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Structure and functions of simple membrane-water interfaces

The structure and functions of the earliest ancestors of contemporary cells are focal points in studies of the origin of life. Probably the first cell-like structures were vesicles - closed, spheroidal structures with aqueous medium trapped inside. The membranous walls of vesicles were most likely bilayers composed of simple amphiphilic material available on early earth. The membrane studied was composed of glycerol 1-monooleate (GMO). Glycerol forms the polar head group and the oily tail contains 18 carbon atoms. All head groups have been found to be located in two narrow regions at the interfaces with water. The membrane interior, formed by the hydrophobic tails, is quite fluid with chain disorder increasing towards the center of the bilayer. These results are in agreement with x-ray and neutron scattering data from related bilayers. The width of the membrane is not constant, but fluctuates in time and space. Occasional thinning defects in the membrane, observed during the course of the simulations, may have a significant influence on rates of passive transport of small molecules across membranes. It has been found that water penetrates the head group region but not the oily interior of the membrane. Water molecules near the interface are oriented by dipoles of the head groups. The resulting electrostatic potential across the interface, determined in our simulations, has been found to be markedly larger than across the water-oil interface. This quantity has been implicated as the source of selectivity, with respect to the sign of the charge, as an ion approaches the interface and during transport of hydrophobic ions across membranes.

Pohorille, A.↗

Physics of Granular Materials: Investigations in Support of Astrobiology

This publication list is submitted as a summary of the work conducted under Cooperative Agreement 1120. The goal of the 1120 research was to study granular materials within a planetary, astrophysical, and astrobiological context. This involved research on the physical, mechanical and electrostatic properties of granular systems, as well as the examination of these materials with atomic force microscopy and x-ray analysis. Instruments for analyzing said materials in planetary environments were developed, including the MECA (Mars Environment Compatibility Assessment) experiment for the MSP '01 lander, the ECHOS/MATADOR experiment for the MSP '03 lander, an ISRU experiment for the '03 lander, and MiniLEAP technology. Flight experiments for microgravity (Space Station and Shuttle) have also been developed for the study of granular materials. As expressed in the publications, work on 1120 encompassed laboratory research, theoretical modeling, field experiments, and flight experiments: a series of successful new models were developed for understanding the behavior of triboelectrostatically charged granular masses, and 4 separate instruments were selected for space flight. No inventions or patents were generated by the research under this Agreement.

Marshall, John R.↗

Overview of the Design, Development, and Application of Nickel-hydrogen Batteries

This document provides an overview of the design, development, and application of nickel-hydrogen (Ni-H2) battery technology for aerospace applications. It complements and updates the information presented in NASA RP-1314, NASA Handbook for Nickel- Hydrogen Batteries, published in 1993. Since that time, nickel-hydrogen batteries have become widely accepted for aerospace energy storage requirements and much more has been learned. The intent of this document is to capture some of that additional knowledge. This document addresses various aspects of nickel-hydrogen technology including the electrochemical reactions, cell component design, and selection considerations; overall cell and battery design considerations; charge control considerations; and manufacturing issues that have surfaced over the years that nickel-hydrogen battery technology has been the major energy storage technology for geosynchronous and low-Earth-orbiting satellites.

Thaller, Lawrence H.↗

Material Development of Faraday Cup Grids for the Solar Probe Plus Mission

The Solar Probe Plus mission will launch a spacecraft to the Sun to study it's outer atmosphere. One of the instruments on board will be a Faraday Cup (FC) sensor. The FC will determine solar wind properties by measuring the current produced by ions striking a metal collector plate. It will be directly exposed to the Sun and will be subject to the temperature and radiation environment that exist within 10 solar radii. Conducting grids within the FC are biased up to 10 kV and are used to selectively transmit particles based on their energy to charge ratio. We report on the development of SiC grids. Tests were done on nitrogen-doped SiC starting disks obtained from several vendors, including annealing under vacuum at 1400 C and measurement of their electrical properties. SiC grids were manufactured using a photolithographic and plasma-etching process. The grids were incorporated into a prototype FC and tested in a simulated solar wind chamber. The energy cutoffs were measured for both proton and electron fluxes and met the anticipated sensor requirements.

Volz, M. P.↗

Heliophysics from and of the Moon - the Solar Occultation Explorer (SOX)

The fundamental processes of the inner corona of the Sun at 1.1 to 3 solar radii can occasionally be investigated in detail by ground-based solar eclipse observations at quasi-yearly intervals. The combination of portable ground-based telescopes and the distant occulting edge provided by the lunar limb allows imaging of coronal structure and ion excitation emission lines at the highest available spatial and spectral resolution. These observations are limited to the visible eastern and western coronal regions and cannot view the intervening region over the central disk in the hemisphere towards Earth. A comparable configuration for continuous coronal observations from a spacecraft, e.g. with an external occulter disk on a 100-meter boom, is conceivable and could generate 3-D data models of the corona via tomographic reconstruction from time series measurements but may not now be technically or economically feasible. The faster and cheaper approach would be to make high cadence eclipse observations from one or more small satellites in lunar orbit. The Solar Occultation Explorer (SOX) is suggested as an explorer-class NASA mission that would conduct eclipse observations at daily to hourly cadence depending on the orbit. This smallsat would carry two principal instrument suites: (1 ) spectroscopic imaging telescope with sub-nm resolution for selected coronal emission lines diagnostic of coronal plasma charge state, denSity, and temperature, and (2) in-situ field & particle instrument suite for measurements of the solar wind and local lunar environments. The most comparable flight heritage instrument, the LASCO C1 spectrometer on the Solar and Heliospheric Observatory (SOHO) mission, did achieve high visible-band spectral resolution with a Fabry-Perot interferometer but was limited in brightness sensitivity by usage of an internal occulter system and has not been operational since June 1998 The SOX mission concept is undergoing initial study by the Lunar Solar Origins Exploration (LunaSOX) project of the NASA Lunar Advanced Science and Exploration Research (LASER) program. This mission would offer high complementarity with the planned Solar Probe Plus spacecraft, designed to investigate.

Cooper, John F.↗

Charge state distributions of oxygen and carbon in the energy range 1 to 300 keV/e observed with AMPTE/CCE in the magnetosphere

Observations of charge state distributions of oxygen and carbon are presented that were obtained with the charge-energy-mass spectrometer onboard the AMPTE/CCE spacecraft. Data were selected for two different local time sectors (apogee at 1300 LT and 0300 LT, respectively), three L-ranges (4-6, 6-8, and greater than 8), and quiet to moderately disturbed days (Kp less than or equal to 4). The charge state distributions reveal the existence of all charge states of oxygen and carbon in the magnetosphere. The relative importance of the different charge states strongly depends on L and much less on local time. The observations confirm that the solar wind and the ionosphere contribute to the oxygen population, whereas carbon only originates from the solar wind. The L-dependence of the charge state distributions can be interpreted in terms of these different ion sources and of charge exchange and diffusion processes that largely influence the distribution of oxygen and carbon in the magnetosphere.

Kremser, G.↗

Superconducting energy storage magnet

A superconducting magnet is formed having composite conductors arrayed in coils having turns which lie on a surface defining substantially a frustum of a cone. The conical angle with respect to the central axis is preferably selected such that the magnetic pressure on the coil at the widest portion of the cone is substantially zero. The magnet structure is adapted for use as an energy storage magnet mounted in an earthen trench or tunnel where the strength the surrounding soil is lower at the top of the trench or tunnel than at the bottom. The composite conductor may be formed having a ripple shape to minimize stresses during charge up and discharge and has a shape for each ripple selected such that the conductor undergoes a minimum amount of bending during the charge and discharge cycle. By minimizing bending, the working of the normal conductor in the composite conductor is minimized, thereby reducing the increase in resistance of the normal conductor that occurs over time as the conductor undergoes bending during numerous charge and discharge cycles.

Boom, Roger W.↗

The Crimean Solar Maximum Year Workshop, selected reports

Problems associated with the transport of energy and acceleration of charged particles in solar flares are considered. Existing theories are compared with observation with a view to either discriminating between rival theories (such as whether hard X-rays are emitted by thermal or nonthermal bremsstrahlung), constraining existing theories (such as deduction of the number of nonthermal electrons present from spectroscopic diagnostics in the soft X-ray part of the spectrum), or suggesting theories (such as attempting to explain the observed spatial structure of microwave emission relative to alpha).

Emslie, A. G.↗

Ionene polymers for selectively inhibiting the vitro growth of malignant cells

Ionene polymers of the structure ##STR1## WHERE X AND Y ARE INTEGERS FROM 3 TO 16, Z.sup.- is an anion such as a halogen and n is an integer from 50 to 150 are found to bind negatively charged mammalian cells such as malignant cells and can be utilized to selectively inhibit the growth of malignant cells in vitro.

Rembaum, Alan↗

Selectable-Tip Corrosion-Testing Electrochemical Cell

The figure depicts aspects of an electrochemical cell for pitting- corrosion tests of material specimens. The cell is designed to generate a region of corrosion having a pit diameter determined by the diameter of a selectable tip. The average depth of corrosion is controlled by controlling the total electric charge passing through the cell in a test. The cell is also designed to produce minimal artifacts associated with crevice corrosion. There are three selectable tips, having diameters of 0.1 in. (0.254 cm), 0.3 in. (0.762 cm), and 0.6 in. (1.524 cm), respectively.

Lomness, Janice↗

Multi-color imaging of selected southern interacting galaxies

The authors present preliminary results from a study of selected Arp-Madore Southern Hemisphere peculiar galaxies. Broadband charge coupled device (CCD) images (BVRI) of a subset of these galaxies allow us to study each galaxy's optical morphology, color, and (in a crude manner) degree of nuclear activity, and to compare them with similar data we possess on other active galaxies. Many of these galaxies have optical morphologies closely resembling those of powerful radio galaxies (Smith and Heckman 1989), yet their radio emission is unremarkable. Accurate positions for subsequent spectroscopic studies have been determined along with broad band photometry and morphology studies. Detailed observations of these comparatively bright, low-redshift, well-resolved interacting systems should aid our understanding of the role interactions play in triggering galaxy activity. This work is the initial effort in a long term project to study the role played by the dynamics of the interaction in the production and manifestations of activity in galaxies, and the frequency of galaxy mergers.

Smith, Eric P.↗

A High-Speed, Event-Driven, Active Pixel Sensor Readout for Photon-Counting Microchannel Plate Detectors

Silicon array readouts for microchannel plate intensifiers offer several attractive features. In this class of detector, the electron cloud output of the MCP intensifier is converted to visible light by a phosphor; that light is then fiber-optically coupled to the silicon array. In photon-counting mode, the resulting light splashes on the silicon array are recognized and centroided to fractional pixel accuracy by off-chip electronics. This process can result in very high (MCP-limited) spatial resolution for the readout while operating at a modest MCP gain (desirable for dynamic range and long term stability). The principal limitation of intensified CCD systems of this type is their severely limited local dynamic range, as accurate photon counting is achieved only if there are not overlapping event splashes within the frame time of the device. This problem can be ameliorated somewhat by processing events only in pre-selected windows of interest or by using an addressable charge injection device (CID) for the readout array. We are currently pursuing the development of an intriguing alternative readout concept based on using an event-driven CMOS Active Pixel Sensor. APS technology permits the incorporation of discriminator circuitry within each pixel. When coupled with suitable CMOS logic outside the array area, the discriminator circuitry can be used to trigger the readout of small sub-array windows only when and where an event splash has been detected, completely eliminating the local dynamic range problem, while achieving a high global count rate capability and maintaining high spatial resolution. We elaborate on this concept and present our progress toward implementing an event-driven APS readout.

Kimble, Randy A.↗

A High-Speed, Event-Driven, Active Pixel Sensor Readout for Photon-Counting Microchannel Plate Detectors

Silicon array readouts for microchannel plate intensifiers offer several attractive features. In this class of detector, the electron cloud output of the MCP intensifier is converted to visible light by a phosphor; that light is then fiber-optically coupled to the silicon array. In photon-counting mode, the resulting light splashes on the silicon array are recognized and centroided to fractional pixel accuracy by off-chip electronics. This process can result in very high (MCP-limited) spatial resolution while operating at a modest MCP gain (desirable for dynamic range and long term stability). The principal limitation of intensified CCD systems of this type is their severely limited local dynamic range, as accurate photon counting is achieved only if there are not overlapping event splashes within the frame time of the device. This problem can be ameliorated somewhat by processing events only in pre-selected windows of interest of by using an addressable charge injection device (CID) for the readout array. We are currently pursuing the development of an intriguing alternative readout concept based on using an event-driven CMOS Active Pixel Sensor. APS technology permits the incorporation of discriminator circuitry within each pixel. When coupled with suitable CMOS logic outside the array area, the discriminator circuitry can be used to trigger the readout of small sub-array windows only when and where an event splash has been detected, completely eliminating the local dynamic range problem, while achieving a high global count rate capability and maintaining high spatial resolution. We elaborate on this concept and present our progress toward implementing an event-driven APS readout.

Kimble, Randy A.↗

An APL program for the distribution of energy deposition by charged particles passing through thin absorbers

An APL program which numerically evaluates the probability density function (PDF) for the energy deposited in a thin absorber by a charged particle is proposed, with application to the construction, pointing, and control of spacecraft. With this program, the PDF of the restricted energy loss distribution of Watts (1973) is derived, and Vavilov's (1957) distribution is obtained by proper parameter selection. The method is demonstrated with the example of the effect of charged particle induced radiation on the Hubble Space Telescope (HST) pointing accuracy. A Monte Carlo study simulates the photon noise caused by charged particles passing through the photomultiplier tube window, and the stochastic variation of energy loss is introduced into the simulation by generating random energy losses from a power law distribution. The program eliminates annoying loop procedures, and model parameter sensitivity can be studied using the graphical output.

Howell, L. W.↗

The Generation of Lighting in the Solar Nebula

The process that melted and formed the chondrules, mm-sized glassy beads within meteorites, has not been conclusively identified. Origin by lightning in the solar nebula is consistent with many features of chondrules, but no viable model of lightning has yet been advanced. We present a model demonstrating how lightning could be generated in the solar nebula which differs from previous models in three important aspects. First, we identify a new', powerful charging mechanism that is based on the differences in contact potentials between particles of different composition, a form of triboelectric charging. In the presence of fine silicate grains and fine iron metal grains, large silicate particles (the chondrules) can acquire charges of +10(exp 5) e. Second, we assume that the chondrule precursor particles are selectively concentrated in clumps 1 - 100 km in size by the turbulent concentration mechanism described by Cuzzi et al. (1996). The concentration of these highly charged particles into clumps, in a background of negatively charged metal grains, is what generates the strong electric fields. Third, we make refinements in the estimates of the breakdown electric field and the ionization rate. We calculate that electric fields large enough to trigger breakdown easily could have existed over regions large enough (approx. 100km) to generate very large discharges of electrical energy (approx. 10(exp 16)erg). The discharges would have been sufficiently energetic and frequent to have formed the chondrules. We place constraints on the generation of lightning and conclude that it could not be generated if the abundance of Al-26 in chondrules was as high as the level in the CAls. This conclusion is consistent with isotopic analyses of chondrules. This possibly implies that Al-26 was non-uniformly distributed in the solar nebula or that the chondrules formed several Myr after the CAIs.

Cuzzi, Jeffrey↗

Some characteristic features of the construction of the amplifying channel for working with semiconductor detectors in the charged particle energy spectrometer

A transistorized spectrometric amplifier with a shaper is reported that selects the shape of the frequency characteristic of the amplifying channel for which the primary frequency spectrum of the signal will pass, but where the noise spectrum is limited to the maximum. A procedure is presented for selecting the shaping circuits and their inclusion principles.

Kuzyuta, E. I.↗

Improved Signal Chains for Readout of CMOS Imagers

An improved generic design has been devised for implementing signal chains involved in readout from complementary metal oxide/semiconductor (CMOS) image sensors and for other readout integrated circuits (ICs) that perform equivalent functions. The design applies to any such IC in which output signal charges from the pixels in a given row are transferred simultaneously into sampling capacitors at the bottoms of the columns, then voltages representing individual pixel charges are read out in sequence by sequentially turning on column-selecting field-effect transistors (FETs) in synchronism with source-follower- or operational-amplifier-based amplifier circuits. The improved design affords the best features of prior source-follower-and operational- amplifier-based designs while overcoming the major limitations of those designs. The limitations can be summarized as follows: a) For a source-follower-based signal chain, the ohmic voltage drop associated with DC bias current flowing through the column-selection FET causes unacceptable voltage offset, nonlinearity, and reduced small-signal gain. b) For an operational-amplifier-based signal chain, the required bias current and the output noise increase superlinearly with size of the pixel array because of a corresponding increase in the effective capacitance of the row bus used to couple the sampled column charges to the operational amplifier. The effect of the bus capacitance is to simultaneously slow down the readout circuit and increase noise through the Miller effect.

Pain, Bedabrata↗