Search NASA⌕ Search

SEARCH · Search NASA

Results for “double sampling”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

The SDSS/APOGEE catalogue of HgMn stars

ABSTRACT We report on H-band spectra of chemically peculiar Mercury–Manganese (HgMn) stars obtained via the SDSS/APOGEE survey. As opposed to other varieties of chemically peculiar stars such as classical Ap/Bp stars, HgMn stars lack strong magnetic fields and are defined by extreme overabundances of Mn, Hg, and other heavy elements. A satisfactory explanation for the abundance patterns remains to be determined, but low rotational velocity is a requirement and involvement in binary/multiple systems may be as well. The APOGEE HgMn sample currently consists of 269 stars that were identified among the telluric standard stars as those whose metallic absorption content is limited to or dominated by the H-band Mn ii lines. Due to the fainter magnitudes probed by the APOGEE survey as compared to past studies, only 9/269 stars in the sample were previously known as HgMn types. The 260 newly identified HgMn stars represents a more than doubling of the known sample. At least 32 per cent of the APOGEE sample are found to be binary or multiple systems, and from multi-epoch spectroscopy, we were able to determine orbital solutions for at least one component in 32 binaries. Many of the multilined systems include chemically peculiar companions, with noteworthy examples being the HgMn+Ap/Bp binary HD 5429, the HgMn+HgMn binary HD 298641, and the HgMn+Bp Mn + Am triple system HD 231263. As a further peculiarity, roughly half of the sample produces narrow emission in the C i 16895 Å line, with widths and radial velocities that match those of the Mn ii lines.

Chojnowski, S. Drew↗
DOE OSTI2018

Standardized protocols and procedures can precisely and accurately quantify non-structural carbohydrates

Non-structural carbohydrates (NSCs), the stored products of photosynthesis, building blocks for growth, and fuel for respiration, are central to plant metabolism, but their measurement is challenging. Differences in methods and procedures among laboratories can cause results to vary widely, limiting our ability to integrate and generalize patterns in plant C balance among studies. A recent assessment found that NSC concentrations measured for a common set of samples can vary by an order of magnitude, but sources for this variability were unclear. We measured a common set of nine plant material types, and two synthetic samples with known NSC concentrations, using a common protocol for sugar extraction and starch digestion, and three different sugar quantification methods (ion chromatography, enzyme, acid) in six laboratories. We also tested how sample handling, extraction solvent, and centralizing parts of the procedure in one laboratory affected results. NSC concentrations measured for synthetic samples were within about 11.5% of known values for all three methods. However, differences among quantification methods were the largest source of variation in NSC measurements for natural plant samples because the three methods quantify different NSCs. The enzyme method quantified only glucose, fructose, and sucrose, with ion chromatography we additionally quantified galactose, while the acid method quantified a large range of mono- and oligosaccharides. For some natural samples, acid method quantification doubled sugar relative to the other methods, demonstrating that trees allocate C to a range of sugar molecules. Sample handling had little effect on measurements, while ethanol sugar extraction improved accuracy over water extraction. Our results demonstrate that reasonable accuracy of NSC measurements can be achieved when different methods are used, as long as protocols are robust and standardized. Thus, we provide detailed protocols for the extraction, digestion and quantification of NSCs in plant samples, which should improve the comparability of NSC measurements among laboratories.

Landhäusser, Simon M.↗
DOE OSTI2018

13 TeV pp collisions, SM type, PYTHIA8 generator: tev13pp_pythia8_minbias_a14

MinBias events used to mix with signal processes. 5k events per file. Pythia8 Minimum bias (ND+SD+DD) sample with Tune A14 with NNPDF23LO PDF, inspired by ATLAS run2. Events include non-diffractive, single diffractive and double diffractive events. The sample used by hs-toolkit for mixing with signal events.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2014

Structural, electronic and magnetic properties of the series of double perovskites (Ca,Sr){sub 2−x}La{sub x}FeIrO{sub 6}

Polycrystalline samples of the series of double perovskites Sr{sub 2−x}La{sub x}FeIrO{sub 6} were synthesized. Their structural, electronic and magnetic properties were investigated by X-ray powder diffraction, Mössbauer spectroscopy, magnetic susceptibility, heat capacity and electrical resistivity experiments. The compounds crystallize in a monoclinic structure and were fitted in space group P2{sub 1}/n, with a significant degree of Fe/Ir cationic disorder. As in Ca{sub 2−x}La{sub x}FeIrO{sub 6} the Sr-based system seems to evolve from an antiferromagnetic ground state for the end members (x=0.0 and x=2.0) to a ferrimagnetic order in the intermediate regions (x∼1). Since Mössbauer spectra indicate that Fe valence remains 3+ with doping, this tendency of change in the nature of the microscopic interaction could be attributed to Ir valence changes, induced by La{sup 3+} electrical doping. Upon comparing both Ca and Sr series, Sr{sub 2−x}La{sub x}FeIrO{sub 6} is more structurally homogenous and presents higher magnetization and transition temperatures. Magnetic susceptibility measurements at high temperatures on Sr{sub 1.2}La{sub 0.8}FeIrO{sub 6} indicate a very high ferrimagnetic Curie temperature T{sub C}∼700K. For the Sr{sub 2}FeIrO{sub 6} compound, electrical resistivity experiments under applied pressure suggest that this material might be a Mott insulator. - Graphical abstract: The Weiss constant as a function of La doping for the (Ca,Sr){sub 2−x}La{sub x}FeIrO{sub 6} series, indicating changes in Fe–Ir magnetic coupling on both families. - Highlights: • The double perovskite series (Ca,Sr){sub 2−x}La{sub x}FeIrO{sub 6} were synthesized. • Changes in the Fe-Ir magnetic coupling due to La doping on both series. • Evidence of high T{sub C} on Sr{sub 1.2}La{sub 0.8}FeIrO{sub 6}. • Indication of Mott insulator behavior on Sr{sub 2}FeIrO{sub 6}.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Radio-to- γ -ray monitoring of the narrow-line Seyfert 1 galaxy PMN J0948 + 0022 from 2008 to 2011

Here, we present more than three years of observations at different frequencies, from radio to high-energy γ-rays, of the Narrow-Line Seyfert 1 (NLS1) Galaxy PMN J0948 + 0022 (z = 0.585). This source is the first NLS1 detected at energies above 100 MeV and therefore can be considered the prototype of this emerging new class of γ-ray emitting active galactic nuclei (AGN). The observations performed from 2008 August 1 to 2011 December 31 confirmed that PMN J0948 + 0022 generates a powerful relativistic jet, which is able to develop an isotropic luminosity at γ-rays of the order of 10 48 erg s -1 , at the level of powerful quasars. The evolution of the radiation emission of this source in 2009 and 2010 followed the canonical expectations of relativistic jets with correlated multiwavelength variability (γ-rays followed by radio emission after a few months), but it was difficult to retrieve a similar pattern in the light curves of 2011. The comparison of γ-ray spectra before and including 2011 data suggested that there was a softening of the high-energy spectral slope. We selected five specific epochs to be studied by modelling the broad-band spectrum, which are characterised by an outburst at γ-rays or very low/high flux at other wavelengths. The observed variability can largely be explained by changes in the injected power, the bulk Lorentz factor of the jet, or the electron spectrum. The characteristic time scale of doubling/halving flux ranges from a few days to a few months, depending on the frequency and the sampling rate. The shortest doubling time scale at γ-rays is 2.3 ± 0.5 days. Finally, these small values underline the need of highly sampled multiwavelength campaigns to better understand the physics of these sources.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

The x-ray source application test cassette for radiation exposures at the OMEGA laser

We have designed a sample cassette that can be used to position up to six samples in the OMEGA laser chamber. The cassette accommodates round samples up to 38.1 mm (1.5{sup Double-Prime }) in diameter and square samples up to 27 mm on a side, any of which can be up to 12.7 mm thick. Smaller specimens are centered with spacers. The test cassette allows each sample to have a unique filter scheme, with multiple filter regions in front of each sample. This paper will present mechanical design considerations and operational aspects of the x-ray source application cassette.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Broadband, 920-nm mirror thin film damage competition

This year’s competition proposed to survey the state-of-the-art broadband, near-IR multilayer dielectric (MLD) mirrors designed for ultra-short, pulsed laser applications. The requirements for the coatings were a minimum reflection of 99.5% at 45-degree incidence angle for S-polarization from 830 nm to 1010 nm and group delay dispersion (GDD) < ± 50 fs 2 . The participants in this effort selected the coating materials, coating design, and deposition method. Samples were damage tested at a single testing facility to enable direct comparison among the participants using a 25 ± 5 fs OPCPA laser system operating at 5 Hz. A double blind test assured sample and submitter anonymity. The damage performance results, sample rankings, details of the deposition processes, coating materials and substrate cleaning methods are shared here. We found that multilayer coatings using tantala and/or hafnia as high index materials were top performers within several coating deposition groups. Specifically, dense coatings by ion-beam sputtering (IBS), magnetron sputtering (MS), and electron-beam ion assisted deposition (e-beam IAD) exhibited highest damage initiation onset (LIDT) while e-beam coatings were low performers. In addition, damage growth onset (LDGT) was also examined and the results are reported here for all samples as this performance metric plays an important role in establishing the safe operational conditions for larger aperture, ultrashort pulsed lasers. As a result, not all coating samples in the survey met the GDD requirements stated above and associated measurements are discussed in the context of the present and past competitions focused on similar broadband, near-IR MLD coatings.

42 ENGINEERING↗
DOE OSTI2018

Structural and Magnetic Properties of the Series of Double-Perovskite Sr{sub 2−x}Bi{sub x}MnMoO{sub 6}

Polycrystalline samples of a series of double-perovskite Sr{sub 2−x}Bi{sub x}MnMoO{sub 6} (x = 0, 0.05, 0.10, 0.15, 0.20, and 0.25) were synthesized by solid-state reaction, and their structural and magnetic properties were investigated by means of X-ray power diffraction and magnetic measures. Rietveld analysis of room-temperature XRD data shows that all the samples are single phases and belong to the I4/m space group. The degree of Mn/Mo order (η) and the unit-cell volume decrease monotonically with the increase of Bi concentration. The field dependence of the magnetization suggests that all the samples are anti-ferromagnetism. With Bi doping, the magnetization increases at low Bi concentration (x ≤ 0.15), which indicates the formation of ferrimagnetic interaction between the Mo{sup 5+} and Mn{sup 2+} caused by the effect of the electron doping in the compounds; however, due to the decline of the Mn/Mo order (η), the magnetization tends to decrease upon the Bi concentration in the high doping levels (0.15 ≤ x ≤ 0.25). The non-monotonic variation of the Neel temperature (T{sub N}) is consistent with the variation tendency of magnetization upon Bi doping.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Double sided measurements and associated error bars for planar samples or subassemblies

Many of the high energy density (HED) experiments use targets with planar components usually in a multilayer stack as the physics package which is at the heart of the experiment. The physics package contains the sample part under study as well as other components as shown in Fig. 1, that when exposed to the laser drive applies pressure onto or shock the main component to take it to the desired state in the phase diagram. These other components may include the ablator, pusher, x-ray pre-heat shield, window or other special components. The components are usually glued together. Currently, experiments on NIF and Omega in the Dynamic Materials campaign use several platforms such as Diffraction, EOS and Strength (Ref 1-3) which all use such planar stack physics packages.

42 ENGINEERING↗
DOE OSTI2014

Enhanced magnetoresistance induced by oxygen deficiency in La{sub 0.4}Ca{sub 0.6}MnO{sub 3-δ} oxides

We report electrical features and magnetoresistance behavior of the oxygen deficient La{sub 0.4}Ca{sub 0.6}MnO{sub 3-δ} perovskites (δ = 0, 0.15, and 0.2). These samples will be referred to as S0, S15, and S20, respectively. The dependence of electrical transport on temperature and magnetic field is systematically investigated between 2 K and 400 K in magnetic field ranging up to 5 T. The parent compound shows a stable charge ordering/antiferromagnetic state with a semiconductor-like behavior in all considered temperature range. The variable range hopping and thermally activated hopping models are found to fit well with the electrical resistivity data at low and high temperatures, respectively. Oxygen deficiency tends to weaken the charge ordering and induce ferromagnetism and metallicity at low temperature. Metal insulator transition appears at higher fields for lower oxygen deficit (S15 sample) and without field for the S20 sample. The resistivity data for S15 sample are discussed in the framework of the variable-range hopping model. Abnormal transport properties were observed in the S20 sample, characterized by the double metal-insulator transitions and low minimum behavior. These results are discussed in terms of phenomenological percolation model, based on the phase segregation of ferromagnetic metallic clusters and paramagnetic insulating regions. While the parent compound shows no magnetoresistance, a large magnetoresistance is observed in the deficient samples at low temperature reaching 90% and 75% at 2 T for S15 and S20 samples, respectively. Noticeably, these values reached 98% and 91% at 5 T. The appearance of colossal magnetoresistance is attributed to the spin dependent hopping between spin clusters and/or ferromagnetic domains.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Single and double acceptor-levels of a carbon-hydrogen defect in n-type silicon

In the present study, we discuss the origin of two dominant deep levels (E42 and E262) observed in n-type Si, which is subjected to hydrogenation by wet chemical etching or a dc H-plasma treatment. Their activation enthalpies determined from Laplace deep level transient spectroscopy measurements are E{sub C}-0.06 eV (E42) and E{sub C}-0.51 eV (E262). The similar annealing behavior and identical depth profiles of E42 and E262 correlate them with two different charge states of the same defect. E262 is attributed to a single acceptor state due to the absence of the Poole-Frenkel effect and the lack of a capture barrier for electrons. The emission rate of E42 shows a characteristic enhancement with the electric field, which is consistent with the assignment to a double acceptor state. In samples with different carbon and hydrogen content, the depth profiles of E262 can be explained by a defect with one H-atom and one C-atom. From a comparison with earlier calculations [Andersen et al., Phys. Rev. B 66, 235205 (2002)], we attribute E42 to the double acceptor and E262 to the single acceptor state of the CH{sub 1AB} configuration, where one H atom is directly bound to carbon in the anti-bonding position.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2012

DOUBLE-PEAKED NARROW-LINE ACTIVE GALACTIC NUCLEI. II. THE CASE OF EQUAL PEAKS

Active galactic nuclei (AGNs) with double-peaked narrow lines (DPAGNs) may be caused by kiloparsec-scale binary AGNs, bipolar outflows, or rotating gaseous disks. We examine the class of DPAGNs in which the two narrow-line components have closely similar intensity as being especially likely to involve disks or jets. Two spectroscopic indicators support this likelihood. For DPAGNs from Smith et al., the 'equal-peaked' objects (EPAGNs) have [Ne V]/[O III]ratios lower than for a control sample of non-double-peaked AGNs. This is unexpected for a pair of normal AGNs in a galactic merger, but may be consistent with [O III] emission from a rotating ring with relatively little gas at small radii. Also, [O III]/H{beta} ratios of the redshifted and blueshifted systems in the EPAGN are more similar to each other than in a control sample, suggestive of a single ionizing source and inconsistent with the binary interpretation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Boulder damage symposium annual thin film laser damage competition

Optical instruments and laser systems are often fluence-limited by multilayer thin films deposited on the optical surfaces. When comparing publications within the laser damage literature, there can be confusing and conflicting laser damage results. This is due to differences in testing protocols between research groups studying very different applications. In this series of competitions, samples from multiple vendors are compared under identical testing parameters and a single testing service. Unlike a typical study where a hypothesis is tested within a well-controlled experiment with isolated variables, this competition isolates the laser damage testing variables so that trends can be observed between different deposition processes, coating materials, cleaning techniques, and multiple coating suppliers. The resulting series of damage competitions has also been designed to observe general trends of damage morphologies and mechanisms over a wide range of coating types (high reflector and antireflector), wavelengths (193 to 1064 nm), and pulse lengths (180 fs to 13 ns). A double blind test assured sample and submitter anonymity were used in each of the competitions so only a summary of the deposition process, coating materials, layer count and spectral results are presented. Laser resistance was strongly affected by substrate cleaning, coating deposition method, and coating material selection whereas layer count and spectral properties had minimal impact.

42 ENGINEERING↗
DOE OSTI2021

Thin-film chemical expansion of ceria based solid solutions: laser vibrometry study

The chemical expansion of Pr 0.1 Ce 0.9 O 2-δ (PCO) and CeO 2-δ thin films is investigated in the temperature range between 600 °C and 800 °C by laser Doppler vibrometry (LDV). It enables non-contact determination of nanometer scale changes in film thickness at high temperatures. The present study is the first systematic and detailed investigation of chemical expansion of doped and undoped ceria thin films at temperatures above 650 °C. The thin films were deposited on yttria stabilized zirconia substrates (YSZ), operated as an electrochemical oxygen pump, to periodically adjust the oxygen activity in the films, leading to reversible expansion and contraction of the film. This further leads to stresses in the underlying YSZ substrates, accompanied by bending of the overall devices. Film thickness changes and sample bending are found to reach up to 10 and several hundred nanometers, respectively, at excitation frequencies from 0.1 to 10 Hz and applied voltages from 0–0.75 V for PCO and 0–1 V for ceria. At low frequencies, equilibrium conditions are approached. As a consequence maximum thin-film expansion of PCO is expected due to full reduction of the Pr ions. The lower detection limit for displacements is found to be in the subnanometer range. At 800 °C and an excitation frequency of 1 Hz, the LDV shows a remarkable resolution of 0.3 nm which allows, for example, the characterization of materials with small levels of expansion, such as undoped ceria at high oxygen partial pressure. As the correlation between film expansion and sample bending is obtained through this study, a dimensional change of a free body consisting of the same material can be calculated using the high resolution characteristics of this system. A minimum detectable dimensional change of 5 pm is estimated even under challenging high-temperature conditions at 800 °C opening up opportunities to investigate electro-chemo-mechanical phenomena heretofore impossible to investigate. The expansion data are correlated with previous results on the oxygen nonstoichiometry of PCO thin films, and a defect model for bulk ceria solid solutions is adopted to calculate the cation and anion radii changes in the constrained films during chemical expansion. The constrained films exhibit anisotropic volume expansion with displacements perpendicular to the substrate plane nearly double that of bulk samples. The PCO films used here generate high total displacements of several 100 nm’s with high reproducibility. Consequently, PCO films are identified to be a potential core component of high-temperature actuators. They benefit not only from high displacements at temperatures where most piezoelectric materials no longer operate while exhibiting, low voltage operation and low energy consumption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

A Comparative Study of Single-pulse and Double-pulse Laser-Induced Breakdown Spectroscopy with Uranium-containing Samples

Laser-induced breakdown spectroscopy (LIBS) holds potential advantages in special nuclear material (SNM) sensing and nuclear forensics which require rapid analysis, minimal sample preparation and stand-off distance capability. SNM, such as U, however, result in crowded emission spectra with LIBS, and characteristic emission lines are challenging to discern. It is well-known that double-pulse LIBS (DPLIBS) improves the signal intensity for analytes over conventional single-pulse LIBS (SPLIBS). This study investigates U signal in a glass matrix using DPLIBS and compares to signal features obtained using SPLIBS. DPLIBS involves sequential firing of 1.06 µm Nd:YAG pre-pulse and 10.6 µm TEA CO2 heating pulse in near collinear geometry. Optimization of experimental parameters including inter-pulse delay and energy follows identification of characteristic lines and signals for bulk analyte Ca and minor constituent analyte U for both DPLIBS and SPLIBS. Spatial and temporal coupling of the two pulses in the proposed DPLIBS technique yields improvements in analytical merits with negligible further damage to the sample compared to SPLIBS. Subsequently, the study discusses optimum plasma emission conditions of U lines and relative figures of merit in both SPLIBS and DPLIBS. Investigation into plasma characteristics also addresses plausible mechanisms related to observed U analyte signal variation between SPLIBS and DPLIBS.

Skrodzki, P. J.↗
DOE OSTI2014

Comparative study of optical and structural properties of electrospun 1-dimensional CaYAl{sub 3}O{sub 7}:Eu{sup 3+} nanofibers and bulk phosphor

We report the optical and structural studies of Eu{sup 3+}-doped 1-dimensional CaYAl{sub 3}O{sub 7} nano-fiber phosphor. CaYAl{sub 3}O{sub 7}:Eu{sup 3+} phosphors were synthesized by electrospinning technique and the pristine nano-fibers were annealed at 900 °C to form well crystallized uniform fibers. Under ultraviolet excitation, the CaYAl{sub 3}O{sub 7}:Eu{sup 3+} exhibited red emission, due to transitions in the 4f states of Eu{sup 3+}. In order to explore the difference between the quantum efficiency of nano-fiber and bulk CaYAl{sub 3}O{sub 7}:Eu{sup 3+} phosphor, detailed structural and optical analyses were carried out. The structural analysis of the CaYAl{sub 3}O{sub 7}:Eu{sup 3+} nano-fibers indicates that the structural environment surrounding the dopant Eu{sup 3+} ion was more unstable in nano-fiber when compared to a bulk sample. Decay curves for both the samples when fitted with double exponential decay model indicate that the nano-fiber has shorter decay time, arising from the larger contribution from the non-radiative decay, due to defect levels introduced in the host lattice. - Highlights: • Synthesis of red nano-phosphor through electrospinning • Luminescence properties of bulk and nano-phosphors are compared. • Inferior emission intensity of the nano-phosphor is analyzed using MEM. • Charge cloud around nano-phosphor was found to be oblique.

36 MATERIALS SCIENCE↗