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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Scale Analysis of Moist Thermodynamics in a Simple Model and the Relationship Between Moisture Modes and Gravity Waves

Observations and theory of convectively-coupled equatorial waves suggest that they can be categorized into two distinct groups. Moisture modes are waves whose thermodynamics are governed by moisture fluctuations. The thermodynamics of the gravity wave group, on the other hand, are rooted in buoyancy (temperature) fluctuations. On the basis of scale analysis it is found that a simple nondimensional parameter –akin to the Rossby number– can explain the processes that lead to the existence of these two groups. This parameter, defined as Nmode, indicates that moisture modes arise when anomalous convection lasts sufficiently long so that dry gravity waves eliminate the temperature anomalies in the convective region, satisfying weak temperature gradient (WTG) balance. This process causes moisture anomalies to dominate the distribution of moist enthalpy (or moist static energy), and hence the evolution of the wave. Conversely, convectively-coupled gravity waves arise when anomalous convection eliminates the moisture anomalies more rapidly than dry gravity waves can adjust the troposphere towards WTG balance, causing temperature to govern the moist enthalpy distribution and evolution. Spectral analysis of reanalysis data indicates that slowly-propagating waves (cp ~ 3 m s-1) are likely to be moisture modes while fast waves (cp ~ 30 m s-1) exhibit gravity wave behavior, with "mixed moisture-gravity" waves existing in between. While these findings are obtained from a highly idealized framework, it is hypothesized that they can be extended to understand simulations of convectively-coupled waves in GCMs and the thermodynamics of more complex phenomena.

Angel F Adames↗

Fast modular reactor nuclear design parameters of fuel cycle and power distributions

This paper describes conceptual design of a 112 MW thermal (50 MW electric) Fast Modular Reactor (FMR) system operating at 7 MPa with inlet/outlet temperatures of 509/800 Celsius degrees. The reactor system includes the reactor core, fuel assemblies, fuel rods, reactor internals, reflector, neutron control system, flow control, and structural components. The nuclear design and analysis were conducted to search for a baseline core with a cycle length greater than 8-year and the power peaking factor less than 1.5 by adjusting the fuel assembly, reactor core, and reflector configurations. The neutron transport calculations of the baseline core showed that a refueling interval of 9-year is achieved with a total peaking factor of 1.47 and a fuel rod average linear power of 3.6 kW/m. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

On recursive least-squares filtering algorithms and implementations

In many real-time signal processing applications, fast and numerically stable algorithms for solving least-squares problems are necessary and important. In particular, under non-stationary conditions, these algorithms must be able to adapt themselves to reflect the changes in the system and take appropriate adjustments to achieve optimum performances. Among existing algorithms, the QR-decomposition (QRD)-based recursive least-squares (RLS) methods have been shown to be useful and effective for adaptive signal processing. In order to increase the speed of processing and achieve high throughput rate, many algorithms are being vectorized and/or pipelined to facilitate high degrees of parallelism. A time-recursive formulation of RLS filtering employing block QRD will be considered first. Several methods, including a new non-continuous windowing scheme based on selectively rejecting contaminated data, were investigated for adaptive processing. Based on systolic triarrays, many other forms of systolic arrays are shown to be capable of implementing different algorithms. Various updating and downdating systolic algorithms and architectures for RLS filtering are examined and compared in details, which include Householder reflector, Gram-Schmidt procedure, and Givens rotation. A unified approach encompassing existing square-root-free algorithms is also proposed. For the sinusoidal spectrum estimation problem, a judicious method of separating the noise from the signal is of great interest. Various truncated QR methods are proposed for this purpose and compared to the truncated SVD method. Computer simulations provided for detailed comparisons show the effectiveness of these methods. This thesis deals with fundamental issues of numerical stability, computational efficiency, adaptivity, and VLSI implementation for the RLS filtering problems. In all, various new and modified algorithms and architectures are proposed and analyzed; the significance of any of the new method depends crucially on specific application.

Hsieh, Shih-Fu↗

Optical Sensors for Monitoring Gamma and Neutron Radiation

For safety and efficiency, nuclear reactors must be carefully monitored to provide feedback that enables the fission rate to be held at a constant target level via adjustments in the position of neutron-absorbing rods and moderating coolant flow rates. For automated reactor control, the monitoring system should provide calibrated analog or digital output. The sensors must survive and produce reliable output with minimal drift for at least one to two years, for replacement only during refueling. Small sensor size is preferred to enable more sensors to be placed in the core for more detailed characterization of the local fission rate and fuel consumption, since local deviations from the norm tend to amplify themselves. Currently, reactors are monitored by local power range meters (LPRMs) based on the neutron flux or gamma thermometers based on the gamma flux. LPRMs tend to be bulky, while gamma thermometers are subject to unwanted drift. Both electronic reactor sensors are plagued by electrical noise induced by ionizing radiation near the reactor core. A fiber optic sensor system was developed that is capable of tracking thermal neutron fluence and gamma flux in order to monitor nuclear reactor fission rates. The system provides near-real-time feedback from small- profile probes that are not sensitive to electromagnetic noise. The key novel feature is the practical design of fiber optic radiation sensors. The use of an actinoid element to monitor neutron flux in fiber optic EFPI (extrinsic Fabry-Perot interferometric) sensors is a new use of material. The materials and structure used in the sensor construction can be adjusted to result in a sensor that is sensitive to just thermal, gamma, or neutron stimulus, or any combination of the three. The tested design showed low sensitivity to thermal and gamma stimuli and high sensitivity to neutrons, with a fast response time.

Boyd, Clark D.↗

High Flux Isotope Reactor Neutron Spectrum Shape Estimation From Activation Experiment Data

Here, this article provides a comprehensive review of historical irradiation dosimetry available for different locations within the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL). This article includes a summary of the available measured activation target data covering a span of over 15 years and 39 experimental campaigns, including 200 individual sample locations evaluated. Using this broad set of data, we reconstruct historic average neutron spectra shapes for HFIR at various locations, including within the flux trap region, beryllium reflectors, and hydraulic tube (HT) regions, at both the 100- and 85-MW operational power. Our findings indicate that the general axial flux distribution shows a relatively small change in transition from 100- to 85-MW operating power, with differences of -6% to +15% for the thermal energy range and around -16% to +8% for the fast range, indicating a sharper drop-off of the thermal neutron flux away from the axial center. Compared with historical dosimetry estimates of the HFIR flux shape, we generally find a moderately broader axial profile shape for thermal neutrons in the interior target regions for the 100-MW samples evaluated but relatively close agreement for the present 85-MW flux shape for both thermal and fast fluxes.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Genomic insights into redox-driven microbial processes for carbon decomposition in thawing Arctic soils and permafrost

Climate change is rapidly transforming Arctic landscapes where increasing soil temperatures speed up permafrost thaw. This exposes large carbon stocks to microbial decomposition, possibly worsening climate change by releasing more greenhouse gases. Understanding how microbes break down soil carbon, especially under the anaerobic conditions of thawing permafrost, is important to determine future changes. Here, we studied the microbial community dynamics and soil carbon decomposition potential in permafrost and active layer soils under anaerobic laboratory conditions that simulated an Arctic summer thaw. The microbial and viral compositions in the samples were analyzed based on metagenomes, metagenome-assembled genomes, and metagenomic viral contigs (mVCs). Following the thawing of permafrost, there was a notable shift in microbial community structure, with fermentative Firmicutes and Bacteroidota taking over from Actinobacteria and Proteobacteria over the 60-day incubation period. The increase in iron and sulfate-reducing microbes had a significant role in limiting methane production from thawed permafrost, underscoring the competition within microbial communities. We explored the growth strategies of microbial communities and found that slow growth was the major strategy in both the active layer and permafrost. Our findings challenge the assumption that fast-growing microbes mainly respond to environmental changes like permafrost thaw. Instead, they indicate a common strategy of slow growth among microbial communities, likely due to the thermodynamic constraints of soil substrates and electron acceptors, and the need for microbes to adjust to post-thaw conditions. The mVCs harbored a wide range of auxiliary metabolic genes that may support cell protection from ice formation in virus-infected cells.

54 ENVIRONMENTAL SCIENCES↗

On the Goertler vortex instability mechanism at hypersonic speeds

The linear instability of the hypersonic boundary layer on a curved wall is considered. As a starting point real-gas effects are ignored and the viscosity of the fluid is taken to be related to the temperature either by Chapman's Law or by Sutherland's Law. It is shown that the flow is susceptible to Goertler vortices. If Chapman's Law is used the vortices are trapped in the logarithmically thin adjustment layer in which the temperature of the basic flow changes rapidly to its free stream value and the nonuniqueness of the neutral stability curve associated with incompressible Goertler vortices is shown to disappear at high Mach numbers if the appropriate 'fast' streamwise dependence of the instability is built into the disturbance flow structure. If, on the other hand, Sutherland's Law is used, the vortices are found to spread into an O(1) region and the concept of a unique neutral stability curve is not tenable because of the nonparallel effects. For both laws the leading order terms in the expansions of the Goertler number are independent of the wave number and are due to the curvature of the basic state.

Hall, P.↗

Analytical expressions for radiative properties of planar Rayleigh scattering media, including polarization contributions

The objective of this paper is to provide a convenient and fast way for computing the radiative properties of planar Rayleigh scattering media. Analytical expressions are developed for the three molecular atmospheric functions which are required in remote sensing: the atmospheric reflectance, the transmission function, and the spherical albedo. The expressions are adjusted by using accurate computations performed with successive orders of a scattering code. The accuracy of the code is first checked by using previously published tabulations. The required accuracy of 0.001 in the reflectance unit is achieved by numerical adjustments. The contribution of polarization is considered implicitly. The expressions are shown to be valid for a fairly large range of observational conditions.

Vermote, E.↗

Elimination LArTPC Simulation Uncertainty

Liquid Argon Time Projection Chambers (LArTPC) are crucial for measuring muons and neutrinos by capturing the paths of fast-moving particles through argon gas. However, these detectors face challenges such as electron-ion recombination, diffusion, and attenuation, which introduce uncertainties in simulation models. This study, conducted by Ka ren Mkrtchyan at FERMILAB, aims to reduce these uncertainties by adjusting the amplitude and width of signals detected by the TPC wires. Initial findings indicate that the current modification algorithm requires further refinement to better align simulations with observed data. Ongoing work focuses on correcting computational bugs and enhancing the simulation model for improved accuracy and statistical confidence.

Mkrtchyan, Ka'ren↗

Working Principle of an Ionic Liquid Interlayer During Pressureless Lithium Stripping on Li 6.25 Al 0.25 La 3 Zr 2 O 12 (LLZO) Garnet‐Type Solid Electrolyte

Abstract Solid‐state‐batteries employing lithium metal anodes promise high theoretical energy and power densities. However, morphological instability occurring at the lithium/solid–electrolyte interface when stripping and plating lithium during cell cycling needs to be mitigated. Vacancy diffusion in lithium metal is not sufficiently fast to prevent pore formation at the interface above a certain current density during stripping. Applied pressure of several MPa can prevent pore formation, but this is not conducive to practical application. This work investigates the concept of ionic liquids as “self‐adjusting” interlayers to compensate morphological changes of the lithium anode while avoiding the use of external pressure. A clear improvement of the lithium dissolution process is observed as it is possible to continuously strip more than 70 μm lithium (i. e., 15 mAh cm −2 charge) without the need for external pressure during assembly and electrochemical testing of the system. The impedance of the investigated electrodes is analyzed in detail, and contributions of the different interfaces are evaluated. The conclusions are corroborated with morphology studies using cryo‐FIB‐SEM and chemical analysis using XPS. This improves the understanding of the impedance response and lithium stripping in electrodes employing liquid interlayers, acting as a stepping‐stone for future optimization.

Fuchs, Till↗

Species-Selective Detection of Volatile Organic Compounds by Ionic Liquid-Based Electrolyte Using Electrochemical Methods

The detection of volatile organic compounds (VOCs) is an important topic for environmental safety and public health. However, the current commercial VOC detectors suffer from cross-sensitivity and low reproducibility. In this work, we present species-selective detection for VOCs using an electrochemical cell based on ionic liquid (IL) electrolytes with features of high selectivity and reliability. The voltammograms measured with the IL-based electrolyte absorbing different VOCs exhibited species-selective features that were extracted and classified by linear discriminant analysis (LDA). The detection system could identify as many as four types of VOCs, including methanol, ethanol, acetone, formaldehyde, and additional water. A mixture of methanol and formaldehyde was detected as well. The sample required for the VOCs classification system was 50 μL, or 1.164 mmol, on average. The response time for each VOC measurement is as fast as 24 s. The volume of VOCs such as formaldehyde in solution could also be quantified by LDA and electrochemical impedance spectroscopy techniques, respectively. The system showed a tunable detection range for 1.6 and 16% (w/v) CH 2 O solution by adjusting the composition of the electrolyte. The limit of detection was as low as 1 μL. For the 1.6% CH 2 O solution, the linearity calibration range was determined to be from 5.30 to 53.00 μmol with a limit of detection at 0.53 μmol. The mechanisms for VOCs determination and quantification are also thoroughly discussed. Finally, it is expected that this work could provide a new insight into the concept of electrochemical detection of VOCs with machine learning analysis and be applied to both VOCs gas monitoring and fluid detection.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Polymer Inhibitors Enable >900 cm2 Dynamic Windows Based on Reversible Metal Electrodeposition with High Solar Modulation

Dynamic windows with adjustable tint give users control over the flow of light and heat to decrease the carbon footprint of buildings and improve the occupants’ comfort. Despite the benefits of dynamic windows, they are rarely deployed in buildings because the existing technology cannot achieve fast and colour-neutral tinting at an agreeable cost. Reversible metal electrodeposition is a promising approach to solve these problems. Here, we demonstrate the use of polymer inhibitors to reversibly deposit metal films with controlled morphology in dynamic windows. The windows that employ the polymer inhibitor can readily tint to below 0.001% visible transmittance in less than 3 min and exhibit high infrared reflectance (>70%), colour-neutral transmittance (C*<5) and an ultrawide range of optical and solar modulation (..delta..Tvis=0.76 and ..delta..SHGC=0.56). The polymer inhibitors also increase the efficiency and improve the durability of the windows and enable construction of >900 cm2 dynamic windows with fast response and excellent uniformity.

36 MATERIALS SCIENCE↗

Benchmark Specification of Advanced Burner Test Reactor

As an effort to assess the Argonne Reactor Computation (ARC) suite of fast reactor analysis codes, a numerical benchmark problem was developed using the reference 250 MWt Advanced Burner Test Reactor (ABTR) metallic core fueled with beginning of equilibrium cycle compositions (Chang et al., 2006). Material thermal expansion at operating condition was modeled by adjusting the hexagonal pitch, axial meshes, and the fuel and structure material densities appropriately. Irradiation swelling of metal fuel was considered, and the bond sodium was displaced into the lower part of fission gas plenum.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Low-cost, fast-response drive circuit for electromagnetic torque motors

Fast-response coil drive circuit, for electromagnetic torque motors, reduces the inductive coil time constant with a minimum of circuit sophistication. The low-cost modulator servoamplifier is used with a compatible preamplifier stage which provides the servo-loop function of summing, adjustable gain and compensation.

Zeller, J. R.↗

Pumped Storage Hydropower (PSH) FAST Commissioning Prize Technical Analysis

The US energy landscape has undergone major changes over the past 10 years and will continue to see significant changes in future decades as the power grid increases its reliance on variable renewable energy resources. Because of the inherent variability of these resources, renewable energy growth may require additional energy storage capacity to provide flexible load-following capabilities and other grid services that can quickly adjust to changes in energy demand and generation. Pumped storage hydropower (PSH)—one such energy storage technology—uses pumps to convey water from a lower reservoir to an upper reservoir for energy storage and releases water back to the lower reservoir via a powerhouse for hydropower generation. PSH facility pump and generation cycling often follows economic and energy demand conditions. Across the United States, 43 PSH facilities are in operation and 55 projects are in various permitting or licensing stages. Altogether, the 43 operational projects provide the wide majority (95%) of utility-scale electricity storage in the United States. These facilities also provide significant power and nonpower grid benefits, including large-scale electrical system reserve capacity, grid reliability support, and electricity supply-demand balancing through quick-response capabilities and operational flexibility. PSH systems can accomplish these at a scale (e.g., size) and cost that makes these systems highly attractive from a technical standpoint. Although these research concepts are still in their infancy, they demonstrate promising potential as future PSH energy storage technologies. Although PSH has many advantages, development in the United States has effectively stalled since the 1990s, partially because of the magnitude of project costs and financing interest during development and construction, the length of time from project investment until project revenue begins, permitting challenges, construction risks, competition from other storage technologies (e.g., batteries, hydrogen storage), and electricity market evolution and uncertainty. In short, the time, cost, and risk associated with modern PSH development have resulted in limited growth in the United States recently, despite the growing energy storage demand stemming from increased wind and solar power deployment. Technology innovation is needed to help reduce PSH commissioning time, cost, and risk, particularly during the post-licensing phase of project development. To address challenges facing the PSH industry and to improve PSH commissioning timelines, the US Department of Energy (DOE) Water Power Technologies Office (WPTO) initiated the PSH Furthering Advancements to Shorten Time to (FAST) Commissioning Prize project.

13 HYDRO ENERGY↗

Electrical Systems of Pumped Storage Hydropower Plants: Electrical Generation, Machines, Power Electronics, and Power Systems

Adjustable-speed (AS) pumped storage hydropower (PSH) technology has the potential to become a large, consistent contributor to grid stability enabling higher penetrations of wind and solar energy on the future U.S. power system. AS-PSH has high-value characteristics, such as fast response to provide ancillary services to the grid, because it is a power converter interface with the grid (like battery storage), but at the same time it has the energy content large enough to supply both short-term (seconds-to-minutes) and long-term (minutes-to-hours) of energy needs, like more conventional power plants. However, designs must be optimized to lower the capital expenditure (CapEx) and to provide a high-quality grid interface capability (e.g. power quality, ancillary service provider, fault-tolerant or fault ride-through capability), which is a primary factor in the acceptance of AS-PSH into a utility’s generation mix. This CapEx will be greatly affected by the cost savings associated with the civil structure, turbine design, power electronics, control systems, or unique generator designs. A holistic design must be considered to get a full picture of the benefits of the technology proposed. The AS-PSH can be controlled to reduce the impact of transient disturbance on a power system and at the same time can be controlled to minimized subsequent component fatigue and potential oscillation modes within the plant, with the overall impact in reducing the operational expenditures (OpEx).Generating clean power to meet standards such as Institute of Electrical and Electronics Engineers (IEEE) 519 and International Electrotechnical Commission (IEC) 1000-3-2 will be a continuing challenge. For many technology developers, however, improved AS-PSH technologies will become a key component of generator-storage systems of the future given the prospects of increased performance and decreasing costs, and the ever-increasing penetration of renewables (e.g wind power and solar power).

13 HYDRO ENERGY↗

An efficient adaptive patched grid gas dynamic solver for complex flows

The patched mesh CSCM flow solver is used with a fast adaptive grid technique to compute complex two dimensional and axisymmetric, inviscid and viscous flows accurately and efficiently. The patched grid technique allows the user to generate the initial grid around complex regions with minimal effort. The adaptive grid strategy permits the grid points to adjust to the solution in accordance with the flow structure and user specified grid constraints and thus improve the accuracy of the solution. Solutions to challenging flow problems are obtained with adapted grids and the numerical examples and the results presented here show clearly the effectiveness of the adaptive grid solution strategy to obtain highly accurate numerical solutions with minimal human effort and computational resources.

Venkatapathy, E.↗

Using Computer Simulations to Optimize Biofuel Production

The DOE strives to ensure America's security and prosperity by addressing energy challenges. NREL shares this goal and tries to achieve a clean energy world. Fossil fuels are problematic for both organizations. Using them endangers American security. Their supply is finite and burning them causes environmental damage. Biofuels are a good alternative to fossil fuels. They are renewably produced on American soil and can lower greenhouse gas emissions. Also, cars and planes need no costly mechanical adjustments to use biofuels. However, the fuels themselves are expensive. For my SULI project, I reduced the cost of biofuels by optimizing the production process through computer simulations. Existing simulations were accurate but slow. One simulation takes up to eight hours, and researchers must do hundreds. My solution reduces the computing time. I treated the biomass particles in the simulation as one-dimensional. That simplified the simulation equations, making them easier for the computer to solve. Still, biomass particles are three-dimensional. The 1D assumption was wrong and produced inaccurate results. To maintain accuracy while increasing speed, I developed a method to convert 1D simulation results into usable 3D data. I adjusted the 1D simulation until the output matched the 3D results for a specific environment. I found out how much the simulation changed when the environment changed. Machine learning algorithms defined a relationship between 1D and 3D data for all environments. This lets scientists convert fast 1D simulation results into valid 3D data.

1D↗