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At least 109 records · Page 6

Anisotropic magnetism and electronic structure of trigonal EuAl 2 Ge 2 single crystals

Understanding the interplay between magnetic and electronic degrees of freedom is of profound recent interest in different Eu-based magnetic topological materials. Here, we studied the magnetic and electronic properties of the layered Zintl-phase compound EuAl 2 Ge 2 crystallizing in the trigonal CaAl 2 Si 2 -type structure. We report zero-field neutron diffraction, temperature T - and magnetic-field H-dependent magnetic susceptibility χ(T, H), isothermal magnetization M(T, H), heat capacity C p (T, H), and electrical resistivity ρ(T, H) measurements, together with T-dependent angle-resolved photoemission spectroscopy (ARPES) measurements complemented with first-principle calculations. EuAl 2 Ge 2 undergoes second-order A-type antiferromagnetic (AFM) ordering below T N = 27.5(5) K, with the Eu moments (Eu 2+ , S = 7/2) aligned ferromagnetically in the ab plane while these layers are stacked antiferromagnetically along the c axis. The critical fields at which all moments become parallel to the field are 37.5(5) and 52.5(5) kOe for H ∥ ab and H ∥ c, respectively. The H = 0 magnetic structure consists of trigonal AFM domains associated with ab-plane magnetic anisotropy and a field-induced reorientation of the Eu spins in the domains is also evident at T = 2 K below the critical field H c1 = 2.5(1) kOe. The ρ(T) measurements reveal metallic behavior transforming into a slight resistivity increase on cooling towards T N . A pronounced loss of spin-disorder scattering is observed below T N . The ARPES results show that EuAl 2 Ge 2 is metallic both above and below T N , and the Fermi surface is anisotropic with two hole pockets at the zone center and one small electron pocket at each M point. In the AFM phase, we directly observe folded bands in ARPES due to the doubling of the magnetic unit cell along the c axis with an enhancement of quasiparticle weight due to the complex change in the coupling between the magnetic moments and itinerant electrons on cooling below T N . The observed electronic structure is well reproduced by first-principle calculations, which also predict the presence of nontrivial electronic states near the Fermi level in the AFM phase with Z 2 topological numbers 1;(000)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

End-Use Savings Shapes Measure Documentation: Variable Refrigerant Flow With 25% Upsizing Allowance for Heating

This documentation focuses on a single end-use savings shape upgrade - a variable refrigerant flow with heat recovery (VRF HR) heating and cooling system coupled with a dedicated outdoor air system (DOAS) for ventilation and where 25% upsizing (or 125% of the original size) is allowed for heating in colder climates (i.e., heating dominant regions). This document will primarily discuss the additional changes to the sizing algorithm and modeling approach, while a comprehensive overview of the fundamental modeling methodology and background of the VRF HR DOAS upgrade, including applicability and other key assumptions can be found in the original documentation: Variable Refrigerant Flow with Heat Recovery and Dedicated Outdoor Air System. To provide more context on the 25% upsizing algorithm, if the building is a cooling dominant (e.g., design cooling load higher than design heating load ), then the outdoor unit capacity of the VRF heat pump is sized based on the design cooling load. However, if the building is heating dominant, then this building is a candidate for the 25% upsizing allowance. Once the 25% upsizing is allowed, if the 25% upsized capacity (or 125% from the original size) represented with design condition exceeds the design heating load, then the design heating load is used for calculating the rated capacity of the outdoor unit. And if the 25% upsized capacity represented with the design condition does not exceed the design heating load, then the 25% upsized capacity represented with rated condition is used for the capacity of the outdoor unit while the remaining heating load is handled with the supplemental/backup electric resistance coil.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Carbon Nanotube and Graphene Oxide Reinforced Composites for Lightning Strike Protection of Composite Structures

Carbon fiber reinforced plastics (CFRP) composites have become the primary materials in the aerospace industry. Future transportation means, such as urban air mobility (UAM), will be employing CFRP structures. However, lightning strike damage on composite structures is a serious concern. CFRP composites possess low through-thickness electrical conductivity (≈ 1 S/m), which can cause extreme resistive heat in the event of lightning strikes. Research on polymeric lightning strike protection has gained momentum in the past few years. Researchers have studied various conductive fillers to improve the CFRP performance against lightning strikes. Carbon nanotubes (CNTs) and graphene oxide (GO) have been studied as future lightning Strike Protection (LSP) materials the most. The use of CNT and GO-based composites has shown improved mechanical properties and improved electrical conductivity of the composites. Researchers investigated CNTs and GO as the fillers to the matrix system, sizing the carbon fibers and the surface coating on top of the CFRP surface. This chapter highlights the remarkable improvement in the lightning damage suppression of CNT and GO-based composites and their structural applications. Special attention is given to their potential use as LSP material in future aircraft.

Kumar, Vipin↗

A thermodynamic model of integrated liquid-to-liquid thermoelectric heat pump systems

Thermoelectric (TE) heat pumps (TEHPs) are advantageous for heating and cooling in various applications because of their modularity and simple design. A TEHP system includes the TE modules with p- and n-type materials bonded to substrates, plus heat exchangers, thermal interfaces to the heat exchangers, and heat transfer fluids. Although modeling an individual TE module has been extensively studied, limited studies have reported performance at the larger system-level. Furthermore, no prior study has addressed the impact of temperature-dependent TE material properties (e.g., electric resistivity, thermal conductivity, and Seebeck coefficient) on overall heat-pump-system-level performance. Here, this work presents a mathematical model for TEHP system performance based on Goldsmid's approach for TE material performance, “effective” TE material properties, Gnielinski's correlation for convective heat transfer, and thermal balance theory for a heat exchange network. This combined approach provides an accurate model of the liquid-to-liquid TEHP system. Three different approaches—one empirical, one based on the manufacturer's specifications, and one drawn from the literature—were then used to determine values for TE material properties. The first two methods treated properties as constants, while the last approach treated properties as surface-temperature-based functions. Finally, experimental TEHP data was used to validate the models, all with relative absolute deviations of approximately 10% when predicting heating capacity and 10%–25% when forecasting cooling capacity up to a 30 K surface temperature lift. The results demonstrated that, at the TEHP system level, the TE material properties could be treated as constants, avoiding solver iterations and reducing the performance uncertainty by up to 95%.

42 ENGINEERING↗

Coal-derived electrically conductive asphalt pavements for snow/ice melting: From laboratory to field

Timely removal of ice and snow from roads is critical to safe, fast, and uninterrupted transportation networks in cold regions. Constructing electrically conductive asphalt pavements to melt the ice and snow on the roads through resistive eating is an emerging alternative technology to traditional snow/ice removal approaches such as utilizing snowplow machines and deicing chemicals. Carbon-based fibers and fillers including carbon fiber and graphite have been widely reported to make electrically conductive hot mix asphalt mixtures for pavement snow/ice-melting applications. This study aimed to develop and demonstrate a novel type of electrically conductive asphalt pavements for snow/ice-melting, which utilizes electrically conductive cold mix asphalt (CMA) mixtures incorporating coal-derived carbon-based coke aggregate as resistive heating elements. Both laboratory experiments and field tests were conducted to investigate the electrical, mechanical, and thermal properties of such electrically conductive asphalt mixtures and pavements. The laboratory experiment results indicated that the electrically conductive CMA mixtures incorporating coke aggregate had sufficiently high electrical conductivity and satisfactory mechanical performance and the pavement prototype slab utilizing a thin layer of such CMA mixtures could successfully raise the pavement surface temperatures to 8.3–11.7 °C rom a low temperature of –5 °C with an input power density of 473 W/m 2 . The field test results showed that the full-scale coal-derived electrically conductive asphalt pavements were able to increase the pavement surface temperatures when electricity was applied, but the magnitude of temperature increase was highly dependent on the power density. Furthermore, it is promising to use coke aggregate to construct coal-derived electrically conductive asphalt pavements for snow/ice melting.

36 MATERIALS SCIENCE↗

Potentiometric entropy and operando calorimetric measurements reveal fast charging mechanisms in PNb 9 O 25

The Wadsley–Roth compound PNb 9 O 25 is a promising fast charging lithium ion battery anode material with high operating voltage to prevent solid electrolyte interface formation. Here, in this work, we present potentiometric entropy measurements featuring signatures of semiconductor-to-metal transition and intralayer ordering upon lithiation in the anode material PNb 9 O 25 that could not be observed with in situ X-ray diffraction. In addition, the instantaneous heat generation rates at the PNb 9 O 25 working electrode and at the lithium metal counter electrode during galvanostatic cycling were measured individually for the first time by operando isothermal calorimetry. The heat generation rate decreased at the PNb 9 O 25 electrode upon lithiation due to the decrease in electrical resistivity caused by the semiconductor-to-metal transition observed in potentiometric entropy measurements. Furthermore, the heat generation rate at the lithium metal electrode was positive during delithiation due to the exothermic plating of Li + ions on the lithium metal counter electrode associated with dendrite formation. Furthermore, calorimetric measurements established that the entropy change dominated the reversible heat generation rate at each electrode. Finally, the contribution of enthalpy of mixing was relatively small even at high C-rates thanks to the high Li + ion mobility in PNb 9 O 25 confirming its promises as a fast charging anode material.

25 ENERGY STORAGE↗

Pressure tuning of structural and magnetic transitions in EuAg 4 As 2

We report temperature-dependent measurements of ambient-pressure specific heat, magnetic susceptibility, anisotropic resistivity, and thermal expansion as well as in-plane resistivity under pressure up to 20.8 kbar on single crystals of EuAg 4 As 2 . Based on thermal expansion and in-plane electrical transport measurements at ambient pressure this compound has two, first-order, structural transitions in the 80–120 K temperature range. Ambient-pressure specific heat, magnetization, and thermal expansion measurements show a cascade of up to seven transitions between 8 and 16 K associated with the ordering of the $Eu^{2+}$ moments. In-plane electrical transport is able to detect the more prominent of these transitions, at 15.5, 9.9, and 8.7 K, as well as a weak feature at 11.8 K at ambient pressure. Pressure-dependent electrical transport data show that the magnetic transitions shift to higher temperatures under pressure, as does the upper structural transition, whereas the lower structural transition is suppressed and ultimately vanishes. A jump in resistivity, associated with the upper structural transition, decreases under pressure with an extrapolated disappearance (or a change of sign) by 30–35 kbar. In the 10–15 kbar range a kink in the pressure dependency of the upper structural transition temperature as well as the high- and low-temperature in-plane resistivities suggests that a change in the electronic structure may occur in this pressure range. The results are compared with the literature data for EuAg 4 As 2 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Performance Modeling of a Thermoelectric Heat Pump Clothes Dryer with Very High Air Flow

Previous research has shown that a clothes dryer heated by thermoelectric (Peltier) heat pumps can be up to 85% more efficient than a conventional electric-resistance dryer. A previous thermoelectric prototype used a conventional dryer’s air flow of 120 ft3/min (0.06 m3/s) and provided about 1,300 W of thermoelectric heating capacity at a heating coefficient of performance (COP) of approximately 1.2. In this work, the performance of a clothes dryer with a very high air flow rate, up to 300 ft3/min (1.14 m3/s), and only 400 W of thermoelectric heating capacity was investigated using a thermohydraulic model. Key aspects of the model were validated experimentally. Results for dry time and efficiency are presented for various air flow and heating rates.

Boudreaux, Philip↗

Utilizing coal-derived solid carbon materials towards next-generation smart and multifunction pavements

This project focused on developing an eco-friendly, multifunctional pavement system, called Coal-Derived Carbon Enabled Smart Pavement (CDC-SP), using coal-derived materials. The system utilizes coal-derived pyrolyzed char as a key component to create electrically conductive asphalt concrete for smart pavements that offer self-heating, self-sensing, and self-healing capabilities. These functions are made possible by the conductive properties of coal-char, which enable Ohmic heating for snow and ice deicing, piezoresistivity for self-sensing, and induction heating for self-healing of cracks caused by stress or aging. The team successfully created CDC-SP samples with over 50% coal char composition, demonstrating desirable mechanical properties such as rutting resistance, moisture susceptibility, and cracking resistance. These samples also exhibited strong electrical and thermal conductivity, making them ideal for heating applications. Extensive tests confirmed the pavement’s effectiveness in melting ice and snow and maintaining durability under environmental conditions. The CDC-SP presents a promising approach to integrating U.S. domestic coal resources into infrastructure projects, providing environmental and economic benefits by enhancing pavement performance while utilizing low-cost coal-derived materials. Further research and compliance with industry standards are recommended before commercial scaling.

01 COAL, LIGNITE, AND PEAT↗

Physical properties of the layered $\mathcal{f}$-electron van der Waals magnet Ce 2 Te 5

Here. we report a detailed study of the magnetic, transport, and thermodynamic properties of Ce 2 Te 5 single crystals, a layered $\mathcal{f}$-electron van der Waals magnet. Four consecutive transitions at ~5.2, 2.1, 0.9, and 0.4 K were observed in the ac-plane electrical resistivity $\rho(T)$, which were further confirmed in specific heat $C_\text{p}(T)$ measurements. Analysis of the magnetic susceptibility $\chi(T)$, the magnetic-field variation of $\rho(T)$, and the increase of the first transition temperature ($T_c$ ~ 5.2 K) with applied magnetic field indicates ferromagnetic order, while the decrease of the other transitions with field suggests different states with dominant antiferromagnetic interactions below $T_2$ ~ 2.1 K, $T_3$ ~ 0.9 K, and $T_4$ = 0.4 K. Critical behavior analysis around Tc that gives critical exponents $\beta$ = 0.31(2), $\gamma$ = 0.99(2), $\delta$ = 4.46(1), and $T_c$ = 5.32(1) K indicates that Ce 2 Te 5 shows a three-dimensional magnetic critical behavior. Moreover, the Hall resistivity ρxy indicates that Ce2Te5 is a multiband system with a relatively high electron mobility ~2900 cm 2 V –1 s –1 near $T_c$, providing further opportunities for future device applications.

36 MATERIALS SCIENCE↗

Dual-season thermal energy storage-integrated heat pump system for load shifting: experiments, modeling and nationwide analysis

Here, this paper proposes and validates a dual-season thermal energy storage-integrated heat pump (TES-HP) system that shifts building electric load in both cooling and heating modes using a single phase-change TES. The design uses the TES as a heat sink for the condenser in summer and a heat source for the evaporator in winter, thereby reducing on-peak electric demand while ensuring compatible with existing air-distribution systems. A 14-kW TES-HP prototype with six operating modes and novel refrigerant charge management strategies was experimentally tested under varied conditions. Subsequently, data-driven polynomial performance curves were developed and validated against experiments, then coupled with a phase change material (PCM) model and a calibrated building model within a rule-based controller. Single-day case studies demonstrated effective on-peak demand reduction while maintaining thermal comfort. During cooling, hourly power was lowered by up to 1.5 kW; in heating, average hourly power decreased from over 3.5 kW to 1.8 kW, compared to an HP-only system, achieving 64.5 % load shifting, and the need for resistance heating was eliminated. Seasonal simulations showed typical on-peak electricity savings of 25–35 % in cooling and 40–65 % in heating, with the largest benefits on the hottest and coldest days. Extended response-surface analysis and nationwide mapping quantified load shifting as functions of ambient and TES temperatures, revealing a seasonal trade-off in TES phase-change temperature. These results demonstrate the TES-HP system as a practical and scalable solution for grid-interactive buildings that reduces on-peak demand and electricity use while maintaining thermal comfort and enhancing grid flexibility and reliability.

Grid-interactive buildings↗

Superconductivity in WBe 2

WBe 2 , which occurs in space group 194, with hexagonal symmetry P6 3 /mmc, is prepared by arc-melting at temperatures above 2200 C, where Be vapor loss is significant. This study is motivated by recent work on MoB 2 and WB 2 , both superconductors (T c =32 and 17 K respectively) under high (∼70 GPa) pressure. In order to avoid the known Be-rich superconducting phases (WBe 13 and WBe 22 ) in the complex phase diagram, both known to be superconducting at 4.1 K, the sample was prepared with a slight (∼5 %) excess of W. The resultant sample, prepared using high purity (99.999 %) Be, is essentially single phase WBe 2 , with some spread in its superconducting properties due to the known homogeneity range. (WBe 2 forms in space group 194 between approximately W 1.02 Be 1.98 and W 0.88 Be 2.12 .) Characterization was carried out with x-ray diffraction, electrical resistivity, ρ, in zero and applied magnetic fields, and specific heat. The resistivity in zero and applied fields and specific heat data indicate that our sample of WBe 2 is a bulk superconductor at ambient pressure with a T c onset in ρ at 1.05 K, and T c (ρ→0) at ∼0.86 K. Furthermore, there is no signature of superconductivity in ρ at 4.1 K, indicating successful avoidance of WBe 13 and WBe 22 . The ρ data in field indicate an upper critical field of approximately 400 gauss.

Electrical transport↗

Fast-airflow tumble clothes dryer with small thermoelectric heat pump: Experimental evaluation

Residential clothes drying accounts for about 5% of the total residential-sector energy consumption in the United States. Most dryers use electric resistance heaters to dry clothes and have low efficiencies. Higher-efficiency dryers that use vapor compression heat pumps are expensive and complex and have not gained a large market share in the United States. A novel tumble clothes dryer using a small thermoelectric heat pump with faster airflow than typical dryers is presented in this work. The benchtop performance of the thermoelectric heat pump and high-speed blower are presented, and the development of the prototype dryer is described. The dryer was tested for efficiency and dry time for a range of airflow rates and applied currents to the thermoelectric heat pump. The combined efficiency factor was 5.09–6.29 lb BDW /kWh (specific moisture extraction rate of 1.23–1.53 kg w /kWh) with 100–138 min dry times for these tests. The measured efficiency was 36 %–68 % greater than the minimum efficiency standard in the United States, and compared with vapor compression heat pump–based clothes dryers, the prototype dryer had less expensive, less complex components and did not use refrigerants. Finally, the performance of this small thermoelectric heat pump clothes dryer is also compared with previous iterations of the thermoelectric tumble clothes dryer described in the literature.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Electrical and structural properties of VO 2 in an electric field

We examined the electrical and local structural properties of a VO 2 film at different electric fields using electrical resistance and x-ray absorption fine structure (XAFS) measurements at the V K edge in the temperature range of 30–100 °C. The T c value of the metal-to-insulator transition (MIT) during both heating and cooling decreases with electric field. When the electric field exceeds a certain value, the MIT becomes sharper due to Joule heating. Furthermore, the MIT, the structural phase transition (SPT), and the pre-edge peak transition of the VO 2 do not congruently occur at a uniform temperature. A metallic VO 2 is observed in only the rutile (or M2) symmetry. An electric field induces a substantial amount of conduction electrons in insulating VO 2 . Simultaneously measured resistance and XAFS reveal that Joule heating caused by an external electric field significantly affects the MIT and SPT of VO 2 .

36 MATERIALS SCIENCE↗

End-Use Savings Shapes: Measure Documentation: Add Exhaust Air Heat/Energy Recovery

This documentation focuses on a single end-use savings shape measure—Add Exhaust Air Heat/Energy Recovery. This measure adds exhaust air energy recovery or heat recovery to existing air handling units (AHU) with outdoor air. Systems that already have energy/heat recovery are not modified. Furthermore, food service building types are also not modified by this measure due to the added complication of integrating cooking hood exhaust that could cause heat exchanger fouling from kitchen exhaust. In total, this measure is applicable airloops serving ~70% of the floor area in ComStock. In practice, energy/heat recovery systems are retrofitted to existing air delivery systems either as separate systems that provide outdoor air to the AHUs or are directly integrated to an AHU; the modeling approach used in this study is agnostic of the energy recovery type and simply accounts recovery effectiveness, added static pressure, and other controls which are described further in this document. Energy recovery with sensible and latent exchange gets added in humid climate zones, while heat recovery with sensible-only exchange gets added in drier climate zones. Energy recovery is modeled as a fixed membrane plate counterflow heat exchanger, while heat recovery is modeled as a sensible-only fixed aluminum plate counterflow heat exchanger. Both systems include a bypass (for temperature control and economizer lockout) and electric resistance preheat coil for frost prevention.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Increasing the Number of Installed Residential Heat Pump Water Heaters in the USA Through Improved Technology and Utility Programs

Heat pump water heaters (HPWHs) offer an efficient alternative to electric resistance water heaters, but they suffer from limited market penetration. This paper reviews the current state of HPWHs in the USA, focusing on technology developments and programs to increase adoption. What technological improvements are needed to make HPWHs a good fit in more homes? Additionally, what are the best ways of promoting HPWHs to consumers? Improved communication and controls will allow HPWHs to provide demand response and follow dynamic utility rates. To enable fuel-switching, HPWHs are being developed that only need a standard 120V outlet. Split HPWHs can alleviate the cooling and noise that limit the use of HPWHs in small homes, multifamily buildings, and cold climates. Additionally, new utility programs aim to train installers and provide incentives to distributors to increase the number of HPWHs installed. Some utilities offer novel incentive programs that have led to increased customer uptake. Those advances, coupled with improved controls for load shifting and new products such as split HPWHs and HPWHs that can run on 120V power, may finally move the market forward.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Systematic over-estimation of lattice thermal conductivity in materials with electrically-resistive grain boundaries

Reducing the thermal conductivity κ of a material via nano-structuring to create small grain sizes is one of the most common strategies to improve thermoelectric materials. In such polycrystalline materials heat carrying phonons are scattered at the grain boundaries, which directly improves the thermoelectric quality factor and ultimately the figure-of-merit zT. In some cases, however, such as in Mg 3 Sb 2 , SnSe, and Mg 2 Si an opposite trend is found where higher lattice thermal conductivity reported in small grain polycrystalline material than in large grain or single crystal materials. This unphysical result indicates a problem with the conventional use of the Wiedemann–Franz law. Here, we trace this problematic finding to the electrical resistance at the grain boundaries, which leads to an overestimation of the phonon or lattice contribution of the thermal conductivity κ L . In materials with significant grain boundary electrical resistance, the estimated electronic contribution to the thermal conductivity LσT is low because the measured electrical conductivity σ is low. However within the grain electrons may still be transporting more heat than the total conductivity suggests, leading to an overestimation of κ L if the conventional κ L = κ – LσT is used with the measured values of κ and σ. Here, the overestimation of κL in small-grain samples is shown to be pervasive across a broad range of thermoelectric materials, including Mg 3 Sb 2 , Mg 2 Si, PbTe, PbSe, SnSe, (Hf,Zr)CoSb, CoSb 3 , and Bi 2 Te 3 alloys, and a correction is necessary to properly understand and predict their charge and heat transport.

36 MATERIALS SCIENCE↗