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All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

ATD-2 Benefits Mechanism

NASA has been developing and demonstrating a suite of decision support capabilities for integrated arrival, departure, and surface (IADS) operations in a metroplex environment. The effort is being made in three phases, under NASA’s Airspace Technology Demonstration 2 (ATD-2) sub-project, through a close partnership with the Federal Aviation Administration (FAA), air carriers, airport, and general aviation community. The Phase 1 Baseline IADS capabilities provide enhanced operational efficiency and predictability of flight operations through data exchange and integration, tactical surface metering, and automated coordination of release time of controlled flights for overhead stream insertion. The Phase 2 Fused IADS capabilities include the fusion of strategic and tactical surface metering, Atlanta Center airspace tactical scheduling, Electronic Flight Data (EFD) integration, Terminal Flight Data Manager (TFDM) Terminal Publication (TTP) prototype, and Mobile App for General Aviation (GA) community. In the Phase 2 field evaluation, strategic surface metering provides advance notice of metering and additional stability to the assigned gate holds. The users of the IADS system in Phases 1 and 2 include the personnel at Charlotte Douglas International Airport (CLT) air traffic control tower, American Airlines ramp tower, CLT terminal radar approach control (TRACON), and Washington and Atlanta Center. This document describes the ATD-2 benefits mechanism used to assess the Phases 1 and 2 IADS capabilities and field evaluation conducted at CLT since September 2017. The ATD-2 benefits mechanism mainly consists of surface metering and overhead stream insertion. This document provides detailed calculation methods of major benefit metrics, such as fuel savings, gas emissions savings, and engine runtime reduction, which can be obtained through surface metering, gate hold of Approval Request (APREQ) flights prior to pushback, and the renegotiation of release time while taxiing. As of April 30, 2020, it is estimated that 5,097,173 pounds of fuel savings and 15,699,292 pounds of CO2 emission reduction have been achieved so far, with a reduction of 3,831 hours in total engine runtime. The amount of CO2 savings is estimated to be equivalent to planting 116,739 urban trees. The pre- and post-metering comparison results using FAA’s Aviation System Performance Metrics (ASPM) data have also shown that the surface metering had no negative impact on the on-time arrival performance of both outbound and inbound flights at CLT.

ATD-2↗
DOE OSTI2022

South Texas Industrial Assessment Center (Final Report)

The South Texas Industrial Assessment Center (ST-IAC) provides small to mid-size manufacturing companies and water treatment plants in the Rio Grande Valley of Texas, free energy assessments to help them reduce costs and stay competitive for sustainable development. The ST-IAC operates within the University of Texas Rio Grande Valley (UTRGV), and is the largest Hispanic-serving IAC in the U.S. Created in 2016, the ST-IAC, situated in the most economically disadvantaged region in the country, has been successful in training students and assessing local industries served by a predominantly Hispanic population. UTRGV, now the second largest Hispanic Serving Institution (HSI) of higher education in the U.S., has a student population of 32,000, of which 90% is Hispanic. While Covid-19 had a negative impact to our program during Budget Periods (BP) 4 and 5, the center still managed to provide opportunities for individuals, manufacturing and water industries in the local region. The program developed an energy engineering program in the region and further advanced national priorities. Those include resilience and sustainability of operations by implementing energy efficiency processes, renewable energy sources, decarbonization, battery storage, and cybersecurity in south Texas.

14 SOLAR ENERGY↗
DOE OSTI2026

Hourly natural gas usage surrounding NIST NEB and NWB GHG monitoring stations in 2023

This dataset includes hourly natural gas usage surrounding two National Institute of Standards and Technology (NIST) greenhouse gas (GHG) monitoring stations, Northwest Baltimore (NWB; 39.3445°N, 76.6851°W) and Northeast Baltimore (NEB; 39.3154°N, 76.5830°W), for the year 2023 in units of therms. The gas usage was provided by the local gas distribution company and includes hourly data averaged across groups of 15 or more addresses to maintain anonymity. The hourly data was averaged spatially within a radius of 1 km from each monitoring station, including all groups containing data from any address within 1km of the monitoring station. This dataset only includes gas usage from service points equipped with advanced metering infrastructure (AMI). Between the two monitoring sites, this dataset includes usage from a total of 3649 service points, which we estimate is at least 44% of the service points in the domain.

Kenion, Helen C. R. [School of Environment and Sus↗
NASA NTRS1985

Magnetic monopole search by 130 m(2)sr He gas proportional counter

A search experiment for cosmic ray magnetic monopoles was performed by means of atomic induction mechanism by using He mixture gas proportional counters of the calorimeter (130 square meters sr) at the center of the Akeno air shower array. In 3,482 hours operation no monopole candidate was observed. The upper limit of the monopole flux is 1.44 x 10 to the minus 13th power cm-z, sec -1, sr-1 (90% C.L.) for the velocity faster than 7 x 0.0001 c.

Hara, T.↗
NASA NTRS1986

Multifrequency dial sensing of the atmospheric gaseous constituents using the first and second harmonics of a tunable CO2 laser radiation

The results of field measurements of concentration of some gaseous components of the atmosphere along the paths, in Sofia, Bulgaria, using a gas analyzer based on the use of a CO2 laser radiation frequency-doubled with ZnGeP2 monocrystals are presented. The gas analyzer is a traditional long path absorption meter. Radiation from the tunable CO2 laser of low pressure and from an additional He-Ne laser is directed to a colliminating hundredfold Gregori telescope with a 300 mm diameter of the principal mirror. The dimensions of the mirrors of a retroreflector 500 x 500 mm and a receiving telescope allow one to totally intercept the beam passed through the atmospheric layer under study and back.

Zuev, V. E.↗
NASA NTRS1971

Application of Derivative Spectrometry to the Analysis of Trace Gases

A derivative spectrometer is sensitive to changes in spectral intensity over narrow wavelength internal. Specifically, a second derivative spectrometer senses the curvature of the incident spectral intensity, providing an output voltage signal proportional to the second derivative of intensity with respect to wavelength. When such an instrument is combined with multi-pass White cell, a unique trace gas analyzer results. The analyzer, operating within the middle ultraviolet spectral region, provides a highly amplified derivative spectrum of any molecular narrow band absorption which is used for trace gas identification. The intensity of any peak within a spectrum is proportional to the trace gas concentration. Such an analyzer, utilizing a 20 meter pathlength White cell, is presently being used to automatically monitor ambient air for SO2, NO, NO2, and O3 with minimum detectable concentration limits in the part per billion range.

Hager, Robert N.↗
NASA NTRS1996

The 1996 Subsonic Aircraft: Contrail and Cloud Effects Special Study

During April 1996 NASA, in conjunction with the DOE, will sponsor a multi-aircraft field campaign to better understand the microphysical and radiative properties of cirrus clouds, the origins of ice nuclei and cloud condensation nuclei in the upper troposphere, and the possible role that the commercial subsonic aircraft fleet might play in altering cloud or aerosol properties. The NASA ER-2 aircraft will be used as a remote sensing platform, while the NASA DC-8 aircraft will be used as an in situ measurement platform. In situ observations will include a full set of size distribution measurements from nano-meter to millimeter sizes, ice water content measurements, gas phase and condensed phase chemical measurements, ice crystal optical phase function measurements, lidar observations of cloud top and cloud base, and atmospheric state measurement. The ER-2 will have lidar, microwave ice water path measurements, as well as visible and infrared spectral measurement. In this presentation the highlights of the mission will be presented. The goal will be to address fundamental questions such as the mode of nucleation of cirrus clouds, the composition of the nuclei on which cirrus form, the degree to which aircraft impact cirrus cloud properties.

Toon, Owen B.↗
DOE OSTI2022

Realistic operation of two residential cordwood-fired outdoor hydronic heater appliances—Part 3: Optical properties of black and brown carbon emissions

Residential biomass combustion is a source of carbonaceous aerosol. Inefficient combustion, particularly of solid fuels produces large quantities of black and brown carbon (BC and BrC). These particle types are important as they have noted effects on climate forcing and human health. One method of measuring these quantities is by measurement of aerosol light-absorption and scattering, which can be performed using an aethalometer and nephelometer, respectively. These instruments are widely deployed in the study of ambient air and are frequently used in air quality modeling and source apportionment studies. In this study, we will describe (1) a method for measuring primary BC and BrC emissions from two residential log-fired wood hydronic heaters and (2) the BC and BrC emission from these devices over a wide range of operating conditions, such as cold-starts, warm-starts, four different levels of output ranging from 15% to 100% maximum rated output, and periods of repeated cycling. The range in flue-gas BC concentrations, measured using an aethalometer at the 880 nanometer (nm) wavelength, were between 5.09 × 10 2 and 2.24 × 10 4 micrograms per cubic meter (µg/m 3 ) while the scattering coefficient of the flue-gas, measured by a nephelometer at 880 nm, ranged between 2.20 × 10 3 and 8.56 × 10 5 inverse megameters (Mm –1 ). The BrC concentrations, measured using the 370 nm wavelength of an aethalometer, were between 9.10 × 10 1 and 3.56 × 10 4 µg/m 3 . The calculated Angstrom Absorption Exponent (AAE) of the flue-gas aerosol ranged between 1.54 and 3.63. Performing a comparison between the measured BC concentration and an external particulate matter (PM) concentration showed that overall BC makes up roughly a quarter of the PM emitted by either of the two appliances. Further for both appliances, the cold-start and the test phase immediately following it had the highest BC and BrC concentrations, the highest measured scattering coefficient, as well as a low AAE.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1994

Raman-shifting an ArF excimer laser to generate new lines for obtaining optical diagnostic based information in flow fields

The application of tunable excimer lasers in combustion and flow diagnostics is almost routine nowadays. The properties of this laser system that enable density and temperature measurements in supersonic and hypersonic flow fields to be conducted are its high power, high repetition rate, and high spectral brightness. The limitation imposed by this system on these measurements is the paucity of lines in the wavelength region, the vacuum-ultraviolet, where species of interest, such as OH, N2, O2, H2, H2O, CO, NO, etc., are susceptible to electronic excitation to high-lying states. To circumvent this problem one normally resorts to nonlinear optical techniques such as frequency conversion via stimulated Raman scattering (SRS), more commonly known as Raman shifting or Raman mixing, to extend these nonintrusive and nonperturbing techniques to the shorter wavelengths in the VUV region and, for that matter, to longer wavelengths in the infrared region, if the need arises. The theoretical basis of SRS and its application are well documented in the literature. In essence, the Raman shift is a consequence of the inelastic scattering of the incident radiation by the sample. Most of the scattered radiation from the molecules of the sample is unchanged in frequency. However, a small fraction of the incident radiation is changed in frequency. This shift is a result of the fact that some of the incident photons on colliding with the molecules of the sample give up some of their energy and emerge with a lower energy resulting in the lower-frequency Stokes radiation. Other incident photons may increase their energy by colliding with the vibrationally excited molecules of the medium and emerge as higher-frequency antistokes radiation. The generation of the latter is the main objective of this project. The process, however, depends on several factors, including the beam quality of the pump laser, the cross-section of the gaseous medium, the gas pressure, and the ambient temperature of the gas near the focal region. Furthermore, since the Raman shifting process is polarization sensitive, it is necessary to have all of the laser energy in a single polarization. These factors were taken into consideration in the execution of the project. The implementation of the Raman shift was accomplished by focusing the 193 nm output of an ArF excimer laser (Lamda-Physik LPX 150) into a 1-meter long high pressure recirculating Raman cell filled with H2 gas. The laser system was modified in order to improve the mode quality of the pump beam to enhance the Raman shifting. To accomplish this feat, a prism beam expander and grating on the oscillator discharge provided wavelength tuning over the excimer gain profile. Furthermore, a triple-pass configuration, as opposed to unstable resonator optics, was employed in the operation of the amplifier cavity so that when the oscillator output radiation, focused by a 51-cm focal length fused silica lens through a 50 micron pinhole (serving as a spatial filter) and recollimated with a 25-cm focal length lens, was fed into the amplifier, it was injection locked, thereby providing tunable radiation with relatively low divergence. The forward scattered radiation emanating from the impingement of the modified pump beam on the Raman cell was detected using an energy meter after the latter had been separated from it using a dispersing prism.

Koker, Edmond B.↗
NASA NTRS2008

Gas in Protoplanetary Disks

Gas makes up the bulk of the mass in a protoplanetary disk, but it is much more difficult to observe than the smaller dust component. The lifetime of gas in a disk has far-reaching consequences, including limiting the time available for giant planet formation and controlling the migration of planetary bodies of all sizes, from Jupiters to meter-sized planetesimals. Here I will discuss what is known about the gas component of protoplanetary disks, highlighting recent results from infrared studies with the Spitzer Space Telescope. Exciting upcoming opportunities for gas studies will also be discussed. In particular, the first large far-IR survey of gas tracers from young disks will be performed using the Herschel Space Observatory, as part of the 'Gas in Protoplanetary Systems' (GASPS) Open Time Key Project.

Roberge, Aki↗
DOE OSTI2020

Life Cycle Analysis of Greenhouse Gas Emissions for the Niagaran Reef Complex CO 2 -EOR Operations

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. A greenhouse gas emissions life cycle analysis (LCA) was completed for 22 years of carbon dioxide-enhanced oil recovery (CO 2 -EOR) operations at the Niagaran reef complex in the northern Michigan Basin based on research by the MRCSP. The objective of the greenhouse gas LCA was to account for the total greenhouse gas emissions generated through the CO 2 -EOR process. Methane produced from the 300 to 500 meter-deep Antrim shale has CO 2 content ranging from 5 percent to 30 percent. Therefore, the produced gas stream is gathered outside of Gaylord, Michigan, at the Chester 10 central gas processing plant, and run through an amine-based CO 2 separation process to remove the CO 2 so the methane can be sold to the market. The CO 2 is periodically dehydrated, compressed, and transported via pipeline for CO 2 -EOR in nearby 5,000- to 6,500-foot (1500-2000 m) deep carbonate Niagaran reefs. The produced mixture of oil, water, and CO 2 is separated at the Dover 36 oil processing facility. The processed CO 2 is recycled to the reefs for CO 2 -EOR in a closed loop system. During this process, a portion of the CO2 remains permanently stored in the reefs.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1986

Investigation of porous polymer gas chromatographic packings for atmospheric analysis of extraterrestrial bodies

Measurement of the permanent gases in the atmospheres of mission targets is a major objective. A 16 meter long Porapak N column was used on the Venus probe and required a rather high carrier gas flow rate. The researchers have, therefore, surveyed commercial porous polymer types which had some ability to resolve nitrogen, oxygen, argon and carbon monoxide gases. Porapaks N and Q appeared superior to most. Batch to batch variation, however, was quite wide, so the researchers learned how to synthesize porous polymer and investigated some of the factors affecting the separations. A polymer was synthesized which was superior to all commercial products and allowed at least a 50% reduction in length and flow rate of carrier gas. Similar studies were made concerning the separation of hydrocarbons and new porous polymers have been synthesized which represent significant improvements in time of analysis, column, and carrier gas flow rate.

Pollock, G. E.↗
NASA NTRS1974

Pressurant requirements for discharge of liquid methane from a 1.52-meter-(5-ft-) diameter spherical tank under both static and slosh conditions

Pressurized expulsion tests were conducted to determine the effect of various physical parameters on the pressurant gas (methane, helium, hydrogen, and nitrogen) requirements during the expulsion of liquid methane from a 1.52-meter-(5-ft-) diameter spherical tank and to compare results with those predicted by an analytical program. Also studied were the effects on methane, helium, and hydrogen pressurant requirements of various slosh excitation frequencies and amplitudes, both with and without slosh suppressing baffles in the tank. The experimental results when using gaseous methane, helium, and hydrogen show that the predictions of the analytical program agreed well with the actual pressurant requirements for static tank expulsions. The analytical program could not be used for gaseous nitrogen expulsions because of the large quantities of nitrogen which can dissolve in liquid methane. Under slosh conditions, a pronounced increase in gaseous methane requirements was observed relative to results obtained for the static tank expulsions. Slight decreases in the helium and hydrogen requirements were noted under similar test conditions.

Dewitt, R. L.↗
NASA NTRS1983

Aggregation of grains in a turbulent pre-solar disk

The growth and evolution of grains in the protostellar nebula are investigated within the context of turbulent low-mass disk models developed by previous investigators. Because of grain collisions promoted by the turbulent velocities, particles aggregate to millimeter size in times of the order of 1000 yrs. During the growth the particles acquire a large inward radial velocity due to gas drag (Weidenschilling, 1977) and spiral into the sun. The calculations indicate that the final size of the particles does not exceed a few centimeters. This result is not very sensitive to the specific nebula parameters. For all conditions investigated it seems impossible to grow meter- or kilometer-sized bodies that could decouple from the gas motion. An additional argument is given that shows that only particles smaller than centimeter size can survive drift into the growing sun by being transported radially outward by turbulent mixing. This agrees well with the maximum size of inclusions and chondrules. Since sedimentation of grains and subsequent dust disk instability is effectively inhibited by turbulent stirring, the formation of planetesimals and planets cannot be explained in the above scenario without further assumptions.

Wieneke, B.↗
NASA NTRS2008

Gas in Protoplanetary Disks

Gas makes up the bulk of the mass in a protoplanetary disk, but it is much more difficult to observe than the smaller dust component. The l ifetime of gas in a disk has far-reaching consequences. including lim iting the time available for giant planet formation and controlling t he migration of planetary bodies of all sizes, from Jupiters to meter-sized planetesimals. Here I will discuss what is known about the gas component of protoplanetary disks, highlighting recent results from i nfrared studies with the Spitzer Space Telescope. Exciting upcoming o pportunities for gas studies will also be discussed. In particular, the first large far-IR survey of gas tracers from young disks will be p erformed using the Herschel Space Observatory, as part of the "Gas in Protoplanetary Systems" (GASPS) Open Time Key Project.

Roberge, Aki↗
DOE OSTI2024

Roles of kaolinite-oil-gas molecular interactions in hydrogen storage within depleted reservoirs

Hydrogen is a clean alternative to fossil fuels, emitting only water vapor during combustion. In a future hydrogen economy, large-scale storage will be an important component of the supply chain. Due to its low volumetric density, conventional surface storage methods are inadequate. Underground hydrogen storage (UHS) offers a viable solution, enabling the storage of millions of cubic meters. Among potential geological sites, including salt caverns, aquifers, and depleted gas reservoirs, depleted oil reservoirs show promise. Studying hydrogen interactions with residual oil and reservoir minerals is vital for understanding the properties of hydrogen and the reservoir post-injection. In this work, we employed molecular dynamics simulations to gain molecular-level insights into these interactions. We investigated hydrogen dissolution in oil, adsorption at kaolinite/oil interfaces, the role of CO 2 as a cushion gas, and the influence of kaolinite’s hydrophobicity on H 2 behavior. The main findings include: (1) hydrogen dissolves more in oil than in water, (2) the introduction of CO 2 suppresses hydrogen dissolution in oil and reduces the interfacial tension (IFT) between oil and gas, (3) CO 2 decreases H 2 partitioning near kaolinite surfaces due to its strong affinity for the hydrophilic gibbsite surface of kaolinite, and (4) CO 2 is more effective than H 2 in reducing IFT between kaolinite and the oil–gas mixture. These findings emphasize the effectiveness of CO 2 as a cushion gas and the important role of clay hydrophobicity in UHS, providing insights that are challenging to obtain experimentally.

08 HYDROGEN↗
DOE OSTI2024

Geophysical Imaging of Flow and Transport (GIFT): FY24 Status Report

The GIFT (Geophysical Imaging of Flow and Transport) system will improve predictive capabilities as a platform for collecting multi-physical (MP) time-lapse datasets from well-controlled laboratory experiments. This will enable more accurate prediction of multi-phase fluid flow during delivery and transport of insitu remedial amendments as important components of the overall Hanford Site cleanup mission. Design and construction of the GIFT system, which consists of a meter-scale test cell and a network of custom gas circulation and analysis systems, was accomplished in fiscal year (FY) 2024, with plans to add liquid circulation to the system and use this new capability for multi-phase deep vadose experiments starting in FY25.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1987

The azimuthal and radial distributions of HI and H2 in NGC 6946

A study was completed of the atomic and molecular components of the ISM in NGC 6946. The distribution of molecular clouds was determined from a fully sampled CO map of the inner disk using the 14-meter telescope of the FCRAO. The distribution of atomic gas was derived from VLA observations at 40" resolution in the D configuration. When comparing the global CO and HI properties with other components of the galaxy, it was found that the azimuthally averaged radial distributions of CO, H-alpha, radio continuum and blue light all exhibit similar roughly exponential falloffs, while the azimuthally averaged HI surface densities vary by only a factor of 2 out to R = 16 kpc. This indicates that while the H-alpha/CO ratio is approximately constant with radius, the CO/HI ratio decreases by a factor of 30 from the center of the galaxy to R = 10 kpc.

Tacconi-Garman, Linda J.↗