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Dust aerosol retrieval results from MISR (multi-angle imaging spectro-radiometer)

Satellite measurements provide important tools for understanding the effect of mineral dust aerosols on past and present climate and climate predictions. Multi-angle instruments such as Multi-angle Imaging Spectro- Radiometer (MISR) provide independent constraints on aerosol properties based on their sensitivity to the shape of aerosol scattering phase functions. The current MISR operational retrieval algorithm (version 16 and higher) was modified by incorporating new non-spherical dust models that account for naturally occurring dust shapes and compositions. We present selected examples of MISR version 16 retrievals over AERONET sunphotometer land and ocean sites during the passage of dust fronts. Our analysis shows that during such events MISR retrieves Angstrom exponents characteristic of large particles, having little spectral variation in extinction over the MISR wavelength range (442, 550, 672 and 866 nm channels), as expected. The retrieved fraction of non-spherical particles is also very high. This quantity is not retrieved by satellite instruments having only nadir-viewing cameras. Our comparison of current (version 16) MISR-retrieved aerosol optical thickness (AOT) with AERONET instantaneous AOT shows better coverage and stronger correlations than when making identical comparisons with previous AOT retrievals (version 15). The MISR algorithm successful mixtures include a non-spherical dust component with high frequency in retrievals over dark water and slightly lower frequency over land. Selection frequencies of non-spherical dust models also decrease in dusty regions affected by pollution.

Multiangle Imaging Spectroradiometer (MISR)↗

Exabiome: Advancing Microbial Science through Exascale Computing

The Exabiome project seeks to improve the understanding of microbiomes through the development of methods for accelerating metagenomic science using exascale computing. This article gives an overview of scientific impact of the three components of the project: metagenome assembly, protein family detection, and comparative analysis of metagenomes. Exabiome developed MetaHipMer, the only metagenome assembler capable of scaling to full exascale systems. MetaHipMer has enabled ground-breaking assemblies on the Frontier supercomputer, with many scientific benefits, such as the discovery of rare species and viral genomes. To investigate protein families, Exabiome developed two exascale tools, PASTIS and HipMCL. Together, these can utilize exascale resources to understand the functional diversity of billions of dark matter proteins and novel protein families. For comparative analysis, Exabiome developed kmerprof, a tool that can be used to compare huge metagenomes for many different scientific purposes, for example, grouping human microbiomes according to body location.

59 BASIC BIOLOGICAL SCIENCES↗

Lunar and Planetary Science XXXV: Viewing the Lunar Interior Through Titanium-Colored Glasses

The session"Viewing the Lunar Interior Through Titanium-Colored Glasses" included the following reports:Consequences of High Crystallinity for the Evolution of the Lunar Magma Ocean: Trapped Plagioclase; Low Abundances of Highly Siderophile Elements in the Lunar Mantle: Evidence for Prolonged Late Accretion; Fast Anorthite Dissolution Rates in Lunar Picritic Melts: Petrologic Implications; Searching the Moon for Aluminous Mare Basalts Using Compositional Remote-Sensing Constraints II: Detailed analysis of ROIs; Origin of Lunar High Titanium Ultramafic Glasses: A Hybridized Source?; Ilmenite Solubility in Lunar Basalts as a Function of Temperature and Pressure: Implications for Petrogenesis; Garnet in the Lunar Mantle: Further Evidence from Volcanic Glasses; Preliminary High Pressure Phase Relations of Apollo 15 Green C Glass: Assessment of the Role of Garnet; Oxygen Fugacity of Mare Basalts and the Lunar Mantle. Application of a New Microscale Oxybarometer Based on the Valence State of Vanadium; A Model for the Origin of the Dark Ring at Orientale Basin; Petrology and Geochemistry of LAP 02 205: A New Low-Ti Mare-Basalt Meteorite; Thorium and Samarium in Lunar Pyroclastic Glasses: Insights into the Composition of the Lunar Mantle and Basaltic Magmatism on the Moon; and Eu2+ and REE3+ Diffusion in Enstatite, Diopside, Anorthite, and a Silicate Melt: A Database for Understanding Kinetic Fractionation of REE in the Lunar Mantle and Crust.

Source record↗

Investigation of CATS Aerosol Products and Application Toward Global Diurnal Variation of Aerosols

We present a comparison of 1064 nm aerosol optical depth (AOD) and aerosol extinction profiles from the Cloud-Aerosol Transport System (CATS) level 2 aerosol product with collocated Aerosol Robotic Network (AERONET) AOD, Moderate Imaging Spectroradiometer (MODIS) Aqua and Terra Dark Target AOD and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) AOD and extinction data for the period of March 2015–October 2017. Upon quality-assurance checks of CATS data, reasonable agreement is found between aerosol data from CATS and other sensors. Using quality-assured CATS aerosol data, for the first time, variations in AODs and aerosol extinction profiles are evaluated at 00:00, 06:00, 12:00 and 18:00 UTC (and/or 00:00, 06:00, 12:00 and 18:00 local time or LT) on both regional and global scales. This study suggests that marginal variations are found in AOD from a global mean perspective, with the minimum aerosol extinction values found at 18:00 LT near the surface layer for global oceans, for both the June–November and December–May seasons. Over land, below 500 m, the daily minimum and maximum aerosol extinction values are found at 12:00 and 00:00/06:00 LT, respectively. Strong diurnal variations are also found over north Africa, the Middle East and India for the December–May season, and over north Africa, south Africa, the Middle East and India for the June–November season.

Logan Lee↗

The Turbulent Life of Phytoplankton

Phytoplankton is a generic name for photosynthesizing microscopic organisms that inhabit the upper sunlit layer (euphotic zone) of almost all oceans and bodies of freshwater. They are agents for "primary production," the incorporation of carbon from the environment into living organisms, a process that, sustains the aquatic food web. It is estimated that phytoplankton contribute about half of the global primary production, the other half being due to terrestrial plants. By sustaining the aquatic food web and controlling the biogeochemical cycles through primary production, phytoplankton exert a dominant influence on life on earth. Turbulence influences this process in three very important ways. First, essential mineral nutrients are transported from the deeper layers to the euphotic zone through turbulence. Second, turbulence helps to suspend phytoplankton in the euphotic zone since in still water, the phytoplankton, especially the larger species, tend to settle out of the sunlit layers. Third, turbulence transports phytoplankton from the surface to the dark sterile waters, and this is an important mechanism of loss. Thus, stable phytoplankton populations are maintained through a delicate dynamic balance between the processes of turbulence, reproduction, and sinking. The first quantitative model for this was introduced by Riley, Stommel and Bumpus in 1949. This is an attempt to extend their efforts through a combination of analysis and computer simulation in order to better understand the principal qualitative aspects of the physical/biological coupling of this natural system.

S Ghosal↗

Mychonastes desiccatus Brown sp. nova (Chlorococcales, Chlorophyta)--an intertidal alga forming achlorophyllous desiccation-resistant cysts

An intertidal Chlorella-like alga Mychonastes desiccatus Brown sp. nova, capable of forming achlorophyllous desiccation-resistant cysts, has been grown in unialgal culture. This small alga was first isolated from a dried sample of a well-studied microbial mat. The mat, located at North Pond, Laguna Figueroa, San Quintin, Baja California, Mexico, is a vertically-stratified microbial community which forms laminated sediments. Morphology, pigment composition and G+C content are within the range typical for the genus Chlorella s. 1. Unlike other chlorellae, however, upon desiccation M. desiccatus forms an achlorophyllous, lipid-filled cyst (thick-walled resting stage) in which no plastid is evident. Rewetting leads to chloroplast differentiation, excystment and recovery of the fully green alga. During desiccation, sporopollenin is deposited within a thickening cell wall. Encystment cannot be induced by growth in the dark. The formation of desiccation-induced cysts allows the alga to survive frequent and intermittent periods of dryness. These chlorellae tolerate wide ranges of acidity and temperature; they both grow and form cysts in media in which sodium ions are replaced with potassium. Although the cysts tolerate crystalline salts, the cell grow optimally in concentrations corresponding from three-quarters to full-strength seawater.

NASA Discipline Exobiology↗

Relationship Between Surface Reflectance in the Visible and Mid-IR used in MODIS Aerosol Algorithm-Theory

Data from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument that flies in polar orbit on the Terra platform, are used to derive the aerosol optical thickness and properties over land and ocean. The relationships between visible reflectance (at blue, rho(sub blue), and red, rho(sub red)) and mid-infrared (at 2.1 microns, rho(sub 2.1)) are used in the MODIS aerosol retrieval algorithm to derive global distribution of aerosols over the land. These relations have been established from a series of measurements indicating that rho(sub blue) is approximately 0.5 rho(sub red) is approximately 0.25 rho(sub 2.1). Here we use a model to describe the transfer of radiation through a vegetation canopy composed of randomly oriented leaves to assess the theoretical foundations for these relationships. Calculations for a wide range of leaf area indices and vegetation fractions show that rho(sub blue) is consistently about 1/4 of rho(sub 2.1) as used by MODIS for the whole range of analyzed cases, except for very dark soils, such as those found in burn scars. For its part, the ratio rho(sub red)/rho(sub 2.1) varies from less than the empirically derived value of 1/2 for dense and dark vegetation, to more than 1/2 for bright mixture of soil and vegetation. This is in agreement with measurements over uniform dense vegetation, but not with measurements over mixed dark scenes. In the later case the discrepancy is probably mitigated by shadows due to uneven canopy and terrain on a large scale. It is concluded that the value of this ratio should ideally be made dependent on the land cover type in the operational processing of MODIS data, especially over dense forests.

Kaufman, Yoram J.↗

Remote Sensing of Snow Cover: Snow Extent - Section

Snow was easily identified in the first image obtained from the Television Infrared Operational Satellite-1 (TIROS-1) weather satellite in 1960 because the high albedo of snow presents a good contrast with most other natural surfaces. Subsequently, the National Oceanic and Atmospheric Administration (NOAA) began to map snow using satellite-borne instruments in 1966. Snow plays an important role in the Earth s energy balance, causing more solar radiation to be reflected back into space as compared to most snow-free surfaces. Seasonal snow cover also provides a critical water resource through meltwater emanating from rivers that originate from high-mountain areas such as the Tibetan Plateau. Meltwater from mountain snow packs flows to some of the world s most densely-populated areas such as Southeast Asia, benefiting over 1 billion people (Immerzeel et al., 2010). In this section, we provide a brief overview of the remote sensing of snow cover using visible and near-infrared (VNIR) and passive-microwave (PM) data. Snow can be mapped using the microwave part of the electromagnetic spectrum, even in darkness and through cloud cover, but at a coarser spatial resolution than when using VNIR data. Fusing VNIR and PM algorithms to produce a blended product offers synergistic benefits. Snow-water equivalent (SWE), snow extent, and melt onset are important parameters for climate models and for the initialization of atmospheric forecasts at daily and seasonal time scales. Snowmelt data are also needed as input to hydrological models to improve flood control and irrigation management.

Hall, Dorothy K.↗

Sr-Nd-Pb isotope systematics of Australasian tektites: Implications for the nature and composition of target materials and possible volatile loss of Pb

The Australasian tektite (AAT) strewn field is the largest strewn field on the Earth with about ~10–30% coverage, both land and ocean, but a clearly identified source impact crater is absent despite the young age of AAT of ca. 790 ka. A genetic link between the Australasian tektites and their unequivocal parental materials is therefore largely impossible to establish. Nevertheless, the nature of the parental materials and the extent of volatilization can be constrained using the splash form tektites, carrying the chemical signatures of high-temperature processes, and the layered (so-called Muong Nong-type) tektites, which are less chemically homogenized and exceptionally abundant in the AAT field. New high-precision Sr, Nd and Pb isotopic measurements were obtained for a chemically and petrographically well-characterized suite of AAT, which included the Muong Nong-type (MN-AAT) with precisely known field locations in Laos and splash forms (SF-AAT) from different parts of the strewn field. Additionally, optically dark and light zones of the MN-AAT were also separately analyzed. Homogeneous ε Nd values from -11.8 to -11.2, combined with a narrow range of two-stage Nd model ages from 1.67 to 1.72 Ga for the entire AAT suite, point to a well-mixed source, in terms of REE, of the crustal segment from which the sedimentary material for tektites was ultimately derived. The Sr isotopic data largely overlap for SF-AAT and MN-AAT ( 87 Sr/ 86 Sr = 0.71636–0.72021) and indicate Paleozoic to Mesozoic sedimentary parentage. However, late Neogene to early Quaternary re-deposition and formation of a thick silt-sized sedimentary section with vertical stratification is required to comply with 10Be data. Lead isotope systematics documents at least three different components which can perhaps be represented by different mineral phases, such as feldspar, zircon, organic matter adsorbed on young sediments etc., sorted during fluvial transport and final deposition. In addition, the SF-AAT have systematically lower Pb contents than the MN-AAT, and generally show isotopically heavier Pb isotopic ratios. This is theoretically consistent with a preferential volatilization of lighter Pb isotopes during evaporation and considerably larger Pb loss from SF-AAT when compared to MN-AAT. Nevertheless, further experimental work would be necessary to unambiguously distinguish kinetic fractionation from source mixing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Air Pollution Scenario over Pakistan: Characterization and Ranking of Extremely Polluted Cities using Long-Term Concentrations of Aerosols and Trace Gases

Pakistan ranks third in the world in terms of mortality attributable to air pollution, with aerosol mass concentrations (PM2.5) consistently well above WHO (World Health Organization) air quality guidelines (AQG). However, regulation is dependent on a sparse network of air quality monitoring stations and insufficient ground data. This study utilizes long-term observations of aerosols and trace gases to characterize and rank the air pollution scenarios and pollution characteristics of 80 selected cities in Pakistan. Datasets used include (1) the Aqua and Terra (AquaTerra) MODIS (Moderate Resolution Imaging Spectroradiometer) Level 2 Collection 6.1 merged Dark Target and Deep Blue (DTB) aerosol optical depth (AOD) retrieval products; (2) the CAMS (Copernicus Atmosphere Monitoring Service) reanalysis PM1, PM2.5, and PM10 data; (3) the MERRA-2 (Modern-Era Retrospective analysis for Research and Applications, Version 2) reanalysis PM2.5 data, (4) the OMI (Ozone Monitoring Instrument) tropospheric vertical column density (TVCD) of nitrogen dioxide (NO2), and VCD of sulfur dioxide (SO2) in the Planetary Boundary Layer (PBL), (5) the VIIRS (Visible Infrared Imaging Radiometer Suite) Nighttime Lights data, (6) MODIS Collection 6 Version 2 global monthly fire location data (MCD14ML), (7) population density, (8) MODIS Level 3 Collection 6 land cover types, (9) AERONET (AErosol RObotic NETwork) Version 3 Level 2.0 data, and (10) ground-based PM2.5 concentrations from air quality monitoring stations. Potential Source Contribution Function (PSCF) analyses were performed by integrating with ground-based PM2.5 concentrations and the NOAA (National Oceanic and Atmospheric Administration) HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) air parcel back trajectories to identify potential pollution source areas which are responsible for extreme air pollution in Pakistan. Results show that the ranking of the top polluted cities depends on the type of pollutant considered and the metric used. For example, Jhang, Multan, and Vehari were characterized as the top three polluted cities in Pakistan when considering AquaTerra DTB AOD products; for PM1, PM2.5, and PM10 Lahore, Gujranwala, and Okara were the top three; for tropospheric NO2 VCD Lahore, Rawalpindi, and Islamabad and for PBL SO2 VCD Lahore, Mirpur, and Gujranwala. The results demonstrate that Pakistan’s entire population has been exposed to high PM2.5 concentrations for many years, with a mean annual value of 54.7 μg/cu. m, over all Pakistan from 2003 to 2020. This value exceeds Pakistan’s National Environmental Quality Standards (Pak-NEQS, i.e., <15 μg/cu. m annual mean) for ambient air defined by the Pakistan Environmental Protection Agency (Pak-EPA) as well as the WHO Interim Target-1 (i.e., mean annual PM2.5 <35 μg/cu. m). The spatial analyses of the concentrations of aerosols and trace gases in terms of population density, nighttime lights, land cover types, and fire location data, and the PSCF analysis indicate that Pakistan’s air quality is strongly affected by anthropogenic sources inside of Pakistan, with contributions from surrounding countries. Statistically significant positive (increasing) trends in PM1, PM2.5, PM10, tropospheric NO2 VCD, and SO2 VCD were observed in ~89%, ~67%, ~48%, 91%, and ~88% of the Pakistani cities (80 cities), respectively. This comprehensive analysis of aerosol and trace gas levels, their characteristics in spatio-temporal domains, and their trends over Pakistan, is the first of its kind. Results will be helpful to the Ministry of Climate Change (Government of Pakistan), Pak-EPA, SUPARCO (Pakistan Space and Upper Atmosphere Research Commission), policymakers, and the local research community to mitigate air pollution and its effects on human health.

Muhammad Bilal↗

Space Solar Power Technology Demonstration for Lunar Polar Applications

A solar power generation station on a mountaintop near the moon's North or South pole can receive sunlight 708 hours per lunar day, for continuous power generation. Power can be beamed from this station over long distances using a laser-based wireless power transmission system and a photo-voltaic receiver. This beamed energy can provide warmth, electricity, and illumination for a robotic rover to perform scientific experiments in cold, dark craters where no other power source is practical. Radio-frequency power transmission may also be demonstrated in lunar polar applications to locate and recover sub-surface deposits of volatile material, such as water ice. High circular polarization ratios observed in data from Clementine spacecraft and Arecibo radar reflections from the moon's South pole suggest that water ice is indeed present in certain lunar polar craters. Data from the Lunar Prospector spacecraft's epi-thermal neutron spectrometer also indicate that hydrogen is present at the moon's poles. Space Solar Power technology enables investigation of these craters, which may contain a billion-year-old stratigraphic record of tremendous scientific value. Layers of ice, preserved at the moon's poles, could help us determine the sequence and composition of comet impacts on the moon. Such ice deposits may even include distinct strata deposited by secondary ejecta following significant Earth (ocean) impacts, linked to major extinctions of life on Earth. Ice resources at the moon's poles could provide water and air for human exploration and development of space as well as rocket propellant for future space transportation. Technologies demonstrated and matured via lunar polar applications can also be used in other NASA science missions (Valles Marineris. Phobos, Deimos, Mercury's poles, asteroids, etc.) and in future large-scale SSP systems to beam energy from space to Earth. Ground-based technology demonstrations are proceeding to mature the technology for such a near-term scientific mission to the moon. This paper reviews the progress to date in demonstrating this technology on Earth and details the plans for near-term applications, to meet NASA's needs, in the moon's polar regions.

Henley, M. W.↗

Use of A-Train Aerosol Observations to Constrain Direct Aerosol Radiative Effects (DARE) Comparisons with Aerocom Models and Uncertainty Assessments

We describe a technique for combining multiple A-Train aerosol data sets, namely MODIS spectral AOD (aerosol optical depth), OMI AAOD (absorption aerosol optical depth) and CALIOP aerosol backscatter retrievals (hereafter referred to as MOC retrievals) to estimate full spectral sets of aerosol radiative properties, and ultimately to calculate the 3-D distribution of direct aerosol radiative effects (DARE). We present MOC results using almost two years of data collected in 2007 and 2008, and show comparisons of the aerosol radiative property estimates to collocated AERONET retrievals. Use of the MODIS Collection 6 AOD data derived with the dark target and deep blue algorithms has extended the coverage of the MOC retrievals towards higher latitudes. The MOC aerosol retrievals agree better with AERONET in terms of the single scattering albedo (ssa) at 441 nm than ssa calculated from OMI and MODIS data alone, indicating that CALIOP aerosol backscatter data contains information on aerosol absorption. We compare the spatio-temporal distribution of the MOC retrievals and MOC-based calculations of seasonal clear-sky DARE to values derived from four models that participated in the Phase II AeroCom model intercomparison initiative. Overall, the MOC-based calculations of clear-sky DARE at TOA over land are smaller (less negative) than previous model or observational estimates due to the inclusion of more absorbing aerosol retrievals over brighter surfaces, not previously available for observationally-based estimates of DARE. MOC-based DARE estimates at the surface over land and total (land and ocean) DARE estimates at TOA are in between previous model and observational results. Comparisons of seasonal aerosol property to AeroCom Phase II results show generally good agreement best agreement with forcing results at TOA is found with GMI-MerraV3. We discuss sampling issues that affect the comparisons and the major challenges in extending our clear-sky DARE results to all-sky conditions. We present estimates of clear-sky and all-sky DARE and show uncertainties that stem from the assumptions in the spatial extrapolation and accuracy of aerosol and cloud properties, in the diurnal evolution of these properties, and in the radiative transfer calculations.

aerosol↗

The Future: Nasa’s Surface Biology and Geology Mission and the Dark (Aquatic) Side

With the release of NASA’s Earth System Observatory (ESO) measurement targets that includes studying the Earth’s Surface Biology and Geology (SBG), a global visible to shortwave infrared imaging spectrometer and a multispectral thermal infrared imager have been planned to launch in the late 2020s. This mission will enable unprecedented interdisciplinary science and applications relevant to studying the biology and geology of the Earth's surface. Measurement targets are directly aligned for studying coastal and inland waters ecosystems and water quality, including coralreef ecosystems, snow and ice, mineralogy, volcanology, biology, ecology, biodiversity, and components of radiative forcing from the surface such as greenhouse gas emissions. The observations not only have scientific value in studying feedbacks and interactions of surface processes (e.g., harmful algal blooms, domoic acid, oil spills, and other hazardous events), but also societal benefit – with the capacity to support real-world decision-making such as response to theseevents and inland water conservation, protection of drinking water quality for public and environmental health, and habitat conservation. The work presented here outlines the conducted mission and architecture study and the initiation of science performance trades (signal sensitivity; spectral, spatial, and temporal resolution; and atmospheric effects) informing the design of the SBG segment of the ESO providing the most value to myriad science and applications as possible. Science and applications synergies and algorithms with the Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) and the Geostationary Littoral Imaging and Monitoring Radiometer (GLIMR) is opportunistic for advancing aquatics research and applications.

THE FUTURE↗

Quantifying Spatiotemporal Variability of Glacier Algal Blooms and the Impact on Surface Albedo in Southwestern Greenland

Albedo reduction due to light-absorbing impurities can substantially enhance ice sheet surface melt by increasing surface absorption of solar energy. Glacier algae have been suggested to play a critical role in darkening the ablation zone in southwestern Greenland. It was very recently found that the Sentinel-3 Ocean and Land Colour Instrument (OLCI) band ratio R709 nm∕R673 nm can characterize the spatial patterns of glacier algal blooms. However, Sentinel-3 was launched in 2016, and current data are only available over three melting seasons (2016–2019). Here, we demonstrate the capability of the MEdium Resolution Imaging Spectrometer (MERIS) for mapping glacier algae from space and extend the quantification of glacier algal blooms over southwestern Greenland back to the period 2004–2011. Several band ratio indices (MERIS chlorophyll a indices and the impurity index) were computed and compared with each other. The results indicate that the MERIS two-band ratio index (2BDA) R709 nm∕R665 nm is very effective in capturing the spatial distribution and temporal dynamics of glacier algal growth on bare ice in July and August. We analyzed the interannual (2004–2011) and summer (July–August) trends of algal distribution and found significant seasonal and interannual increases in glacier algae close to the Jakobshavn Isbrae Glacier and along the middle dark zone between the altitudes of 1200 and 1400 m. Using broadband albedo data from the Moderate Resolution Imaging Spectroradiometer (MODIS), we quantified the impact of glacier algal growth on bare ice albedo, finding a significant correlation between algal development and albedo reduction over algae-abundant areas. Our analysis indicates the strong potential for the satellite algal index to be used to reduce bare ice albedo biases in regional climate model simulations.

surface albedo↗

High resolution chronology of late Cretaceous-early Tertiary events determined from 21,000 yr orbital-climatic cycles in marine sediments

A number of South Atlantic sites cored by the Deep Sea Drilling Project (DSDP) recovered late Cretaceous and early Tertiary sediments with alternating light-dark, high-low carbonate content. The sedimentary oscillations were turned into time series by digitizing color photographs of core segments at a resolution of about 5 points/cm. Spectral analysis of these records indicates prominent periodicity at 25 to 35 cm in the Cretaceous intervals, and about 15 cm in the early Tertiary sediments. The absolute period of the cycles that is determined from paleomagnetic calibration at two sites is 20,000 to 25,000 yr, and almost certainly corresponds to the period of the earth's precessional cycle. These sequences therefore contain an internal chronometer to measure events across the K/T extinction boundary at this scale of resolution. The orbital metronome was used to address several related questions: the position of the K/T boundary within magnetic chron 29R, the fluxes of biogenic and detrital material to the deep sea immediately before and after the K/T event, the duration of the Sr anomaly, and the level of background climatic variability in the latest Cretaceous time. The carbonate/color cycles that were analyzed contain primary records of ocean carbonate productivity and chemistry, as evidenced by bioturbational mixing of adjacent beds and the weak lithification of the rhythmic sequences. It was concluded that sedimentary sequences that contain orbital cyclicity are capable of providing resolution of dramatic events in earth history with much greater precision than obtainable through radiometric methods. The data show no evidence for a gradual climatic deterioration prior to the K/T extinction event, and argue for a geologically rapid revolution at this horizon.

Herbert, Timothy D.↗

Sensitivity of MODIS 2.1 micron Channel for Off-Nadir View Angles for Use in Remote Sensing of Aerosol

Remote sensing of aerosol over land, from MODIS will be based on dark targets using mid-IR channels 2.1 and 3.9 micron. This approach was developed by Kaufman et al (1997), who suggested that dark surface reflectance in the red (0.66 micron -- rho(sub 0.66)) channel is half of that at 2.2 micron (rho(sub 2.2)), and the reflectance in the blue (0.49 micron - rho(sub 0.49)) channel is a quarter of that at 2.2 micron. Using this relationship, the surface reflectance in the visible channels can be predicted within Delta.rho(sub 0.49) approximately Delat.rho(sub 0.66) approximately 0.006 from rho(sub 2.2) for rho(sub 2.2) <= 0.10. This was half the error obtained using the 3.75 micron and corresponds to an error in aerosol optical thickness of Delat.tau approximately 0.06. These results, though applicable to several biomes (e.g. forests, and brighter lower canopies), have only been tested at one view angle - the nadir (theta = 0 deg). Considering the importance of the results in remote sensing of aerosols over land surfaces from space, we are validating the relationships for off-nadir view angles using Cloud Absorption Radiometer (CAR) data. The CAR data are available for channels between 0.3 and 2.3 micron and for different surface types and conditions: forest, tundra, ocean, sea-ice, swamp, grassland and over areas covered with smoke. In this study we analyzed data collected during the Smoke, Clouds, and Radiation - Brazil (SCAR-B) experiment to validate Kaufman et al.'s (1997) results for non-nadir view angles. We will show the correlation between rho(sub 0.472), rho(sub 0.675), and rho(sub 2.2) for view angles between nadir (0 deg) and 55 deg off-nadir, and for different viewing directions in the backscatter and forward scatter directions.

Gatebe, C. K.↗

Global Geologic Map of Europa

Europa, with its indications of a sub-ice ocean, is of keen interest to astrobiology and planetary geology. Knowledge of the global distribution and timing of Europan geologic units is a key step for the synthesis of data from the Galileo mission, and for the planning of future missions to the satellite. The first geologic map of Europa was produced at a hemisphere scale with low resolution Voyager data. Following the acquisition of higher resolution data by the Galileo mission, researchers have identified surface units and determined sequences of events in relatively small areas of Europa through geologic mapping using images at various resolutions acquired by Galileo's Solid State Imaging camera. These works provided a local to subregional perspective and employed different criteria for the determination and naming of units. Unified guidelines for the identification, mapping and naming of Europan geologic units were put forth by and employed in regional-to-hemispheric scale mapping which is now being expanded into a global geologic map. A global photomosaic of Galileo and Voyager data was used as a basemap for mapping in ArcGIS, following suggested methodology of all-stratigraphy for planetary mapping. The following units have been defined in global mapping and are listed in stratigraphic order from oldest to youngest: ridged plains material, Argadnel Regio unit, dark plains material, lineaments, disrupted plains material, lenticulated plains material and Chaos material.

Doggett, T.↗

Electron Backscatter Diffraction (EBSD) Analysis and U-Pb Geochronology of the Oldest Lunar Zircon: Constraining Early Lunar Differentiation and Dating Impact-Related Deformation

The evolution of the early moon was dominated by two processes (i) crystallization of the Lunar Magma Ocean (LMO) and differentiation of potassium-rare earth element-phosphorous-rich residual magma reservoir referred to as KREEP, and (ii) an intense meteorite bombardment referred to as lunar cataclysm . The exact timing of these processes is disputed, and resolution relies on collection and interpretation of precise age data. This study examines the microstructure and geochronology of zircon from lunar impact breccias collected during the Apollo 17 mission. A large zircon clast within lunar breccia 72215,195 shows sector zoning in optical microscopy, cathodoluminescence (CL) imaging and Raman mapping, and indicates that it was a relict fragment of a much larger magmatic grain. Sensitive high resolution ion microprobe (SHRIMP) U-Pb analysis of the zircon shows that U and Th concentration correlate with sector zoning, with darkest CL domains corresponding with high-U and Th (approx.150 and approx.100 ppm respectively), and the brightest-CL sectors containing approx.30-50 ppm U and approx.10-20 ppm Th. This indicates that variations in optical CL and Raman properties correspond to differential accumulation of alpha-radiation damage in each sector. Electron backscatter diffraction (EBSD) mapping shows that the quality of electron backscatter patterns (band contrast) varies with sector zoning, with the poorest quality patterns obtained from high-U and Th, dark-CL zones. EBSD mapping also reveals a deformation microstructure that is cryptic in optical, CL and Raman imaging. Two orthogonal sets of straight discrete and gradational low-angle boundaries accommodate approx.12 misorientation across the grain. The deformation bands are parallel to the crystallographic {a}-planes of the zircon, have misorientation axes parallel to the c-axis, and are geometrically consistent with formation by dislocation creep associated with <100>{010} slip. The deformation bands are unlike curved morphology of crystal-plastic microstructures in tectonically deformed terrestrial zircon, and geometrically similar to dislocation microstructures reported in experimentally shocked zircon. We interpret these crystal-plastic deformation microstructures to have resulted from a significant impact, either directly from impact shock, or during ductile flow directly following the impact. The deformation bands appear to continue undeflected through the non-indexed, radiation-damaged areas of the grain, which suggests that the orientation variation predates any significant mechanical weakening from radiation damage in the grain, and therefore occurred early in its history.

Timms, Nick↗