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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Ammonium enables reversible aqueous Zn battery chemistries by tailoring the interphase
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Electrodeposited Zinc-based Films as Anodes for Aqueous Zinc Batteries
Zinc-based batteries have attracted extensive attention in recent years, due to high safety, high capacities, environmental friendliness, and low cost compared to lithium ion batteries. However, the zinc anode suffers primarily from dendrite formation as a mode of failure in the mildly acidic system. Herein, we report on electrochemically deposited zinc (ED Zn) and copper-zinc (brass) alloy anodes, which are critically compared with a standard commercial zinc foil. The film electrodes are of commercially relevant thicknesses (21 and 25µM). The electrodeposited zinc-based anodes exhibit low electrode polarization (~0.025V) and stable cycling performance in 50 cycle consecutive experiments from 0.26-10 mA cm-2 compared to commercial Zn foil. Coulombic efficiencies at 1 mA cm-2 were over 98% for the electrodeposited zinc-based materials and were maintained for over 100 cycles. Furthermore, full cells with an electrodeposited Zn/brass anode, EMD MnO2 cathode, in 1M ZnSO4 + 0.1M MnSO4 delivered capacities of 96.3, and 163 mAh g-1, respectively, at a 100 mA g-1 compared to 92.1 mAh g-1 for commercial Zn. The zinc-based anodes also show better rate capability, delivering full cell capacities of 35.9 and 47.5 mAh g-1 at high current of up to 3 A g-1. Lastly, the electrodeposited zinc-based anodes show enhanced capacity for up to 100 cycles at 100 mA g-1, making them viable anodes for commercial use.
Rechargeable Aqueous Zn2+-Battery with High Power Density and Long Cycle-life
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In situ electrosynthesis of anthraquinone electrolytes in aqueous flow batteries
In this work, we demonstrate the electrochemical oxidation of an anthracene derivative to a redox-active anthraquinone at room temperature in a flow cell without the use of hazardous oxidants or noble metal catalysts. The anthraquinone, generated in situ, was used as the active species in a flow battery electrolyte without further modification or purification. This potentially scalable, safe, green, and economical electrosynthetic method is also applied to another anthracene-based derivative and may be extended to other redox-active aromatics.
Derivatization and Optimization of Iron Bipyridine Complexes for Non-aqueous Flow Batteries.
Abstract not provided.
Iron-and Bipyridine-based Charge Carriers for Non-Aqueous Flow Batteries.
Abstract not provided.
Derivatization and Optimization of Iron Bipyridine Complexes for Non-Aqueous Flow Batteries.
Abstract not provided.
Investigation of Iron-and Organic-based Bipolar Redox Molecules for Non-aqueous Flow Batteries.
Abstract not provided.
Influence of Linker Group on Bipolar Redox-Active Molecule (BRM) Performance in Non-Aqueous Flow Batteries
Poster presentation at MRS Fall 2024 in Boston, MA
Hydrophobic Molecule Monolayer Brush-Tethered Zinc Anodes for Aqueous Zinc Batteries
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An Overview and Recent Progress in Metal-Based Charge Carriers for Non-aqueous Flow Batteries.
Abstract not provided.
Investigation of Iron-and Organic-based Bipolar Redox Molecules for Non-aqueous Flow Batteries.
Abstract not provided.
Ultrafast Metal Electrodeposition Revealed by In Situ Optical Imaging and Theoretical Modeling towards Fast–Charging Zn Battery Chemistry
Metallic Zn is a preferred anode material for rechargeable aqueous batteries towards a smart grid and renewable energy storage. Importantly, understanding how the metal nucleates and grows at the aqueous Zn anode is a critical and challenging step to achieve full reversibility of Zn battery chemistry, especially under fast-charging conditions. Here, by combining in situ optical imaging and theoretical modeling, we uncover the critical parameters governing the electrodeposition stability of the metallic Zn electrode, that is, the competition among crystallographic thermodynamics, kinetics, and Zn 2+ -ion diffusion. Moreover, steady-state Zn metal plating/ stripping with Coulombic efficiency above 99 % is achieved at 10-100 mA cm -2 in a reasonably high concentration (3 M) ZnSO 4 electrolyte. Significantly, a long-term cycling-stable Zn metal electrode is realized with a depth of discharge of 66.7% under 50 mA cm -2 in both Zn || Zn symmetrical cells and MnO 2 || Zn full cells.
Physics-Guided Continual Learning for Predicting Emerging Aqueous Organic Redox Flow Battery Material Performance
Aqueous organic redox flow batteries (AORFBs) have gained popularity in renewable energy storage due to their low cost, environmental friendliness and scalability. The rapid discovery of aqueous soluble organic (ASO) redox-active materials necessitates efficient machine learning surrogates for predicting battery performance. The physics-guided continual learning (PGCL) method proposed in this study can incrementally learn data from new ASO electrolytes while addressing catastrophic forgetting issues in conventional machine learning. Using a AORFB database with a thousand potential materials generated by a 780 $\text{cm}^2$ interdigitated cell model, PGCL incorporates AORFB physics to optimize the continual learning task formation and training strategies to retain previously learned battery material knowledge. Finally, the trained PGCL demonstrates its capability in assessing emerging ASO materials within the established parameter space when evaluated with the dihydroxyphenazine isomers.
Aqueous redox flow batteries
The present invention provides an aqueous redox flow battery comprising a negative electrode immersed in an aqueous liquid negative electrolyte, a positive electrode immersed in an aqueous liquid positive electrolyte, and a cation-permeable separator between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise a redox reactant. Redox reactant of the positive electrolyte comprises a compound of Formula (I) as described in the specification.