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Results for “crystal design”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Bragg crystal spectrometer for HEAO-B X-ray astronomy experiment

The X-ray astronomy experiment for the HEAO mission is described. The instrument to be flown on the satellite consists of two Bragg crystal spectrometers designed to make measurements with high spectral resolution in the energy range from 0.1 to 10 keV. No sharp spectroscopic features were detected directly in X-ray astronomy except emission lines in the sun; therefore, the objectives and design criteria of this instrument are based on the theoretical models of the different types of extra solar X-ray sources. From the point of view of instrumental techniques it is convenient to divide these into point or stellar sources, whose radiation is parallel, and diffuse sources, and to consider the possible spectral features in each type.

Angel, J. R. P.↗
NASA NTRS1974

The influence of acceleration forces on nucleation, solidification, and deformation processes in tin single crystals

An apparatus was designed and assembled to directionally solidify single crystals under the influence of acceleration forces of various magnitudes. The investigation conducted showed that acceleration gradients produce a preferred growth orientation effect not previously observed for tin. Convection currents at approximately 5-g encourage multiple nucleation and subsequent random orientation of growth direction. Deformation effects such as recrystallization and twinning are observed at acceleration levels greater than 2-g.

Johnston, M. H.↗
NASA NTRS1975

Cryogenic Quartz Crystal Microbalance

A radiatively cooled Cryogenic Quartz Crystal Microbalance designed to monitor highly volatile contaminants on the shuttle is described. Measurements are made with two 15-MHz microbalances having removable, optically polished sensors mounted in a radiant cooler. One sensor operates below the freezing point of water and monitors contamination including that of water vapor. The second sensor is heated and monitors the contamination background. It provides a reference from which the density of the water vapor cloud enveloping the shuttle is determined. The design incorporates a low-power dissipation oscillator, heaters for ice removal, and a method for attaching second-surface mirrors to the radiator employing an indium type solder instead of a room temperature vulcanizer.

D Mckeown↗
NASA NTRS1983

Large-area sheet task: Advanced dendritic-web-growth development

Thermally generated stresses in the growing web crystal were reduced. These stresses, which if too high cause the ribbon to degenerate, were reduced by a factor of three, resulting in the demonstrated growth of high-quality web crystals to widths of 5.4 cm. This progress was brought about chiefly by the application of thermal models to the development of low-stress growth configurations. A new temperature model was developed which can analyze the thermal effects of much more complex lid and top shield configurations than was possible with the old lumped shield model. Growth experiments which supplied input data such as actual shield temperature and melt levels were used to verify the modeling results. Desirable modifications in the melt level-sensing circuitry were made in the new experimental web growth furnace, and this furnace has been used to carry out growth experiments under steady-state conditions. New growth configurations were tested in long growth runs at Westinghouse AESD which produced wider, lower stress and higher quality web crystals than designs previously used.

Duncan, C. S.↗
NASA NTRS1985

An experimental assessment of the imaging quality of the low energy gamma-ray telescope ZEBRA

One gamma-ray detection plane of the ZEBRA telescope, consisting of nine position sensitive scintillation crystal bars designed to operate over the spectral range 0.2 to 10 MeV, has been constructed in the laboratory. A series of experimental images has been generated using a scaled down flight pattern mask in conjunction with a diverging gamma-ray beam. Point and extended sources have been imaged in order to assess quantitatively the performance of the system.

Butler, R. C.↗
NASA NTRS1990

Bragg crystal polarimeters

A Bragg crystal oriented at 45 deg to an incoming beam of X-rays acts as a polarization analyzer. This crystal geometry preferentially reflects those X-rays that satisfy the Bragg condition and whose electric vectors are perpendicular to the plane defined by the incident and reflected photons. X-rays with electric vectors parallel to this plane of incidence are photoelectrically absorbed. The energy bandwidth of nearly perfect crystals is extremely small, which makes them very inefficient X-ray polarimeters. This limitation is particularly acute for observations of the relatively weak X-ray continuum of stellar sources. The bandwidth can be greatly increased by employing mosaic or ideally imperfect crystals. Mosaic crystals possess a high integrated reflectivity, which results in a large increase in the reflection of continuum radiation. A review of the theory and performance characteristics of crystal polarimeters designed for observations of cosmic X-ray sources is presented.

Silver, E.↗
NASA NTRS1990

Effects of additives on the processing and properties of LARC-TPI polyimide

The blending of LARC-TPI polyimide with the thermotropic liquid crystal polymer designated Xydar and with four different oligomeric imide materials has facilitated the resulting resin systems' processing into films while enhancing their mechanical properties and lowering their coefficient of thermal expansion to virtually zero. Two film-formation processes have been evaluated: (1) the casting of polyamic acid films followed by thermal imidization and biaxial stretching, and (2) the blown-film melt-extrusion of fully imidized LARC-TPI polymer. The best results have been obtained through the use of Xydar as a processing aid at levels in the 10-30 percent range.

Elandjian, L.↗
NASA NTRS2010

Study of Fabry-Perot Etalon Stability and Tuning for Spectroscopic Rayleigh Scattering

The Fabry-Perot interferometer is a commonly employed instrument for resolving the spectrum of molecular Rayleigh scattered light for the purpose of evaluating flow properties such as gas velocity and temperature. Rayleigh scattered light from a focused laser beam can be directly imaged through a solid Fabry-Perot etalon onto a CCD detector to provide the spectral content of the scattered light. The spatial resolution of the measurements is governed by the locations of interference fringes. The location of the fringes can be changed by altering the etalon?s physical characteristics, such as thickness and index of refraction. For a fused silica solid etalon the physical properties can be adjusted by changing the etalon temperature; hence changing the order of the interference pattern and the physical fringe locations. Controlling the temperature of the etalon can provide for a slow time-response spatial scanning method for this type of etalon system. A custom designed liquid crystal Fabry-Perot (LCFP) can provide for a fast time-response method of scanning the etalon system. Voltage applied to the liquid crystal interface sets the etalon?s properties allowing Rayleigh measurements to be acquired at varying spatial locations across the image of the laser beam over a very short time period. A standard fused silica etalon and a tunable LCFP etalon are characterized to select the system that is best suited for Rayleigh scattering measurements in subsonic and supersonic flow regimes. A frequency-stabilized laser is used to investigate the apparent frequency stability and temperature sensitivity of the etalon systems. Frequency stability and temperature sensitivity data of the fused silica and LCFP etalon systems are presented in this paper, along with measurements of the LCFP etalon?s tuning capabilities. Rayleigh scattering velocity measurements with both etalon systems are presented, in an effort to determine which etalon is better suited to provide optical flow measurements of velocity, temperature, and density.

Clem, Michelle M.↗
DOE OSTI2023

An AI-driven microstructure optimization framework for elastic properties of titanium beyond cubic crystal systems

Materials design aims to identify the material features that provide optimal properties for various engineering applications, such as aerospace, automotive, and naval. One of the important but challenging problems for materials design is to discover multiple polycrystalline microstructures with optimal properties. This paper proposes an end-to-end artificial intelligence (AI)-driven microstructure optimization framework for elastic properties of materials. In this work, the microstructure is represented by the Orientation Distribution Function (ODF) that determines the volume densities of crystallographic orientations. The framework was evaluated on two crystal systems, cubic and hexagonal, for Titanium (Ti) in Joint Automated Repository for Various Integrated Simulations (JARVIS) database and is expected to be widely applicable for materials with multiple crystal systems. The proposed framework can discover multiple polycrystalline microstructures without compromising the optimal property values and saving significant computational time.

36 MATERIALS SCIENCE↗
NASA NTRS1994

Crystals of Human Serum Albumin for Use in Genetic Engineering and Rational Drug Design

This invention pertains to crystals of serum albumin and processes for growing them. The purpose of the invention is to provide crystals of serum albumin which can be studied to determine binding sites for drugs. Form 2 crystals grow in the monoclinic space P2(sub 1), and possesses the following unit cell constraints: a = 58.9 +/- 7, b = 88.3 +/- 7, c = 60.7 +/- 7, Beta = 101.0 +/- 2 degrees. One advantage of the invention is that it will allow rational drug design

Carter, Daniel C.↗
DOE OSTI2024

Design and fabrication of robust hybrid photonic crystal cavities

Abstract Heterogeneously integrated hybrid photonic crystal cavities enable strong light–matter interactions with solid state, optically addressable quantum memories. A key challenge to realizing high quality factor ( Q ) hybrid photonic crystals is the reduced index contrast on the substrate compared to suspended devices in air. This challenge is particularly acute for color centers in diamond because of diamond’s high refractive index, which leads to increased scattering loss into the substrate. Here, we develop a design methodology for hybrid photonic crystals utilizing a detailed understanding of substrate-mediated loss, which incorporates sensitivity to fabrication errors as a critical parameter. Using this methodology, we design robust, high-Q, GaAs-on-diamond photonic crystal cavities, and by optimizing our fabrication procedure, we experimentally realize cavities with Q approaching 30,000 at a resonance wavelength of 955 nm.

Abulnaga, Alex↗
DOE OSTI2021

An open-endcap blade trap for radial-2D ion crystals

We present the design and experimental demonstration of an open-endcap radio frequency trap to confine ion crystals in the radial-two dimensional (2D) structural phase. The central axis of the trap is kept free of obstructions to allow for site-resolved imaging of ions in the 2D crystal plane, and the confining potentials are provided by four segmented blade electrodes. We discuss the design challenges, fabrication techniques, and voltage requirements for implementing this open-endcap trap. Finally, we validate its operation by confining up to 29 ions in a 2D triangular lattice, oriented such that both in-plane principal axes of the 2D crystal lie in the radial direction.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2022

The role of amorphous ZIF in ZIF-8 crystallization kinetics and morphology

Understanding the composition and structure of amorphous precursor phases is fundamental for elucidating two-step crystallization mechanisms and designing shape- and size-controlled nanomaterials. However, that understanding is largely lacking for metal–organic framework compounds despite their growing significance as functional materials. Here, in this study, we report the crystallization of zeolite imidazolate frameworks-8 (ZIF-8, Zn(C 4 H 5 N 2 ) 2 ) via an amorphous ZIF (am-ZIF) solid precursor phase with a rough stoichiometric composition of Zn(C 4 H 5 N 2 ) 1.78 (C 4 H 6 N 2 ) 0.17 (CH 3 COO) 0.22 . The formation of am-ZIF is attributed to the incomplete deprotonation of 2-Methylimidazole (HmIm) and the involvement of the hydrogen bond between CH 3 COO– and –HN, which can further transform into the dense Dia(Zn) structure with a diamondoid crystal topology in pure water. Taking am-ZIF as a precursor, the tunable dissolution and recrystallization kinetics of am-ZIF into ZIF-8, due to the addition of EtOH and CTAB, allows the selective fabrication of dodecahedral, cubic, and hollow ZIF-8. Overall, an in-depth understanding of the differences in composition and structure of am-ZIF from ZIF-8 and the resulting crystallization kinetics suggests a novel approach to designing metal–organic frameworks with controlled crystal morphology.

36 MATERIALS SCIENCE↗
NASA NTRS1998

The Design of a Transparent Vertical Multizone Furnace: Application to Thermal Field Tuning and Crystal Growth

We present an innovative design of a vertical transparent multizone furnace which can operate in the temperature range of 25 C to 750 C and deliver thermal gradients of 2 C/cm to 45 C/cm for the commercial applications to crystal growth. The operation of the eight zone furnace is based on a self-tuning temperature control system with a DC power supply for optimal thermal stability. We show that the desired thermal profile over the entire length of the furnace consists of a functional combination of the fundamental thermal profiles for each individual zone obtained by setting the set-point temperature for that zone. The self-tuning system accounts for the zone to zone thermal interactions. The control system operates such that the thermal profile is maintained under thermal load, thus boundary conditions on crystal growth ampoules can be predetermined prior to crystal growth. Temperature profiles for the growth of crystals via directional solidification, vapor transport techniques, and multiple gradient applications are shown to be easily implemented. The unique feature of its transparency and ease of programming thermal profiles make the furnace useful in scientific and commercial applications for determining the optimized process parameters for crystal growth.

Duvual, Walter M. B.↗
DOE OSTI2022

De Novo Design of a Highly Stable Ovoid TIM Barrel: Unlocking Pocket Shape towards Functional Design

The ability to finely control the structure of protein folds is an important prerequisite to functional protein design. The TIM barrel fold is an important target for these efforts as it is highly enriched for diverse functions in nature. Although a TIM barrel protein has been designed de novo, the ability to finely alter the curvature of the central beta barrel and the overall architecture of the fold remains elusive, limiting its utility for functional design. Here, we report the de novo design of a TIM barrel with ovoid (twofold) symmetry, drawing inspiration from natural beta and TIM barrels with ovoid curvature. We use an autoregressive backbone sampling strategy to implement our hypothesis for elongated barrel curvature, followed by an iterative enrichment sequence design protocol to obtain sequences which yield a high proportion of successfully folding designs. Designed sequences are highly stable and fold to the designed barrel curvature as determined by a 2.1 Å resolution crystal structure. The designs show robustness to drastic mutations, retaining high melting temperatures even when multiple charged residues are buried in the hydrophobic core or when the hydrophobic core is ablated to alanine. As a scaffold with a greater capacity for hosting diverse hydrogen bonding networks and installation of binding pockets or active sites, the ovoid TIM barrel represents a major step towards the de novo design of functional TIM barrels.

Chu, Alexander E.↗