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At least 109 records · Page 6

Collisional quenching of cometary emission in the 18 centimeter OH transitions

A model of collisional quenching of the OH 2Pi(3/2) J = 3/2 Lambda doublet in cometary comae is presented. It is found that collisions with ions and electrons in the outer coma have a strong quenching effect on the Swings-effect inversion of the Lambda doublet that is responsible for the OH radio emission at 18 cm wavelength. For the conditions of Halley's comet, collisional quenching should lead radio observers to systematically underestimate the OH parent production rate by a factor of approximately 3 relative to its actual value, and in general, radio-derived production rates should always be less than or equal to UV-derived production rates, which are relatively unaffected by this process. The observation that UV production rates exceed those derived by radio techniques is well known; the direct measurement of this ratio, using a consistent coma model, should provide information about the ion and electron content of the cometary coma.

Schloerb, F. Peter↗

Collisional electrostatic ion cyclotron waves as a possible source of energetic heavy ions in the magnetosphere

A new mechanism is proposed for the source of energetic heavy ions (NO/+/, O2/+/, and O/+/) found in the magnetosphere. Simulations using a multispecies particle simulation code for resistive current-driven electrostatic ion cyclotron waves show transverse and parallel bulk heating of bottomside ionospheric heavy ion populations. The dominant mechanism for the transverse bulk heating is resonant ion heating by wave-particle ion trapping. Using a linear kinetic dispersion relation for a magnetized, collisional, homogenous, and multiion plasma, it is found that collisional electrostatic ion cyclotron waves near the NO(+), O2(+), and O(+) gyrofrequencies are unstable to field-aligned currents of 50 microA/sq m for a typical bottomside ionosphere.

Providakes, Jason↗

The effect of catastrophic collisional fragmentation and diffuse medium accretion on a computational interstellar dust system

The effects of catastrophic collisional fragmentation and diffuse medium accretion on a the interstellar dust system are computed using a Monte Carlo computer model. The Monte Carlo code has as its basis an analytic solution of the bulk chemical evolution of a two-phase interstellar medium, described by Liffman and Clayton (1989). The model is subjected to numerous different interstellar processes as it transfers from one interstellar phase to another. Collisional fragmentation was found to be the dominant physical process that shapes the size spectrum of interstellar dust. It was found that, in the diffuse cloud phase, 90 percent of the refractory material is locked up in the dust grains, primarily due to accretion in the molecular medium. This result is consistent with the observed depletions of silicon. Depletions were found to be affected only slightly by diffuse cloud accretion.

Liffman, Kurt↗

Collisional removal of HI from the inner disks of Virgo cluster galaxies

There is sufficient observational evidence to show that many Virgo Cluster spirals are HI deficient in their inner disks (in addition to being HI deficient globally, as previously established). It is shown here that collisions between galaxies in a cluster can lead to the removal of HI gas from these galaxies while leaving the H2 gas, undisturbed. This follows directly from the application of the Spitzer-Baade collisional gas removal mechanism to galaxies consisting of stars and a two-component interstellar medium (ISM) consisting of HI and H2, with HI having the largest filling factor. This can account for both the observed HI deficiency in the inner regions and the normal H2 content of these galaxies. The frequency of galaxy collisions in the Virgo Cluster is shown to be large enough to make collisional gas removal a viable mechanism.

Valluri, Monica↗

Collisional processes in cometary plasmas

The interaction of the solar wind with comets is initiated at large distances from the nucleus by the ionization of cometary neutrals. The resulting contamination of the solar wind with cometary ions mass-loads the solar wind flow, causing it to slow down. The plasma-comet interaction is largely collisionless at large cometocentric distances. However, collisional processes become important in the inner coma (within the cometopause). Collisional processes include charge-transfer between solar wind protons and neutrals, ion-neutral friction, electron and ion thermal cooling, and ion-neutral chemistry. For example, the magnetometer on the Giotto spacecraft observed a diamagnetic cavity near closest approach. This cavity is a consequence of the balance between an inward-directed magnetic pressure gradient force and an outward ion-netural frictional force. Thermalization of the cometary ion distribution function by Coulomb collisions is another important process in the inner coma of an active comet.

Cravens, T. E.↗

Asteroid collisional evolution - An integrated model for the evolution of asteroid rotation rates

A comprehensive model for the changes in asteroid spin rates due to large collisions was developed by combining the theoretical results of Cellino et al. (1990) with previously published work on spin rate changes for cratering impacts (Harris, 1979; Dobrovolskis and Burns, 1984). The spin change algorithm, when incorporated into an existing simulation of collisional effects on asteroid sizes, produced an integrated model for studying the simultaneous evolution of asteroid sizes and spin rates over the solar system history. As a result of an analysis of 32 collisional scenarios with regard to the change in the spin rate as a function of asteroid size, it is concluded that the spin rates of all asteroids, except possibly the largest ones, have been significantly altered by collisions over the solar system history and that, in general, shattering impacts are much more important than cratering events in changing the spin of asteroids.

Farinella, P.↗

Semikinetic modeling of the outflow of ionospheric plasma through the topside collisional to collisionless transition region

A collisional semikinetic model is applied to the study of the topside ionosphere transition region. The paper considers the transition from (1) O(+) to H(+) dominance; (2) subsonic to supersonic H(+) flow; and (3) collisional to collisionless plasma. The H(+) ions flow upward from a relatively low altitude of 500-1000 km to a high altitude of 7000 km. These ions are subjected to collisions with O(+) ions and self collisions, as well as the effects of macroscopic forces such as the magnetic mirror force, gravity, and the ambipolar electric force. When supersonic outflow occurs, the H(+) velocity-distribution function shows a large departure from Maxwellian with a large positive and then negative heat flow, particularly in the region where the flow Mach number passes through one. In cases where subsonic outflow occurs and the H(+) density is relatively low, distribution functions with two peaks can occur. In these situations the H(+) ions have large parallel temperatures and large heat flows when the two peaks are of unequal height.

Wilson, G. R.↗

Collisional effects in laser detection of tropospheric OH

The use of laser-induced fluorescence to measure OH in the troposphere is discussed. It is noted that quantitative laser detection of OH requires knowledge of collisional processes affecting the measurements and interference effects due to OH generated by laser photolytic processes. Collisions induce quenching of the excited A-state, as well as vibrational and rotational energy transfer in the excited and ground states. It is noted that the state-specific nature of these processes is important, especially the rotational level dependence of quenching and vibrational transfer in excited OH. Also important is the temperature dependence according to which quenching cross sections sharply increase with decreasing temperature. Laboratory experiments studying these collisional processes are described, and their implications for laser detection of tropospheric OH are examined.

Crosley, David R.↗

Collisional simulations of particles in a narrow planetary ring

A model is used to investigate how particle-particle collisions might modify some consequences of satellite perturbations relevant to short-term features of narrow planetary rings. A Monte Carlo-like simulation ring-model particle velocity alteration allows the simulation of collisions while individual particles are tracked. Periodic features visible in Voyager images are reproduced in a 2D numerical model which incorporates the collisional simulation as well as the perturbations of adjacent satellites. Collisions are noted to wash out periodic features within one collisional relaxation time.

Kolvoord, Robert A.↗

Collisional effects in He I: An observational analysis

Accurate and reliable helium abundances can test modern theories of galactic and primordial nucleosynthesis. Unfortunately, there is some question whether current theory can account for collisional contributions to He I. We present new observations of two planetary nebulae (PNs) in the range lambda 850-lambda 9650, which we use to assess the importance of collisonal effects in the He I spectrum. The first object, NGC 7027, is expected to show relatively strong collisional enhancement, while the second, NGC 7026, should display only small effects. We derive new collision-to-recombination correction factors, based on new collision strengths from the 29-state quantal calculation of He I extending to n = 5. Our results show that the correction factors based on 'standard' theory are correct, but that the errors acquired in such an observational analysis are appreciable. We find no convincing observational evidence for the existence of an unknown agent depopulating the 2(sup 3)S state in Pns.

Kingdon, J.↗

Collisional Time Scales in the Kuiper Disk and Their Implications

We explore the rate of collisions among bodies in the present-day Kuiper Disk as a function of the total mass and population size structure of the disk. We find that collisional evolution is an important evolutionary process in the disk as a whole, and indeed, that it is likely the dominant evolutionary process beyond approx. 42 AU, where dynamical instability time scales exceed the age of the solar system. Two key findings we report from this modeling work are: that unless the disk's population structure is sharply truncated for radii smaller than approx. 1-2 km, collisions between comets and smaller debris are occurring so frequently in the disk, and with high enough velocities, that the small body (i.e., KM-class object) population in the disk has probably developed into a collisional cascade, thereby implying that the Kuiper Disk comets may not all be primordial, and that the rate of collisions of smaller bodies with larger 100 less R less 400 km objects (like 1992QB(sub 1) and its cohorts) is so low that there appears to be a dilemma in explaining how QB(sub 1)s could have grown by binary accretion in the disk as we know it. Given these findings, it appears that either the present-day paradigm for the formation of Kuiper Disk is failed in some fundamental respect, or that the present-day disk is no longer representative of the ancient structure from which it evolved. This in turn suggests the intriguing possibility that the present-day Kuiper Disk evolved through a more erosional stage reminiscent of the disks around the stars Beta Pictorus, alpha PsA, and alpha Lyr.

Stern, S. Alan↗

Particle Segregation in Collisional Shearing Flows

The size segregation of flowing or shaken grains is a commonly observed phenomenon in industrial processes and in nature. In systems that do not involve much agitation of the grains, several mechanisms that involve gravity have been identified as leading to such segregation. In highly agitated flows, there is a mechanism independent of gravity that is available to drive separation of different grains. This is associated with spatial gradients in the energy of their velocity fluctuations. Because collisions between grains inevitably dissipate energy, collisional granular shear flows are usually of limited extent in the direction transverse to the flow. One consequence of this is that shear flows are strongly influenced by their boundaries. Because grains, on average, slip relative to boundaries, a bumpy or frictional boundary can convert slip energy into fluctuation energy. However, because each collision between a grain and the boundary dissipates fluctuation energy, there is a competition between production and dissipation. In principle, it is possible to design the geometry of the boundary - for example, the size and spacing of the bumps - so that the boundary either produces or dissipates fluctuation energy. This permits the control of the component of the spatial gradient of the fluctuation energy that is normal to the boundary. The gradients in fluctuation energy established by such boundaries may be exploited to drive the separation by size or other properties in a binary mixture of spherical grains. Microgravity makes the visual observations possible by permitting us to employ moderate rates of shear. On earth, the effects of gravity can be minimized by shearing so rapidly that the particle pressure overwhelms gravity. However, in this event, separation takes place too rapidly for visual observation, buoyancy and/or condensation associated with the centripetal acceleration must be accounted for, and the particles can be severely damaged. Because, in the absence of gravity, the only available time scale is proportional to the speed of the moving boundary, this speed can be made arbitrarily slow to permit observations and to avoid particle damage, without altering the phenomenon under study. The primary goal of this research is to carry out a physical experiment in which particle segregation is induced and maintained in a collisional flow of a binary mixture of two different types of spheres.

Jenkins, J. T.↗

Ion Transport Modeling in Non-Collisional RF Sheaths

A reactor scale ICP plasma model does not adequately resolve the submillimeter scale rf sheaths due to severe disparities in length and times scales. These non-collisional sheaths determine the spread in the ion bombardment energy distribution on the wafer. Analytical models based on "damped potential" has been used by various authors to simplify sheath modeling. However, inherent in these models are some assumptions that may be invalid. In this work we show that simplifying assumptions such as a uniform ion flux may be in error by as much as 200% at 13.56MHz. This work involves solving ion transport in non-collisional rf sheaths. A comprehensive study of the dependence of ion flux and energy on uncertainties in the sheath-presheath (i.e. sheath thickness) boundary will also be done.

Meyyappan, M.↗

Chandra Observations of Comet 2P/Encke 2003: First Detection of a Collisionally Thin, Fast Solar Wind Charge Exchange System

We report the results of 15 hr of Chandra observations of comet 2P/Encke 2003 on November 24. X-ray emission from comet Encke was resolved on scales of 500-40,000 km, with unusual morphology due to the presence of a low-density, collisionally thin (to charge exchange) coma. A light curve with peak-to-peak amplitude of 20% consistent with a nucleus rotational period of 11.1 hr was found, further evidence for a collisionally thin coma. We confirm emission lines due to oxygen and neon in the 800-1000 eV range but find very unusual oxygen and carbon line ratios in the 200-700 eV range, evidence for low-density, high effective temperature solar wind composition. We compare the X-ray spectral observation results to contemporaneous measurements of the coma and solar wind made by other means and find good evidence for the dominance of a postshock bubble of expanding solar wind plasma, moving at 600 km/s with charge state composition between that of the "fast" and "slow" solar winds.

Lisse, C. M.↗

Evidence of Collisional Histories of Asteroids, Comets and Meteorites: Comparisons with Shocked Minerals

Evidence of the collisional history of comets and asteroids has been emerging from analyses of cometary forsterite and enstatite returned from Comet Wild 2 by the Stardust mission (Keller et al.Geochim. Cosmochim. Acta 72, 2008; Tomeoka et al. MAPS 43, 2008; Jacobs et al. MAPS 44, 2009). Likewise, shock metamorphism is observed in many meteoritic forsterites and enstatites (McCausland et al. AGU, 2010), suggesting similar collisional histories for asteroids. Further exploration of the effects of collisions is slated for the upcoming Asteroid Impact Mission/Double Asteroid Redirection Test (AIM/DART) mission, expected for launch in 2020. DART will impact Didymoon, the companion of the larger 65803 Didymos (1996 G2) asteroid, and AIM will use its instrumentation to characterize the impact. A suite of relevant impact experiments have been carried out in the Experimental Impact Laboratory at the NASA Johnson Space Center at velocities ranging from approx. 2.0 - 2.8 km/s and temperatures from 25 C to -100 C. Targets include a suite of minerals typically found in cometary dust and in asteroids and meteorites: Mg-rich forsterite (olivine), enstatite (orthopyroxene), diopside (clinopyroxene), magnesite (Mg-rich carbonate), and serpentine (phyllosilicate). Transmission Electron Microscope (TEM) imaging indicates evidence of shock similar to that seen in forsterite and enstatite from Comet Wild 2. Fourier Transform Infrared (FTIR) Spectroscopy will also be used for comparisons with meteorite spectra. A quantitative analysis of the shock pressures required to induce planar dislocations and spectral effects with respect to wavelength will also be presented.

Lederer, Susan M.↗

Collisional-Radiative Models of Neutral and Singly-Ionized Xenon in Hall Thrusters: Experimental Validation and Model Investigations

The recently developed collisional radiative (CR) models for neutral xenon (Xe I) and singly charged xenon ion (Xe II) described by Chaplin et al. in the paper "Insights from Collisional-Radiative Models of Neutral and Singly-Ionized Xenon in Hall Thrusters" also submitted to the 2021 AIAA Propulsion and Energy Forum are more thoroughly investigated. Comparisons between the existing and recently developed JPL Xe I CR models are done and reasons for discrepancies between the two models are explored. An experiment to validate the Xe II CR model is carried out in the anode region of the UCLA Plasma interactions facility. The Xe II CR model is applied to measured xenon ion emission line intensities to determine electron temperature and density. Spatial resolution of these optical measurements is obtained through an Abel inversion for direct comparison to Langmuir probe results. Although the measured electron densities were on the order of $10^{17}$ m$^{-3}$ and the Xe II CR model is most suitable for use with densities above $10^{18}$ m$^{-3}$ due to the strong dependence of the line ratios on electron temperature in that regime, initial results from the validation experiment show reasonable agreements between the optical and Langmuir probe results. The 441 nm to 605 nm line ratio appears to have the most promise for non-intrusive electron temperature measurements with the Xe II CR model. Shortcomings of the Xe II CR model revealed in the validation experiment are to be explored further.

Lobbia, Robert B.↗

Towards understanding the formation of internal fragments generated by collisionally activated dissociation for top-down mass spectrometry

Top-down mass spectrometry (TD-MS) generates fragment ions that returns information on the polypeptide amino acid sequence. In addition to terminal fragments, internal fragments that result from multiple cleavage events can also be formed. Traditionally, internal fragments are largely ignored due to a lack of available software to reliably assign them, mainly caused by a poor understanding of their formation mechanism. To accurately assign internal fragments, their formation process needs to be better understood. Here we applied a statistical method to compare fragmentation patterns of internal and terminal fragments of peptides and proteins generated by collisionally activated dissociation (CAD). Internal fragments share similar fragmentation propensities with terminal fragments (e.g., enhanced cleavages N-terminal to proline and C-terminal to acidic residues), suggesting that their formation follows conventional CAD pathways. Internal fragments should be generated by subsequent cleavages of terminal fragments and their formation can be explained by the well-known mobile proton model. Additionally, internal fragments can be coupled with terminal fragments to form complementary product ions that span the entire protein sequence. These enhance our understanding of internal fragment formation and can help improve sequencing algorithms to accurately assign internal fragments, which will ultimately lead to more efficient and comprehensive TD-MS analysis of proteins and proteoforms.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Collisional excitation of interstellar PN by H 2 : New interaction potential and scattering calculations

Here, rotational excitation of interstellar PN molecules induced by collisions with H 2 is investigated. We present the first ab initio four-dimensional potential energy surface (PES) for the PN–H 2 van der Waals system. The PES was obtained using an explicitly correlated coupled cluster approach with single, double, and perturbative triple excitations [CCSD(T)-F12b]. The method of interpolating moving least squares was used to construct an analytical PES from these data. The equilibrium structure of the complex was found to be linear, with H 2 aligned at the N end of the PN molecule, at an intermolecular separation of 4.2 Å. The corresponding well-depth is 224.3 cm -1 . The dissociation energies were found to be 40.19 cm -1 and 75.05 cm -1 for complexes of PN with ortho-H 2 and para-H 2 , respectively. Integral cross sections for rotational excitation in PN–H 2 collisions were calculated using the new PES and were found to be strongly dependent on the rotational level of the H 2 molecule. These new collisional data will be crucial to improve the estimation of PN abundance in the interstellar medium from observational spectra.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗