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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS2022

Permutations of the Exploration Extra-vehicular Mobility Unit (xEMU) for Mission Specific Objectives

The Advanced Portable Life Support System began first with NASA investment during the Constellation Program focused on new technologies that were central to the new architecture but with a consideration for development of the most flexible and adaptable design to address the varied future needs for Extra-Vehicular Activity (EVA) capability by the agency as part of the exploration of the moon and beyond. Since that time, the Portable Life Support System (PLSS) architecture has been demonstrated at bread-board level, packaged prototype level with Human In-The Loop (HITL) testing, and has now matured into what has become known as the Exploration Extravehicular Mobility Unit (xEMU) PLSS focused on a demonstration on the International Space Station (ISS) and support for initial lunar missions. The xEMU completed Preliminary Design Review (PDR) and the associated Safety Review Panel (SRP) Phase I reviews in 2019-2020 and is progressing through the Design Verification Test (DVT) phase in 2021. As the agency updates planning for lunar both near term, long term, and beyond, there are many possible permutations of the existing architecture that can be accommodated to enable varied mission objectives. This paper will discuss the current baseline DVT design for xEMU as well as potential permutations of the PLSS architecture to accomplish an Apollo style short-duration down and out mission, a long term lunar ultra-lightweight approach, as well as a potential SuitPort accommodating architecture.

Colin Campbell↗
NASA NTRSDate not supplied

The Impact of Atmospheric Dynamics and Anthropogenic Very Short-Lived Chlorine Species on the Recovery of Extra-Polar Ozone

The successful implementation of the Montreal Protocol has led to a decrease in the atmospheric abundance of ozone-depleting substances and a slowing in the destruction of the ozone layer. Previous studies have suggested that atmospheric dynamics, or a rise in compounds not regulated by the Montreal Protocol, such as very short-lived chlorine species (VSL Cl), may lead to a slower than expected recovery of the ozone layer. In this presentation, we examine the expected recovery of total column ozone (TCO) and stratospheric column ozone (SCO) to values observed in 1980 using a novel multiple linear regression (MLR) model that involves a month-by-month regression. The MLR model is trained to TCO anomalies from six data records (SBUV v8.7 MOD, SBUV v8.6 COH, WOUDC, GSG, GTO-ECV, MSR-2) over 1979 to 2021 for the Northern Hemisphere (35N – 60N), the Southern Hemisphere (60S – 35S) and the Tropics (20S – 20N), and SCO anomalies from ML-TOMCAT for these same zonal bands. The MLR includes the effect of halogens (equivalent effective stratospheric chlorine (EESC)), total solar irradiance, stratospheric aerosol optical depth, quasi-biennial oscillation, and the El Niño Southern Oscillation as regressors. We also include the effect of atmospheric dynamics such as the Brewer-Dobson Circulation, Arctic Oscillation, and the Antarctic Oscillation, and VSL Cl species in the formulation of EESC. We use a novel approach to the MLR framework, by separating the observed and regressor time series into the respective months (separating all of the Januarys, Februarys, etc.). Then we conduct a regression for each month from 1979 to 2021 for the three zonal bands denoted above. The model results for each month are combined together to achieve a full monthly time series from 1979 to 2021. We use this novel approach to ascertain the effect of atmospheric dynamics on TCO and SCO, since the dynamical proxies affect ozone in a distinctly different manner for various months. In this presentation, we will quantify the role of both the inclusion of VSL Cl species in the formulation of EESC as well as atmospheric dynamics in explaining the slower than expected recovery of extra-polar TCO and SCO over the past decade.

Laura A. McBride↗
DOE OSTI2022

Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra–Framework Anions in Pore–Space–Partitioned Metal–Organic Frameworks

A multi-stage core-expansion method is proposed here as one component of the integrative binding-site/extender/core-expansion (BEC) strategy. The conceptual deconstruction of the partitioning ligand into three editable parts draws our focus onto progressive core expansion and allows the optimization of both acetylene uptake and selectivity. Herein the effectiveness of this strategy is shown through a family of eight cationic pore-partitioned materials containing three different partitioning ligands and various counter anions. The optimized structure, Co 3 -cpt-tph-Cl (Hcpt=4-(p-carboxyphenyl)-1,2,4-triazole, H-tph=(2,5,8-tri-(4-pyridyl)-1,3,4,6,7,9-hexaazaphenalene) with the largest surface area and highest C 2 H 2 uptake capacity (200 cm 3 /g at 298 K), also exhibits (desirably) the lowest CO 2 uptake and hence the highest C 2 H 2 /CO 2 selectivity. The successful boost in both C 2 H 2 capacity and IAST selectivity allows Co 3 -cpt-tph-Cl to rank among the best crystalline porous materials, ionic MOFs in particular, for C 2 H 2 uptake and C 2 H 2 /CO 2 experimental breakthrough separation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Self-Stabilized LiNi 0.8 Mn 0.1 Co 0.1 O 2 in thiophosphate-based all-solid-state batteries through extra LiOH

Nickle-rich LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NMC 811) cathode material exhibits engaging properties in high energy density and low cost, making it great potential for the next generation high-energy all-solid-state lithium batteries (ASSLBs). However, NMC 811 suffers from severe surface electrochemical, chemical, and voltage incompatibility towards solid-state electrolytes (SSE), especially thiophosphate-based electrolytes like Li 6 PS 5 Cl. Although diverse coating methods have been made to overcome this issue, they are typically cumbersome and expensive. A coating strategy that satisfied all the requirements of cost-efficiency, stability, uniformity, scalability, and easy-achieving is still challenging. Here, we developed a LiOH-based surface stabilization strategy that provides a ~10 nm stable permeable layer on NMC 811. After one-step sintering of NMC 811 precursor mixed with LiOH, which is commonly used for NMC 811 lithiation process, excessive LiOH simultaneously distributes on NMC 811 particles. Unlike other reported methods, this coating method can be easily controlled and fabricated without additional complicated processes. By simply controlling the thickness of LiOH layer, which protects the Li 6 PS 5 Cl solid electrolyte materials from being oxidized, optimized cycling stability can be obtained for 600 cycles with capacity of 130 mAh g – 1 on average at a wide electrochemical window of 2.50–4.20 V (vs. Li-In).

25 ENERGY STORAGE↗
DOE OSTI2020

Sulfurized Polyacrylonitrile for High-Performance Lithium–Sulfur Batteries: In-Depth Computational Approach Revealing Multiple Sulfur’s Reduction Pathways and Hidden Li + Storage Mechanisms for Extra Discharge Capacity

Like no other sulfur host material, polyacrylonitrile-derived sulfurized carbon (SPAN) promises improved electrochemical performance for lithium–sulfur batteries, based on its compatibility with carbonate solvents and ability to prevent self-discharge and shuttle effect. However, a complete understanding of the SPAN’s lithiation mechanism is still missing because its structural features vary widely with synthesis conditions, and its electrochemical performance deviates from elemental sulfur. This study continues our research on the elucidation of the SPAN’s structural characteristics and lithiation mechanisms via computational approaches. Here, our models reproduce most experimental data regarding carbon’s graphitization level and conjugated ordering, sulfur–carbon covalent bonding, sulfur loading, and elemental composition. Our simulations emulate the discharge voltage observed in experiments for the first discharge, which reveals that sulfur follows multiple reduction pathways based on its interaction with the carbon backbone. Sulfur reduction takes place above 1.0 V vs Li/Li + mostly in the SPAN-like material, with no long-chain lithium polysulfide formation. Below 1.0 V vs Li/Li + , the backbone’s electrochemical activity occurs via multiple C–Li and N–Li interactions, mostly with edge carbon atoms and pyridinic nitrogen. Moreover, we identify Li + binding sites throughout the graphitized backbone that might lead to prohibited energy costs for Li + deintercalation, which may explain the irreversible capacity loss between the first and second discharges. This work improves understanding of lithiation mechanisms in sulfurized carbon, which is useful for rationally designing SPAN synthesis pathways tailored to increase sulfur loading and enhanced electrochemical performance.

25 ENERGY STORAGE↗
DOE OSTI2024

Separate the Role of Southern and Northern Extra‐Tropical Pacific in Tropical Pacific Climate Variability

Abstract Observational and modeling studies have elucidated the influential role played by the southern and northern extratropical Pacific (SEP and NEP) forcing in shaping dynamics of tropical Pacific climate variability. However, the relative importance of the NEP and SEP and the timescale on which they impact the tropics remain unclear. Using a linear inverse model (LIM) that selectively incorporates or excludes tropical‐extratropical coupling, we find a reduction in tropical interannual variability (∼40%) and low‐frequency (sub‐decadal to decadal) variability in the southeastern tropical Pacific region (∼70%) in the absence of SEP. Conversely, the absence of NEP yields no significant impact on tropical interannual variability but markedly diminishes low‐frequency variability in the central tropical Pacific region (∼70%). LIM and statistic diagnostics on CMIP6 models show the low‐frequency to total variability ratio in the tropical Pacific depending on their NEP and SEP representation. Models with more (less) low‐frequency power tend to show stronger NEP (SEP) dynamics.

Geology↗
DOE OSTI2022

New Apparatus for Neutron Capture Measurements on Extra Small Radioactive Samples: The DICER Instrument at LANSCE

We report the neutron capture cross section, the probability per unit area a neutron is absorbed by a nucleus followed by the emission of gamma ray(s), is an important quantity in several fields such as astrophysics, nuclear criticality safety, radiochemical diagnostics, nuclear medicine, nuclear forensics and nuclear security. Accurate knowledge of how neutrons interact with matter is a crucial component to understand physical processes in depth. A great example is the understanding of how our universe was created, a quest that requires accurate modeling in which neutron capture cross sections are a key ingredient

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Gravitational waves from breaking of an extra U (1) in SO (10) grand unification

Abstract In a class of gauged $U(1)$ extended Standard Models (SMs), the breaking of the $U(1)$ symmetry is not only a source for Majorana masses of right-handed (RH) neutrinos crucial for the seesaw mechanism, but also a source of stochastic gravitational wave (GW) background. Such $U(1)$ extended models are well-motivated from the viewpoint of grand unification. In this paper, we discuss a successful ultraviolet completion of a $U(1)$ extended SM by an $SO(10)$ grand unified model through an intermediate step of $SU(5) \times U(1)$ unification. With a parameter set that is compatible with the $SO(10)$ grand unification, we find that a first-order phase transition associated with the $U(1)$ symmetry breaking can be strong enough to generate GWs with a detectable size of amplitude. We also find that the resultant GW amplitude reduces and its peak frequency becomes higher as the RH neutrino masses increase.

Physics↗
DOE OSTI2024

Equivalence of EFTs and timelike extra dimensions

A flat 3-brane probing a five-dimensional anti–de Sitter space has the same symmetries and symmetry breaking pattern as one probing a five-dimensional de Sitter space with two time directions. Despite the seemingly different physical setups, we show that the effective field theory of the brane bending mode is identical in both cases. In particular, despite “wrong” signs in the Dirac-Born-Infeld (DBI) action for the two-time de Sitter case, the theories have the same S -matrix. This is consistent with the expectation that effective field theories are determined solely by their degrees of freedom and pattern of symmetry breaking, even in the case of spacetime symmetries. We comment further on the equivalence between the Weyl/dilaton and DBI representations of the EFT of broken conformal symmetry. Published by the American Physical Society 2024

Astronomy & Astrophysics↗