the assumption that the ionospheric load is confined to the F layer, and shows that the ionosphere is often an important dynamic element of the solar wind-ionosphere system throughout the magnetosphere, especially during larger geospace storms. This means that future global circulation models must account for ionospheric plasma inertia, heat capacity, and pressure, to be quantitatively credible.

Moore, Thomas E.↗
NASA NTRS1980

Alkaline battery, separator therefore

An improved battery separator for alkaline battery cells has low resistance to electrolyte ion transfer and high resistance to electrode ion transfer. The separator is formed by applying an improved coating to an electrolyte absorber. The absorber, preferably, is a flexible, fibrous, and porous substrate that is resistant to strong alkali and oxidation. The coating composition includes an admixture of a polymeric binder, a hydrolyzable polymeric ester and inert fillers. The coating composition is substantially free of reactive fillers and plasticizers commonly employed as porosity promoting agents in separator coatings. When the separator is immersed in electrolyte, the polymeric ester of the film coating reacts with the electrolyte forming a salt and an alcohol. The alcohol goes into solution with the electrolyte while the salt imbibes electrolyte into the coating composition. When the salt is formed, it expands the polymeric chains of the binder to provide a film coating substantially permeable to electrolyte ion transfer but relatively impermeable to electrode ion transfer during use.

Schmidt, George F.↗
NASA NTRS1996

Electrically conductive polyimide film containing gold (III) ions, composition, and process of making

An electrically conductive, thermooxidatively stable poltimide, especially a film thereof, is prepared from an intimate admixture of a particular polyimide and gold (III) ions, in an amount sufficient to provide between 17 and 21 percent by weight of gold (III) ions, based on the weight of electrically conductive, thermooxidatively stable polyimide. The particular polyimide is prepared from a polyamic acid which has been synthesized from a dianhydride/diamine combination selected from the group consisting of 3,3',4,4'-benzophenonetetracarboxylic dianhydride and 2,2-bis[4-(4 -aminophenoxy)phenyl]hexafluoropropane; 3,3',4,4'-benzophenonetetracarboxylic dianhydride and 4,4'-oxydianiline; 2,2'-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride and 4,4'-oxydianiline; and 3,3'4,4'-benzophenonetetracarboxylic dianhydride and 2,2-bis(3-aminophenyl)hexafluoropropane.

Caplan, Maggie L.↗
NASA NTRS2005

Polyimide foams

A fully imidized, solvent-free polyimide foam having excellent mechanical, acoustic, thermal, and flame resistant properties is produced. A first solution is provided, which includes one or more aromatic dianhydrides or derivatives of aromatic dianhydrides, and may include one or more aromatic diamines, dissolved in one or more polar solvents, along with an effective amount of one or more blowing agents. This first solution may also advantageously include effective amounts respectively of one or mores catalysts, one or more surfactants, and one or more fire retardants. A second solution is also provided which includes one or more isocyanates. The first and second solutions are rapidly and thoroughly mixed to produce an admixture, which is allowed to foam?in an open container, or in a closed mold?under ambient conditions to completion produce a foamed product. This foamed product is then cured by high frequency electromagnetic radiation, thermal energy, or a combination thereof. Alternatively, the process is adapted for spraying or extrusion.

Vazquez, Juan M.↗
NASA NTRS2008

Mars Rocket Propulsion System

A report discusses the methane and carbon monoxide/LOX (McLOx) rocket for ascent from Mars as well as other critical space propulsion tasks. The system offers a specific impulse over 370 s roughly 50 s higher than existing space-storable bio-propellants. Current Mars in-situ propellant production (ISPP) technologies produce impure methane and carbon monoxide in various combinations. While separation and purification of methane fuel is possible, it adds complexity to the propellant production process and discards an otherwise useful fuel product. The McLOx makes such complex and wasteful processes unnecessary by burning the methane/CO mixtures produced by the Mars ISPP systems without the need for further refinement. Despite the decrease in rocket-specific impulse caused by the CO admixture, the improvement offered by concomitant increased propellant density can provide a net improvement in stage performance. One advantage is the increase of the total amount of propellant produced, but with a decrease in mass and complexity of the required ISPP plant. Methane/CO fuel mixtures also may be produced by reprocessing the organic wastes of a Moon base or a space station, making McLOx engines key for a human Lunar initiative or the International Space Station (ISS) program. Because McLOx propellant components store at a common temperature, very lightweight and compact common bulkhead tanks can be employed, improving overall stage performance further.

Zubrin, Robert↗
NASA NTRS2009

Polyimide foams

A fully imidized, solvent-free polyimide foam having excellent mechanical, acoustic, thermal, and flame resistant properties is produced. A first solution is provided, which includes one or more aromatic dianhydrides or derivatives of aromatic dianhydrides, and may include one or more aromatic diamines, dissolved in one or more polar solvents, along with an effective amount of one or more blowing agents. This first solution may also advantageously include effective amounts respectively of one or mores catalysts, one or more surfactants, and one or more fire retardants. A second solution is also provided which includes one or more isocyanates. The first and second solutions are rapidly and thoroughly mixed to produce an admixture, which is allowed to foam--in an open container, or in a closed mold--under ambient conditions to completion produce a foamed product. This foamed product is then cured by high frequency electromagnetic radiation, thermal energy, or a combination thereof. Alternatively, the process is adapted for spraying or extrusion.

Vazquez, Juan M.↗
NASA NTRS2010

Ar-Ar Studies of Lherzolitic Shergottites Yamato 000097 and 984028

The approx.170 Ma age of the rock(s) is (likely) preserved in minor phases of high K content. Terrestrial Ar appears to have a nearly ubiquitous presence in the gas release, and mixes with Martian Ar in variable proportions. The intermediate temperature release of the plag separate shows an apparently higher approx.270 Ma age, and suggests the presence of terrestrial Ar that "torques" the correlation to a steeper slope than for 170 Ma. The intermediate temperature data of the pyroxene is consistent with a "young" age (either approx.170 to approx.270 Ma) and mostly Martian trapped Ar. The low temperature (needs checking) data also are essentially consistent with the approx.170 Ma age, but an intercept near the terrestrial value is suspicious. Would not have had terrestrial Ar on Mars, so this is more likely a mixing line. Admixtures of terrestrial Ar in the pyroxene extractions seems pervasive, but can t explain the variation in 39/36 along the intermediate temp. "isochron".

Park, J.↗
NASA NTRS2010

The Connection Between Small Gamma-Ray Flares and SEPs with COMPTEL/CGRO

While it is clear that particle acceleration is occurring during flares, what is less clear is the connection between the neutral radiation observed concommitant with the flare and the in-situ observations of SEPs. For the largest SEP events, where current instruments possess the sensitivity to observe nuclear-related gamma-ray emission, the origin of SEPs is generally divided between an escaping accelerated flare population and a population of coronal particles (or some admixture) accelerated through CME-driven shocks. Small flares, as defined by their X-ray emission, have been found to correlate with the presence of small "impulsive" (enriched in electrons and heavy nuclei) SEP events, suggesting that small SEP events are originally flare particles. The difficulty with this interpretation is that small flares lack detectable nuclear-related gamma-ray emission. Whether this emission is there or not is unclear because current instruments capable of high-energy gamma-ray observations operate above the sensitivity threshold for observing gammaray emission from small flares (< C-class). The COMPton TELescope (COMPTEL) aboard the Compton Gamma Ray Observatory (CGRO) provided unprecedented, and as yet unsurpassed, sensitivity to y rays in the 0.7 to 30 MeV energy range and neutrons in the 20 to 150 MeV energy range. This, combined with its nine years of operation, has produced a unique data set of observations for almost a complete solar cycle. The COMPTEL archival data offers the best possibility to investigate a connection between SEP observations in space and small-flare gamma-ray emission. We present preliminary results of a small-flare search within the COMPTEL archival data and discuss the correlation between already well-established compilations of SEP events and small impulsive or 3He-rich SEP events. Establishing a connection and determining the characterization of this connection, would signify an important development in our understanding of how and where flare particles are accelerated and how these very same particles escape into the interplanetary medium. Equally important would be demonstrating the inconsistencies or poor correlation between gamma-ray emission and small impulsive SEP events.

deNolfo, Georgia↗
NASA NTRS2014

Phosphates at the Surface of Mars: Primary Deposits and Alteration Products

Phosphorus is an essential element in terrestrial organisms and thus characterizing the occurrences of phosphate phases at the martian surface is crucial in the assessment of habitability. The Alpha Particle X-Ray Spectrometers onboard Spirit, Opportunity and Curiosity discovered a variety of primary and secondary phosphate phases allowing direct comparisons across the three landing sites. The Spirit rover at Gusev Crater encountered the "Wishstone/Watchtower" class of P-rich (up to 5.2 wt% P2O5) rocks interpreted to be alkaline volcanic rocks with a physical admixture of approximately 10 to 20% merrillite [Usui et al 2008]. These rocks are characterized by elevated Ti and Y and anomalously low Cr and Ni, which could largely reflect the nature of the protoliths: Evolved magmatic rocks. Many of these chemical signatures are also found in pyroclastic deposits at nearby "Home Plate" and in phosphate precipitates derived from fluid interactions with these rocks ("Paso Robles" soils). The Opportunity rover at Meridiani Planum recently analyzed approximately 4 cm clast in a fine-grained matrix, one of numerous rocks of similar appearance at the rim of Endeavour Crater. This clast, "Sarcobatus," has minor enrichments in Ca and P relative to the matrix, and like the P-rich rocks at Gusev, Sarcobatus also shows elevated Al and Ti. On the same segment of the Endeavour rim, subsurface samples were found with exceptional levels of Mn (approximately 3.5 wt% MnO). These secondary and likely aqueous deposits contain strong evidence for associated Mg-sulfate and Ca-phosphate phases. Finally, the Curiosity traverse at Gale crater encountered P-rich rocks compositionally comparable to Wishstone at Gusev, including elevated Y. Phosphorous-rich rocks with similar chemical characteristics are prevalent on Mars, and the trace and minor element signatures provide constraints on whether these are primary deposits, secondary products of physical weathering or secondary products of chemical weathering.

Yen, Albert S.↗
NASA NTRS2017

Far-UV Spectroscopy of Two Extremely Hot, Helium-Rich White Dwarfs

A large proportion of hot post-asymptotic giant branch stars and white dwarfs (WDs) are hydrogen-deficient. Two distinct evolutionary sequences have been identified. One of them comprises stars of spectral type [WC] and PG1159, and it originates from a late helium-shell flash, creating helium-rich stellar atmospheres with significant admixtures of carbon (up to about 50, mass fraction). The other sequence comprises stars of spectral type O(He) and luminous subdwarf O stars which possibly are descendants of RCrB stars and extreme helium stars. Their carbon abundances are significantly lower (of the order of 1 or less) and it is thought that they originate from binary-star evolution (through merger or common-envelope evolution). Here we investigate two of the three hottest known helium-rich (DO) WDs (PG 1034+001 and PG 0038+199). They are the only ones for which spectra were recorded with the Far Ultraviolet Spectroscopic Explorer and the Hubble Space Telescope, allowing a comprehensive ultraviolet spectral analysis. We find effective temperatures of T(eff) =115000 +/- 5000 K and 125000 +/- 5000 K, respectively, and a surface gravity of log g = 7 +/-0.5. In both stars, nitrogen is strongly oversolar while C and O are significantly subsolar. For all other assessed metals (Ne, Si, P, S, Ar, Fe, and Ni) we find abundances close to solar. We conclude that these WDs are immediate descendants of O(He) stars and, hence, result from close-binary evolution.

Werner, K.↗
NASA NTRS2019

Experimental Investigation of Cement Hydration in Gravity-Free Environment

In this work, cement hydration in terrestrial and microgravity environment was compared. This was for the first time, when the International Space Station was utilized to fully investigate the complex process of cement solidification. Microstructural development of hydrating cement occurs in stages during the hydration reaction and hardening process, which results in elaborate combinations of amorphous and crystalline phases. The morphology, volume fraction, and distribution of these phases ultimately determine the hardened cement’s material properties. Minimizing gravity-driven phenomena, such as thermosolutal convective flow and sedimentation ensures crystal growth strictly by diffusion and a microstructure forms differently from that observed in typical laboratory conditions on Earth. A test matrix was developed that includes samples with various w/c ratio and various compositions; incorporating alite, pure water and cement system, cement with chemical admixtures, as well as commercial products. This paper reports on main changes initially observed in the microstructural development of hydrated pure compound of tricalcium silicate (C3S).

Neves, Juliana↗