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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

A reanalysis of rocket measurements of the ultraviolet dayglow

Rocket measurements of O I 989, 1304, 1356 A and N2 Lyman-Birge-Hopfield band emission in the midlatitude dayglow reported by Gentieu et al. (1979) and Eastes et al. (1985) are reexamined. MSIS-83 atomic oxygen densities, the 1304 and 1356 A excitation cross sections of Zipf and Erdman (1985), and SMM solar 1304 A irradiance measurements are consistent with the observed O I and N2 emission intensities. Atmosphere Explorer E (AE-E) measurements of the solar EUV irradiance near solar maximum are consistent with the 1980 rocket airglow data, but the solar EUV irradiance required to explain the 1978 airglow data is a factor of 1.5 larger than indicated by AE-E. Enhancement of the 1304 A excitation cross section due to radiative entrapment of cascade-feeding photons is much less than the factor of two predicted by the cascade model of Julienne and Davis (1976).

Link, R.↗

The evaluation of a metered mixer for RTV silicone for RSRM nozzle backfill operations

Metered mixing specifically for the RSRM backfill operation was investigated. Projected advantages were the elimination of waste RTV silicone produced in the operation and the elimination of entrapped air during the mix. Although metered mixing proved to be a viable method for mixing the Dow Corning DC 90-0006 rubber with its catalyst, applying the technology to the RSRM backfill operation has several disadvantages that are decisive. Use of a metered mixer would increase the amount of material that was being scraped for each backfill and increase the amount of time required to clean up the equipment after each operation. Therefore, use of metered static mixers is not recommended for use in the RSRM nozzle backfill operations. Because metered mixers proved to have significant disadvantages other methods of mixing and dispensing the RTV during the backfill operation are being investigated, and will be reported in a separate document.

Wardell, T. C.↗

P-T condition fo deformation from fluid inclusions in mylonites

Structural petrology of fluid inclusions in deformed rocks can be used to identify inclusions entrapped during various stages of deformation. Standard thermobarometry on these inclusions can then provide estimates of the P-T (pressure-temperature) conditions of deformation. The application of this technique is illustrated using fluid inclusions in mylonites from the Quetico Fault Zone, Canada. The inferred P-T conditions fall with the P-T field of mylonitisation derived from isotopic, microstructural and phase equilibrium studies.

Mclellan, Eileen↗

Hazard avoidance for a Mars rover

The challenging geology of the surface of Mars, when coupled with the impossibility of continuous remote driving from earth, dictate the need for autonomous hazard detection, recognition and possibly hazard avoidance capabilities onboard any robotic Mars roving vehicle. The main technical issues represented by terrain hazards are accidental damage and vehicle entrapment. Several approaches to vehicle design geared to prevent such immobilization threats are identified. The gamut of alternatives for rover autonomy are also presented, and the applicability of the various options for the Mars Rover/Sample Return mission are assessed in the context of the technology state of the art for hazard sensors and processing algorithms.

Spiessbach, Andrew J.↗

Vacuum Powder Injector

Method developed to provide uniform impregnation of bundles of carbon-fiber tow with low-solubility, high-melt-flow polymer powder materials to produce composite prepregs. Vacuum powder injector expands bundle of fiber tow, applies polymer to it, then compresses bundle to hold powder. System provides for control of amount of polymer on bundle. Crystallinity of polymer maintained by controlled melt on takeup system. All powder entrapped, and most collected for reuse. Process provides inexpensive and efficient method for making composite materials. Allows for coating of any bundle of fine fibers with powders. Shows high potential for making prepregs of improved materials and for preparation of high-temperature, high-modulus, reinforced thermoplastics.

Working, Dennis C.↗

Alloy Has High Fatigue Strength In Hydrogen

Experimental nickel-base alloy exhibits exceptional low-cycle-fatigue strength in hydrogen. Alloy one of many intended to be produced by strategy of formulating compositions having potential for exceptional low-cycle-fatigue strength in air, casting these alloys into single crystals, and processing them in such ways that their microstructures contain minimal numbers of both sites favoring initiation of fatigue and sites having high surface energies for entrapment of, and infiltration by, hydrogen.

Cetel, Alan D.↗

The Interstellar Gas Experiment (IGE)

The Interstellar Gas Experiment (IGE) exposed thin metallic foils in order to collect neutral particles from the interstellar gas. These particles were entrapped in the foils along with precipitating magnetospheric and ambient atmospheric particles. Seven of these foils collected particles arriving from seven different directions as seen from the spacecraft for the entire duration of the Long Duration Exposure Facility (LDEF) mission. The authors' mass spectroscopy analysis of the noble gas component of these interstellar particles detected isotopes of helium and neon. These preliminary measurements suggest that the various isotopes are occurring in approximately the expected amounts and that their distribution in direction of arrival is close to what models predict. The analysis to subtract the background fluxes of magnetospheric and atmospheric particles is still in progress. The hope of this experiment is to investigate the noble gas isotopic ratios of this interstellar sample of matter which originated outside the solar system.

Lind, Don↗

Electrodeposited Zinc-Nickel as an Alternative to Cadmium Plating for Aerospace Application

Corrosion evaluation studies were conducted on 4130 alloy steel samples coated with electrodeposited zinc-nickel and samples coated with electrodeposited cadmium. The zinc nickel was deposited by the selection electrochemical metallizing process. These coated samples were exposed to a 5-percent salt fog environment at 35 plus or minus 2 C for a period ranging from 96 to 240 hours. An evaluation of the effect of dichromate coatings on the performance of each plating was conducted. The protection afforded by platings with a dichromate seal was compared to platings without the seal. During the later stages of testing, deposit adhesion and the potential for hydrogen entrapment were also evaluated.

Mcmillan, V. C.↗

Radiation from Gas-Jet Diffusion Flames in Microgravity Environments

This paper presents the first demonstration of quantitative flame-radiation measurement in microgravity environments, with the objective of studying the influences and characteristics of radiative transfer on the behavior of gas-jet diffusion flames with possible application to spacecraft fire detection. Laminar diffusion flames of propane, burning in quiescent air at atmospheric pressure, are studied in the 5.18-Second Zero-Gravity Facility of NASA Lewis Research Center. Radiation from these flames is measured using a wide-view angle, thermopile-detector radiometer, and comparisons are made with normal-gravity flames. The results show that the radiation level is significantly higher in microgravity compared to normal-gravity environments due to larger flame size, enhanced soot formation, and entrapment of combustion products in the vicinity of the flame. These effects are the consequences of the removal of buoyancy which makes diffusion the dominant mechanism of transport. The results show that longer test times may be needed to reach steady state in microgravity environments.

Bahadori, M. Yousef↗

Oxygen isotope fractionation in stratospheric CO2

A new cryogenic collection system has been flown on board a balloon gondola to obtain separate samples of ozone and carbon dioxide without entrapping major atmospheric gases. Precision laboratory isotopic analysis of CO2 samples collected between 26 and 35.5 km show a mass-independent enrichment in both O-17 and O-18 of about 11 per mil above tropospheric values. Ozone enrichment in its heavy isotopes was 9 to 16 percent in O3-50 and 8 to 11 percent in O3-49, respectively (Schueler et al., 1990). A mechanism to explain the isotope enrichment in CO2 has been recently proposed by Yung et al. (1991). The model is based on the isotope exchange between CO2 and O3 via O(1D), resulting in a transfer of the ozone isotope enrichment to carbon dioxide. Predicted enrichment and measured values agree well.

Thiemens, M. H.↗

Oxygen desorption from YBa2Cu3O(7-x) and Bi2CaSr2Cu2O(8 + delta) superconductors

Oxygen desorption experiments from YBa2Cu3O(7-x) (YBCO) and Bi2CaSr2Cu2O(8 + delta) (BSCCO) superconductors were carried out using a quadrupole mass spectrometer for monitoring the desorbing species and X-ray photoemission spectroscopy for surface characterization. Molecular oxygen was found to desorb from both superconductors following photoirradiation with ultraviolet/optical radiation and subsequent heating at over 150 C. Both YBCO and BSCCO were found to have similar oxygen desorption rates and similar activation energies. The desorption data as well as the X-ray photoemission data indicate that the oxygen desorption is not intrinsic to the superconductors but rather due to molecular oxygen entrapped in the material.

Mesarwi, A.↗

Volatiles in interplanetary dust particles and aerogels

Volatiles measured in 25 interplanetary dust particles (IDPs) are a mixture of both indigenous materials and contaminants associated with the collection and processing of the ODPs prior to analysis. Most IDPs have been collected in the stratosphere using a silicone oil/freon mixture (20:1 ratio) coated on collector plates. Studies have shown that silicone oil, freon and hexane residues remain with the ODPs, despite attempts to clean the IDPs. Analysis of the IDPs with the LMMS-technique produces spectra with a mixture of indigeneous and contaminants components. The contamination signal can be identified and removed; however, the contamination signal may obscure some of the indigeneous component's signal. Employing spectra stripping techniques, the indigenous volatile constituents associated with the IDPs can be identified. Volatiles are similar to those measured in CI or CM carbonaceous chondrites. Collection of IDPs in low-Earth orbit utilizing a Cosmic Dust Collection Facility attached to Space Station Freedom has been proposed. The low-density material aerogel has been proposed as a collection substrate for IDPs. Our studies have concentrated on identifying volatile contaminants that are associated with aerogel. We have found that solvents used for the preparation of aerogel remain in aerogel and methods must be developed for removing the entrapped solvents before aerogels can be used for an IDP collection substrate.

Gibson, E. K., Jr.↗

High temperature static strain gage development

Final results are presented from a program to develop a thin film static strain gage for use on the blades and vanes of running, test stand gas turbine engines with goals of an 3 x 3 mm gage area and total errors of less than 10 pct. of + or - 2,000 microstrain after 50 hrs at 1250 K. Pd containing 13 Wt. pct. Cr was previously identified as a new strain sensor alloy that appeared to be potentially usable to 1250 K. Subsequently, it was discovered, in contrast with its behavior in bulk, that Pd-13Cr suffered from oxidation attack when prepared as a 4.5 micron thick thin film. Continuing problems with electrical leakage to the substrate and the inability of sputtered alumina overcoats to prevent oxidation led to the discovery that sputtered alumina contains appreciable amounts of entrapped argon. After the argon has been exsolved by heating to elevated temperatures, the alumina films undergo a linear shrinkage of about 2 pct. resulting in formation of cracks. These problems can be largely overcome by sputtering the alumina with the substrate heated to 870 K. With 2 micron thick hot sputtered alumina insulation and overcoat films, total 50 hr drifts of about 100 microstrain (2 tests) and about 500 microstrain (1 test) were observed at 1000 and 1100 K, respectively. Results of tests on complete strain gage systems on constant moment bend bars with Pd temperature compensation grids revealed that oxidation of the Pd grid was a major problem even when the grid was overcoated with a hot or cold sputtered alumina overcoat.

Hulse, C. O.↗

The interstellar gas experiment

The Interstellar Gas Experiment (IGE) exposed thin metallic foils to collect neutral interstellar gas particles. These particles penetrate the solar system due to their motion relative to the sun. Thus, it is possible to entrap them in the collecting foils along with precipitating magnetospheric and perhaps some ambient atmospheric particles. For the entire duration of the Long Duration Exposure Facility (LDEF) mission, seven of these foils collected particles arriving from seven different directions as seen from the spacecraft. In the mass spectroscopic analysis of the noble gas component of these particles, we have detected the isotopes of He-3, He-4, Ne-20, and Ne-22. In the foil analyses carried out so far, we find a distribution of particle arrival directions which shows that a significant part of the trapped particles are indeed interstellar atoms. The analysis needed to subtract the competing fluxes of magnetospheric and atmospheric particles is still in progress.

Lind, D. L.↗

The interstellar gas experiment: Analysis in progress

The interstellar gas experiment (IGE) exposed thin metallic foils in order to collect neutral interstellar particles which penetrate the solar system due to their motion relative to the sun. These atoms were entrapped in the collecting foils along with precipitating magnetospheric ions and with ambient atmospheric atoms. For the entire duration of the LDEF mission, seven of the foils collected particles arriving from seven different directions as seen from the spacecraft. In the mass spectrometric analysis of the trapped noble gas component, we detected the He-3, He-4, Ne-20, and Ne-22 isotopes. In order to infer the isotopic ratios in the interstellar medium from the measured concentrations found in the foil piece, several lines of investigation had to be initiated. The flux of incident noble gas atoms from the ambient atmosphere was estimated by detailed calculations. The contributions proved to be negligible, supporting the experimental evidence. Foil and machine backgrounds for the four isotopes which were measured had to be assessed individually. While this was easy for He-4, spurious foil background of He-3 had to be monitored carefully by analyzing unflown foil pieces. Trapped Ne concentrations are not far above the background. During the flight, a stuck electrical relay precluded the foil-trays from sequencing as designed. Therefore, we could not use the seasonal variation of the direction of the incoming interstellar atoms to make the distinction between interstellar and magnetospheric components of the trapped particles. Instead, we had to try the method of stepwise heating to extract the interstellar component at lower temperatures than we use to extract the magnetospheric component (the interstellars hit the foil with lower energies than most of the magnetospherics). New limiting values for the isotopic composition of the interstellar medium, unavailable yet from any other method of measurement, are emerging from this analysis.

Buehler, F.↗

Mars surface weathering products and spectral analogs: Palagonites and synthetic iron minerals

There are several hypotheses regarding the formation of Martian surface fines. These surface fines are thought to be products of weathering processes occurring on Mars. Four major weathering environments of igneous rocks on Mars have been proposed; (1) impact induced hydrothermal alterations; (2) subpermafrost igneous intrusion; (3) solid-gas surface reactions; and (4) subaerial igneous intrusion over permafrost. Although one or more of these processes may be important on the Martian surface, one factor in common for all these processes is the reaction of solid or molten basalt with water (solid, liquid, or gas). These proposed processes, with the exception of solid-gas surface reactions, are transient processes. The most likely product of transient hydrothermal processes are layer silicates, zeolites, hydrous iron oxides and palagonites. The long-term instability of hydrous clay minerals under present Martian conditions has been predicted; however, the persistence of such minerals due to slow kinetics of dehydration, or entrapment in permafrost, where the activity of water is high, can not be excluded. Anhydrous oxides of iron (e.g., hematite and maghemite) are thought to be stable under present Martian surface conditions. Oxidative weathering of sulfide minerals associated with Martian basalts has been proposed. Weathering of sulfide minerals leads to a potentially acidic permafrost and the formation of Fe(3) oxides and sulfates. Weathering of basalts under acidic conditions may lead to the formation of kaolinite through metastable halloysite and metahalloysite. Kaolinite, if present, is thought to be a thermodynamically stable phase at the Martian surface. Fine materials on Mars are important in that they influence the surface spectral properties; these fines are globally distributed on Mars by the dust storms and this fraction will have the highest surface area which should act as a sink for most of the absorbed volatiles near the surface of Mars. Therefore, the objectives of this study were to: (1) examine the fine fraction mineralogy of several palagonitic materials from Hawaii; and (2) compare spectral properties of palagonites and submicron sized synthetic iron oxides with the spectral properties of the Martian surface.

Golden, D. C.↗

Cyclic oxidation resistance of a reaction milled NiAl-AlN composite

Based upon recent mechanical property tests a NiAl-AlN composite produced by cryomilling has very attractive high temperature strength. This paper focuses on the oxidation resistance of the NiAl-AlN composite at 1473 and 1573 K as compared to that of Ni-47Al-0.15Zr, one of the most oxidation resistant intermetallics. The results of cyclic oxidation tests show that the NiAl-AlN composite has excellent properties although not quite as good as those of Ni-47Al-0.15Zr. The onset of failure of the NiAl-AlN was unique in that it was not accompanied by a change in scale composition from alumina to less protective oxides. Failure in the composite appears to be related to the entrapment of AlN particles within the alumina scale.

Lowell, Carl E.↗

Feasibility of using neutron radiography to inspect the Space Shuttle solid rocket booster aft skirt, forward skirt and frustum. Part 1: Summary report

The space shuttle's solid rocket boosters (SRB) include components made primarily of aluminum that are parachuted back for retrieval from the ocean and refurbished for repeated usage. Nondestructive inspection methods used on these aging parts to reduce the risk of unforeseen problems include x-ray, ultrasonics, and eddy current. Neutron radiography tests on segments of an SRB component show that entrapped moisture and naturally occurring aluminum corrosion can be revealed by neutron radiography even if present in only small amounts. Voids in sealant can also be evaluated. Three alternatives are suggested to follow-up this study: (1) take an SRB component to an existing neutron radiography system; (2) take an existing mobile neutron radiography system to the NASA site; or (3) plan a dedicated system custom designed for NASA applications.

Barton, J. P.↗