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At least 109 records · Page 6

Firm Synthesizer and Supply-chain Simulator (SynthFirm) v1.0

SynthFirm is a large-scale agent-based freight demand model which generates a complete synthetic population of firms in the U.S. and the business-to-business commodity flows between them. Using publicly available data sources as inputs, SynthFirm simulates detailed firm and fleet characteristics, commodity production and consumption, formation of supply chains, and selection of shipping modes, all of which are essential drivers of commodity flow at a disaggregate level.

Xu, Xiaodan↗

Firm Synthesizer and Supply-chain Simulator (SynthFirm) v2.0

SynthFirm is a national-scale agent-based freight demand model which generates a complete synthetic population of firms in the U.S. and the business-to-business commodity flows between them. Using publicly available data sources as inputs, SynthFirm simulates detailed firm and fleet characteristics, commodity production and consumption, formation of supply chains, and selection of shipping modes, all of which are essential drivers of commodity flow at a disaggregate level. The SynthFirm 2.0 version includes national commercial vehicle fleet generation, international trade simulation and automized model validation pipeline, which allows seemless deployment across the nation and build a comprehensive freight inventories at national scale or for selected region.

Yang, Hung-Chia [Lawrence Berkeley National Labora↗

Comparing Server Energy Use and Efficiency Using Small Sample Sizes

This report documents a demonstration that compared the energy consumption and efficiency of a limited sample size of server-type IT equipment from different manufacturers by measuring power at the server power supply power cords. The results are specific to the equipment and methods used. However, it is hoped that those responsible for IT equipment selection can used the methods described to choose models that optimize energy use efficiency. The demonstration was conducted in a data center at Lawrence Berkeley National Laboratory in Berkeley, California. It was performed with five servers of similar mechanical and electronic specifications; three from Intel and one each from Dell and Supermicro. Server IT equipment is constructed using commodity components, server manufacturer-designed assemblies, and control systems. Server compute efficiency is constrained by the commodity component specifications and integration requirements. The design freedom, outside of the commodity component constraints, provides room for the manufacturer to offer a product with competitive efficiency that meets market needs at a compelling price. A goal of the demonstration was to compare and quantify the server efficiency for three different brands. The efficiency is defined as the average compute rate (computations per unit of time) divided by the average energy consumption rate. The research team used an industry standard benchmark software package to provide a repeatable software load to obtain the compute rate and provide a variety of power consumption levels. Energy use when the servers were in an idle state (not providing computing work) were also measured. At high server compute loads, all brands, using the same key components (processors and memory), had similar results; therefore, from these results, it could not be concluded that one brand is more efficient than the other brands. The test results show that the power consumption variability caused by the key components as a group is similar to all other components as a group. However, some differences were observed. The Supermicro server used 27 percent more power at idle compared to the other brands. The Intel server had a power supply control feature called cold redundancy, and the data suggest that cold redundancy can provide energy savings at low power levels. Test and evaluation methods that might be used by others having limited resources for IT equipment evaluation are explained in the report.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Improving the Economic Viability of Biological Utilization of Coal Power Plant CO 2 by Improved Algae Productivity and Integration with Wastewater Treatment

The overall goal of this project was to improve the cost-effectiveness of systems using algae to capture and beneficially utilize CO 2 from the flue gas of coal-fired power plants. Algal biomass cultivation is an attractive alternative for carbon capture and utilization because it can uptake more CO 2 per land area than any other photosynthetic crop. Also, the resulting biomass can be used to make valuable large-market commodity products, such as biofuels and animal feed. However, the use of algal carbon capture has been limited by several factors including: (1) high costs for growing algae (>$\$1,300$/ton), (2) large land requirements for algae cultivation, and (3) environmental concerns about the large amount of water and nutrient inputs needed for growing algae. This project has taken direct aim at resolving these key limitations and demonstrated several viable approaches to improve the economic and environmental feasibility of algal carbon capture. In particular, this project demonstrated a significant increase in average annual algal productivity from baseline values of 8 g/m 2 -day to above 20 g/m 2 -day. This supports a much lower projected cost of algae production (<$\$500$/ton) and reduces land requirements by more than 50%. Additionally, this project confirmed the ability to grow multiple algae species with wastewater nutrients, which facilitates the potential for substantial new revenue streams for algae cultivation based on tipping fees for nutrient laden wastewater. This study highlighted that there is more potential value in wastewater nutrient treatment credits than in the primary commodity products made from algae. The use of wastewater inputs also mitigates the concerns associated with the large amount of water needed for growing algae. The algal biomass grown for this project using wastewater and simulated flue gas inputs were characterized for potential use as an animal feed ingredient. The algae had a protein content in the range of 35-40%, which is between some common commodity animal feed products— distiller’s grains (~25-30% protein) and soybean meal (45-50% protein). In-vitro digestion tests using cattle rumen fluids, showed that this algae biomass was best suited for use as “bypass protein”, which is digested in the animal intestine. Based on the protein content and amino acid profile of the algae grown in this study, it was estimated to have market value in the range of $\$190$-$\$280$/ton. There is potential for higher value feed products if the algae content of omega-3 fatty acids or antioxidants is accounted for. This project also did small scale demonstration of forward osmosis algae dewatering and nanofiltration of hydrothermal liquefaction aqueous products, which were shown to improve the cost and energy balance for producing algal products. When all the improvements demonstrated in this study were included in techno-economic analysis, it showed there was a viable pathway to profitable algal CO 2 utilization with a payback period in the range of six to ten years.

01 COAL, LIGNITE, AND PEAT↗

Plant Growth Promotion Diversity in Switchgrass-Colonizing, Diazotrophic Endophytes

Endophytic nitrogen-fixing (diazotrophic) bacteria are essential members of the microbiome of switchgrass ( Panicum virgatum ), considered to be an important commodity crop in bioenergy production. While endophytic diazotrophs are known to provide fixed atmospheric nitrogen to their host plant, there are many other plant growth-promoting (PGP) capabilities of these organisms to be demonstrated. The diversity of PGP traits across different taxa of switchgrass-colonizing endophytes is understudied, yet critical for understanding endophytic function and improving cultivation methods of important commodity crops. Here, we present the isolation and characterization of three diazotrophic endophytes: Azospirillum agricola R1C, Klebsiella variicola F10Cl, and Raoultella terrigena R1Gly. Strains R1C and F10Cl were isolated from switchgrass and strain R1Gly, while isolated from tobacco, is demonstrated herein to colonize switchgrass. Each strain exhibited highly diverse genomic and phenotypic PGP capabilities. Strain F10Cl and R1Gly demonstrated the highest functional similarity, suggesting that, while endophyte community structure may vary widely based on host species, differences in functional diversity are not a clearly delineated. The results of this study advance our understanding of diazotrophic endophyte diversity, which will allow us to design robust strategies to improve cultivation methods of many economically important commodity crops.

59 BASIC BIOLOGICAL SCIENCES↗

Estimating the variable cost for high-volume and long-haul transportation of densified biomass and biofuel

This article analyzes rail transportation costs of products that have similar physical properties as densified biomass and biofuel. The results of this cost analysis are useful to understand the relationship and quantify the impact of a number of factors on rail transportation costs of denisfied biomass and biofuel. These results will be beneficial and help evaluate the economic feasibility of high-volume and long-haul transportation of biomass and biofuel. High-volume and long-haul rail transportation of biomass is a viable transportation option for biofuel plants, and for coal plants which consider biomass co-firing. Using rail optimizes costs, and optimizes greenhouse gas (GHG) emissions due to transportation. Increasing bioenergy production would consequently result in lower GHG emissions due to displacing fossil fuels. To estimate rail transportation costs we use the carload waybill data, provided by Department of Transportation’s Surface Transportation Board for products such as grain and liquid type commodities for 2009 and 2011. We used regression analysis to quantify the relationship between variable transportation unit cost ($/ton) and car type, shipment size, rail movement type, commodity type, etc. The results indicate that: (a) transportation costs for liquid is $2.26/ton–$5.45/ton higher than grain type commodity; (b) transportation costs in 2011 were $1.68/ton–$5.59/ton higher than 2009; (c) transportation costs for single car shipments are $3.6/ton–$6.68/ton higher than transportation costs for multiple car shipments of grains; (d) transportation costs for multiple car shipments are $8.9/ton and $17.15/ton higher than transportation costs for unit train shipments of grains.

09 BIOMASS FUELS↗

SIGNATURES OF ILLICIT NUCLEAR PROCUREMENT NETWORKS: AN OVERVIEW OF PRELIMINARY APPROACHES AND RESULTS

The illicit trafficking of strategic nuclear commodities (defined here as the goods needed for a covert nuclear program excluding special nuclear materials) poses a significant challenge to the international nuclear nonproliferation community. Export control regulations, both domestically and internationally, seek to inhibit the spread of strategic nuclear commodities by restricting their sale to parties that may use them for nefarious purposes. However, export controls alone are not sufficient for preventing the illicit transfer of strategic nuclear goods. There are two major pitfalls to relying solely on export control regulations for the deterrence of proliferation of strategic goods. First, export control enforcement today relies heavily on the honesty and willingness of participants to adhere to the legal framework already in place. Secondly, current practices focus on the evaluation of single records which allow for the necessary goods to be purchased separately and hidden within the thousands of legitimate commerce transactions that occur each day, disregarding strategic information regarding several purchases. Our research presents two preliminary data-centric approaches for investigating procurement networks of strategic nuclear commodities. Pacific Northwest National Laboratory (PNNL) has been putting significant effort into nonproliferation activities as an institution, both in terms of the classical nuclear material focused approach and in the examination of other strategic goods necessary to implement a nuclear program. In particular, the PNNL Signature Discovery Initiative (SDI) has codified several scientific methodologies for the detection, characterization, and prediction of signatures that are indicative of a phenomenon of interest. The methodologies and tools developed under SDI have already been applied successfully to problems in bio-forensics, cyber security and power grid balancing efforts and they have now made the nonproliferation of strategic goods into a challenge problem for testing their methodology and tools. As a first step towards the detection and characterization of illicit procurement networks, our research examines procurement networks as defined by a system of entities (people or companies) that enter into transactions of specific items with one another. Once we have defined such networks, we are interested in answering questions about the behavior and characterization of such networks. The questions we wish to answer regarding procurement networks are, first, “Can we detect networks within large, noisy datasets?” and second, “To what extent can we compare multiple networks and identify their similarities?” As procurement networks can be naturally viewed as a graph, we have employed several graph analytic tools to aid in these tasks. In particular, Graphscape, an SDI tool, uses a novel method to approximate edit distance, a graph distance measure based on the number of changes needed to transform one graph into another, in order to measure how similar two given graphs are to each other. Given a set of graphs where vertices represent companies and edges represent a shipment from company A to company B, we can calculate an all-for-all comparison of graphs. In this way, we are able to determine which graphs are most similar, and which require more changes to transform one into the other. The set of graphs to be compared can be further specialized to provide more insight, e.g., using different time periods to explore events in a company life cycle.

graph analysis↗

A Demonstration of Blockchain-Based Energy Transactions between Laboratory Test Homes

Current electricity payment mechanisms and accessible value streams are inhibiting innovation in energy markets that stand to enhance grid security and resilience and enable increased integration of distributed energy resources (DER). In the era of near-instantaneous settlement times brought about by blockchain technology, the unidirectional (customer --> utility) monthly settlement of the incumbent infrastructure appears arcane. The lack of an effective market interface for DER results in fewer value streams for customers, underutilized assets for utilities, and reduced opportunities for vendors/manufacturers. A secure, real-time energy market enabled by blockchain technology presents a transformative opportunity to unlock innovations in DER and integrated controls. Blockchain technology provides a compelling pathway to energy market evolution, however there are several challenges to be addressed, including: simultaneous exchange of currency and energy commodities, ensuring customer privacy, incorporating transmission/distribution losses in energy trading contracts. To address the first of these - commodity tracking - we have established peer-to-peer energy transactions between two test homes at the National Renewable Energy Laboratory. Our research architecture demonstrates integration with high-fidelity metering for commodity tracking, and integration with NREL's foresee(TM) controls platform which orchestrates building loads and DER to execute the energy contract. The digital currency Dash, which supports enhanced privacy features and instant transactions, is employed for transaction settlement. BlockCypher's blockchain-agnostic web services are used to provide future flexibility in integrating various payment and contract options. In this paper we describe the technology, the research methodology employed, and present results on transaction execution speed and compliance with energy trading contracts.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Polyketide synthases as a platform for chemical product design

To reduce the effects of greenhouse gas emissions on climate change, scientific efforts have sought to develop biofuels and bio‐based commodity chemicals as petrochemical replacements primarily for their environmental benefits. As the biological design space is far greater than chemical synthesis, there has been a drive to leverage this ability to create and replace fine and specialty chemicals. While polyketide synthases have traditionally been studied for their biosynthesis of pharmaceutical chemicals, the unique advantages of engineering polyketide synthases for the production of biofuels, commodity chemicals, and both pharmaceutical and nonpharmaceutical fine and specialty chemicals are discussed. With our increased understanding of polyketide biosynthetic logic, new computational tools for prospective polyketide synthesis pathways for the creation of existing and novel biochemicals are also outlined. © 2018 American Institute of Chemical Engineers AIChE J , 64: 4201–4207, 2018

Zargar, Amin↗

Introducing perennial biomass crops into agricultural landscapes to address water quality challenges and provide other environmental services: Integrating perennial bioenergy crops into agricultural landscapes

The world is faced with a difficult multiple challenge of meeting nutritional, energy, and other basic needs, under a limited land and water budget, of between 9 and 10 billion people in the next three decades, mitigating impacts of climate change, and making agricultural production resilient. More productivity is expected from agricultural lands, but intensification of production could further impact the integrity of our finite surface water and groundwater resources. Integrating perennial bioenergy crops in agricultural lands could provide biomass for biofuel and potential improvements on the sustainability of commodity crop production. This article provides an overview of ways in which research has shown that perennial bioenergy grasses and short rotation woody crops can be incorporated into agricultural production systems with reduced indirect land use change, while increasing water quality benefits. Current challenges and opportunities as well as future directions are also highlighted.

Cacho, J. F.↗

Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives

Catalytic fast pyrolysis (CFP) is a conversion process that integrates rapid thermochemical depolymerization of solid feedstocks with catalytic transformation to yield small molecules for fuel and chemical products. This process is well-suited for the conversion of nonfossil feedstocks such as biomass and waste plastics, and thereby holds great potential for the production of renewable commodities. In spite of many technological developments in various aspects of CFP achieved over decades of research, this technology has yet to attain commercial success for the production of fuels and chemicals from renewable feedstocks. Effective CFP processes require careful coordination of chemical and physical phenomena that span very large length and time scales. A broad spectrum of scientific progress in both pyrolysis and catalytic upgrading has provided the foundation for successful deployment of CFP, although additional progress in process-scale integration is yet required for commercial realization. Modeling and simulation tools provide an important framework wherein the CFP technologies by be better understood and evaluated from a holistic perspective. Here we provide a detailed description of the multiscale phenomena underlying CFP, describe challenges and associated technical progress, and suggest strategies for an integrated approach to advance this technology toward commercialization.

09 BIOMASS FUELS↗

Portable SHMEMCache: A High-Performance Key-Value Store on OpenSHMEM and MPI

The integration of Big Data frameworks and HPC capabilities has drawn enormous interests in recent years. SHMEMCache is a distributed key-value store built on the OpenSHMEM global address space. It has solved several practical issues in leveraging OpenSHMEM’s one-sided operations for a distributed key-value store and providing efficient key-value operations on both commodity machines and supercomputers. However, being based solely on OpenSHMEM, SHMEMCache cannot leverage one-sided operations from a variety of software packages. This results in several limitations for SHMEMCache. First, we cannot make SHMEMCache available to a wider range of platforms. Second, an opportunity for potential performance improvement is missed. Third, there is a lack of deep understanding about how different one-sided operations can fit in with SHMEMCache and other distributed key-values in general. For example, the one-sided operations in OpenSHMEM and MPI have many differences in their interfaces, memory semantics and synchronization methods, all of which can have distinct implications and also increase the complexity in supporting both OpenSHMEM and MPI for SHMEMCache. Therefore, we have taken on an effort on leveraging different one-sided operations for SHMEMCache and proposed a design of portable SHMEMCache. Based on this new framework, we have supported both OpenSHMEM and MPI for SHMEMCache. We have also conducted an extensive set of experiments to compare the performance of the two versions on both commodity machines and the Titan supercomputer.

Computer Science↗

Balancing global water availability and use at basin scale in an integrated assessment model

Water is essential for the world’s food supply, for energy production, including bioenergy and hydroelectric power, and for power system cooling. Water is already scarce in many regions of the world and could present a critical constraint as society attempts simultaneously to mitigate climate forcing and adapt to climate change, and to provide for a larger and more prosperous human population. Numerous studies have pointed to growing pressures on the world’s scarce fresh water resources from population and economic growth, and climate change. This study goes further. We use the Global Change Assessment Model to analyze interactions between population, economic growth, energy, land and water resources simultaneously in a dynamically evolving system where competing claims on water resources from all claimants—energy, land, and economy—are reconciled with water resource availability—from renewable water, non-renewable groundwater sources and desalinated water—across 14 geopolitical regions, 151 agriculture-ecological zones, and 235 major river basins. We find that previous estimates of global water withdrawal projections are overestimated. Model simulations show that it is more economical in some basins to alter agricultural and energy activities rather than utilize non-renewable groundwater or desalinated water. This study highlights the importance of accounting for water as a binding factor in agriculture, energy and land use decisions in IAMs and implications for global responses to water scarcity, particularly in the trade of agricultural commodities and land-use decisions.

basin↗

Electrochemical Reduction Selectivity of Crotonaldehyde on Copper

Lignocellulosic waste is a potential feedstock for the generation of fuels and commodity chemicals, but existing conversion methods are too cost-intensive to be viable long-term solutions. Electrochemical reductions are promising for decentralized biomass valorization due to their modular scaling and capacity to run intermittently and without high temperatures or pressures. Using crotonaldehyde as a multi-functional model compound for the many partially unsaturated oxygenates found in processed biomass, we here demonstrate the production of butanal, butanol, butene, and butane (variously useful as commodity chemicals and major components of liquified petroleum gas) under ambient conditions by reductive bulk electrolysis with a copper mesh working electrode. We identify an optimum potential for reduced organic production under the reaction conditions and compare product distributions from reductions of intermediate species to further propose branching reaction pathways. Though butanal is typically the most abundant product from crotonaldehyde reduction, most of the butene and butane appear to result from a pathway involving initial reduction of the aldehyde group. We discuss evidence that selectivity is driven by interplay between crotonaldehyde reduction, local pH shifts due to the hydrogen evolution reaction, and changes in site reactivity and availability due to electrode fouling. This demonstration of model electrochemical biomass valorization also serves to inform further exploration into reduction of multi-functional molecules and electrochemical biomass processing in general.

biomass↗

Unconventional Energy Resources: 2015 Review

This paper includes 10 summaries for energy resource commodities including coal and unconventional resources, and an analysis of energy economics and technology prepared by committees of the Energy Minerals Division of the American Association of Petroleum Geologists. Unconventional energy resources, as used in this report, are those energy resources that do not occur in discrete oil or gas reservoirs held in structural or stratigraphic traps in sedimentary basins. Such resources include coalbed methane, oil shale, U and Th deposits and associated rare earth elements of industrial interest, geothermal, gas shale and liquids, tight gas sands, gas hydrates, and bitumen and heavy oil. Current U.S. and global research and development activities are summarized for each unconventional energy resource commodity in the topical sections of this report, followed by analysis of unconventional energy economics and technology.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Economics of plant oil recovery: A review

Plant oil is a major agricultural commodity used in food, feed, and chemicals. Presently plant oil is produced from oil seeds either using mechanical pressing or solvent extraction. These technologies have steadily improved for increased oil recovery; however, production cost is especially important for a commodity. Here in this paper three technologies and their costs are reviewed for on-farm pressing, industrial mechanical pressing, and solvent extraction. Solvent extraction is the dominant technology because it offers high oil recovery and low production cost. In contrast, industrial mechanical pressing has the highest production cost because of its low oil yield; nevertheless, the simple process results in the lowest fixed capital investment. For on-farm pressing, lower material cost results in lower production cost than industrial mechanical pressing. Additionally, credits from co-products play an important role in determining total revenues, especially for mechanical pressing. Therefore, broadening the applications and values of the co-product is also critical for profitability for the plant oil industry.

09 BIOMASS FUELS↗

Evapotranspiration of advanced perennial bioenergy grasses produced on marginal land in the U.S. Midwest

The production of dedicated energy crops for biofuel and co-products can help develop a sustainable and viable bioeconomy under a changing climate. The co-production of perennial bioenergy and commodity crops in an agricultural landscape has the potential to reduce greenhouse gas emissions and provide numerous ecosystem services. However, as production of advanced, higher-yielding cultivars occurs, their impact on water resources needs to be considered. Estimates of evapotranspiration (ET) of perennial grasses compared to commodity crops are not always consistent in the literature. In this study, ET was estimated using an energy-balance model with Landsat satellite imagery and ground-based weather data to compare the large-scale production of advanced switchgrass cultivars (‘Independence’, ‘Liberty’, and ‘Carthage’), predecessor cultivars (‘Shawnee’ and ‘Sunburst’), and other perennial grasses (big bluestem and a low-diversity mixture) to corn grown continuously on marginal soils in the U.S. Midwest. Results showed significant differences in ET between corn and perennial grass treatments at four of the five field sites. However, differences between crop treatments were not consistent across sites, nor were the differences between advanced and predecessor switchgrass varieties. Production year played a large role in daily and cumulative ET across all sites. Differences in crop biomass yield between establishment and post-establishment years may contribute to these interannual differences. Site and interannual variations in precipitation and temperature may also be major contributing factors. Overall, the results of this study indicate that differences in ET between perennial bioenergy grasses and corn are likely dependent upon location of production and weather conditions.

09 BIOMASS FUELS↗

What are the effects of Agro-Ecological Zones and land use region boundaries on land resource projection using the Global Change Assessment Model?

Understanding the potential impacts of climate change is complicated by mismatched spatial representations between gridded Earth System Models (ESMs) and Integrated Assessment Models (IAMs), whose regions are typically larger and defined by geopolitical and biophysical criteria. In this study we address uncertainty stemming from the construction of land use regions in an IAM, the Global Change Assessment Model (GCAM), whose regions are currently based on historical climatic conditions (1961-1990). We re-define GCAM’s regions according to projected climatic conditions (2070-2099), and investigate how this changes model outcomes for land use, agriculture, and forestry. By 2100, we find potentially large differences in projected global and regional area of biomass energy crops, fodder crops, harvested forest, and intensive pasture. These land area differences correspond with changes in agricultural commodity prices and production. These results have broader implications for understanding policy scenarios and potential impacts, and for evaluating and comparing IAM and ESM simulations.

54 ENVIRONMENTAL SCIENCES↗