Search NASA⌕ Search

SEARCH · Search NASA

Results for “gradient structure”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Finite element flow-thermal-structural analysis of aerodynamically heated leading edges

Hypersonic vehicles operate in a hostile aerothermal environment which has a significant impact on their aerothermostructural performance. Significant coupling occurs between the aerodynamic flow field, structural heat transfer, and structural response creating a multidisciplinary interaction. A long term goal of the Aerothermal Loads Branch at the NASA Langley Research Center is to develop a computational capability for integrated fluid, thermal and structural analysis of aerodynamically heated structures. The integrated analysis capability includes the coupling between the fluid and the structure which occurs primarily through the thermal response of the structure, because: (1) the surface temperature affects the external flow by changing the amount of energy absorbed by the structure, and (2) the temperature gradients in the structure result in structural deformations which alter the flow field and attendant surface pressures and heating rates. In the integrated analysis, a finite element method is used to solve: (1) the Navier-Stokes equations for the flow solution, (2) the energy equation of the structure for the temperature response, and (3) the equilibrium equations of the structure for the structural deformation and stresses.

Dechaumphai, Pramote↗
DOE OSTI2025

Analytical and numerical studies of dark current in radiofrequency structures for short-pulse high-gradient acceleration

High-gradient acceleration is a key research area that could enable compact linear accelerators for future colliders, light sources, and other applications. In the pursuit of high-gradient operation, rf breakdown limits the attainable accelerating gradient in normal-conducting rf structures. Recent experiments at the Argonne Wakefield Accelerator suggest a promising approach: using short rf pulses with durations of a few nanoseconds. Experimental studies show that these 𝒪⁡(1⁢ ⁢ns) rf pulses can mitigate breakdown limitations, resulting in higher gradients. For example, an electric field of nearly 400 MV/m was achieved in an 𝑋-band photoemission gun driven by 6-ns-long rf pulses, with rapid rf conditioning and low dark current observed. Despite these promising results, the short-pulse regime remains an underexplored parameter space, and rf breakdown physics under nanosecond-long pulses requires further investigation. In this paper, we present analytical and numerical simulations of dark current dynamics in accelerating cavities operating in the short-pulse regime. We study breakdown-associated processes spanning different time scales, including field emission, multipacting, and plasma formation, using simulations of the 𝑋-band photogun cavities. The results reveal the advantages of using short rf pulses to reduce dark current and mitigate rf breakdown, offering a path toward a new class of compact accelerators with enhanced performance and reduced susceptibility to breakdown.

Linear accelerators↗
NASA NTRS2001

Oxytropism: a new twist in pollen tube orientation

Chemical gradients and structural features within the pistil have been previously proposed as factors determining the directionality of pollen tube growth. In this study, we examine the behavior of pollen of eight species germinated in a dynamic oxygen gradient. While the germination rates of some species decreased directly with decreasing oxygen tension, other species showed no decrease in germination at oxygen tensions as low as 2 kPa. In one species, germination was consistently greater at decreased oxygen tensions than at ambient atmospheric levels. In three of the eight species tested, the developing pollen tube showed clear directional growth away from the more-oxygenated regions of the growth medium, while in one species growth was towards the more-oxygenated region. The remaining four species showed random tube growth. The pattern of oxytropic responses among the taxa suggests that this tropic behavior is both widespread and phylogenetically unpredictable.

NASA Discipline Plant Biology↗
DOE OSTI2022

High gradient off-axis coupled C-band Cu and CuAg accelerating structures

Here, we report the high gradient testing results of two single-cell off-axis coupled standing wave accelerating structures. Two brazed standing wave off-axis coupled structures with the same geometry were tested: one made of pure copper (Cu) and one made of a copper–silver (CuAg) alloy with a silver concentration of 0.08%. A peak surface electric field of 450 MV/m was achieved in the CuAg structure for a klystron input power of 14.5 MW and a 1 μs pulse length, which was 25% higher than the peak surface electric field achieved in the Cu structure. The superb high gradient performance was achieved because of the two major optimizations in the cavity's geometry: (1) the shunt impedance of the cavity was maximized for a peak surface electric field to accelerating gradient ratio of ~2 for a fully relativistic particle, and (2) the peak magnetic field enhancement due to the input coupler was minimized to limit pulse heating. These tests allow us to conclude that C-band accelerating structures can operate at peak fields similar to those at higher frequencies while providing a larger beam iris for improved beam transport.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Experimental studies of a high-gradient X-band welded hard-copper split accelerating structure

We report on recent research on high-gradient radio frequency (RF) accelerating structures indicates that the use of hard copper alloys provides improvement in high gradient performance over annealed copper. Such structures are made by bonding individually manufactured parts. However, there are no well-established bonding techniques that preserve the hardness, surface finish and cleanliness required for high gradient operation. To preserve the copper hardness, RadiaBeam has developed a novel high-gradient split accelerating structure, based on electron beam welding joining technique. This technique provides efficient bonding with strong, clean welds and minimal thermal loading, while maintaining a clean inner RF environment. Our RF design and fabrication methodology limits the small heat affected zone to the outer cavity envelop, with virtually no distortions or thermal loading of critical RF surfaces. It also incorporates provisions to precisely control the gap despite conventional issues with weld joint shrinkage. To date we have manufactured and validated an RF accelerating structure joined by electron-beam welding that incorporates a novel open split design to significantly reduce the assembly complexity and cost. In this paper, we will present the electromagnetic design of this structure, discuss bonding, and present the results of high-power tests, where the accelerating gradients of 140 MV m -1 with surface peak fields of 400 MV m -1 were achieved for flat-top pulse length of 600 ns with an RF breakdown rate of 10 -4 1/(pulsecm).

43 PARTICLE ACCELERATORS↗
NASA NTRS1972

Study of a columnar grain structure produced in a superalloy by gradient-annealing prealloyed powder extrusions

Annealing in a temperature gradient was used to produce a structure of continuous columnar grains in alloy 713 C made by extrusion of prealloyed powder. The columnar-grained specimens had tensile strengths within plus or minus 5 percent of those of the as-cast alloy at 760 C and 980 C but were significantly stronger at room temperature. Stress-rupture tests at 760 C and 980 C showed lives scattered from 17 to 376 percent of those of as-cast 713 C tested under the same conditions. X-ray diffraction studies showed the large grains formed upon annealing to have a well-defined texture, although the as-extruded material had none.

Miner, R. V., Jr.↗
NASA NTRS2018

Morphology and Kinematics of Filaments in the Serpens and Perseus Molecular Clouds

We present H(exp 13)CO(exp +) (J= 1-0) and HNC (J= 1-0) maps of regions in Serpens South, Serpens Main, and NGC 1333 containing filaments. We also observe the Serpens regions using H(exp 13)CN (J= 1-0). These dense gas tracer molecular line observations carried out with CARMA have an angular resolution of approximately 7", a spectral resolution of approximately 0.16 km s (exp -1), and a sensitivity of 50-100 mJy beam (exp -1). Although the large-scale structure compares well with the Herschel dust continuum maps, we resolve finer structure within the filaments identified by Herschel. The H(exp 13)CO(exp +) emission distribution agrees with the existing CARMA diazenylium(exp +) (J= 1-0) maps, so they trace the same morphology and kinematics of the filaments. The H(exp 13)CO(exp +) maps additionally reveal that many regions have multiple structures partially overlapping in the line of sight. In two regions, the velocity differences are as high as 1.4 km s(exp -1). We identify eight filamentary structures having typical widths of 0.03 - 0.08 pc in these tracers. At least 50% of the filamentary structures have distinct velocity gradients perpendicular to their major axis, with average values in the range of 4-10 km s(exp -1) pc (exp -1). These findings are in support of the theoretical models of filament formation by 2D inflow in the shock layer created by colliding turbulent cells. We also find evidence of velocity gradients along the length of two filamentary structures; the gradients suggest that these filaments are inflowing toward the cloud core.

Dhabal, Arnab↗
DOE OSTI2021

A diagrammatic approach for automatically deriving analytical gradients of tensor hyper-contracted electronic structure methods

In this work, we introduce a diagrammatic approach to facilitate the automatic derivation of analytical nuclear gradients for tensor hyper-contraction (THC) based electronic structure methods. The automatically derived gradients are guaranteed to have the same scaling in terms of both operation count and memory footprint as the underlying energy calculations, and the computation of a gradient is roughly three times as costly as the underlying energy. The new diagrammatic approach enables the first cubic scaling implementation of nuclear derivatives for THC tensors fitted in molecular orbital basis (MO-THC). Furthermore, application of this new approach to THC-MP2 analytical gradients leads to an implementation, which is at least four times faster than the previously reported, manually derived implementation. Finally, we apply the new approach to the 14 tensor contraction patterns appearing in the supporting subspace formulation of multireference perturbation theory, laying the foundation for developments of analytical nuclear gradients and nonadiabatic coupling vectors for multi-state CASPT2.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Environmental effects on the dynamics and control of an orbiting large flexible antenna system

Solar radiation pressure on the vibrating antenna structure, temperature gradients induced by solar heating, and stabilizing gravity-gradient torques were considered when the linear regulator theory was used to obtain orientation and shape control of a hoop/column antenna system being considered for the land mobile satellite system. A finite element model of the antenna system which includes all six rigid modes and seven flexible modes was used. Results show that the environmental disturbances affect only the rigid modes of the structure. The effect of solar radiation pressure interacting with the vibrating system is smaller than the solar radiation pressure acting on the thermally deformed structure. To reduce control effort in order to maintain shape and orientation, thermal deformations must be minimized in the preliminary design of the system.

Krishna, R.↗
NASA NTRS1984

Environmental effects on the dynamics and control of an orbiting large flexible antenna system

Solar radiation pressure on the vibrating antenna structure, temperature gradients induced by solar heating, and stabilizing gravity-gradient torques were considered when the linear regulator theory was used to obtain orientation and shape control of a hoop/column antenna system being considered for the land mobile satellite system. A finite element model of the antenna system which includes all six rigid modes and seven flexible modes was used. Results show that the environmental disturbances affect only the rigid modes of the structure. The effect of solar radiation pressure interacting with the vibrating system is smaller than the solar radiation pressure acting on the thermally deformed structure. To reduce control effect in order to maintain shape and orientation, thermal deformations must be minimized in the preliminary design of the system.

Krishna, R.↗
NASA NTRS1985

Doppler lidar sampling strategies and accuracies: Regional scale

It has been proposed that a Doppler lidar be placed in a polar orbit and scanned to provide estimates of lower tropospheric winds twice per day and with a spatial resolution of 300 km. Initial feasibility studies conducted primarily by NOAA and NASA presented an optimistic outlook for a space based lidar. The technology appeared within reach and initial computer simulations suggested that acceptable accuracies could be obtained. Those early studies exposed, however, several potential problem areas which included: (1) the algorithms for computing the wind vectors did not perform well when there were coherent gradients in the wind fields; and (2) the lifetime and power requirements of the lidar put severe restrictions on the pulse repetition frequency (PRF). These two basic problems are currently being addressed by a Doppler lidar simulation study focussed upon three primary objectives: (1) to develop optimum scan parameters and shot patterns for a satellite-based Doppler lidar; (2) to develop robust algorithms for computing wind vectors from lidar returns; and (3) to evaluate the impact of coherent mesoscale structures (wind gradients, clouds, aerosols) on up-scale wind estimates. An overview is provided of the simulation efforts with particular emphasis upon rationale and methodology. Since this research is currently underway, any results shown are meant only as evidence of progress.

Emmitt, G. D.↗
DOE OSTI2020

Significantly Improved Cyclability of Conversion-Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction

Electrode stabilization by surface passivation has been explored as the most crucial step to develop long-cycle lithium-ion batteries (LIBs). In this work, functionally graded materials consisting of “conversion-type” iron-doped nickel oxyfluoride (NiFeOF) cathode covered with a homologous passivation layer (HPL) are rationally designed for long-cycle LIBs. The compact and fluorine-rich HPL plays dual roles in suppressing the volume change of NiFeOF porous cathode and minimizing the dissolution of transition metals during LIBs cycling by forming a structure/composition gradient. The structure and composition of HPL reconstructs during lithiation/delithiation, buffering the volume change and trapping the dissolved transition metals. As a result, a high capacity of 175 mAh g -1 (equal to an outstanding volumetric capacity of 936 Ah L -1 ) with a greatly reduced capacity decay rate of 0.012% per cycle for 1000 cycles is achieved, which is superior to the NiFeOF porous film without HPL and commercially available NiF 2 -FeF 3 powders. Finally, the proposed chemical and structure reconstruction mechanism of HPL opens a new avenue for the novel materials development for long-cycle LIBs.

25 ENERGY STORAGE↗
DOE OSTI2022

The impact of habitat fragmentation on domatia-dwelling mites and a mite-plant-fungus tritrophic interaction

Abstract Context Habitat fragmentation is a leading threat to biodiversity, yet the impacts of fragmentation on most taxa, let alone interactions among those taxa, remain largely unknown. Objectives We studied how three consequences of fragmentation—reduced patch connectivity, altered patch shape, and edge proximity—impact plant-dwelling mite communities and mite-plant-fungus interactions within a large-scale habitat fragmentation experiment. Methods We sampled mite communities from the leaves of Quercus nigra (a plant species that has foliar domatia which harbor fungivorous and predacious mites) near and far from edge within fragments of varying edge-to-area ratio (shape) and connectivity via corridors. We also performed a mite-exclusion experiment across these fragmentation treatments to test the effects of mite presence and fungal hyphal abundance on leaf surfaces. Results Habitat edges influenced the abundance and richness of leaf-dwelling mites; plants closer to the edge had higher mite abundance and species richness. Likewise, hyphal counts were higher on leaves near patch edges. Despite both mite and fungal abundance being higher at patch edges, leaf hyphal counts were not impacted by mite abundance on those leaves. Neither patch shape nor connectivity influenced mite abundance, mite species richness, or the influence of mites on leaf surface fungal abundance. Conclusion Our results suggest that mites and foliar fungi may be independently affected by edge-structured environmental gradients, like temperature, rather than trophic effects. We demonstrate that large-scale habitat fragmentation and particularly edge effects can have impacts on multiple levels of microscopic communities, even in the absence of cascading trophic effects.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2026

Pattern-enhanced Resonant Soft X-ray Scattering for Operando monitoring of electrochemical solid-liquid interfaces

Unveiling interfaces at sub-nanometer scales is essential for advancing the understanding of complex chemical transformations. However, characterizing solid-liquid interfaces with high dimensional sensitivity and temporal resolution remains challenging, due to their dynamic nature and inaccessibility by conventional probes. Here we present an approach, Pattern-enhanced Resonant Soft X-ray Scattering, to overcome the challenges. Rooted in a “sample-as-optics” philosophy, this technique utilizes precisely engineered line-grating nanopatterns to modulate near-field X-ray illumination, coherently enhancing scattering signals from the line-gratings. We implement the method using Ni line-grating nanopatterns in electrochemical water oxidation. The periodic nanostructures serve as diffractive optical elements to reveal the Ni oxidation gradients and structural dynamics at the electrode-electrolyte interfaces. Finite-element simulations corroborate the observed trends by modeling variations in compositions and structures during electrocatalysis. Through integrating advanced sample design with coherent wave nature of soft X-rays, our approach opens accessible pathways to operando exploring chemical evolution and sub-nanometer dimensional variations simultaneously in electrochemical systems. This non-destructive method is efficient and element-specific, making it valuable for probing chemical and dimensional dynamics with appropriate modeling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Weighted active space protocol for multireference machine-learned potentials

Multireference methods such as multiconfiguration pair-density functional theory accurately capture electronic correlation in systems with strong multiconfigurational character, but their cost precludes direct use in molecular dynamics. Combining these methods with machine-learned interatomic potentials (MLPs) can extend their reach. However, the sensitivity of multireference calculations to the choice of the active space complicates the consistent evaluation of energies and gradients across structurally diverse nuclear configurations. To overcome this limitation, we introduce the weighted active space protocol (WASP), a systematic approach to assign a consistent active space for a given system across uncorrelated configurations. By integrating WASP with MLPs and enhanced sampling techniques, we propose a data-efficient active learning cycle that enables the training of an MLP on multireference data. We demonstrated the approach on the TiC + -catalyzed C–H activation of methane, a reaction that poses challenges for Kohn–Sham density functional theory due to its significant multireference character. This framework enables accurate and efficient modeling of catalytic dynamics, establishing a paradigm for simulating complex reactive processes beyond the limits of conventional electronic-structure methods.

enhanced sampling↗
DOE OSTI2022

Beyond Pristine Metal–Organic Frameworks: Preparation of Hollow MOFs and Their Composites for Catalysis, Sensing, and Adsorption Removal Applications

Metal–organic frameworks (MOFs) have been broadly applied to numerous domains with a substantial surface area, tunable pore size, and multiple unsaturated metal sites. Recently, hollow MOFs have greatly attracted the scientific community due to their internal cavities and gradient pore structures. Hollow MOFs have a higher tunability, faster mass-transfer rates, and more accessible active sites when compared to traditional, solid MOFs. Hollow MOFs are also considered to be candidates for some functional material carriers. For example, composite materials such as hollow MOFs and metal nanoparticles, metal oxides, and enzymes have been prepared. These composite materials integrate the characteristics of hollow MOFs with functional materials and are broadly used in many aspects. This review describes the preparation strategies of hollow MOFs and their composites as well as their applications in organic catalysis, electrochemical sensing, and adsorption separation. Finally, we hope that this review provides meaningful knowledge about hollow-MOF composites and their derivatives and offers many valuable references to develop hollow-MOF-based applied materials.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Magnetic fields throughout the heliosphere

Recent measurement results on the heliospheric magnetic fields are reviewed. Findings in the areas of spatial gradients, sector structure and the heliospheric current sheet, changes in solar wind structure with solar cycle and radial distance, solar modulation of Galactic cosmic rays, and the interaction of the solar wind with the interstellar medium are addressed.

Smith, Edward J.↗
NASA NTRS1994

Contrasting conditions of surface water balance in wet years and dry years as a possible land surface-atmosphere feedback mechanism in the West African Sahel

The climate of West Africa, in particular the Sahel, is characterized by multiyear persistence of anomalously wet or dry conditions. Its Southern Hemisphere counterpart, the Kalahari, lacks the persistence that is evident in the Sahel even though both regions are subject to similar large-scale forcing. It has been suggested that land surface-atmosphere feedback contributes to this persistence and to the severity of drought. In this study, surface energy and water balance are quantified for nine stations along a latitudinal transect that extends from the Sahara to the Guinea coast. In the wetter regions of West Africa, the difference between wet and dry years is primarily reflected in the magnitude of runoff. For the Sahel and drier locations, evapotranspiration and soil moisture are more sensitive to rainfall anomalies. The increase in evapotranspiration, and hence latent heating, over the Sahel in wet years alters the thermal structure and gradients of the overlying atmosphere and thus the strength of the African easterly jet (AEJ) at 700 mb. The difference between dry and wet Augusts corresponds to a decrease in magnitude of the AEJ at 15 deg N on the order of 2.6 m/s, which is consistent with previous studies of observed winds. Spatial patterns were also developed for surface water balance parameters for both West Africa and southern Africa. Over southern Africa, the patterns are not as spatially homogeneous as those over West Africa and are lower in magnitude, thus supporting the suggestion that the persistence of rainfall anomalies in the Sahel might be due, at least in part, to land-atmosphere feedback, and that the absence of such persistence in the Kalahari is a consequence of less significant changes in surface water and energy balance.

Lare, A. R.↗