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NASA NTRS1978

Infrared /JHK/ photometry of meteorites and asteroids

The paper reports JHK colors observed for ten asteroids and synthesized JHK colors for seven meteorite groups, samples of iron and nickel metal, pyroxene, olivine, feldspar, a lunar anorthite and some terrestrial mineral samples. Pronounced differences are apparent between the chondritic and achondritic meteorite classes; the chondritic classes show less subdued trends in J-H color which reflect their metamorphic grade. We find small but significant differences between the JHK colors of the predominant C and S classes of asteroids. All JHK colors of asteroids observed here fall within the limited domain defined by the various chondritic and iron-rich meteorites but are strikingly different from those of most achondritic meteorites.

Leake, M.↗
NASA NTRS1977

Petrology of crystalline matrix breccias from Apollo 17 rake samples

The petrology, mineralogy, and composition of 13 crystalline matrix breccias from the Apollo 17 rake samples are described. The breccias have matrices of uniform modal mineralogy (plagioclase, 50-54%; olivine and pyroxene, 41-46%) but diverse textures. Clast characteristics, including the proportion of plagioclase, the composition in comparison with matrix, and the textures of different clast types, are reported. The majority of bulk matrix compositions plot on or very near the plagioclase-olivine cotectic in the system olivine-anorthite-silica. If the matrix compositions represent impact total melts, the inferred cotectic control requires that the source material was itself an igneous differentiate with compositions along the plagioclase-olivine cotectic. Alternatively, the proximity of the matrix compositions to the plagioclase-olivine cotectic could be accounted for if the breccia matrices represent a suite of impact-generated partial melts.

Warner, R. D.↗
NASA NTRS1975

Shock-induced subsolidus reduction-decomposition of orthopyroxene and shock-induced melting in norite 78235

Lunar rock 78235 is a coarse-grained igneous rock which was chipped from the top of a boulder about 1/2 m in size at Station 8 at the base of the Sculptured Hills, Taurus-Littrow Valley. The rock is a shocked coarse-grained norite with a relict subophitic texture; it is composed of about equal proportions of chromian bronzite and anorthite. Evidence is presented for the shock history of the rock. It is concluded that 78235 is a deep-seated norite of cumulate origin which has been intensely shocked. Although it may be possible to account for the observed shock-induced features by invoking a single shock event, the evidence is best explained by a history which includes at least two discrete shock events. In the first identifiable shock event much of the plagioclase was transformed to maskelynite and the associated bronzite was deformed and acquired a mosaic structure. In a later shock event, localized melting of both plagioclase pyroxene occurred.

Sclar, C. B.↗
NASA NTRS1975

Lunar petrogenesis in a well-stirred magma ocean

The principal group of low-KREEP highlands rocks as indicated by quartz-olivine-anorthite pseudoternary phase diagrams shows chemical trends which violate the Bowen reaction principle, in that the greater the concentration of magnesian and mafic minerals, the more sodic the coexisting plagioclase tends to be. It is suggested that this trend was established during the primary differentiation of the lunar crust and is a result of crystallization in a vigorously convecting (well-stirred) system. Under these conditions all plagioclase crystals, all pyroxene crystals, and all of the residual liquid remain fairly uniform in composition until advanced crystallization immobilizes the system. The rock suite then established would vary continuously from anorthositic types at the top to ultramafic types at the bottom.

Wood, J. A.↗
NASA NTRS1979

A geologic assessment of potential lunar ores

Although bulk lunar soil is not a suitable feedstock for extracting metals, certain minerals such as anorthite and ilmenite can be separated and concentrated. These minerals can be considered as potential ores of aluminum, silicon, titanium, andiron. A separation and metal extraction plant could also extract large amounts of oxygen and perhaps hydrogen from these minerals. Anorthie containing 19 percent aluminum and 20 percent silicon can be concentrated from some highland soils where it is present in amounts up to 60 percent. Ilmenite containing 32 percent titanium and 37 percent iron can be concentrated from some mare soils where it is present in amounts up to 10 percent. The ideal mining site would be located at the boundary between a high-titanium mare and a high-aluminum highlands. Such area may exist around the rims of some eastern maria, particularly Tranquilitatis. A location on Earth with raw materials as described above would be considered an economically valuable ore deposit if conventional terrestrial resources were not available.

Mckay, D. S.↗
NASA NTRS1977

Extraction processes for the production of aluminum, titanium, iron, magnesium, and oxygen and nonterrestrial sources

The suitability of existing terrestrial extractive metallurgical processes for the production of Al, Ti, Fe, Mg, and O2 from nonterrestrial resources is examined from both thermodynamic and kinetic points of view. Carbochlorination of lunar anorthite concentrate in conjunction with Alcoa electrolysis process for Al; carbochlorination of lunar ilmenite concentrate followed by Ca reduction of TiO2; and subsequent reduction of Fe2O3 by H2 for Ti and Fe, respectively, are suggested. Silicothermic reduction of olivine concentrate was found to be attractive for the extraction of Mg becaue of the technological knowhow of the process. Aluminothermic reduction of olivine is the other possible alternative for the production of magnesium. The large quantities of carbon monoxide generated in the metal extraction processes can be used to recover carbon and oxygen by a combination of the following methods: (1) simple disproportionation of CO,(2) methanation of CO and electrolysis of H2O, and (3) solid-state electrolysis of gas mixtures containing CO, CO2, and H2O. The research needed for the adoption of earth-based extraction processes for lunar and asteroidal minerals is outlined.

D Bhogeswara Rao↗
NASA NTRS1978

Clast assemblages of possible deep-seated /77517/ and immiscible-melt /77538/ origins in Apollo 17 breccias

Breccia samples 77517 and 77538 are composed of abundant mineral and lithic clasts set in porous, poorly sintered matrices. Clast assemblages in the two rocks are of contrasting composition and origin. Breccia 77517 has Mg-rich olivine and pyroxene and calcic plagioclase clasts, indicating limited, almost exclusively ANT-suite parentage. A significant feature is the presence of an assemblage (aluminous enstatite, forsterite, anorthite, aluminous spinel) corresponding to spinel cataclasite, a rock type of deep-seated (about 60 km) crustal origin. Breccia 77538 contains Fe-rich pyroxene and rather sodic plagioclase clasts, indicative of predominantly KREEP and/or mare derivation. An important feature is the occurrence of high-K and high-Fe lithic clasts whose compositions resemble those of immiscible-melts produced during late-stage magmatic crystallization, and which probably originated via silicate liquid immiscibility in a KREEP or mare basalt magma. Both rocks contain numerous fine-grained breccia clasts which represent material that has been modified by impact processes at or very near the moon's surface.

Warner, R. D.↗
NASA NTRS1978

Major and trace element chemistry of separated fragments from a hibonite-bearing Allende inclusion

The major and trace elements of separated fragments and a bulk sample from CG-11, a hibonite-bearing inclusion in the Allende meteorite, were analyzed. Major element abundances were used to determine the minerology of separated fragments. The high degree of correlation between Eu/Sm ratios and Lu/Yb ratios for the samples studied indicates that their rare earth element (REE) distributions are governed by two components. One, Lu-, Eu-rich, is probably hibonite; the other, depleted in these elements, seems to be associated with the secondary alteration phases, grossular, nepheline and anorthite. The REE distribution in CG-11 precludes melting events after formation of the secondary alteration phases, but a melting event involving the primary minerals cannot be excluded. The enrichment of Lu with respect to other measured REE in hibonite can be explained by present REE condensation models. Two Hf-bearing components, most likely hibonite and perovskite, are necessary to account for variations in Sc/Hf ratios in the fragments studied. The lithophile volatiles Na, Mn, Fe, Zn, and probably Cr increase in the same order as the amount of secondary alteration minerals; the volatile siderophile elements Co and Au, however, do not.

Davis, A. M.↗
NASA NTRS1978

The formation kinetics of lunar glasses

The kinetic treatment of crystallization and glass formation, involving the construction of time-temperature-transformation curves (TTT) corresponding to a given degree of crystallinity, is extended to permit the description of crystallization of a body initially cooled to a glassy state. The key assumption is that if at any time and temperature a crystallite is smaller than the critical size corresponding to that temperature, it will melt completely and can be ignored in any further calculations of the crystal distribution. This approach is used to predict the temperature of maximum crystallization rate for the matrix composition of lunar breccia 67975; results are shown to be in excellent agreement with experiment. Theoretical results obtained for anorthite indicate a barrier to nucleation in the range of 75 kT when the ratio of the undercooling to the liquidus temperature is 0.2. Measured nucleation barriers for the 67975 matrix composition are in the range of 42 to 45 kT.

Uhlmann, D. R.↗
NASA NTRS1978

Reflectance measurements of lunar materials in the vacuum ultraviolet

The spectral reflectances of materials have been measured in the vacuum ultraviolet region of the spectrum for possible planetary compositional remote-sensing applications. These materials, which include lunar and terrestrial silicate rocks and minerals, have one or more characteristic absorption peaks between about 8 and 13 eV. The peaks are visible in the spectra of powders and rough surfaces as well as polished surfaces. In lunar samples the most prominent peaks are at 10.25 eV, due to augite, and at 9.0 eV, due to anorthite. Spectra of lunar soils have minima between 6 eV (0.20 micron) and 8 eV (0.16 micron) depending on composition. Soils that have high reflectances in the visible have low reflectances in the VUV. The pyroxene content of the soils results in reflectance maxima at about 10 eV (0.12 micron). Peaks due to olivine and augite can be identified in the spectra of meteorites.

Hapke, B. W.↗
NASA NTRS1979

Li, Be, and B in minerals of a refractory-rich Allende inclusion

The abundances of Li, Be, and B and the isotopic ratios of Li and B have been measured by ion microprobe in melilite, pyroxene, anorthite, and spinel grains in a coarse-grained inclusion from the Allende meteorite. Based on the measurements, it is estimated that the bulk inclusion contains 200 ppb Li, 310 ppb Be, and 18 ppm B. The B is probably due to contamination. The Li-7/Li-6 ratios in spinels, pyroxene, and melilite are indistinguishable at the + or - 15% level and lie within the uncertainty (+ or - 15%) of the range of values reported for samples of the earth and meteorites. It has been determined that this inclusion contains an excess of Al-correlated Mg-26, implying that Al-26 was once present in it. The Li-Be-B effects for two solar-system proton-irradiation models which propose to account for Al-26 in Allende inclusions have been calculated. It is found that the predicted Li-Be-B abundances and isotopic ratios are grossly different from those observed in any solar-system materials.

Phinney, D.↗
NASA NTRS1980

Possible isotopic fractionation effects in sputtered minerals

A model which makes definite predictions for the fractionation of isotopes in sputtered material is discussed. The fractionation patterns are nonlinear, and the pattern for a particular set of isotopes depends on the chemical matrix within which those isotopes are contained. Calculations are presented for all nonmonoisotopic elements contained in the minerals perovskite, anorthite, ackermanite, enstatite, and troilite. All isotopes are fractionated at the level of approximately 4-6 deg/o per atomic mass unit. Oxygen is always positively fractionated (heavier isotopes sputtered preferentially), and heavier elements are generally negatively fractioned (light isotopes sputtered preferentially). The value of Delta (O-18:O-16) is always less by about 1.8 deg/o than a linear extrapolation based upon the calculated delta (O-17:O-16) value would suggest. The phenomenon of both negative and positive fractionation patterns from a single target mineral are used to make an experimental test of the proposed model.

Haff, P. K.↗
NASA NTRS1981

A once-molten, coarse-grained, Ca-rich inclusion in Allende

A compact, spheroidal Type B inclusion in Allende contains melilite laths that project radially inward from the inclusion edge which show interference growth textures. The combined textural and chemical features of this object cannot be explained by independent vapor-solid condensation of grains in space, followed by random aggregation of these grains into an inclusion. Instead, it probably formed from a once-molten droplet that crystallized in response to radiative cooling from its outer surface. The crystallization sequence in this and another similar inclusion in which oxygen isotopes have been measured is melilite-spinel-anorthite-fassaite; this sequence shows that oxygen isotopic heterogeneities in coarse-grained inclusions were formed after complete solidification of these objects by partial exchange with a less O-16-rich gas, and not during or before a melting event.

Macpherson, G. J.↗
NASA NTRS1980

Lunar highland melt rocks - Chemistry, petrology and silicate mineralogy

A selected suite containing several of the largest samples of lunar highland melt rocks includes impact melt specimens (anorthositic gabbro, low-K Fra Mauro) and volcanic specimens (intermediate-K Fra Mauro). Although previous assumptions of LKFM volcanism have fallen into disfavor, no fatal arguments against this hypothesis have been presented, and the evidence of a possibly 'inherited igneous' olivine-plagioclase cosaturation provides cause for keeping a volcanic LKFM hypothesis viable. Comparisons of silicate mineralogy with melt rock compositions provide information on the specimen's composition and cooling history. Plagioclase-rock compositions can be matched to the experimentally determined equilibria for appropriate samples to identify melt rocks with refractory anorthitic clasts. Olivine-rock compositions indicate that melt rock vitrophyres precipitate anomalously Fe-rich olivine; the cause of this anomaly is not immediately evident. The Al-Ti and Ca-Fe-Mg zonation in pyroxene provide information on relative cooling rates of highland melt rocks, but Cr- and Al-content (where Al-rich low-Ca pyroxene cores are preserved in rapidly cooled samples) can be correlated with composition of the host rock.

Vaniman, D. T.↗
NASA NTRS1981

Possible isotopic fractionation effects in material sputtered from minerals

A model is presented which predicts isotope fractionation in material sputtered from mineral surfaces. According to the model, the fractionation is a function of the fractional abundances of each isotope, the low-energy collision cross sections and the atomic masses, and the fractionation pattern can be nonlinear. Calculations are illustrated for all sets of isotopes in the minerals perovskite, anorthite, akermanite, enstatite and troilite, and it is found that while O is always positively fractionated, with heavier isotopes sputtered preferentially, heavier elements are generally negatively fractionated. It is noted that the model may be tested by experiments on a system such as CaF2, CaI2, in which the Ca sputtered from CaF2 is predicted to be strongly fractionated in a negative sense and that sputtered from CaI2 is predicted to be strongly fractionated in a positive sense.

Haff, P. K.↗
NASA NTRS1981

Ni partitioning between diopside and silicate melt - A redetermination by ion microprobe and recognition of an experimental complication

The capabilities of and potential problems with ion microprobe analysis are illustrated in the determination of Ni distribution between silicate melt and diopside as a function of concentration. Samples of diopside and a melt in the albite-anorthite-diopside system were doped with Ni to levels of 5.22 and 1.08 wt % and 1060, 138, 42 and 30 ppm, and with 3 ppm of Ni-63, and characterized by both electron and ion microprobe techniques. Measurements of Ni-62 distribution by the ion probe method give a ratio of 1.87 for the ratio of count rates in the diopsides with the glass, which is slightly lower than the value of 2.05 obtained from beta-track mapping. The measurements required the secondary ion signal to be linear with concentration in the range measured, and a calibration to correct for differential secondary ion yields from different phases. It is found, however, that partition coefficients measured for Ni-58 and Ni-60 are not constant with Ni concentration, probably due to Ni migration during crystallization. The results thus show ion microprobe analyses to be feasible for simultaneous measurements of distributions of more than one element, and of elements inappropriate for beta-track mapping or electron probe analysis.

Steele, I. M.↗
NASA NTRS1980

On the barrier to crystal nucleation in lunar glasses

The paper describes an analytical method for calculating in detail the size distributions of small crystallites and nuclei in supercooled liquids as they are being quenched to form a glass and subsequently reheated above the glass transition to produce crystallization. This method is applied to experiments performed using differential thermal analysis (DTA) to estimate the barriers to crystal nucleation and the cooling rates required to form glasses or bodies with various degrees of crystallinity. DTA data and derived nucleation barriers are reported for anorthite and for the following lunar compositions: 15498, 15418, matrix and intrusion compositions of breccia 15286, Apollo 15 green glass, Luna 24 highland basalt, and 65016.

Yinnon, H.↗
NASA NTRS1982

Crystallization sequences of Ca-Al-rich inclusions from Allende - An experimental study

The results of equilibrium crystallization experiments at one atmosphere on a sample of the Type B Ca-Al-rich inclusions (CAI) of the Allende meteorite are reported. All the experiments were performed on a synthetic sample approximating the Allende CAI characteristics. The crystallization sequence observed comprised spinel at 1550 C, then melilite at 1400 C, anorthite at 1260 C, and then Ti-Al-rich clinopyroxene, formed at 1230 C. The observation that pyroxenes similar to the titaniferous fassaites found in Type B inclusions can be formed by equilibrium crystallizations of melts with Type B composition indicate that some Type B CAIs were at least partially molten. If the temperatures were not too far above the solidus, the molten condensate compositions would be similar to that occurring in gas-to-solid condensation.

Stolper, E.↗