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At least 109 records · Page 6

Probing and Tuning Spatiotemporal pH Evolution in Aqueous Zinc Ion Batteries

Aqueous zinc-ion batteries (AZIBs) offer a combination of safety and low cost, but they suffer from dynamic pH fluctuations that drive parasitic reactions and capacity fading. In this review, we report the current mechanistic understanding of the dynamic pH evolution across the electrolyte-electrode interface and its role in triggering interphase instability. We summarize advanced strategies to regulate pH, including electrolyte engineering, electrode surface modification, and interphase construction. We further discuss current methods for probing pH dynamics and outline potential future approaches for gaining deeper mechanistic and design insights.

Zheng, Xueli [SLAC]↗

Science Opportunities and Capabilities Enabled by LCLS-II and LCLS-II HE

X-Ray Science with LCLS-II and LCLS-II HE: Chemical dynamics: Reaction dynamics, charge transfer, molecular photocatalysts, natural & artificial photosynthesis; Catalysis: Homogeneous and heterogeneous catalysis, interfacial & geo/environmental chemistry; Materials Physics: Heterogeneity, spontaneous fluctuations, nonequilibrium dynamics, extreme environments; Quantum Materials: Emergent phenomena & collective excitations; Biological Function & Structural Dynamics: Dynamics in physiological environments.

43 PARTICLE ACCELERATORS↗

Title Coherent X-ray Studies of Surface Growth and Patterning Processes

X-ray Photon Correlation Spectroscopy (XPCS) is being developed as a tool to study nanoscale dynamics of fluctuations during thin film growth and surface patterning. XPCS examines the evolution of the X-ray scattering speckle pattern in reciprocal space to reveal dynamics information not accessible through any other means. Unlike low-coherence conventional X-ray scattering, which incoherently averages over different regions of a sample, coherent X-ray scattering is sensitive to the detailed structure of a given sample at that moment in time. In thin film growth processes, heterodyning, which occurs due to coherent mixing of two scattered signals, can be used to investigate the relationship between surface growth velocity and defect propagation. And, for polycrystalline thin film growth, the spatial coherence of the X-ray beam can substitute for the missing spatial coherence of the growth process to track layered growth in detail, even in a growth regime in which there are no conventional growth oscillations of the X-ray intensity. This has opened the door for detailed dynamics studies of individual atomic layers during real-world growth and patterning, not just in perfect single-crystal growth cases, which greatly expands the applicability of in-situ X-ray scattering methods. Step-flow dynamics in mounded polycrystalline growth has been studied separately for two thin film organic semiconductors deposited by thermal deposition in a vacuum environment, C60 and diindenoperylene (DIP). Highly oriented polycrystalline thin films are readily obtained in both systems, where mounds are composed of crystalline monolayer-height steps and terraces in a so-called wedding cake morphology. The formation of mounds is understood to be due to significant Ehrlich-Schwoebel step edge barriers that inhibit molecules from hopping down from one layer to the one below. The mounds exhibit local step flow, which can be monitored using coherent X-ray scattering. This is made possible due to heterodyning between scattering from the average mounds and the moving steps, which becomes visible in XPCS analysis. The effect of desorption, i.e. re-evaporation of deposited molecules is found to be important for understanding these processes. The impact of this work is to enable testing of models of step dynamics, the shape of mounds, and merging of mounds to form continuous thin films. Highly ordered polycrystalline thin films deposited on inexpensive substrates have applications in thin film solar cells and other organic electronic devices. In a separate set of experiments, speckle analysis during self-organized ion beam nanopatterning reveals memory stretching back to the beginning of patterning in the early stages and enables measurement of the velocity of self-organized patterns across surfaces providing the possibility of stringent new tests of the theory of pattern formation and motion.

36 MATERIALS SCIENCE↗

Design Considerations of DC/DC Regulator for High-Power Dynamic Wireless Charging Systems

Due to fast fluctuating input voltage, dynamic wireless charging requires a post-regulator stage for battery charging control and management. This regulator stage has a high requirement on efficiency, size as well as control performance to ensure tight regulation and fast trainset. This paper addresses the control challenges by modeling the system and designing the compensator with input voltage feedforward control. In addition, high resolution PWM is implemented to improve transient performance and current balancing among the phases. Experimental results prove the effectiveness of the proposed schemes and validates 180 kW closed-loop 4-phase operation at 99% efficiency.

Xue, Lincoln↗

Examination of stiff ion temperature gradient mode physics in simulations of DIII-D H-mode transport

A systematic evaluation of gyrokinetic and gyrofluid model predictions of ion temperature gradient (ITG) stability and transport using parameters from DIII-D high confinement mode (H-mode) plasmas has been performed. The nonlinear CGYRO code is used to make the gyrokinetic predictions, and the quasilinear TGLF model for the corresponding gyrofluid predictions. The assessments are made at three radii (normalized toroidal flux ρtor = 0.4, 0.55, and 0.7) in three different plasma scenarios with varying levels of neutral beam heating and torque. For each of the nine cases (3 radii × 3 scenarios) considered, ITG turbulence is found to be the dominant long-wavelength instability and transport mechanism. The inclusions of both transverse magnetic fluctuations and dynamic fast beam ions are stabilizing for all cases considered, with strongest effects seen at ρor = 0.4 where the fast ion population and normalized plasma pressure β = 2μ0nT/B2 are highest. The further inclusion of parallel magnetic fluctuations does not have a meaningful impact on the ITG turbulence in these scenarios, but does destabilize (in combination with fast ions) new high-frequency instabilities at ρtor = 0.4 in the high power scenarios. In each case the linear and nonlinear ITG critical gradients are predicted to be lower than the measured ITG scale lengths and their associated uncertainties. Inclusion of equilibrium flow shear in the transport predictions generally leads to an upshift in effective critical gradient rather than a qualitative change in the predicted stiffness, with stronger responses typically seen in the gyrokinetic predictions than in the gyrofluid results. However, in most cases these upshifted gradients still remain below the measured values and their uncertainties. Although the predicted critical gradients are below the measured gradients, both models predicted flux-matching gradients consistent with measured values in six of the nine cases considered, with no clear systematic over- or underprediction. Thus, while the experimental ion temperature profiles do not appear to be closely pinned to the ITG critical gradient, both gyrokinetic and gyrofluid models are able to accurately match the measured gradients reasonably well in most cases.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Electronic Transport through Self Assembled Thiol Molecules: Effect of Monolayer Order, Dynamics and Temperature

We present the charge transport and tunneling conductance of self assembled organic thiol molecules and discuss the influence of order and dynamics in the monolayer on the transport behavior and the effect of temperature. Conjugated thiol molecular wires and organometals such as terpyridine metal complexes provide a new platform for molecular electronic devices and we study their self assembly on Au(111) substrates by the scanning tunneling microscope. Determining the organization of the molecule and the ability to control the nature of its interface with the substrate is important for reliable performance of the molecular electronic devices. By concurrent scanning tunneling microscopy and spectroscopy studies on SAMs formed from oligo (phenelyne ethynelyne) monolayers with and without molecular order, we show that packing and order determine the response of a self assembled monolayer (SAM) to competing interactions. Molecular resolution STM imaging in vacuum shows that the OPES adopt an imcommensurate SAM structure on Au(111) with a rectangular unit cell. Tunneling spectroscopic measurements were performed on the SAM as a function of junction resistance. STS results show that the I-Vs are non linear and asymmetric due to the inherent asymmetry in the molecular structure, with larger currents at negative sample biases. The asymmetry increases with increasing junction resistance due to the asymmetry in the coupling to the leads. This is brought out clearly in the differential conductance, which also shows a gap at the Fermi level. We also studied the effect of order and dynamics in the monolayer on the charge transport and found that competing forces between the electric field, intermolecular interactions, tip-molecule physisorption and substrate-molecule chemisorption impact the transport measurements and its reliability and that the presence of molecular order is very important for reproducible transport measurements. Thus while developing new electronic platforms based on molecules, it is important to have a good control of the molecule-substrate interface, for the devices to perform reliably. While such a control would minimize fluctuations and dynamics in the ensemble, the real challenge is to develop device architectures that are tolerant to fluctuations, since they cannot be totally eliminated in these low dimensional soft systems. Results of temperature dependent STS measurements will also be discussed.

Dholakia, Geetha↗

Experimental Combustion Dynamics Behavior of a Multi-Element Lean Direct Injection (LDI) Gas Turbine Combustor

An experimental investigation of the combustion dynamic characteristics of a research multi-element lean direct injection (LDI) combustor under simulated gas turbine conditions was conducted. The objective was to gain a better understanding of the physical phenomena inside a pressurized flametube combustion chamber under acoustically isolated conditions. A nine-point swirl venturi lean direct injection (SV-LDI) geometry was evaluated at inlet pressures up to 2,413 kPa and non-vitiated air temperatures up to 867 K. The equivalence ratio was varied to obtain adiabatic flame temperatures between 1388 K and 1905 K. Dynamic pressure measurements were taken upstream of the SV-LDI, in the combustion zone and downstream of the exit nozzle. The measurements showed that combustion dynamics were fairly small when the fuel was distributed uniformly and mostly due to fluid dynamics effects. Dynamic pressure fluctuations larger than 40 kPa at low frequencies were measured at 653 K inlet temperature and 1117 kPa inlet pressure when fuel was shifted and the pilot fuel injector equivalence ratio was increased to 0.72.

dynamics↗

The Induced Magnetic Field of the Moon: Conductivity Profiles and Inferred Temperature

Electromagnetic induction in the moon driven by fluctuations of the interplanetary magnetic field is used to determine the lunar bulk electrical conductivity. The present data clearly show the north-south and east-west transfer function difference as well as high frequency rollover. The difference is shown to be compatible over the mid-frequency range with a noise source associated with the compression of the local remanent field by solar wind dynamic pressure fluctuations. Models for two, three, and four layer; current layer, double current layer, and core plus current layer moons are generated by inversion of the data using a theory which incorporates higher order multipoles. Core radii conductivities generally are in the range 1200 to 1300 km and 0.001 to 0.003 mhos/m; and for the conducting shell 1500 to 1700 km with 0.0001 to 0.0007 mhos/m with an outer layer taken as nonconducting. Core temperature based on available olivine data is 700 to 1000 C.

Sonett, C. P.↗

Dynamic scaling of order parameter fluctuations in model B

Brookhaven National Laboratory has performed a dedicated set of experiments, called the Beam Energy Scan (BES), with the goal of location a possible critical point in the phase diagram of nuclear matter, This point is analogous to the endpoint of the liquid-gas phase transition in water, where the liquid phase corresponds to a phase of hadrons, and the gas phase to a plasma of quarks and gluons. In order to describe the data generated by these experiments we have studied numerical simulations of the stochastic diffusion equation with a conserved charge. Here, we focus on the dynamics in the vicinity of a critical point in the Ising universality class. The model we consider is expected to describe the critical dynamics near a possible QCD critical point if the coupling of the order parameter to the momentum density of the fluid can be neglected. The simulations are performed on a spatial lattice, and the time evolution is performed using a Metropolis algorithm. We determine the dynamical critical exponent z ≃ 3.972(2), which agrees with predictions of the epsilon expansion. We also study non-equilibrium sweeps of the reduced temperature and observe approximate Kibble-Zurek scaling.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

The induced magnetic field of the moon - Conductivity profiles and inferred temperature.

Electromagnetic induction in the moon driven by fluctuations of the interplanetary magnetic field is used to determine the lunar bulk electrical conductivity. The earlier data are now augmented by an order of magnitude. The present data clearly show the north-south and east-west transfer function difference as well as the high-frequency rollover suggested earlier. The difference is shown to be compatible over the midfrequency range (0.001 to 0.01 Hz) with a noise source associated with the compression of the local remanent field by solar wind dynamic pressure fluctuations. The rollover of the transfer functions is shown to result from higher order magnetic multipole radiation; electric multipoles appear supressed, although a vestigial TM interaction may still be present. Models for two, three, and four layer; current layer, double current layer, and core plus current layer moons are generated by inversion of the data, using a theory that incorporates higher-order multipoles.

Sonett, C. P.↗

Layer-Dependent Magnetism and Spin Fluctuations in Atomically Thin van der Waals Magnet CrPS 4

van der Waals (vdW) magnets, an emerging family of two-dimensional (2D) materials, have received tremendous attention due to their rich fundamental physics and significant potential for cutting-edge technological applications. In contrast to the conventional bulk counterparts, vdW magnets exhibit significant tunability of local material properties, such as stacking engineered interlayer coupling and layer-number dependent magnetic and electronic interactions, which promise to deliver previously unavailable merits to develop multifunctional microelectronic devices. As a further ingredient of this emerging topic, here we report nanoscale quantum sensing and imaging of atomically thin vdW magnet chromium thiophosphate CrPS 4 , revealing its characteristic layer-dependent 2D static magnetism and dynamic spin fluctuations. We also show a large tunneling magnetoresistance in CrPS 4 -based spin filter vdW heterostructures. Here, the excellent material stability, robust strategy against environmental degradation, in combination with tailored magnetic properties highlight the potential of CrPS 4 in developing state-of-the-art 2D spintronic devices for next-generation information technologies.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Hybrid Fuel Cell and Battery Storage Power Management for Grid-Interactive EV Charging Station

With the increasing adoption of renewable energy sources in grid-interactive Electric Vehicle (EV) charging stations, the role of energy storage systems has become critical. While large energy storage systems have mitigated the intermittency of renewable energy, integrating multi-source energy management with prioritized charging can further enhance the reliability of charging stations (CS). This paper presents a decentralized energy management (DEM) approach combining battery energy storage (BES) and fuel cell (FC) systems using a rule-based line resistance correction droop (LRCD) control technique. The proposed droop control dynamically adjusts the gain to balance the state-of-charge (SoC) of the BES, enhancing power support longevity and improving battery life under varying capacity conditions by reducing current stress. Additionally, the paper addresses the challenges of using fuel cells in linear regions to optimize efficiency and manage various charging scenarios. The CS integrates unity power factor grid interaction, and power support for auxiliary loads, maintaining harmonic distortion within 5% during grid islanding. The approach evaluates DC bus voltage regulation under various scenarios of PV array power fluctuations and dynamic load variations, in both grid-connected and standalone operations. In conclusion, the proposed control strategy is validated on a laboratory prototype through various dynamic load variation and grid islanding scenarios.

Khalid, Mohd [Oak Ridge National Laboratory (ORNL)↗

Topology control of human fibroblast cells monolayer by liquid crystal elastomer

Eukaryotic cells in living tissues form dynamic patterns with spatially varying orientational order that affects important physiological processes such as apoptosis and cell migration. The challenge is how to impart a predesigned map of orientational order onto a growing tissue. Here, we demonstrate an approach to produce cell monolayers of human dermal fibroblasts with predesigned orientational patterns and topological defects using a photoaligned liquid crystal elastomer (LCE) that swells anisotropically in an aqueous medium. The patterns inscribed into the LCE are replicated by the tissue monolayer and cause a strong spatial variation of cells phenotype, their surface density, and number density fluctuations. Unbinding dynamics of defect pairs intrinsic to active matter is suppressed by anisotropic surface anchoring allowing the estimation of the elastic characteristics of the tissues. The demonstrated patterned LCE approach has potential to control the collective behavior of cells in living tissues, cell differentiation, and tissue morphogenesis.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Findings from the Supersonic Qualification Program of the Mars Science Laboratory Parachute System

In 2012, the Mars Science Laboratory Mission (MSL) will deploy NASA's largest extra-terrestrial parachute, a technology integral to the safe landing of its advanced robotic explorer on the surface. The supersonic parachute system is a mortar deployed 21.5 m disk-gap-band (DGB) parachute, identical in geometric scaling to the Viking era DGB parachutes of the 1970's. The MSL parachute deployment conditions are Mach 2.3 at a dynamic pressure of 750 Pa. The Viking Balloon Launched Decelerator Test (BLDT) successfully demonstrated a maximum of 700 Pa at Mach 2.2 for a 16.1 m DGB parachute in its AV4 flight. All previous Mars deployments have derived their supersonic qualification from the Viking BLDT test series, preventing the need for full scale high altitude supersonic testing. The qualification programs for Mars Pathfinder, Mars Exploration Rover, and Phoenix Scout Missions were all limited to subsonic structural qualification, with supersonic performance and survivability bounded by the BLDT qualification. The MSL parachute, at the edge of the supersonic heritage deployment space and 33% larger than the Viking parachute, accepts a certain degree of risk without addressing the supersonic environment in which it will deploy. In addition, MSL will spend up to 10 seconds above Mach 1.5, an aerodynamic regime that is associated with a known parachute instability characterized by significant canopy projected area fluctuation and dynamic drag variation. This aerodynamic instability, referred to as "area oscillations" by the parachute community has drag performance, inflation stability, and structural implications, introducing risk to mission success if not quantified for the MSL parachute system. To minimize this risk and as an alternative to a prohibitively expensive high altitude test program, a multi-phase qualification program using computation simulation validated by subscale test was developed and implemented for MSL. The first phase consisted of 2% of fullscale supersonic wind tunnel testing of a rigid DGB parachute with entry-vehicle to validate two high fidelity computational fluid dynamics (CFD) tools. The computer codes utilized Large Eddy Simulation and Detached Eddy Simulation numerical approaches to accurately capture the turbulent wake of the entry vehicle and its coupling to the parachute bow-shock. The second phase was the development of fluid structure interaction (FSI) computational tools to predict parachute response to the supersonic flow field. The FSI development included the integration of the CFD from the first phase with a finite element structural model of the parachute membrane and cable elements. In this phase, a 4% of full-scale supersonic flexible parachute test program was conducted to provide validation data to the FSI code and an empirical dataset of the MSL parachute in a flight-like environment. The final phase is FSI simulations of the full-scale MSL parachute in a Mars type deployment. Findings from this program will be presented in terms of code development and validation, empirical findings from the supersonic testing, and drag performance during supersonic operation.

EDL↗

Significance of the Direct Excitation Mechanism for High-Frequency Response of Premixed Flames to Flow Oscillations

Premixed flames are sensitive to flow disturbances, which can arise from acoustic or vortical fluctuations. For transverse instabilities, it is known that a dominant mechanism for flame response is “injector coupling,” whereby pressure oscillations associated with transverse waves excite axial flow disturbances. These axial flow disturbances then excite heat release oscillations. The objective of this paper is to consider another mechanism—the direct sensitivity of the unsteady heat release to transverse acoustic waves—and to compare its significance relative to the induced axial disturbances, in a linear framework. The rate at which the flame adds energy to the disturbance field is quantified using the Rayleigh criterion and evaluated over a range of control parameters, such as flame length and swirl number. The results show that radial modes induce heat release fluctuations that always add energy to the acoustic field, whereas heat release fluctuations induced by mixed radial-azimuthal modes can add or remove energy. These amplification rates are then compared to the flame response from induced axial fluctuations. For combustor-centered flames, these results show that the direct excitation mechanism has negligible amplification rates relative to the induced axial mechanism for radial modes. For transverse modes, the fact that the nozzle is located at a pressure node indicates that negligible induced axial velocity disturbances are excited; as such, the direct mechanism dominates. As a result, for flames that are not centered on pressure nodes, the direct mechanism for mixed modes dominates for certain nozzle locations and flame angles.

42 ENGINEERING↗

A real time dynamic data acquisition and processing system for velocity, density, and total temperature fluctuation measurements

The real time Dynamic Data Acquisition and Processing System (DDAPS) is described which provides the capability for the simultaneous measurement of velocity, density, and total temperature fluctuations. The system of hardware and software is described in context of the wind tunnel environment. The DDAPS replaces both a recording mechanism and a separate data processing system. DDAPS receives input from hot wire anemometers. Amplifiers and filters condition the signals with computer controlled modules. The analog signals are simultaneously digitized and digitally recorded on disk. Automatic acquisition collects necessary calibration and environment data. Hot wire sensitivities are generated and applied to the hot wire data to compute fluctuations. The presentation of the raw and processed data is accomplished on demand. The interface to DDAPS is described along with the internal mechanisms of DDAPS. A summary of operations relevant to the use of the DDAPS is also provided.

Clukey, Steven J.↗

Thermal fluctuations and carrier localization induced by dynamic disorder in MAPbI 3 described by first-principles based tight-binding model

Halide perovskites are strongly influenced by large amplitude anharmonic lattice fluctuations at room temperature. We develop a tight binding model for dynamically disordered MAPbI$_3$ based on density functional theory (DFT) calculations to calculate electronic structure for finite temperature crystal structures at the length scale of thermal disorder and carrier localization. The model predicts individual Hamiltonian matrix elements and band structures with high accuracy, owing to the inclusion of additional matrix elements and descriptors for non-Coulombic interactions. We apply this model to electronic structure at length and time scales inaccessible to first principles methods, finding an increase in band gap, carrier mass, and the sub-picosecond fluctuations in these quantities with increasing temperature as well as the onset of carrier localization in large supercells induced by thermal disorder at 300 K. Finally, we identify the length scale $L^*= 5$ nm as the onset of localization in the electronic structure, associated with associated with decreasing band edge fluctuations, increasing carrier mass, and Rashba splitting approaching zero.

36 MATERIALS SCIENCE↗

Plant myo -inositol transport influences bacterial colonization phenotypes

Plant microbiomes are assembled and modified through a complex milieu of biotic and abiotic factors. Despite dynamic and fluctuating contributing variables, specific host metabolites are consistently identified as important mediators of microbial interactions. We combine information from a large-scale metatranscriptomic dataset from natural poplar trees and experimental genetic manipulation assays in seedlings of the model plant Arabidopsis thaliana to converge on a conserved role for transport of the plant metabolite myo-inositol in mediating host-microbe interactions. While microbial catabolism of this compound has been linked to increased host colonization, we identify bacterial phenotypes that occur in both catabolism-dependent and -independent manners, suggesting that myo-inositol may additionally serve as a eukaryotic-derived signaling molecule to modulate microbial activities. Our data suggest host control of this compound and resulting microbial behavior are important mechanisms at play surrounding the host metabolite myo-inositol.

59 BASIC BIOLOGICAL SCIENCES↗