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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Evidence for a 5d F-theorem

Renormalization group flows are studied between 5d SCFTs engineered by (p, q) 5-brane webs with large numbers of external 5-branes. A general expression for the free energy on S5 in terms of single-valued trilogarithm functions is derived from their supergravity duals, which are characterized by the 5-brane charges and additional geometric parameters. The additional geometric parameters are fixed by regularity conditions, and we show that the solutions to the regularity conditions extremize a trial free energy. These results are used to survey a large sample of O(10 5 ) renormalization group flows between different 5d SCFTs, including Higgs branch flows and flows that preserve the SU(2) R- symmetry. In all cases the free energy changes monotonically towards the infrared, in line with a 5d F -theorem.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Constraints on quasinormal modes and bounds for critical points from pole-skipping

We consider a holographic thermal state and perturb it by a scalar operator whose associated real-time Green’s function has only gapped poles. These gapped poles correspond to the non-hydrodynamic quasinormal modes of a massive scalar perturbation around a Schwarzschild black brane. Relations between pole-skipping points, critical points and quasinormal modes in general emerge when the mass of the scalar and hence the dual operator dimension is varied. First, this novel analysis reveals a relation between the location of a mode in the infinite tower of quasinormal modes and the number of pole-skipping points constraining its dispersion relation at imaginary momenta. Second, for the first time, we consider the radii of convergence of the derivative expansions about the gapped quasinormal modes. These convergence radii turn out to be bounded from above by the set of all pole-skipping points. Furthermore, a transition between two distinct classes of critical points occurs at a particular value for the conformal dimension, implying close relations between critical points and pole-skipping points in one of those two classes. We show numerically that all of our results are also true for gapped modes of vector and tensor operators.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

How the Size and Density of Charge-Transfer Excitons Depend on Heterojunction’s Architecture

We have characterized the size, intensity, density, and distribution of charge-transfer (CT) excitons as a function of the acceptor–donor architecture of prototypical organic interfaces. This characterization was done by computational analysis of 17 models of varying numbers, positions, and orientations of the donor and acceptor molecules. The models’ building blocks were phenyl-C61-butyric acid methyl ester (PCBM) fullerene acceptors and dual-band donor polymers composed of thiophene, benzothiadiazole, and benzotriazole subunits. The electronic structure of the donor–acceptor complexes was computed with the time-dependent long-range-corrected density-functional tight-binding method and analyzed with the fragment-based one-electron transition density matrix. In all models, the complexes with edge-on orientation have denser spectra of low-energy CT states lying below the absorption bands compared to the complexes with face-on orientation. This CT-state distribution in edge-on complexes provides a gate to efficiently populate cold CT excitons. Moreover, the cold CT excitons have a higher degree of charge separation in the edge-on than in the face-on complexes. The CT amount and the CT exciton size generally increase with the energy of the CT states, although the electron remains localized on a single molecule in cold CT states. Delocalization over two PCBM molecules was observed for high-energy CT states. The exciton size also depends on the orientation. Larger excitons are produced by the delocalization of the electrons perpendicularly to the interface. When the delocalization is parallel, the smaller electron–hole distances yield moderately sized CT excitons.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modeling Geologic Waste Repository Systems Below Residual Saturation

The heat generated by high-level radioactive waste can pose numerical and physical challenges to subsurface flow and transport simulators if the liquid water content in a region near the waste package approaches residual saturation due to evaporation. Here, residual saturation is the fraction of the pore space occupied by liquid water when the hydraulic connectivity through a porous medium is lost, preventing the flow of liquid water. While conventional capillary pressure models represent residual saturation using asymptotically large values of capillary pressure, here, residual saturation is effectively modeled as a tortuosity effect alone. Treating the residual fluid as primarily dead-end pores and adsorbed films, relative permeability is independent of capillary pressure below residual saturation. To test this approach, PFLOTRAN is then used to simulate thermal-hydrological conditions resulting from direct disposal of a dual-purpose canister in unsaturated alluvium using both conventional asymptotic and revised, smooth models. Importantly, while the two models have comparable results over 100 000 years, the number of flow steps required is reduced by approximately 94%.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Adapting to a Changing World: Managing the Promise and Peril of Emerging Technologies and the Nuclear Nexus

This paper is focused on emerging technologies in three areas: outer space, cyberspace, and artificial intelligence. Technologies in each of these areas share a number of characteristics that make them a challenge for legally-binding approaches to arms control. For example, they each have significant definitional challenges. They are also dual use and within the reach of non-state actors. Verifying compliance with any legally-binding agreements in these areas poses significant challenges, at least at this time. Moreover, the rapid pace of technological change also contributes to the difficulty of crafting legally-binding arms control measures. The United States has generally championed a more normative approach to the governance of emerging technologies—the idea being that international agreement on norms serves as the basis for collective action to respond to activities that deviate from those norms.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Truncation effects in the charge representation of the O(2) model

The O(2) model in Euclidean space-time is the zero-gauge-coupling limit of the compact scalar quantum electrodynamics. In this work, we obtain a dual representation of it called the charge representation. We study the quantum phase transition in the charge representation with a truncation to “spin $\textit{S}$," where the quantum numbers have an absolute value less than or equal to $\textit{S}$. The charge representation preserves the gapless-to-gapped phase transition even for the smallest spin truncation $\textit{S}$ = 1. The phase transition for $\textit{S}$ = 1 is an infinite-order Gaussian transition with the same critical exponents $\textit{δ}$ and $\textit{η}$ as the Berezinskii-Kosterlitz-Thouless (BKT) transition, while there are true BKT transitions for $\textit{S}$ ≥ 2 . The essential singularity in the correlation length for $\textit{S}$ = 1 is different from that for $\textit{S}$ ≥ 2 . The exponential convergence of the phase-transition point is studied in both Lagrangian and Hamiltonian formulations. We discuss the effects of replacing the truncated $\hat{U}^±$ = exp ($± i\hat{θ}$) operators by the spin ladder operators $\hat{S}^±$ in the Hamiltonian. The marginal operators vanish at the Gaussian transition point for $\textit{S}$ = 1, which allows us to extract the $\textit{η}$ exponent with high accuracy.

36 MATERIALS SCIENCE↗

Estimating Ice Water Content for Winter Storms from Millimeter-Wavelength Radar Measurements Using a Synthesis of Polarimetric and Dual-Frequency Radar Observations

The potential of millimeter-wavelength radar-based ice water content (IWC) estimation is demonstrated using a Ka-band Scanning Polarimetric Radar (KASPR) for the U.S. northeast coast winter storms. Two IWC relations for Ka-band polarimetric radar measurements are proposed: one that uses a combination of the radar reflectivity Z and the estimated total number concentration of snow particles N t and the other based on the joint use of Z, specific differential phase K DP , and the degree of riming f rim . A key element of the algorithms is to obtain the “Rayleigh-equivalent” value of Z measured at the Ka band, i.e., the corresponding Z at a longer radar wavelength for which Rayleigh scattering takes place. This is achieved via polarimetric retrieval of the mean volume diameter D m and incorporating the relationship between the dual-wavelength ratio DWR S/Ka and D m . Those techniques allow for retrievals from single millimeter-wavelength radar measurements and do not necessarily require the dual-wavelength ratio (DWR) measurements, if the DWR–D m relation and Rayleigh assumption for Ka-band K DP are valid. Comparison between the quasivertical profile product obtained from KASPR and the columnar vertical profile product generated from the nearby WSR-88D S-band radar measurements demonstrates that the DWR S/Ka can be estimated from the two close radars without the need for collocated radar beams and synchronized antenna scanning and can be used for determining the Rayleigh-equivalent value of Z. As a result, the performance of the suggested techniques is evaluated for seven winter storms using surface disdrometer and snow accumulation measurements.

Cloud retrieval↗

Atomically Precise Single-Site Catalysts via Exsolution in a Polyoxometalate–Metal–Organic-Framework Architecture

Single-site catalysts (SSCs) achieve a high catalytic performance through atomically dispersed active sites. A challenge facing the development of SSCs is aggregation of active catalytic species. Reducing the loading of these sites to very low levels is a common strategy to mitigate aggregation and sintering; however, this limits the tools that can be used to characterize the SSCs. Here we report a sintering-resistant SSC with high loading that is achieved by incorporating Anderson–Evans polyoxometalate clusters (POMs, MMo 6 O 24 , M = Rh/Pt) within NU-1000, a Zr-based metal–organic framework (MOF). The dual confinement provided by isolating the active site within the POM, then isolating the POMs within the MOF, facilitates the formation of isolated noble metal sites with low coordination numbers via exsolution from the POM during activation. The high loading (up to 3.2 wt %) that can be achieved without sintering allowed the local structure transformation in the POM cluster and the surrounding MOF to be evaluated using in situ X-ray scattering with pair distribution function (PDF) analysis. Notably, the Rh/Pt···Mo distance in the active catalyst is shorter than the M···M bond lengths in the respective bulk metals. Furthermore, models of the active cluster structure were identified based on the PDF data with complementary computation and X-ray absorption spectroscopy analysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantum chaos and unitary black hole evaporation

The formation and evaporation of small AdS black holes in a theory with a holographic dual is governed by the usual rules of quantum mechanics. The eigenstate thermalization hypothesis explains the validity of semiclassical gravity for local bulk observables and can be used to quantify the magnitude of quantum corrections to the semi-classical approximation. The holographic dual produces a basis of black hole states with finite energy width, and observables that are smooth functions on the classical phase space will self-average over a large number of energy eigenstates, exponential in the Bekenstein-Hawking entropyS, leading to results that are consistent with semiclassical gravity up to small corrections of order e –S/2 . As expected, the semiclassical description breaks down for transition amplitudes that reflect the unitary evolution of the holographic theory.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Virtual prototyping of liquid metal blanket performance in fusion pilot plant

Liquid metal blanket is a dominant design option for the next step fusion devices responsible for harvesting energy from fusion reaction, and simultaneously producing fuel for the same reaction through tritium breeding. Liquid metal blankets introduce additional complexity to the design due to fluid motion, fluid structure interaction, and magnetohydrodynamic (MHD) effects arising from the motion of the conducting fluid through the magnetic field. They are also directly affected by the plasma heat flux and neutronic fluence. PPPL is currently developing a virtual prototyping system for numerical analysis of the liquid metal blankets for future fusion devices. The system has a customized 3D computational fluid dynamics (CFD) code in its core, allowing MHD flow and conjugate heat transfer analysis in blankets fluids and solids. The code was successfully used before for dual coolant blanket analysis [A. Khodak et al., Fusion Eng. and Des. 137 (2018)]. Recently the same code was modified to allow verified simulation of MHD flows at high Hartmann numbers of several thousand typical for blanket applications. CFD code receives volumetric heat source distribution from the neutronic analysis based on MCNP code. In addition, direct tritium breeding simulation will be performed allowing optimization of the blanket performance. 2D axisymmetric version of neutronics code will be used for rapid optimization, with 3D version employed for detailed analysis. The surface heat distribution on the plasma facing wall will be defined by the software HEAT allowing 3D modeling of the heat flux based on the magnetic field distribution including gyro-orbit effects. Results of thermal analysis are imported into structural analysis code also included in the system. Finally, direct import of CAD geometry will be used for analyzing all components and as a result design option can be efficiently optimized.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Improved guided-wave acoustic defect detection and localization in pipes under varying temperature conditions using deep learning

Early defect detection in pipelines is critical across industries, particularly in the oil and gas sector, where failures result in significant maintenance costs and operational disruptions. Acoustic guided-wave techniques are widely used for nondestructive evaluation of pipeline defects due to their long-distance propagation capability. However, environmental variations, sensitivity limitations, and complex signal interpretation challenges limit the effectiveness of traditional signal processing approaches with guided-wave signals. Recent advances in deep learning methods have demonstrated remarkable success in solving complex real-world problems in many fields. In particular, deep-learning-based signal processing holds substantial promise to overcome limitations and challenges of conventional signal processing. This study presents a deep learning framework for pipeline inspection using acoustic guided-wave signals under temperature varying environments. The proposed framework employs a dual-path one-dimensional convolutional autoencoder that combines defect detection, localization, and temperature prediction functions. The proposed system utilizes multi-mode and broadband acoustic waves with an optimized number of sensors that provide high accuracy while retaining practical simplicity. Experimental validation is performed on a carbon steel pipe. The results indicate exceptional defect detection accuracy and precise defect localization with a mean absolute error of 66 mm. The proposed technique also predicts the effective average temperature of the pipe with a mean absolute error of 0.2°C. Comparative analysis shows superior performance of the proposed method over a traditional method previously developed by the authors' team. These results highlight the potential of integrating deep learning methods into guided-wave pipeline inspection systems to improve reliability under varying environmental conditions.

42 ENGINEERING↗

Measurement of neutral gadolinium oscillator strengths using dual-comb absorption spectroscopy in laser-produced plasmas

The oscillator strengths of 43 transitions of neutral gadolinium from 530 to 535 nm were determined based on high-resolution absorption spectra measured by probing a laser-produced plasma (LPP) using time-resolved dual-comb spectroscopy (DCS). Absorption spectra were measured at various time delays, ranging from 33 to 252 µs after the onset of the plasma formation, over which the temperature and number density varied as the ablation plume evolved. A Boltzmann analysis was used to determine the excitation temperature and column density of Gd in the ablation plume, based on measured absorption from 20 Gd I spectral lines with known oscillator strengths. Oscillator strengths were then determined for additional dipole-allowed Gd I transitions identified in the absorption spectra, 19 of which were previously unreported. Oscillator strengths of all measured transitions were compared with literature values when available and show good agreement in most cases. Time-resolved measurement of atomic absorption in the cooling plasma provides access to a range of excitation temperatures and optical densities for the atoms in the ablation plume, allowing repeated measurements under different conditions, thereby improving confidence in the results. The high spectral bandwidth and resolution capabilities of DCS make it well-suited to measuring the dense optical spectrum of Gd, and the technique is applicable to other elements, especially lanthanides and actinides.

(280.4788) Optical Sensing, (280.5395) Plasma Diag↗

Third-Party Aggregation Rulemaking in MISO and SPP Footprints

The report highlights key considerations for retail regulators in the footprints of the Southwest Power Pool (SPP) or Midcontinent Independent System Operator (MISO) in states that previously opted out of allowing third-party aggregation participation under FERC Order 719 and that may want to explore reversing the decision due to a changing policy environment under new FERC orders (i.e., 2222) and/or tightening resource adequacy constraints. Through a document review and a series of 27 interviews with regulators, aggregators, and other industry professionals, this document provides a high-level policy overview of the retail regulator’s role in a selection of processes, rules, and regulations to better understand how states have treated and/or integrated aggregators into wholesale markets. The report summarizes findings in two sections: General Findings and Specific Policy Findings. The General Findings offer high level takeaways such as the fact that 17 of the 20 states in MISO and SPP footprints opted out of third party aggregations following Order 719. Additionally, there is only one state that is fully restructured in the MISO and SPP footprints whereas the rest are vertically integrated, and the majority of third-party aggregations in the U.S. take place in restructured states outside of these footprints. Even so, third-party aggregations do take place in MISO and SPP albeit in small numbers and in an ad hoc regulatory environment. The specific policy findings delve deeper into specific examples of state actions on the topics of jurisdiction, registration and licensing, data governance, dual participation, and dispute resolution. Tables in each category organize state actions into Tiers I-III, which roughly correspond to the possible level of involvement or possible change necessary by state regulators and/or legislators to implement these actions. The tier level does not indicate any value judgement, as each state has respective regulatory limitations and each decision comes with various tradeoffs. One main tradeoff is between simplicity and quick implementation versus comprehensive and prolonged implementation. In many cases, actions in Tier I could be implemented without significant changes by relying on the use of existing processes for an aggregator context. On the other hand, many actions in Tier III are more narrowly designed to address aggregators specifically, but often require more significant changes including the involvement of additional parties through stakeholder engagement or legislative action. In some cases, these tiers are discrete. However, state regulators may also choose to progress through these various tiers sequentially as they phase in aggregators while learning from their experience. With the ability to stack bulk system level services, distributed energy resource aggregations in MISO and SPP could provide various private benefits (e.g., increased value streams to the owner) as well as societally beneficial grid services (e.g., peaking capacity, ancillary services, and other services that increase the grid’s overall operational efficiency). In deciding how to best to enable these benefits, states and retail regulators must weigh various tradeoffs if considering reversing a previous opt out.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Robust Parameter Design on Dual Stochastic Response Models With Constrained Bayesian Optimization

In engineering system design, minimizing the variations of the quality measurements while guaranteeing their overall quality up to certain levels, namely the robust parameter design (RPD), is crucial. Recent works have dealt with the design of a system whose response-control variables relationship is a deterministic function with a complex shape and function evaluation is expensive. In this work, we propose a Bayesian optimization method for the RPD of stochastic functions. Dual stochastic response models are carefully designed for stochastic functions. The heterogeneous variance of the sample mean is addressed by the predictive mean of the log variance surrogate model in a two-step approach. We establish an acquisition function that favors exploration across the feasible and optimality-improvable regions to effectively and efficiently solve the stochastic constrained optimization problem. Further, the performance of our proposed method is demonstrated by the extensive numerical and case studies. Note to Practitioners-Many manufacturing processes involve undesirable variations, which create variations in the final products. For example, many emerging manufacturing processes, such as nanomanufacturing, involve complex physical and chemical dynamics and transformation, creating variations in the manufacturing output. In such processes, it is crucial to design the manufacturing processes or products so that they have minimum variations in their quality. Meanwhile, it is also important to maintain the overall quality of the designed processes or products. Furthermore, acquiring data from many advanced manufacturing processes is often very costly, especially in the designing stage. In this work, we propose a data-driven method that automatically finds the best setting of manufacturing processes or products with the minimum variations of quality and a given constraint on the average quality satisfied. Our proposed method is used before conducting every experiment; It analyzes the historical data from previous experiments and provides a setting to be used in the next experiment. Our proposed method efficiently utilizes the historical data, and thus finds the best robust setting by conducting only a small number of experiments.

42 ENGINEERING↗

The 𝑚=2 amplituhedron and the hypersimplex: Signs, clusters, tilings, Eulerian numbers

The hypersimplex Δ <#comment/> k + 1 , n \Delta _{k+1,n} is the image of the positive Grassmannian G r k + 1 , n ≥ <#comment/> 0 Gr^{\geq 0}_{k+1,n} under the moment map. It is a polytope of dimension n − <#comment/> 1 n-1 in R n \mathbb {R}^n . Meanwhile, the amplituhedron A n , k , 2 ( Z ) \mathcal {A}_{n,k,2}(Z) is the projection of the positive Grassmannian G r k , n ≥ <#comment/> 0 Gr^{\geq 0}_{k,n} into the Grassmannian G r k , k + 2 Gr_{k,k+2} under a map Z ~ <#comment/> \tilde {Z} induced by a positive matrix Z ∈ <#comment/> M a t n , k + 2 > 0 Z\in Mat_{n,k+2}^{>0} . Introduced in the context of scattering amplitudes , it is not a polytope, and has full dimension 2 k 2k inside G r k , k + 2 Gr_{k,k+2} . Nevertheless, there seem to be remarkable connections between these two objects via T-duality , as conjectured by Łukowski, Parisi, and Williams [Int. Math. Res. Not. (2023)]. In this paper we use ideas from oriented matroid theory, total positivity, and the geometry of the hypersimplex and positroid polytopes to obtain a deeper understanding of the amplituhedron. We show that the inequalities cutting out positroid polytopes —images of positroid cells of G r k + 1 , n ≥ <#comment/> 0 Gr^{\geq 0}_{k+1,n} under the moment map—translate into sign conditions characterizing the T-dual Grasstopes —images of positroid cells of G r k , n ≥ <#comment/> 0 Gr^{\geq 0}_{k,n} under Z ~ <#comment/> \tilde {Z} . Moreover, we subdivide the amplituhedron into chambers , just as the hypersimplex can be subdivided into simplices, with both chambers and simplices enumerated by the Eulerian numbers. We use these properties to prove the main conjecture of Łukowski, Parisi, and Williams [Int. Math. Res. Not. (2023)]: a collection of positroid polytopes is a tiling of the hypersimplex if and only if the collection of T-dual Grasstopes is a tiling of the amplituhedron A n , k , 2 ( Z ) \mathcal {A}_{n,k,2}(Z) for all Z Z . Moreover, we prove Arkani-Hamed–Thomas–Trnka’s conjectural sign-flip characterization of A n , k , 2 \mathcal {A}_{n,k,2} , and Łukowski–Parisi–Spradlin–Volovich’s conjectures on m = 2 m=2 cluster adjacency and on positroid tiles for A n , k , 2 \mathcal {A}_{n,k,2} (images of 2 k 2k -dimensional positroid cells which map injectively into A n , k , 2 \mathcal {A}_{n,k,2} ). Finally, we introduce new cluster structures in the amplituhedron.

Parisi, Matteo↗

Topological confinement in Skyrme holography

Abstract We study phase transitions in five-dimensional Einstein gravity with a negative cosmological constant, coupled to a Skyrme matter field. These transitions are topological generalizations of the Hawking–Page transition between thermal anti de Sitter (AdS) spacetime and an AdS black hole. Phases are characterized by a topological number associated with the Skyrme field configuration. Depending on that topological number and on the Skyrme coupling strength, there occur transitions between those phases at two, one, or no value(s) of the temperature. Through the holographic (AdS/CFT) correspondence, these solutions are dual to topologically non-trivial states in a conformal field theory with an SU (2)-symmetry, which support either confined or deconfined (quasi-)particles at strong coupling. We compare to similar known phase transitions, and discuss potential applications to confinement in topological phases of condensed matter and the quark–gluon plasma.

Astronomy & Astrophysics↗

Bounding entanglement entropy with Clifford double cosets

Following on our previous work studying the orbits of quantum states under Clifford circuits via reachability graphs, we introduce contracted graphs whose vertices represent classes of quantum states with the same entropy vector. These contracted graphs represent the double cosets of the Clifford group, where the left cosets are built from the stabilizer subgroup of the starting state and the right cosets are built from the entropy-preserving operators. We study contracted graphs for stabilizer states, as well as 𝑊 states and Dicke states, discussing how the diameter of a state's contracted graph constrains the entropic diversity of its two-qubit Clifford orbit. We derive an upper bound on the number of entropy vectors that can be generated using any 𝑛-qubit Clifford circuit, for any quantum state. Here, we speculate on the holographic implications for the relative proximity of gravitational duals of states within the same Clifford orbit. Although we concentrate on how entropy evolves under the Clifford group, our double-coset formalism, and thus the contracted graph picture, is extendable to generic gate sets and generic state properties.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Spectrum of end of the world branes in holographic BCFTs

We study overlaps between two regularized boundary states in conformal field theories. Regularized boundary states are dual to end of the world branes in an AdS black hole via the AdS/BCFT. Thus they can be regarded as microstates of a single sided black hole. Owing to the open-closed duality, such an overlap between two different regularized boundary states is exponentially suppressed as $\langle$ψ a |ψ b $\rangle$~e -O (h$^{(min)}_{ab}$) , where h$^{(min)}_{ab}$ is the lowest energy of open strings which connect two different boundaries a and b. Our gravity dual analysis leads to h$^{(min)}_{ab}$ = c/24 for a pure AdS 3 gravity. This shows that a holographic boundary state is a random vector among all left-right symmetric states, whose number is given by a square root of the number of all black hole microstates. We also perform a similar computation in higher dimensions, and find that h$^{(min)}_{ab}$ depends on the tensions of the branes. In our analysis of holographic boundary states, the off diagonal elements of the inner products can be computed directly from on-shell gravity actions, as opposed to earlier calculations of inner products of microstates in two dimensional gravity.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗