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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Fine-scale structure of a cold hydrogen layer

Neutral-hydrogen absorption-line interferometer observations are reported for five continuum radio sources situated behind an extensive layer of cold interstellar H I gas. In contrast to low-spatial-resolution emission-line observations reported earlier which show the large-scale uniformity of the layer, the high-spatial-resolution absorption-line observations reveal variations in the velocity and density within the layer. The new results together with the old indicate the apparent coexistence of a large-scale mechanism for triggering the formation of cold hydrogen and an instability mechanism leading to small-scale irregularities.

Baker, P. L.↗
NASA NTRS1975

Radio recombination line observations of the C II region NGC 2023

The reflection nebula NGC 2023 has been observed at four frequencies in a study of its carbon recombination line emission. The observations show the recombination line region to be about 2 pc in diameter, with an average electron density of about 0.2 per cu cm and electron temperature of about 20 K. The electron density increases exponentially near the B1.5 star HD 37903, the illuminating star of NGC 2023. The most reasonable interpretation of the observational results is that the carbon emission lines arise in a cold C II region surrounding HD 37903. The coexistence of the C II region with a region of enhanced CO emission suggests that the CO in NGC 2023 may be excited by electron collisions.

Knapp, G. R.↗
NASA NTRS1974

Equilibria bearing on the behavior of titanate phases during crystallization of iron silicate melts under strongly reducing conditions

Titanate phase relations at liquidus temperatures are determined for the CaAl2Si2O8-Fe2TiO4-FeTi2O5 system in contact with metallic iron by reflected- and transmitted-light microscopy, electron microprobe, and X-ray diffraction analyses. Results of critical equilibration runs are presented, various primary phase areas and liquidus isotherms are illustrated, and the geometry of the system is described. Three piercing points are determined, and it is noted that the compositional interrelations among coexisting crystalline and liquid phases as well as the sequence of the various titanate phases are indicative of the significant effects of the various cations on the relative stability of these phases. It is found that Al2O3 exerts a strong stabilizing effect on the phase assemblage of ulvospinel plus ferropseudobrookite relative to ilemite.

Lipin, B. R.↗
NASA NTRS1975

Distribution and significance of chromium in meteorites

Chromium is present as a minor element in all meteorite types. Depending on the meteorite type it is lithophile (most frequent), chalcophile (less frequent), or siderophile (rare). Chromium is an indicator of physical and chemical conditions of meteorite formation, especially of the state of oxidation. The Cr contents of meteoritic chromites are related to classification and can be used to distinguish among meteorite types that contain this mineral. The distribution of Cr between coexisting pyroxenes may indicate the degree of equilibration of this mineral pair. Siderophile Cr appears to result from primitive condensation processes rather than secondary reduction processes. The lack of much experimental data on Cr in silicate systems limits the interpretation of the occurrences of Cr-silicate phases, ureyite and krinovite, in the meteorite type in which they occur.

Bunch, T. E.↗
NASA NTRS1977

Aluminum-26 in the early solar system - Fossil or fuel

The isotopic composition of Mg was measured in different phases of a Ca-Al-rich inclusion in the Allende meteorite. Large excesses of Mg-26 of up to 10% were found. These excesses correlate strictly with the Al-27/Mg-24 ratio for four coexisting phases with distinctive chemical compositions. Models of in situ decay of Al-26 within the solar system and of mixing of interstellar dust grains containing fossil Al-26 with normal solar system material are presented. The observed correlation provides definitive evidence for the presence of Al-26 in the early solar system. This requires either injection of freshly synthesized nucleosynthetic material into the solar system immediately before condensation and planet formation, or local production within the solar system by intense activity of the early sun. Planets promptly produced from material with the inferred Al-26/Al-27 would melt within about 300,000 years.

Lee, T.↗
NASA NTRS1976

An experimental study of phosphate reduction and phosphorus-bearing lunar metal particles

Results are reported for two sets of experiments conducted to investigate the distribution and origin of phosphorus in lunar metal particles. The first set measured the equilibrium oxygen fugacity as a function of temperature for synthesized Fe-Ni and Fe-Ni-P alloys; the second set imposed various oxygen pressures so that the P distribution among the coexisting phases could be observed. The conditions of temperature, oxygen fugacity, and time necessary to produce P contents similar to those found in lunar metal particles are determined. The results show that: (1) the P distribution in lunar-type metal is controlled by oxygen fugacity, temperature, and bulk composition; (2) the P distribution is limited by the reaction rate at the metal surface and by the amount of phosphate in contact with the metal; (3) the nucleation and growth rate of phosphate controls the rate of P loss during oxidation; and (4) an oxygen fugacity of 10 to the -20th power atm at 950 C is required to saturate iron with P. It is concluded that a reducing species such as carbon may establish a local equilibrium and prevent oxygen communication with the surrounding rock.

Friel, J. J.↗
NASA NTRS1976

Further characterization of spectral features attributable to titanium on the moon

The following transitions are observed in the electronic absorption spectra of lunar titanaugites: Fe(2+) spin-allowed and spin-forbidden crystal field; Ti(3+) spin allowed and Jahn-Teller split crystal field; Ti(3+)-Ti(4+) CT; Fe(2+)-Ti(4+) CT; and O(2-)-Fe(2+), Ti(3+), Ti(4+) CT. Of these, the transitions involving Ti(3+) are unique to lunar or nonferric-bearing titanaugites. All titanaugites have the Fe(2+) crystal field and Fe(2+)-Ti(4+) CT transitions in common. These features in the diffuse reflectance spectra of lunar materials give rise to the '1.0 band' and to the observed absorption around 0.5-0.6 micron, respectively. Since regolith contains a variety of phases with coexisting Fe(2+), Ti(3+), and Ti(4+) ions, several metal-metal charge transfer processes are possible.

Burns, R. G.↗
NASA NTRS1978

Calcium isotopic anomalies in the Allende meteorite

Isotopic anomalies in Ca are reported which were found in two Ca-Al-rich inclusions of the Allende meteorite. The corrected Ca data show nonlinear isotopic effects in Ca-48 of +13.5 per mil and in Ca-42 of +1.7 per mil for one sample. The second sample shows a Ca-48 depletion of -2.9 per mil, but all other isotopes are normal. Samples with large excesses in Mg-26 show no Ca anomalies. The effects demonstrate that isotopic anomalies exist for higher-atomic-number refractory elements in solar-system materials and do not appear to be readily explainable by a simple model. Observed anomalous Mg and Ca compositions for coexisting mineral phases are uniform within each inclusion and require initial isotopic homogeneity within an inclusion but the preservation of wide variations between inclusions. Assuming formation of these inclusions by condensation from a gaseous part of the solar nebula, this implies isotopic heterogeneity on a scale of 10 to 100 km within the nebula.

Lee, T.↗
NASA NTRS1977

Chemical compositions and possible immiscibility of two silicate melts in 12013

The lunar sample 12013, a complex mixture of gray breccia and black breccia, is described. The gray breccia consists of mostly basaltic and gabbroic lithic clasts as well as plagioclase and pyroxene mineral clasts set in a matrix of smaller clasts and a felsite of granitic composition, while the black breccia is comprised of mostly mineral clasts, some lithic clasts, and felsite blebs enclosed in an aphanitic groundmass of basaltic composition. Textural relationships indicate that the felsite and the black breccia groundmass crystallized from melts which coexisted prior to the final lithification of 12013 but failed to mix. Both the felsite and the black breccia groundmass have extreme enrichments of incompatible elements. The critical feature of their compositions is a 'splitting up' of incompatible element associations so that the highest REE and P concentrations are in the black breccia groundmass, and the highest K, Ba, and Rb concentrations are in the felsite.

Quick, J. E.↗
NASA NTRS1978

Zr and Nb partition coefficients - Implications for the genesis of mare basalts, KREEP, and sea floor basalts

The distribution coefficients of Zr and Nb have been found between armalcolite, ilmenite, clinopyroxene, rutile, plagioclase, and a coexisting high-Ti mare basalt melt in the 1105-1128 C temperature range. Henry's Law is not broken over the compositional range evaluated. The distribution coefficients of clinopyroxene are strongly dependent on melt and crystal compositions. The Al2O3 activity in the melt is a strong controlling parameter. It is concluded that: (1) Apollo 11 (low K) and Apollo 17 high-Ti mare basalts may have been generated by the partial melting of an ilmenite-rich cumulate, (2) Apollo 11 (high K) basalts may have been generated by a small amount of partial melting of a more fractionated ilmenite-rich cumulate, (3) KREEP magmas may have been formed as residual melts produced by fractional crystallization of the lunar magma ocean, and (4) anomalous (type II) MOR basalts may have been generated by small degrees of partial melting of a relatively undepleted mantle with clinopyroxene remaining in the residium.

Mccallum, I. S.↗
NASA NTRS1978

Implications of liquid-liquid distribution coefficients to mineral-liquid partitioning

In order to evaluate the influence of a silicate liquid structure on mineral-liquid partitioning, element partitioning data is obtained for coexisting anhydrous immiscible granitic and ferrobasaltic magmas. It is found that: (1) mineral-liquid distribution coefficients indicate the competition of crystal and liquid for cation incorporation, (2) increased polymerization of the residual liquid during crystal-liquid fractionation increases the mineral-liquid distribution coefficients for high-charge-density cations, (3) incompatible element ratios of low- and high-charge-density cations may vary during crystal-liquid fractionation because of changes in the melt composition and structure, (4) relative solubilities of REE's in melts do not vary with melt polymerization, (5) the changes of Sm/Eu ratios during crystal-liquid fractionation depend on the melt composition, and (6) minor components and volatiles can significantly influence the silicate melt structure and the mineral-liquid distribution coefficients.

Ryerson, F. J.↗
NASA NTRS1975

Lunar petrogenesis in a well-stirred magma ocean

The principal group of low-KREEP highlands rocks as indicated by quartz-olivine-anorthite pseudoternary phase diagrams shows chemical trends which violate the Bowen reaction principle, in that the greater the concentration of magnesian and mafic minerals, the more sodic the coexisting plagioclase tends to be. It is suggested that this trend was established during the primary differentiation of the lunar crust and is a result of crystallization in a vigorously convecting (well-stirred) system. Under these conditions all plagioclase crystals, all pyroxene crystals, and all of the residual liquid remain fairly uniform in composition until advanced crystallization immobilizes the system. The rock suite then established would vary continuously from anorthositic types at the top to ultramafic types at the bottom.

Wood, J. A.↗
NASA NTRS1979

Some TEM observations of Al2O3 scales formed on NiCrAl alloys

The microstructural development of Al2O3 scales on NiCrAl alloys has been examined by transmission electron microscopy. Voids were observed within grains in scales formed on a pure NiCrAl alloy. Both voids and oxide grains grew measurably with oxidation time at 1100 C. The size and amount of porosity decreased towards the oxide-metal growth interface. The voids resulted from an excess number of oxygen vacancies near the oxidemetal interface. Short-circuit diffusion paths were discussed in reference to current growth stress models for oxide scales. Transient oxidation of pure, Y-doped, and Zr-doped NiCrAl was also examined. Oriented alpha-(Al, Cr)2O3 and Ni(Al, Cr)2O4 scales often coexisted in layered structures on all three alloys. Close-packed oxygen planes and directions in the corundum and spinel layers were parallel. The close relationship between oxide layers provided a gradual transition from initial transient scales to steady state Al2O3 growth.

Smialek, J.↗
NASA NTRS1978

Cochannel interference analysis between spaceborne and terrestrial radars

An analysis of cochannel interference between spaceborne and terrestrial radars is presented. A generic modeling methodology is applied, which, it is felt, will represent the worst-case situation. In order to account for Doppler shifts, auto- and cross-ambiguity functions have been developed for determining matched filter outputs. The results support the ability of such radar systems to coexist relatively harmoniously utilizing currently accepted assignment procedures.

Nicholas, J. J., Jr.↗
NASA NTRS1978

Observational program options and system requirements for the search for extraterrestrial intelligence /SETI/

The possibility that intelligent life may be widespread in the universe is now being investigated. A formula for estimating the number of coexisting communicative civilizations has been developed by Drake. A good way of conducting a search for extraterrestrial intelligence (SETI) is to examine the microwave window of the electromagnetic spectrum for narrow-band signals which such civilizations may be transmitting. Two specific search strategies are described. Both employ existing antennas equipped with sophisticated multichannel spectrum analyzers and pattern recognition devices. The Ames Research Center proposal is a high sensitivity, high-resolution search of nearby promising stars and selected sky areas in the 'water hole' (1400-1727 MHz). The Jet Propulsion Laboratory proposal is for a survey of most of the sky over a significant portion of the free-space microwave window at lower sensitivities and resolutions. The approaches are complementary and both are being pursued. The consummation of these programs could achieve one of the most profound discoveries in the history of human civilization, or at least will show the way to future efforts.

Billingham, J.↗
NASA NTRS1978

Determination of the Fe-rich portion of the Fe-Ni-C phase diagram

The iron-enriched section of the phase diagram for the ternary alloy Fe-Ni-C of various compositions is determined at 773, 873, 923, and 1003 C. The two-phase tie lines and three-phase tie triangles are measured by electron microprobe analyses. Tie lines in samples without bulk equilibrium are obtained by extrapolated interface compositions under the assumption of local equilibrium at the interface. It is shown that Ni addition somewhat reduces carbon solubility in austenite while decreasing the stability of the carbide phase. In particular, the carbide is always poor in Ni relative to the coexisting metal phase(s).

Romig, A. D., Jr.↗
NASA NTRS1978

Effects of kinetics on the crystallization of quartz normative basalt 15597 - An experimental study

Equilibrium experiments on a residual liquid composition from the dynamic crystallization study on quartz normative basalt (QNB) 15597 are used to evaluate the effects of kinetics on the crystallization of pyroxene-porphyritic basalts. The results indicate that the liquids coexisting with pyroxene phenocryst rims before the precipitation of groundmass plagioclase + pyroxene have left the equilibrium liquid line of descent and metastably penetrated the plagioclase primary phase volume. The precipitation of groundmass plagioclase + pyroxene brings the basalt system closer to equilibrium with respect to the residual liquid and crystals. At rapid cooling rates pyroxene phenocryst growth produces substantial compositional gradients in the residual silicate liquid at the pyroxene/liquid interface. The compositional gradients enhance the nucleation and growth of groundmass phases at the phenocryst interface, because effects related to constitutional supercooling for these phases (e.g., plagioclase, pyroxene, etc.) favor nucleation at the interface.

Grove, T. L.↗
NASA NTRS1978

Experimental partitioning of rare earth elements and scandium among armalcolite, ilmenite, olivine and mare basalt liquid

An experimental study was carried out to measure partition coefficients for two rare-earth elements (Sm and Tm) and Sc among armalcolite, ilmenite, olivine and liquid coexisting in a system modeled on high-Ti mare basalt 74275. This 'primitive' sample was chosen for study because its major and trace element chemistry as well as its equilibrium phase relations at atmospheric pressure are known from previous studies. Beta-track analytical techniques were used so that partition coefficients could be measured in an environment whose bulk trace element composition is similar to that of the natural basalt. Partition coefficients for Cr and Mn were determined in the same experiments by microprobe analysis. The only equilibrium partial melting model appears to be one in which ilmenite is initially present in the source region but is consumed by melting before segregation of the high-Ti mare basalt liquid from the residue.

Irving, A. J.↗