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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Polarization and the envelopes of B(e) supergiants in the Magellanic Clouds

We report optical linear polarization observations of nine B(e) supergiants in the Magellanic Clouds. Several of them have large intrinsic polarizations. The data are consistent with nonspherically symmetric envelopes, around the B(e) stars, that possess a range of intrinsic polarizations. Comparison of the polarimetric data with the viewing aspect, inferred from the spectroscopy of the individual objects, agrees with this interpretation. The polarization correlates best with the infrared excess due to dust, suggesting the latter as the cause of most of the polarization. We cannot find, using the available data, a statistically significant difference between the polarization distributions of Galactic and Magellanic B(e) stars. Comparison of our data with previous polarimetric data, recovered from the literature for four stars, seems to indicate that the envelopes are stable.

Magalhaes, A. M.↗
NASA NTRS1994

A HIRES analysis of the FIR emission of supernova remnants

The high resolution (HiRes) algorithm has been used to analyze the far infrared emission of shocked gas and dust in supernova remnants. In the case of supernova remnant IC 443, we find a very good match between the resolved features in the deconvolved images and the emissions of shocked gas mapped in other wavelengths (lines of H2, CO, HCO+, and HI). Dust emission is also found to be surrounding hot bubbles of supernova remnants which are seen in soft X-ray maps. Optical spectroscopy on the emission of the shocked gas suggests a close correlation between the FIR color and local shock speed, which is a strong function of the ambient (preshock) gas density. These provide a potentially effective way to identify regions of strong shock interaction, and thus facilitate studies of kinematics and energetics in the interstellar medium.

Wang, Zhong↗
NASA NTRS2018

Efficacy of FTIR Analysis in Determining CO2 Loading on Diglycolamine

In support of advanced air revitalization technologies to enable human spaceflight beyond low earth orbit, performance studies have been conducted using a liquid amine, Diglycolamine (DGA) between teams at NASA?s Johnson Spaceflight Center (JSC) and Ames Research Center (ARC). Liquid amines have been used in regenerable earth-based systems to remove CO2 from industrial systems as well as for closed-environment air revitalization because they can be regenerated at lower temperatures than solid sorbent systems. As an additional advantage to solid sorbent based systems, liquid sorbents can be cycled between an adsorbing contactor and degassing chamber, thereby reducing system complexity by operation in a continuous loop. In an effort to inform a regeneration system design for micro-gravity applications, ARC has performed a number of tests to characterize the degas mechanics of DGA. In order to accurately measure the amount of CO2 captured or released by the amine, methods such as gravimetric weighing and chemical decomposition are reasonable, however the initial design for a scaled down degas system required analysis on small sample sizes. In order to accomplish CO2 loading measurements with a sample size of approximately 500µL, Fourier-transform infrared spectroscopy (FTIR) was used. Calibration against acid decomposition showed relatively good correlation and test data showed reasonable adherence to expected trends, however more extensive testing should be conducted to fully validate the usage of FTIR to determine CO2 loading on DGA.

Diglycolamine↗
NASA NTRS1996

NO(y) Correlation with N2O and CH4 in the Midlatitude Stratosphere

Total reactive nitrogen (NO(y)), nitrous oxide (NO2), methane (CH4), and ozone (03) were measured on board a balloon launched from Aire sur l'Adour (44 deg N, 0 deg W), France on October 12, 1994. Generally, NO(y) was highly anti-correlated with N2O and CH4 at altitudes between 15 and 32 km. The linear NO(y) - N2O and NO(y) - CH4 relationships obtained by the present observations are very similar to those obtained on board ER-2 and DC-8 aircraft previously at altitude below 20 km in the northern hemisphere. They also agree well with the data obtained by the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument at 41 deg N in November 1994. Slight departures from linear correlations occurred around 29 km, where N2O and CH4 mixing ratios were larger than typical midlatitude values, suggesting horizontal transport of tropical airmasses to northern midlatitudes in a confined altitude region.

Kondo, Y.↗
NASA NTRS1979

Chemical abundances in Hg-Mn stars

An abundance analysis has been conducted of 21 elements in 21 Hg-Mn, two Si-Cr, and six normal stars using model atmospheres and high-dispersion spectroscopy in the visible and UV. Manganese line strengths imply abundances that correlate well with stellar effective temperature. Within the studied sample of Hg-Mn stars there appears to be no correlation of abundances of any element with projected rotational velocity. Abundances in several Hg-Mn stars show patterns that are probably consistent with diffusion but difficult to reconcile with equilibrium nucleosynthesis. In general, no combination of gross stellar physical parameters is sufficient to characterize the patterns of line strengths observed in Hg-Mb Hg-Mn stars.

Heacox, W. D.↗
NASA NTRS2006

Characterization and Petrologic Interpretation of Olivine-Rich Basalts at Gusev Crater, Mars

Rocks on the floor of Gusev crater are basalts of uniform composition and mineralogy. Olivine, the only mineral to have been identified or inferred from data by all instruments on the Spirit rover, is especially abundant in these rocks. These picritic basalts are similar in many respects to certain Martian meteorites (olivine-phyric shergottites). The olivine megacrysts in both have intermediate compositions, with modal abundances ranging up to 20-30%. Associated minerals in both include low-calcium and high-calcium pyroxenes, plagioclase of intermediate composition, iron-titanium-chromium oxides, and phosphate. These rocks also share minor element trends, reflected in their nickel-magnesium and chromium-magnesium ratios. Gusev basalts and shergottites appear to have formed from primitive magmas produced by melting an undepleted mantle at depth and erupted without significant fractionation. However, apparent differences between Gusev rocks and shergottites in their ages, plagioclase abundances, and volatile contents preclude direct correlation. Orbital determinations of global olivine distribution and compositions by thermal emission spectroscopy suggest that olivine-rich rocks may be widespread. Because weathering under acidic conditions preferentially attacks olivine and disguises such rocks beneath alteration rinds, picritic basalts formed from primitive magmas may even be a common component of the Martian crust formed during ancient and recent times.

McSween, H. Y.↗
NASA NTRS2018

Segregation-Assisted Plasticity in Ni-Based Superalloys

Correlative high resolution transmission electron microscopy and energy dispersive X-ray spectroscopy are used to study deformation-induced planar faults in the single crystal superalloy MD2 crept at 800°C and 650 MPa. Segregation of Cr and Co at microtwins, APBs, CISFs/SISFs and CESFs/SESFs is confirmed and quantified. The extent of this is found to depend upon the fault type, being most pronounced for the APB. The CESF/SESF is studied in detail due to its role as a precursor of the microtwins causing the majority of plasticity under these conditions. Quantitative modelling is carried out to rationalize the findings; the experimental results are consistent with a greater predicted velocity for the lengthening of the CESF/SESF { compared with the other types of fault { and hence confirm its role in the diffusion-assisted plasticity needed for the microtwinning mechanism to be operative.

Barba, D.↗
NASA NTRS2006

Electrostatic Properties of PE and PTFE Subjected to Atmospheric Pressure Plasma Treatment; Correlation of Experimental Results with Atomistic Modeling

The use of an atmospheric pressure glow discharge (APGD) plasma was used at KSC to increase the hydrophilicity of spaceport materials to enhance their surface charge dissipation and prevent possible ESD in spaceport operations. Significant decreases in charge decay times were observed after tribocharging the materials using the standard KSC tribocharging test. The polarity and amount of charge transferred was dependent upon the effective work function differences between the respective materials. In this study, polyethylene (PE) and polytetrafluoroethylene (PTFE) were exposed to a He+O2 APGD. The pre and post treatment surface chemistry was analyzed by X-ray photoelectron spectroscopy and contact angle measurements. Semi-empirical and ab initio calculations were performed to correlate the experimental results with some plausible molecular and electronic structure features of the oxidation process. For the PE, significant surface oxidation was observed, as indicated by XPS showing C-O, C=O, and O-C=O bonding, and a decrease in the surface contact angle from 98.9 deg to 61.2 deg. For the PTFE, no C-O bonding appeared and the surface contact angle increased indicating the APGD only succeeded in cleaning the PTFE surface without affecting the surface structure. The calculations using the PM3 and DFT methods were performed on single and multiple oligomers to simulate a wide variety of oxidation scenarios. Calculated work function results suggest that regardless of oxidation mechanism, e.g. -OH, =0 or a combination thereof, the experimentally observed levels of surface oxidation are unlikely to lead to a significant change in the electronic structure of PE and that its increased hydrophilic properties are the primary reason for the observed changes in its electrostatic behavior. The calculations for PTFE argue strongly against significant oxidation of that material, as confirmed by the XPS results.

Trigwell, Steve↗
NASA NTRS1973

Atom beam surface interaction studies: Experimental system development

Quantitative deposition by standard techniques of adsorbates containing C and Si onto selected substrates is studied. The interaction kinetics of a beam of oxygen, nitrogen, or hydrogen atoms of known flux are investigated by Auger electron spectroscopy and LEED. Desborbed molecules will be analyzed by mass spectroscopy using modulated beam techniques. Experimental conditions permitting, two sets of measurements will be correlated.

Gregory, J. C.↗
NASA NTRS1985

Fourier transform-infrared spectroscopic methods for microbial ecology: analysis of bacteria, bacteria-polymer mixtures and biofilms

Fourier transform-infrared (FT-IR) spectroscopy has been used to rapidly and nondestructively analyze bacteria, bacteria-polymer mixtures, digester samples and microbial biofilms. Diffuse reflectance FT-IR (DRIFT) analysis of freeze-dried, powdered samples offered a means of obtaining structural information. The bacteria examined were divided into two groups. The first group was characterized by a dominant amide I band and the second group of organisms displayed an additional strong carbonyl stretch at approximately 1740 cm-1. The differences illustrated by the subtraction spectra obtained for microbes of the two groups suggest that FT-IR spectroscopy can be utilized to recognize differences in microbial community structure. Calculation of specific band ratios has enabled the composition of bacteria and extracellular or intracellular storage product polymer mixtures to be determined for bacteria-gum arabic (amide I/carbohydrate C-O approximately 1150 cm-1) and bacteria-poly-beta-hydroxybutyrate (amide I/carbonyl approximately 1740 cm-1). The key band ratios correlate with the compositions of the material and provide useful information for the application of FT-IR spectroscopy to environmental biofilm samples and for distinguishing bacteria grown under differing nutrient conditions. DRIFT spectra have been obtained for biofilms produced by Vibrio natriegens on stainless steel disks. Between 48 and 144 h, an increase in bands at approximately 1440 and 1090 cm-1 was seen in FT-IR spectra of the V. natriegens biofilm. DRIFT spectra of mixed culture effluents of anaerobic digesters show differences induced by shifts in input feedstocks. The use of flow-through attenuated total reflectance has permitted in situ real-time changes in biofilm formation to be monitored and provides a powerful tool for understanding the interactions within adherent microbial consortia.

NASA Discipline Number 61-10↗
NASA NTRS1995

Nondestructive Determination of Heat/Fire Damage to Polymer- Matrix Composites Using Obliquely Insonified Ultrasonic Waves

Heat and fire damage to composite structures cause loss of strength that cannot be detected by current NDE methods unless physical damage occurs. Further, there is a lack of fundamental understanding of the mechanism of damage from thermal exposure of organic matrix composites to elevated temperatures. Information compiled from field reports and lab experiments increasingly suggests that there is material degradation and it is not necessarily involved with the introduction of physical defects. In recent years, various researchers examined the potential to identifying thermal degradation to organic matrix composites prior to delamination. The methods that were used include: ultrasonics, backscattered X-ray, eddy current, thermography, drift and LPF spectroscopies, acousto-ultrasonics and hardness testing. None of these methods were able to correlate NDE results with loss of mechanical properties.

polymer-matrix composite fire damage NDE nondestru↗
NASA NTRS2011

Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing

Evaluation of metal-based structures has long relied on atmospheric exposure test sites to determine corrosion resistance in marine environments. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions of the corrosive environment. Their success for correlation to atmospheric exposure is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated laboratory testing, which often focuses on the electrochemical reactions that occur during corrosion conditions, has yet to be universally accepted as a useful tool in predicting the long term service life of a metal despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard and their use is imperative, a method that correlates timescales from atmospheric exposure to accelerated testing would be very valuable. This work uses surface chemistry to interpret the chemical changes occurring on low carbon steel during atmospheric and accelerated corrosion conditions with the objective of finding a correlation between its accelerated and long-term corrosion performance. The current results of correlating data from marine atmospheric exposure conditions at the Kennedy Space Center beachside corrosion test site, alternating seawater spray, and immersion in typical electrochemical laboratory conditions, will be presented. Key words: atmospheric exposure, accelerated corrosion testing, alternating seawater spray, marine, correlation, seawater, carbon steel, long-term corrosion performance prediction, X-ray photoelectron spectroscopy.

Montgomery, Eliza L.↗
NASA NTRS2007

Nonthermal X-ray Spectral Flattening toward Low Energies in Early Impulsive Flares

The determination of the low-energy cutoff to nonthermal electron distributions is critical to the calculation of the nonthermal energy in solar flares. The most direct evidence for low-energy cutoffs is flattening of the power-law, nontherma1 X-ray spectra at low energies. However, because of the plasma preheating often seen in flares, the thermal emissions at low energies may hide such spectral flattening of the nonthermal component. We select a category of flares, which we call "early impulsive flares", in which the > 25 keV hard X-ray (HXR) flux increase is delayed by less than 30 s after the flux increase at lower energies. Thus, the plasma preheating in these flares is minimal, so the nonthermal spectrum can be determined to lower energies than in flares with significant preheating. Out of a sample of 33 early impulsive flares observed by the Ramaty High Energy Solar Spectroscopy Imager (RHESSI), 9 showed spectral flattening toward low energies. In these events, the break energy of the double power-law fit to the HXR spectra lies in the range of 10-50 keV, significantly lower than the value we have seen for other flares that do not show such early impulsive emissions. In particular, it correlates with the HXR flux. After correcting the spatially-integrated spectra for albedo from isotropically emitted X-rays and using RHESSI imaging spectroscopy to exclude the extended albedo halo, we find that albedo associated with isotropic or nearly isotropic electrons can only account for the spectral flattening in 3 flares near Sun center. The spectral flattening in the remaining 6 flares is found to be consistent with the existence of a low-energy cutoff in the electron spectrum, falling in the range of 15-50 keV, which also correlates with the HXR flux.

Holman, Gordon D.↗
NASA NTRS2003

Determination of Lubricants on Ball Bearings by FT-IR using an Integrating Sphere

The lifetime determination of space lubricants is done at our facility by accelerated testing. Several micrograms of lubricant are deposited on the surface of a ball by syringing tens of micro liters of dilute lubricant solution. The solvent evaporates and the mass of lubricant is determined by twenty weighings near the balance reliability limit. This process is timely but does not produce a good correlation between the mass of lubricant and the volume of solution applied, as would be expected. The amount of lubricant deposited on a ball can be determined directly by Fourier Transform - Infrared Spectroscopy using an integrating sphere. In this paper, we discuss reasons for choosing this methodology, optimization of quantification conditions and potential applications for the technique. The volume of lubricant solution applied to the ball gives better correlation to the IR intensity than does the weight.

Street, K. W.↗
NASA NTRS1979

Electron energy-loss spectra in molecular fluorine

Electron energy-loss spectra in molecular fluorine, for energy losses from 0 to 17.0 eV, have been taken at incident electron energies of 30, 50, and 90 eV and scattering angles from 5 to 140 deg. Features in the spectra above 11.5 eV energy loss agree well with the assignments recently made from optical spectroscopy. Excitations of many of the eleven repulsive valence excited electronic states are observed and their location correlates reasonably well with recent theoretical results. Several of these excitations have been observed for the first time and four features, for which there are no identifications, appear in the spectra.

Nishimura, H.↗
NASA NTRS2010

The Multispectral Microscopic Imager: Integrating Microimaging with Spectroscopy for the In-Situ Exploration of the Moon

To maximize the scientific return, future robotic and human missions to the Moon will need to have in-situ capabilities to enable the selection of the highest value samples for returning to Earth, or a lunar base for analysis. In order to accomplish this task efficiently, samples will need to be characterized using a suite of robotic instruments that can provide crucial information about elemental composition, mineralogy, volatiles and ices. Such spatially-correlated data sets, which place mineralogy into a microtextural context, are considered crucial for correct petrogenetic interpretations. . Combining microscopic imaging with visible= nearinfrared reflectance spectroscopy, provides a powerful in-situ approach for obtaining mineralogy within a microtextural context. The approach is non-destructive and requires minimal mechanical sample preparation. This approach provides data sets that are comparable to what geologists routinely acquire in the field, using a hand lens and in the lab using thin section petrography, and provide essential information for interpreting the primary formational processes in rocks and soils as well as the effects of secondary (diagenetic) alteration processes. Such observations lay a foundation for inferring geologic histories and provide "ground truth" for similar instruments on orbiting satellites; they support astronaut EVA activities and provide basic information about the physical properties of soils required for assessing associated health risks, and are basic tools in the exploration for in-situ resources to support human exploration of the Moon.

Nunez, J. I.↗
NASA NTRS2010

Optical Studies on Antimonide Superlattice Infrared Detector Material

In this study the material quality and optical properties of type II InAs/GaSb superlattices are investigated using transmission and photoluminescence (PL) spectroscopy. The influence of the material quality on the intensity of the luminescence and on the electrical properties of the detectors is studied and a good correlation between the photodetector current-voltage (IV) characteristics and the PL intensity is observed. Studies of the temperature dependence of the PL reveal that Shockley-Read-Hall processes are limiting the minority carrier lifetime in both the mid-IR wavelength and the long-IR wavelength detector material studied. These results demonstrate that PL spectroscopy is a valuable tool for optimization of infrared detectors.

heterostructure↗