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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Ocean chlorophyll studies from a U-2 aircraft platform

Chlorophyll gradient maps of large ocean areas were generated from U-2/OCS data obtained over test sites in the Pacific and the Atlantic Oceans. The delineation of oceanic features using the upward radiant intensity relies on an analysis method which presupposes that radiation backscattered from the atmosphere and the ocean surface can be properly modeled by using a measurement made at 778 nm. The calculation of atmospheric radiance was performed by using a method developed by Dave. An estimation of the chlorophyll concentration is performed by properly ratioing radiances measured at 472 and 548 nm after removing the atmospheric effects. The correlation between the remotely sensed data and the in situ surface chlorophyll measurements has been validated in two sets of data. The results show that the correlation between the in situ measured chlorophyll and the derived quantity is a negative exponential function, and the correlation coefficient was calculated to be -0.965.

Kim, H. H.↗
NASA NTRS1981

Analysis of testbed airborne multispectral scanner data from Superflux II

A test bed aircraft multispectral scanner (TBAMS) was flown during the James Shelf, Plume Scan, and Chesapeake Bay missions as part of the Superflux 2 experiment. Excellent correlations were obtained between water sample measurements of chlorophyll and sediment and TBAMS radiance data. The three-band algorithms used were insensitive to aircraft altitude and varying atmospheric conditions. This was particularly fortunate due to the hazy conditions during most of the experiments. A contour map of sediment, and also chlorophyll, was derived for the Chesapeake Bay plume along the southern Virginia-Carolina coastline. A sediment maximum occurs about 5 nautical miles off the Virginia Beach coast with a chlorophyll maximum slightly shoreward of this. During the James Shelf mission, a thermal anomaly (or front) was encountered about 50 miles from the coast. There was a minor variation in chlorophyll and sediment across the boundary. During the Chesapeake Bay mission, the Sun elevation increased from 50 degrees to over 70 degrees, interfering with the generation of data products.

Bowker, D. E.↗
NASA NTRS1999

New Chemical, Bio-Optical and Physical Observations of Upper Ocean Response to the Passage of a Mesoscale Eddy Off Bermuda

A mesoscale eddy advected across the Bermuda Testbed Mooring site over a 30-day period centered on July 14, 1995. Temperature and current measurements along with biogeochemical measurements were used to characterize the biological response of the upper ocean associated with the introduction of nitrate into the euphotic layer due to the doming of isotherms associated with the eddy. Complementary shipboard data showed an anomalous water mass, which extended from a depth of approximately 50 to 1000 m, manifesting as a cold surface expression and warm anomaly at depth. Although mesoscale eddies are frequently observed in the Sargasso Sea, the present observations are particularly unique because of the high-temporal-resolution measurements of the new instrumentation deployed on the mooring. Analyzers that measure nitrate plus nitrite were placed at depths of 80 and 200 m and bio-optical sensors were located at depths of 20, 35, 45, 71, and 86 m. Peak nitrate values of nearly 3.0 micro-M at 80 m and chlorophyll a values of 1.4 mg/cubic m at 71 m were observed, a well as a 25- to 30-meter shoaling of the 1% light level depth. A Doppler shift from the inertial period (22.8 hours) to 25.2 hours was observed in several time series records due to the movement of the eddy across the mooring. Inertial pumping brought cold, nutrient-rich waters farther into the euphotic zone than would occur solely by isothermal lifting. Silicic acid was depleted to undetectable levels owing to the growth of diatoms within the eddy. The chlorophyll a values associated with the eddy appear to be the largest recorded during the eight years of the ongoing US JGOFS Bermuda Atlantic Time Series Study program.

McNeil, J. D.↗
NASA NTRS2023

Leaf Functional Traits in Relation to Species Composition in an Arctic–Alpine Tundra Grassland

The relict arctic–alpine tundra provides a natural laboratory to study the potential impacts of climate change and anthropogenic disturbance on tundra vegetation. The Nardus stricta-dominated relict tundra grasslands in the Krkonoše Mountains have experienced shifting species dynamics over the past few decades. Changes in species cover of the four competing grasses—Nardus stricta, Calamagrostis villosa, Molinia caerulea, and Deschampsia cespitosa—were successfully detected using orthophotos. Leaf functional traits (anatomy/morphology, element accumulation, leaf pigments, and phenolic compound profiles), were examined in combination with in situ chlorophyll fluorescence in order to shed light on their respective spatial expansions and retreats. Our results suggest a diverse phenolic profile in combination with early leaf expansion and pigment accumulation has aided the expansion of C. villosa, while microhabitats may drive the expansion and decline of D. cespitosa in different areas of the grassland. N. stricta—the dominant species—is retreating, while M. caerulea did not demonstrate significant changes in territory between 2012 and 2018. We propose that the seasonal dynamics of pigment accumulation and canopy formation are important factors when assessing potential “spreader” species and recommend that phenology be taken into account when monitoring grass species using remote sensing.

Lena Hunt↗
NASA NTRS1999

New Chemical, Bio-Optical and Physical Observations of Upper Ocean Response to the Passage of a Mesoscale Eddy off Bermuda

A mesoscale eddy advected across the Bermuda Testbed Mooring site over a 30-day period centered on July 14, 1995. Temperature and current measurements along with biogeochemical measurements were used to characterize the biological response of the upper ocean associated with the introduction of nitrate into the euphoric layer due to the doming of isotherms associated with the eddy. Complementary shipboard data showed an anomalous water mass, which extended from a depth of approximately 50 to 1000 m, manifesting as a cold surface expression and warm anomaly at depth. Although mesoscale eddies are frequently observed in the Sargasso Sea, the present observations are particularly unique because of the high-temporal-resolution measurements of the new instrumentation deployed on the mooring. Analyzers that measure nitrate plus nitrite were placed at depths of 80 and 200 m and bio-optical sensors were located at depths of 20, 35, 45, 71, and 86 m. Peak nitrate values of nearly 3.0 microns at 80 m and chlorophyll alpha values of 1.4 mg/cu m at 71 m were observed, as well as a 25- to 30-meter shoaling of the 1% light level depth. A Doppler shift from the inertial period (22.8 hours) to 25.2 hours was observed in several time series records due to the movement of the eddy across the mooring. Inertial pumping brought cold, nutrient-rich waters farther into the euphotic zone than would occur solely by isothermal lifting. Silicic acid was depleted to undetectable levels owing to the growth of diatoms within the eddy. The chlorophyll alpha values associated with the eddy appear to be the largest recorded during the 8 years of the ongoing U.S. JGOFS Bermuda Atlantic Time Series Study (BATS) program.

McNeil, J. D.↗
NASA NTRS1996

Response of Two Plant Species to Two Ultraviolet-B Radiation Regimes

The depleted stratospheric ozone layer has been directly linked to increased levels of ultraviolet radiation at the earth's surface. It is important to understand what effect this will have on plants. We tested the hypothesis that in response to increased UV-B radiation (280-320 man), soybean (Glycine max Merrill) and alfalfa (Mercado Saliva L.) would produce higher concentrations of flavonoids than plants screened from UV-B. Soybean and alfalfa plants were grown successively in a growth chamber that provided UV-B radiation intensities 45% above summer field levels. A wooden frame was used to suspend mylar-D film over one group of plants and mono-acetate film over another group. Mylar is opaque in the 280-316 nm range, and acetate absorbs most radiation from 280-290 nm and then reduces intensities in the 290-320 nm range by roughly 15%. Leaf chlorophyll concentration was determined with a Minolta SPAD-502 chlorophyll meter; the BRAD meter was calibrated with N,N- extractions. Flavonoids were extracted with an acidified methanol/water solution. Soybean grown under the acetate treatment showed 26% smaller internodal lengths and higher concentrations of flavonoids compared to plants grown under mylar. Significant results for alfalfa included 22% greater leaf flavonoid concentration under acetate, 14% greater leaf chlorophyll concentration under mylar, and 32% greater above-ground biomass under mylar. We found that increased UV-B radiation leads to increased production of UV-B absorbing compounds (i.e. flavonoids) in soybean and alfalfa leaves. This suggests that a protective mechanism in these plants is triggered by UV-B. In response, flavonoids are produced that absorb UV-B, and consequently decrease potentially damaging effects to the plants. In addition, we hypothesize that this flavonoid protection mechanism saturates at certain UV-B intensities.

Levy, Daniel L.↗
NASA NTRS2001

The First SeaWiFS HPLC Analysis Round-Robin Experiment (SeaHARRE-1)

Four laboratories, which had contributed to various aspects of SeaWiFS calibration and validation activities, participated in the first SeaWiFS HPLC Analysis Round-Robin Experiment (SeaHARRE-1): Horn Point Laboratory (USA), the Joint Research Centre (Italy), the Laboratoire de Physique et Chimie Marines (France), and the Marine and Coastal Management group (South Africa). The analyses of the data are presented in Chapter 1 and the individual methods of the four groups are presented in Chapters 2-5. The average (or overall) conclusions of the round-robin are derived from 12 in situ stations occupied during a cruise in the Mediterranean Sea, although, only 11 stations are used in the analyses. The data set is composed of 12 replicates taken during each sampling opportunity with 3 replicates going to each of the 4 laboratories. The average (or overall) results from the intercomparison of 15 pigments or pigment associations are as follows (in some cases, data subsets that exclude pigments which were not analyzed by all the laboratories, or that had unusually large variances, are used to exclude a variety of problematic pigments): a) the accuracy of the four methods in determining the concentration of total chlorophyll a is 7.9%, (one method did not separate mono- and divinyl chlorophyll a, and if the samples containing significant divinyl chlorophyll a concentrations are ignored, the four methods have an accuracy of 6.7%); b) the accuracy in determining the full set of pigments is 19.1%; c) there is a reduction in accuracy of approximately - 12.2% for every decade (factor of 10) decrease in concentration (based on a data subset); d) the precision of the four methods using a subset data is 8.617( 6.2% for an edited subset); e) the repeatability of the four methods using the subset data is 9.2% (7.2%; for an edited subset, and f) the reproducibility of the four methods using the subset data is 21.31% (15.0% for an edited subset).

Hooker, Stanford B.↗
NASA NTRS2005

An Agent-Based Interface to Terrestrial Ecological Forecasting

The latest generation of NASA Earth Observing System (EOS) satellites has brought a new dimension to continuous monitoring of the living part of the Earth System, the biosphere. EOS data can now provide weekly global measures of vegetation productivity and ocean chlorophyll, and many related biophysical factors such as land cover changes or snowmelt rates. However, the highest economic value would come from forecasting impending conditions of the biosphere, to allow decision makers to mitigate dangers or exploit positive trends. NASA's strategic plan for the Earth Science Enterprise i d e n a s ecological forecasting as a focus for research. Ecological forecasting predicts the effects of changes in the physical, chemical and biological environment on ecosystem activity. Possible applications of such a system include predicting shortfalls or bumper crops of agricultural production, populations of threatened or invasive species or wildfire danger in time to allow improves preparation and logistical efficiency. Petabytes of remote sensing data are now available to help measure, understand and forecast changes in the Earth system, but using these data effectively can be surprisingly hard. The volume and variety of data files and formats are daunting. Simple data management activities, such as locating and transferring files, changing file formats, gridding point data, and scaling and reprojecting gridded data, can consume far more personnel time and resources than the actual data analysis. Some scientists commit to a particular data source or resolution just because using anything different would be more effort that it's worth. Better tools can help, but most of the tools developed to date are little more than shell scripts; they lack the flexibility to meet the diverse needs of users and are difficult to extend to handle changes in available data sources.

Golden, Keith↗
DOE OSTI2025

Temporal Study 2022-2024: Sensor-Based Time Series of Surface Water Temperature, Specific Conductance, Total Dissolved Solids, Turbidity, Chlorophyll A, and Dissolved Oxygen from across Multiple Watersheds in the Yakima River Basin in Washington, USA

This dataset supports a broader study examining the drivers of temporal variability in sediment respiration rates in the Yakima River Basin. The dataset provides periodic (bi-weekly or monthly) in situ hydrological and water chemistry sensor data, handheld sensor water chemistry data, general environmental context photos, and field metadata collected at six sites across the Yakima River Basin in Washington, USA. Sample and sensor data from previous years (2021-2022) can be found at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/1898912 and https://data.ess-dive.lbl.gov/datasets/doi:10.15485/1892054, respectively. Related sample data from 2022-2024 are available at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/2562910. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions This dataset contains a folder of environmental context photographs and videos and (1) file-level metadata; (2) data dictionary; (3) readme; (4) field metadata; (5) field protocols; (6) international generic sample number (IGSN) mapping file; (7) handheld sensor data; and (8) two sensor subfolders. Each sensor subfolder (BarotrollAtm and MantaRiverData) contains a subfolder containing sensor time series data and plots. The BarotrollAtm Data subfolder contains In Situ Rugged BaroTROLL sensor pressure and air temperature data. The MantaRiverData subfolder contains Eureka Manta+ 35B multisonde temperature, specific conductance, and chlorophyll A. All files are .csv, .pdf, .jpg, .jpeg, .mp4, .png, or .mov.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2001

Results of the Second SeaWiFS Data Analysis Round Robin, March 2000 (DARR-00)

The accurate determination of upper ocean apparent optical properties (AOPs) is essential for the vicarious calibration of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) instrument and the validation of the derived data products. To evaluate the importance of data analysis methods upon derived AOP values, the Second Data Analysis Round Robin (DARR-00) activity was planned during the latter half of 1999 and executed during March 2000. The focus of the study was the intercomparison of several standard AOP parameters: (1) the upwelled radiance immediately below the sea surface, L(sub u)(0(-),lambda); (2) the downward irradiance immediately below the sea surface, E(sub d)(0(-),lambda); (3) the diffuse attenuation coefficients from the upwelling radiance and the downward irradiance profiles, L(sub L)(lambda) and K(sub d)(lambda), respectively; (4) the incident solar irradiance immediately above the sea surface, E(sub d)(0(+),lambda); (5) the remote sensing reflectance, R(sub rs)(lambda); (6) the normalized water-leaving radiance, [L(sub W)(lambda)](sub N); (7) the upward irradiance immediately below the sea surface, E(sub u)(0(-)), which is used with the upwelled radiance to derive the nadir Q-factor immediately below the sea surface, Q(sub n)(0(-),lambda); and (8) ancillary parameters like the solar zenith angle, theta, and the total chlorophyll concentration, C(sub Ta), derived from the optical data through statistical algorithms. In the results reported here, different methodologies from three research groups were applied to an identical set of 40 multispectral casts in order to evaluate the degree to which differences in data analysis methods influence AOP estimation, and whether any general improvements can be made. The overall results of DARR-00 are presented in Chapter 1 and the individual methods used by the three groups and their data processors are presented in Chapters 2-4.

Hooker, Stanford B.↗
NASA NTRS1983

Remote sensing of sediment and chlorophyll with the test-bed aircraft multispectral scanner

An instrument known as the test-bed aircraft multispectral scanner (TBAMS) was used in a research flight over the entrance to the Chesapeake Bay. Upwelled radiances from the TBAMS data were correlated with the water parameters, particularly sediment and chlorophyll a. Several algorithms were demonstrated for monitoring sediment and chlorophyll, with a three-band ratio being the best. The primary advantage of the three-band ratio was found to be its apparent insensitivity to atmospheric and Sun-angle variations.

Bowker, D. E.↗
NASA NTRS1980

Remote sensing of benthic microalgal biomass with a tower-mounted multispectral scanner

A remote sensing instrument was mounted on a 50-ft tower overlooking North Inlet Estuary, South Carolina in order to conduct a remote sensing study of benthic microalgae. The instrument was programmed to take multispectral imagery data along a 90 deg horizontal frame in six spectral bands ranging from 400-1050 nm and had a ground resolution of about 3 cm. Imagery measurements were encoded in digital form on magnetic tape and were stored, decoded, and manipulated by computer. Correlation coefficients were calculated on imagery data and chlorophyll a concentrations derived from ground truth data. The most significant correlation occurred in the blue spectral band with numerical values ranging from -0.81 to -0.88 for three separate sampling periods. Mean values of chlorophyll a for a larger section of mudflat were estimated using regression equations. The scanner has provided encouraging results and promises to be a useful tool in sampling the biomass of intertidal benthic microalgae.

Jobson, D. J.↗
NASA NTRS2000

SeaWiFS Postlaunch Calibration and Validation Analyses

The effort to resolve data quality issues and improve on the initial data evaluation methodologies of the SeaWiFS Project was an extensive one. These evaluations have resulted, to date, in three major reprocessings of the entire data set where each reprocessing addressed the data quality issues that could be identified up to the time of the reprocessing. Three volumes of the SeaWiFS Postlaunch Technical Report Series (Volumes 9, 10, and 11) are needed to document the improvements implemented since launch. Volume 10 continues the sequential presentation of postlaunch data analysis and algorithm descriptions begun in Volume 9. Chapter 1 of Volume 10 describes an absorbing aerosol index, similar to that produced by the Total Ozone Mapping Spectrometer (TOMS) Project, which is used to flag pixels contaminated by absorbing aerosols, such as, dust and smoke. Chapter 2 discusses the algorithm being used to remove SeaWiFS out-of-band radiance from the water-leaving radiances. Chapter 3 provides an itemization of all significant changes in the processing algorithms for each of the first three reprocessings. Chapter 4 shows the time series of global clear water and deep-water (depths greater than 1,000m) bio-optical and atmospheric properties (normalized water-leaving radiances, chlorophyll, atmospheric optical depth, etc.) based on the eight-day composites as a check on the sensor calibration stability. Chapter 5 examines the variation in the derived products with scan angle using high resolution data around Hawaii to test for residual scan modulation effects and atmospheric correction biases. Chapter 6 provides a methodology for evaluating the atmospheric correction algorithm and atmospheric derived products using ground-based observations. Similarly, Chapter 7 presents match-up comparisons of coincident satellite and in situ data to determine the accuracy of the water-leaving radiances, chlorophyll a, and K(490) products.

Hooker, Stanford B.↗
DOE OSTI2021

Unpacking the drivers of diurnal dynamics of sun-induced chlorophyll fluorescence (SIF): Canopy structure, plant physiology, instrument configuration and retrieval methods

Sun-induced chlorophyll fluorescence (SIF) from spaceborne sensors is a promising tool for global carbon cycle monitoring, but its application is constrained by insufficient understanding of the drivers underlying diurnal SIF dynamics. SIF measurements from ground-based towers can reveal diurnal SIF dynamics across biomes and environmental conditions; however, meaningful interpretation of diurnal variations requires disentangling impacts from canopy structure, plant physiology, instrument configuration and retrieval methods, which often interact with and confound each other. This study aims to unpack these drivers using 1) concurrent ground and airborne canopy-scale and leaf-scale measurements at a corn field, 2) a mechanistic SIF model that explicitly considers the dynamics of photochemistry (via the fraction of open photosystem II reaction centers, qL) and photoprotection (via nonphotochemical quenching, NPQ) as well as their interactive dependence on the sub-canopy light environment, and 3) cross-comparison of SIF instrument configurations and retrieval methods. We found that crop row orientations and sun angles can introduce a distinctive midday dip in SIF in absence of stress, due to a midday drop of absorbed photosynthetically active radiation (APAR) when crop rows are north-south oriented. Canopy structure caused distinctive responses in both qL and NPQ at different positions within the vertical canopy that collectively influenced fluorescence quantum yield (Φ F ) at the leaf scale. Once integrated at the canopy scale, diurnal dynamics of both APAR and canopy escape probability (ε) are critical for accurately shaping diurnal SIF variations. While leaf-level qL and NPQ exhibited strong diurnal dynamics, their influence was attenuated at the canopy scale due to opposing effects on SIF at different canopy layers. Furthermore, different system configurations (i.e., bi-hemispherical vs. hemispherical-conical) and retrieval methods can bias the SIF magnitude and distort its diurnal shapes, therefore confounding the interpretation of inherent strength and dynamics of SIF emission. Our findings demonstrate the importance of crop row structures, interactive variations in canopy structure and plant physiology, instrument configuration, and retrieval method in shaping the measured dynamics of diurnal SIF. This study highlights the necessity to account for these factors to accurately interpret satellite SIF, and informs future synthesis work with different SIF instrumentation and retrieval methods across sites.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Structure of a dimeric photosystem II complex from a cyanobacterium acclimated to far-red light

Photosystem II (PSII) is the water-splitting enzyme central to oxygenic photosynthesis. To drive water oxidation, light is harvested by accessory pigments, mostly chlorophyll (Chl) a molecules, which absorb visible light (400–700 nm). Some cyanobacteria facultatively acclimate to shaded environments by altering their photosynthetic machinery to additionally absorb far-red light (FRL, 700–800 nm), a process termed far-red light photoacclimation or FaRLiP. During far-red light photoacclimation, FRL-PSII is assembled with FRL-specific isoforms of the subunits PsbA, PsbB, PsbC, PsbD, and PsbH, and some Chl-binding sites contain Chls d or f instead of the usual Chl a. The structure of an apo-FRL-PSII monomer lacking the FRL-specific PsbH subunit has previously been determined, but visualization of the dimeric complex has remained elusive. Here, we report the cryo-EM structure of a dimeric FRL–PSII complex. The site assignments for Chls d and f are consistent with those assigned in the previous apo-FRL-PSII monomeric structure. All sites that bind Chl d or Chl f at high occupancy exhibit a FRL-specific interaction of the formyl moiety of the Chl d or Chl f with the protein environment, which in some cases involves a phenylalanine sidechain. The structure retains the FRL-specific PsbH2 subunit, which appears to alter the energetic landscape of FRL-PSII, redirecting energy transfer from the phycobiliprotein complex to a Chl f molecule bound by PsbB2 that acts as a bridge for energy transfer to the electron transfer chain. Collectively, these observations extend our previous understanding of the structure-function relationship that allows PSII to function using lower energy FRL.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1975

Shortgrass prairie spectral measurements

The spectral methods of vegetation analysis not only measure herbage biomass on a nondestructive basis but also can be adapted to aircraft and satellite devices to map the spatial distribution over an area in an efficient and economical fashion. This study reviews the ground-based in situ field spectrometry in the 0.350-0.800 micron region of the spectrum. A statistical analysis of in situ spectroreflectance data from sample plots of the shortgrass prairie shows that green biomass, chlorophyll concentration, and leaf water content are directly interrelated to that composite property of the plot which is called functioning green biomass. Spectrocorrelation data indicate the spectral regions of optimum sensitivity for a remote estimation of the green biomass, chlorophyll, and leaf water content. The near-infrared region of the spectrum shows a high positive spectrocorrelation to these three sample parameters, regardless of the amount of standing dead vegetation.

Tucker, C. J.↗
DOE OSTI2021

D-Band EPR and ENDOR Spectroscopy of 15 N-Labeled Photosystem I

For billions of years, nature has optimized the photosynthetic machinery that converts light energy into chemical energy. Key primary reactions of photosynthesis occur in large membrane protein-cofactor complexes. The light-induced sequential electron transfer reactions occur through a chain of donor/acceptor cofactors embedded in the protein matrix resulting in a long-lived transmembrane charge-separated state. EPR is the method of choice to study electron transfer and the interaction of protein environment with redox-active cofactors. However, the spectra of organic cofactor radicals typically are not fully resolved and severely overlap at conventional X-band EPR. Even at Q-band EPR, this overlap is present and often a serious problem. As a result, there is a large variation of the reported EPR data and limited understanding of electronic structures of several redox-active cofactors. These serious problems can often be overcome by the excellent spectral resolution provided by high-frequency EPR (HF EPR). In this work, we study the electronic structure of the primary electron donor P 700 and the secondary electron acceptor A 1 of Photosystem I (PSI) using 130 GHz (D-band) EPR and Electron-Nuclear-Double-Resonance (ENDOR) spectroscopy. PSI was isotopically labeled with 15 N (I = $\frac{1/2}$) to avoid quadrupolar interactions in the most abundant nitrogen isotope 14 N (I = 1) and simplify the ENDOR spectra. ENDOR spectroscopy is central for determining the hyperfine coupling of nitrogen atoms of the two chlorophyll molecules comprising oxidized P 700 and the involvement of protein nitrogen atoms with reduced A 1 . While HF ENDOR of A 1 - allows identification of two nitrogen atoms, HF ENDOR of P 700 + still does not permit unique assignment of the recorded hyperfine couplings.

15N↗
NASA NTRS1982

Reflectance measurements of cotton leaf senescence altered by mepiquat chloride

Spectrophotometric reflectance measurements were made on plant-attached leaves to evaluate growth chamber-grown cotton leaf (Gossypium hirsutum L.) senescence (chlorophyll degradation as criterion) that was delayed by mepiquat chloride (1,1-dimethylpiperidinium chloride) rates of 0, 10, 40, 70, and 100 g a.i./ha. Mepiquat chloride (MC increased both chlorophyll and leaf water contents as compared with that of untreated leaves. Reflectance was inversely and linearly correlated (r = -0.873**) with eater content at the 1.65 micrometer wavelength and was inversely correlated (r = -0.812**) with chlorophyll concentration at the 0.55 micrometer wavelength but best fit a quadratic equation. Either wavelength measurement might be useful to remotely detect cotton leaf senescence or fields of MC-treated cotton plants.

Gausman, H. W.↗