Some effects of roughness and variable entropy on transition at a Mach number of 8.
Tests at Mach 8 on cone, analyzing effect of roughness elements and variable entropy on transition and heat transfer distribution
HEAT TRANSFER↗
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Mach Number Effects on Turbine Blade Transition Length Prediction
The effect of a Mach number correction on a model for predicting the length of transition was investigated. The transition length decreases as the turbulent spot production rate increases. Much of the data for predicting the spot production rate comes from low speed flow experiments. Recent data and analysis showed that the spot production rate is affected by Mach number. The degree of agreement between analysis and data for turbine blade heat transfer without film cooling is strongly dependent of accurately predicting the length of transition. Consequently, turbine blade heat transfer data sets were used to validate a transition length turbulence model. A method for modifying models for the length of transition to account for Mach number effects is presented. The modification was made to two transition length models. The modified models were incorporated into the two-dimensional Navier-Stokes code, RVCQ3D. Comparisons were made between predicted and measured midspan surface heat transfer for stator and rotor turbine blades. The results showed that accounting for Mach number effects significantly improved the agreement with the experimental data.
Boyle, R. J.↗
Correlated solvent coordinates accelerate multi-donor proton-coupled electron transfer
The rate of charge transfer within a discrete donor–acceptor (D/A) pair is well-described by semi-classical electron transfer theory, but the effects of multiple equivalent redox sites remain less understood. We report a series of ground-state intramolecular proton-coupled electron transfer (PCET) complexes designed to isolate the effects of donor number, N, while holding geometry, coupling, and driving forces constant. The [Ru(L) 3−N (OH) N ] 2+ complexes incorporate one, two, or three identical phenolic electron donors linked to Ru through rigid phenanthroline bridges (OH = 2,4-di-tert-butyl-6-(1-methyl-1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol). Upon flash photolysis and oxidative quenching with methyl viologen (MV 2+ ), the transient Ru(III) oxidizes an appended phenol by PCET with the hydrogen-bonded imidazole nitrogen atom functioning as the base. The rate increased by 3.4-fold and 5.7-fold (1.7-fold and 1.9-fold after statistical correction) for two- and three-donor complexes compared to the single-donor system. The supra-statistical acceleration is attributed to a reduced effective outer sphere reorganization energy (λ m ) modeled by a partially shared solvent reaction coordinate, in which a subset of solvent dipoles is already oriented to stabilize charge from any donor. The final phenoxyl radical state is localized due to the transfer of a proton, and the recombination reaction with the viologen radical is not accelerated. These results demonstrate the effects of solvent dynamics on intramolecular PCET rates, offering a new strategy for the design of synthetic charge transfer systems.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
The effects of delta rays on the number of particle-track traversals per cell in laboratory and space exposures
It is a common practice to estimate the number of particle-track traversals per cell or cell nucleus as the product of the ion's linear energy transfer (LET) and cell area. This practice ignores the effects of track width due to the lateral extension of delta rays. We make estimates of the number of particle-track traversals per cell, which includes the effects of delta rays using radial cutoffs in the ionization density about an ion's track of 1 mGy and 1 cGy. Calculations for laboratory and space radiation exposures are discussed, and show that the LET approximation provides a large underestimate of the actual number of particle-track traversals per cell from high-charge and energy (HZE) ions. In light of the current interest in the mechanisms of radiation action, including signal transduction and cytoplasmic damage, these results should be of interest for radiobiology studies with HZE ions.
NASA Discipline Radiation Health↗
Heat and Momentum Transfer Studies in High Reynolds Number Wavy Films at Normal and Reduced Gravity Conditions
We examined the effect of the gas flow on the liquid film when the gas flows in the countercurrent direction in a vertical pipe at normal gravity conditions. The most dramatic effect of the simultaneous flow of gas and liquid in pipes is the greatly increased transport rates of heat, mass, and momentum. In practical situations this enhancement can be a benefit or it can result in serious operational problems. For example, gas-liquid flow always results in substantially higher pressure drop and this is usually undesirable. However, much higher heat transfer coefficients can be expected and this can obviously be of benefit for purposes of design. Unfortunately, designers know so little of the behavior of such two phase systems and as a result these advantages are not utilized. Due to the complexity of the second order boundary model as well as the fact that the pressure variation across the film is small compared to the imposed gas phase pressure, the countercurrent gas flow affect was studied for the standard boundary layer model. A different stream function that can compensate the shear stress affect was developed and this stream function also can predict periodic solutions. The discretized model equations were transformed to a traveling wave coordinate system. A stability analysis of these sets of equations showed the presence of a Hopf bifurcation for certain values of the traveling wave velocity and the shear stress. The Hopf celerity was increased due to the countercurrent shear. For low flow rate the increases of celerity are more than for the high flow rate, which was also observed in experiments. Numerical integration of a traveling wave simplification of the model also predicts the existence of chaotic large amplitude, nonperiodic waves as observed in the experiments. The film thickness was increased by the shear.
Balakotaiah, V.↗
Comparative experimental study of heat transfer processes in accumulation energy recovery exchangers
In this study, an experimental comparison between three different energy accumulating ceramic heat exchangers for energy recovery in ventilation systems was presented. The units were selected to represent three different approaches on the energy recovery process: honeycomb structure with more accumulation mass (more energy can be stored in one unit)- Unit 1.1, honeycomb structure with lower accumulation mass- Unit 1.2, and a rectangular structure with expanded heat transfer surface- Unit 1.3. The achieved results are useful for the future application of such units in ventilation systems. It was established that all evaluated units demonstrated an acceptable effectiveness of thermal energy recovery from the exhaust air. Their average energy recovery efficiency ranged between 70 % and 80 %, aligning with expected performance benchmarks for regenerative heat exchangers employed in contemporary mechanical ventilation systems. It was also established that the factor which has the highest impact on thermal effectiveness is the heat transfer surface available in the tested heat exchangers. Units with the highest number of channels (i.e., with the highest amount of single channel walls, which can be used for heat transfer) achieve the highest thermal effectiveness. However, higher thermal effectiveness can negatively affect the ventilation potential of the units. Unit 1.3, which was characterized by the highest thermal efficiency, was also characterized by the lowest achievable flow rate. It was also found that the important technical aspect that should be taken into account when analyzing accumulation energy recovery units is also the fluctuation of the supply air temperature. The ability to ensure minimal temperature fluctuations is a significant operational advantage, as it ensures a higher level of safety at lower outside temperatures.
Energy recovery↗
Where Have All of the Electrons Gone? Understanding the Role of Alternative Electron Flow and O 2 Reduction in Balancing Cellular Redox (Final Technical Report)
An informed understanding of the fundamentals of light-driven electron transfer reactions in photoautotrophic organisms is necessary to enable improved photosynthetic efficiencies for the production of renewable fuels and novel biomaterials. To obtain high photosynthetic yields, light energy must be efficiently coupled to the fixation of CO 2 . Sub-optimal environmental conditions and metabolic routing (caused by blocks in biosynthetic routes) can severely impact the conversion of light energy to biomass and lead to reactive oxygen production, which in turn can cause cellular damage and productivity losses. Hence, plants, algae, and photosynthetic bacteria have evolved a network of alternative outlets to sustain the flow of photosynthetically derived-electrons. Our research was focused on the nature and integration of these outlets. The data obtained in this project will inform efforts to rationally engineer crop plants and algae to improve photosynthetic yields by enhancing electron transfer reactions to CO 2 reduction and targeted biomass accumulation. A major project research thrust was focused on identifying and quantifying the flow of photosynthetic reductant through electron transfer circuits that result in the light-dependent reduction of O 2 . New energy management strategies were identified that are used when normal carbon assimilation pathways are compromised due to nutrient deprivation, and/or by a reduction in starch synthesis/carbon storage, all conditions resulting in highly reduced intracellular redox pools. The green alga Chlamydomonas reinhardtii, and likely many other algae, have multiple O 2 -reducing pathways that play critical roles in maintaining cellular metabolic balance and scavenging electrons that could potentially cause cellular damage, which in some instances leads to reduced photosynthetic yields but increased fitness. We explored the activities of three essential outlets associated with Chlamydomonas reinhardtii photosynthetic electron transport: (1) reduction of O 2 to H 2 O through Flavodiiron proteins (FLVs) and (2) Plastid Terminal Oxidases (PTOX), and (3) the synthesis of starch. Real-time measurements of O 2 exchange demonstrated that FLVs immediately engage during dark to light transitions, allowing electron transport when the CBBC is not fully activated. Under these conditions, we quantified, for the first time, maximal FLV activity and its overall capacity to direct photosynthetic electrons towards O 2 reduction. However, when starch synthesis is compromised, a greater proportion of electrons is directed toward O 2 reduction through the FLVs, while PTOX, which is sensitive to the PQ pool redox state, is activated. This suggests, that starch synthesis has an important role in priming/regulating CBBC and electron transport. We also identified a biological ‘switch’ in the green alga Chlamydomonas reinhardtii that reversibly restricts photosynthetic electron transport (PET) at the cytochrome b 6 f complex when reductant and ATP generated by PET are in excess of the capacity of carbon metabolism to utilize these products; we specifically show a restriction at this switch when sta6 mutant cells, which cannot synthesize starch, are limited for nitrogen (growth inhibition) and subjected to a dark to light transition. This restriction causes diminished electron flow to PSI, which prevents PSI photodamage, and the plastid alternative oxidase (PTOX) becomes fully activated, serving as an electron valve that dissipates excitation energy absorbed by PSII, thereby lessening PSII photoinhibition. Furthermore, illumination of the cells following the dark acclimation gradually diminishes the restriction at the switch. Future engineering of these switches may allow more effective electron transfer to lipid (biofuel) pathways and diminish the number of electrons “wasted” in the reduction of O 2 to water. Lastly, we explored metabolic routing of electrons during algal fermentation and discovered multiple novel pathways that are activated when the preferred anoxic routes are blocked. These provide valuable products (e.g. lactate, glycerol) that can be used in broad portfolio of biotechnological applications.
59 BASIC BIOLOGICAL SCIENCES↗
Aerothermodynamic Calculations on X-34 at Mach 6 Wind Tunnel Conditions
The effects of Reynolds number and turbulence on surface heat-transfer rates are numerically investigated for a 0.015 scale X-34 vehicle at wind tunnel conditions. Laminar heating rates, non-dimensionalized by Fay-Riddell stagnation heating, do not change appreciably with an order of magnitude variation in Reynolds number. Modeling a turbulent versus laminar boundary layer at the same Reynolds number increases the windside heating by a factor of four, portions on the leeside by a factor of two, and causes a 30 percent increase in wing leading edge heating. A discrepancy between laminar and turbulent heating trends on the windside centerline is explained by the presence of attached windside vortices in the laminar solutions, structures that are inhibited by the turbulence modeling.
Wood, William A.↗
A new approach to the correlation of boundary layer mass transfer rates with thermal diffusion and/or variable properties
A rational approach to the correlation of boundary layer mass transport rates, applicable to many commonly encountered laminar flow conditions with thermal diffusion and/or variable properties, is outlined. The correlation scheme builds upon already available constant property blowing/suction solutions by introducing appropriate correction factors to account for the additional ('pseudo' blowing and source) effects identified with variable properties and thermal diffusion. Applications of the scheme to the particular laminar boundary layer mass transfer problems considered herein (alkali and transition metal compound vapor transport) indicates satisfactory accuracy up to effective blowing factors equivalent to about one third of the 'blow off' value. As a useful by-product of the variable property correlation, we extend the heat-mass transfer analogy, for a wide range of Lewis numbers, to include variable property effects.
Srivastava, R.↗
Film cooling on a convex wall: Heat transfer and hydrodynamic measurements for full and partial coverage
Turbine-blade cooling is an important issue for high-efficiency turbine engines, and discrete-hole injection is widely used as a cooling method. In the present study, detailed measurements were made of the heat transfer and hydrodynamics of a film-cooled flow on a convex wall, both for full and partial coverage. Two important parameters were altered: the blowing ratio, m, and the number of rows of injection holes. Three values of m were tested: m = 0.2, 0.4, and 0.6. In the blown region, m = 0.4 results in the lowest Stanton numbers of the three blowing ratios tested. This indicates that the value of m = 0.4 is near optimum on the convex wall from the point of view of cooling effect by injection. In the recovery region, Stanton numbers gradually approach the no injection values. Although the heat-transfer behavior during recovery from injection looks relatively complicated, the behavior of Stanton number can be explained in terms of two mechanisms: recovery from the thermal effect of injection and recovery from the turbulence augmentation. This interpretation of the data is supported by the hydrodynamic and temperture-profile measurements. For partial blowing cases, the data follow the full-coverage values inside the blown region. In the unblown region, both in the curved and in the flat plate, the effect of the number of blown rows is clearly seen. Hydrodynamic boundary-layer profiles were measured with the aid of a triple hot-water probe. Three mean-velocity components and six turbulence quantities were simultaneously measured, and inside the blown region strong three-dimensionality was observed.
Furuhama, K.↗
Effect of emitters on quantum state transfer in coupled cavity arrays
Over the last decade, conditions for perfect state transfer in quantum spin chains have been discovered and their experimental realizations addressed, as have their extensions to more complex geometries of coupled cavity-emitter arrays. In this paper we further consider such studies and situations in which quantum state transfer can occur with high fidelity, even when the cavity-cavity coupling rates and cavity-emitter interaction rates are comparable. This is accomplished through the development and use of a Monte Carlo approach to the inverse eigenvalue problem, which allows the determination of coupling rates which optimize quantum state transfer fidelity and subsequent time evolution of the polariton wave function through exact diagonalization of the resulting Jaynes-Cummings-Hubbard Hamiltonian. The effect of inhomogeneous emitter locations is also evaluated. Furthermore, our key results include the demonstration that our methodology can be used successfully to establish Hamiltonian parameters for high-fidelity state transfer in more general lattice geometries and excitation number sectors, and also a determination of the effects of fluctuations in those parameters about their optimal values.
77 NANOSCIENCE AND NANOTECHNOLOGY↗
Analysis of Turbulent Flow and Heat Transfer on a Flat Plate at High Mach Numbers with Variable Fluid Properties
A previous analysis of turbulent heat transfer and flow with variable fluid properties in smooth passages is extended to flow over a flat plate at high Mach numbers, and the results are compared with experimental data. Velocity and temperature distributions are calculated for a boundary layer with appreciative effects of frictional heating and external heat transfer. Viscosity and thermal conductivity are assumed to vary as a power or the temperature, while Prandtl number and specific heat are taken as constant. Skin-friction and heat-transfer coefficients are calculated and compared with the incompressible values. The rate of boundary-layer growth is obtained for various Mach numbers.
Deissler, R. G.↗
Drag and Heat Transfer on a Parabolic Body of Revolution (NACA RM-10) in Free Flight to Mach Number 2 with Both Constant and Varying Reynolds Number and Heating Effects on Turbulent Skin Friction
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Maloney, Joseph P↗
CFD Simulations of Molten Salts Within Plasma-Facing Components with Twisted Tape Inserts Under One-Sided–Heated Conditions
For liquid immersion blankets (LIBs), the heat removal within different plasma-facing components (PFCs) requires substantial heat removal capabilities that could benefit from the usage of heat transfer enhancements. Of consideration are twisted tape insert heat transfer enhancements that are ribbon-like metal pieces inserted within cooling channels that increase fluid mixing, resulting in higher heat transfer and pressure drop. Unlike traditional applications, PFCs such as divertor coolant tubes experience a significantly higher heat flux on one side versus the other or entirely one-sided heating. These conditions are not well studied for molten salts where the higher Prandtl numbers characteristic of the fluids are significantly higher than water, gases, and liquid metals. As an effort to study this knowledge gap, large eddy simulations were done with Prandtl numbers representative of FLiBe at proposed operating conditions. In this study, the effects of applying a surface heat flux to one side of a tube versus the entire tube with a twisted tape insert were investigated for the heat transfer coefficient and effects on the temperature profile. The findings of the study suggest that for Prandtl number fluids above unity, the Nusselt number was largely unaffected by the change in boundary condition. Both boundary conditions showed good agreement with the Manglik and Bergles Nusselt number correlation for tight-fitting twisted tapes. Finally, the outcomes of this study will be useful for future design studies of LIBs to provide fundamental guidance implementing twisted tape inserts and their performance in one-sided–heated conditions.
molten salts↗
Stagnation-point heat transfer correlation for ionized gases
Based on previous laminar boundary-layer solutions for argon, xenon, nitrogen, and air, it is shown that the effect of gas ionization on stagnation-point heat transfer can be correlated with the variation of the frozen Prandtl number across the boundary layer. A formula is obtained for stagnation-point heat transfer in a noble gas and is shown to be valid from the low-temperature range to the region of strong ionization. It is concluded that the considered effect can be well correlated by the 0.7 power of the Prandtl-number ratio across the boundary layer.
Bade, W. L.↗
Continuum Description of the Role of Negative Transference Numbers on Ion Motion in Polymer Electrolytes
New experimental techniques such as electrophoretic NMR (eNMR) are emerging as powerful methods for directly measuring ion velocities in electrolytes under applied electric fields. The aim of this theoretical study is to predict the spatial- and temporal-dependence of these velocities of ions as a function of the magnitude of the applied field and salt concentration. It has recently been shown that mixtures of poly(ethylene oxide)-based (PEO) and lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) electrolytes exhibit negative cation transference numbers in a certain salt concentration range. In this range, the cation motion at early times is directed to the positive electrode at all locations in the cell; ion migration dominates in this regime. As time progresses, the cation velocity in finite zones near both the electrodes changes sign. These zones grow rapidly with time, reflecting the increasing importance of diffusion, and a point in time is reached beyond which the cation velocity in the entire cell is directed toward the negative electrode. Overall, our work reveals the limited time window over which the results of eNMR can be used to determine the transference number. More importantly, it shows how to account for the effect of diffusional flux in such experiments.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Thermal effects in an accelerating thrust bearing
This study is mainly concerned with the development of transient temperatures in a thrust bearing. The effect of Prandtl number on temperatures was also investigated. All lubricant properties were assumed to be constant. It was found that the location of highest temperatures depended on the bearing ratio. The effect of Prandtl number on temperatures was small. However, its effect on the heat transfer at the surfaces was significant.
Doo, R.↗
Study of the ammonia ice cloud layer in the north tropical zone of Jupiter from the infrared interferometric experiment on Voyager
An average of 51 Voyager 1 IRIS spectra of Jupiter's North Tropical Zone was analyzed to infer the abundance, vertical extent, and size distribution of the particles making up the ammonia cloud in this region. It is assumed that the cloud base coincides with the level at which 100% saturation of ammonia vapor occurs. The vertical distribution of particulates above this level is determined by assuming a constant total ammonia mixing ratio and adjusting the two phases so that the vapor is saturated throughout the cloud. A constant scaling factor then adjusts the base number density. A radiative transfer program is used that includes the effects of absorption and emission of all relevant gases as well as anisotropic scattering by cloud particles. Mie scattering from a gaussian particle size distribution is assumed. The vertical thermal structure is inferred from a temperature retrieval program that utilizes the collision induced S(0) and S(1) molecular hydrogen lines between 300 and 700.cm, and the 1304.cm methane band.
Shaffer, William A.↗