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At least 109 records · Page 6

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NASA NTRS1972

Erosion of graphite surface exposed to hot supersonic hydrogen gas

A theoretical model based on laminar boundary layer flow equations is developed to predict the erosion rate of a graphite (AGCarb-101) surface exposed to a hot supersonic stream of hydrogen gas. The supersonic flow in the nozzle outside the boundary layer formed over the surface of the specimen is determined by assuming one-dimensional isentropic conditions. An overall surface reaction rate expression based on the experimental studies by Clarke and Fox is used to describe the interaction of hydrogen with graphite. A satisfactory agreement is found between the results of the computation, and the available experimental data. Some shortcomings of the model, and further possible improvements are discussed.

Sharma, O. P.↗

NASA NTRS1989

Size distribution of dust grains: A problem of self-similarity

Distribution functions describing the results of natural processes frequently show the shape of power laws, e.g., mass functions of stars and molecular clouds, velocity spectrum of turbulence, size distributions of asteroids, micrometeorites and also interstellar dust grains. It is an open question whether this behavior is a result simply coming about by the chosen mathematical representation of the observational data or reflects a deep-seated principle of nature. The authors suppose the latter being the case. Using a dust model consisting of silicate and graphite grains Mathis et al. (1977) showed that the interstellar extinction curve can be represented by taking a grain radii distribution of power law type n(a) varies as a(exp -p) with 3.3 less than or equal to p less than or equal to 3.6 (example 1) as a basis. A different approach to understanding power laws like that in example 1 becomes possible by the theory of self-similar processes (scale invariance). The beta model of turbulence (Frisch et al., 1978) leads in an elementary way to the concept of the self-similarity dimension D, a special case of Mandelbrot's (1977) fractal dimension. In the frame of this beta model, it is supposed that on each stage of a cascade the system decays to N clumps and that only the portion beta N remains active further on. An important feature of this model is that the active eddies become less and less space-filling. In the following, the authors assume that grain-grain collisions are such a scale-invarient process and that the remaining grains are the inactive (frozen) clumps of the cascade. In this way, a size distribution n(a) da varies as a(exp -(D+1))da (example 2) results. It seems to be highly probable that the power law character of the size distribution of interstellar dust grains is the result of a self-similarity process. We can, however, not exclude that the process leading to the interstellar grain size distribution is not fragmentation at all. It could be, e.g., diffusion-limited growth discussed by Sander (1986), who applied the theory of fractal geometry to the classification of non-equilibrium growth processes. He received D=2.4 for diffusion-limited aggregation in 3d-space.

Henning, TH.↗

NASA NTRS1988

Interlaminar fracture toughness of thermoplastic composites

Edge delamination tension and double cantilever beam tests were used to characterize the interlaminar fracture toughness of continuous graphite-fiber composites made from experimental thermoplastic polyimides and a model thermoplastic. Residual thermal stresses, known to be significant in materials processed at high temperatures, were included in the edge delamination calculations. In the model thermoplastic system (polycarbonate matrix), surface properties of the graphite fiber were shown to be significant. Critical strain energy release rates for two different fibers having similar nominal tensile properties differed by 30 to 60 percent. The reason for the difference is not clear. Interlaminar toughness values for the thermoplastic polyimide composites (LARC-TPI and polyimidesulfone) were 3 to 4 in-lb/sq in. Scanning electron micrographs of the EDT fracture surfaces suggest poor fiber/matrix bonding. Residual thermal stresses account for up to 32 percent of the strain energy release in composites made from these high-temperature resins.

Hinkley, J. A.↗

NASA NTRS1990

Shock induced polymorphic transition in quartz, carbon, and boron nitride

The model proposed by Ahrens (1988) to explain the mechanism of the polymorphism in silicates is revised, and the revised model is applied to the quartz/stishovite, graphite/diamond, and graphite-boron nitride (g-BN) phase transformations. In this model, a key assumption is that transformation to a high-density amorphous or possibly liquid phase which rapidly crystallized to the high-pressure phase is triggered by the high temperatures in the shear band and upon crossing the metastable extension of a melting curve. Good agreement between the calcualted results and published data is obtained. The present theory predicts the standard entropy for cubic BN to be 0.4-0.5 J/g K.

Tan, Hua↗

NASA NTRS1989

Interlaminar fracture toughness of thermoplastic composites

Edge delamination tension and double cantilever beam tests were used to characterize the interlaminar fracture toughness of continuous graphite-fiber composites made from experimental thermoplastic polyimides and a model thermoplastic. Residual thermal stresses, known to be significant in materials processed at high temperatures, were included in the edge delamination calculations. In the model thermoplastic system (polycarbonate matrix), surface properties of the graphite fiber were shown to be significant. Cricital strain energy release rates for two different fibers having similar nominal tensile properties differed by 30 to 60 percent. The reason for the difference is not clear. Interlaminar toughness values for the thermoplastic polyimide composites (LARC-TPI and polyimidesulfone) were 3 to 4 in-lb/sq in. Scanning electron micrographs of the EDT fracture surfaces suggest poor fiber/matrix bonding. Residual thermal stresses account for up to 32 percent of the strain energy release in composites made from these high-temperature resins.

Hinkley, Jeffrey A.↗

NASA NTRS1992

Mechanism for diamond nucleation and growth on single crystal copper surfaces implanted with carbon

The nucleation and growth of diamond crystals on single-crystal copper surfaces implanted with carbon ions is studied. Microwave plasma-enhanced chemical-vapor deposition is used for diamond growth. The single-crystal copper substrates were implanted either at room or elevated temperature with carbon ions prior to diamond nucleation. This procedure leads to the formation of a graphite film on the copper surface which greatly enhances diamond crystallite nucleation. A simple lattice model is constructed for diamond growth on graphite as 111 line (diamond) parallel to 0001 line (graphite) and 110 line (diamond) parallel to 1 1 -2 0 (graphite).

Ong, T. P.↗

DOE OSTI2025

Operando FTIR investigation of salt dynamics in Li-ion batteries during fast charging

Li-ion batteries, when charged at fast-charging rates ($>$2C), suffer from reduced lifetimes and can undergo catastrophic failure. During high-rate charging, Li-ions are unable to rapidly transport through high-loading electrodes ($>$4 mAh cm −2 ). This results in unequal charge distributions, potentials, and utilization of the active material, which can lead to Li plating. Li-ion concentration polarization, in which Li-ions deplete in the anode and accumulate in the cathode during charging, precedes Li plating. An operando FTIR-ATR graphite/NMC cell developed in this research captured Li-ion concentration polarization in real-time. During fast charging, decreases in Li-ion concentration ($>$95%) were measured at the back of the anode. This is the first verification of complete Li-ion depletion within the anode at high C-rates. The measurements also showed graphite stage transition. A P2D model was developed for comparison to the operando measurements. The measurements agreed with the model in some cases, but disparities existed at high C-rates and loadings. In the experiment, the Li-ion concentration often failed to recover to 1.2 M until several hours after charging, whereas the model Li-ion concentration rapidly recovered. The contrast between the model and experiment results indicates that further investigation is required to improve understanding of Li-ion concentration dynamics during fast charging.

25 - ENERGY STORAGE↗

NASA NTRS1987

Electrical resistivity (4K to 2100K) of annealed vapor growth carbon fibers

Carbon fibers have been grown from methane gas, on iron seeded substrates at 1370 K, and subsequently annealed to a series of temperatures between 2800 K and 3475 K. The subsequent measurement of the electrical resistivity are reported as a function of temperature from 4 K to 2100 K. The two band model for the resistivity of graphite is well fit to the data, and results in physically reasonable parameters of the fits. The resistivity vs temperature results for two boron doped fibers are reported as well. The product of the resistivity times density for these fibers is lower than that product for any refractory metal, for temperatures above about 1000 K, suggesting the usefulness of these fibers as high temperature materials in space applications.

Ahmed, Akhter U.↗

NASA NTRS1996

The Inventory of Interstellar Materials Available for the Formation of the Solar System

Dr. Derek Sears, the editor of the journal Meteoritics and Planetary Science, has established a policy of having each issue of the journal contain an invited review of an area that he deems to be of special cur-rent importance. Typically 20 to 25 pages of the beginning of the journal are devoted to each review. He has asked me to prepare such a review summarizing what we know about the composition and structure of interstellar materials. The attached paper is the result. This is a good time for such a review since tremendous progress has been made in the field of interstellar dust in recent years through the use of telescopic observations, theoretical studies, laboratory studies of analogs, and the study of actual interstellar samples found in meteorites. It is increasing clear that the interstellar medium (ISM) contains an enormous diversity of materials created by a wide range of chemical and physical processes. This understanding is a far cry from the picture of interstellar materials held as recently as two decades ago, a picture which incorporated only a few generic types of grains and few molecules. In the paper I review our current knowledge of the more abundant materials thought to exist in the ISM. The review concentrates on matter in interstellar dense molecular clouds since it is the materials in these environments from which new stars and planetary systems are formed, although materials in circumstellar environments and in the diffuse ISM are also discussed. The paper focuses largely on solid materials since they contain a major fraction of the heavier elements in clouds and because solids are most likely to survive incorporation into new planetary systems in identifiable form. The paper concludes with discussion of some of the implications resulting from the identification of these interstellar materials. I also present some new thoughts, the most intriguing being that meteoritic 'microdiamonds' may be the same material that modelers of the interstellar extinction call graphite! If my suggestion is correct it will help resolve the dilemma associated with the current over-subscription of cosmic C and should lead to some new approaches to both extinction models and the study of meteoritic interstellar microdiamonds.

Sandford, Scott A.↗

NASA NTRS1996

The Interstellar Polarization Feature Associated with the 2175 Angstrom Extinction Bump

The most successful model at fitting the wavelength dependence of interstellar extinction consists of two populations of bare silicate and graphite grains (Mathis, Rumpl & Nordsieck, (MRN)). The graphite grains are needed to fit the strong 2175 A extinction bump, with the silicates providing most of the smooth extinction seen at other wavelengths. From observations of the IR silicate absorption features, it was inferred that the silicate grains, non-spherical and aligned to the Galactic magnetic field, were responsible for the interstellar polarization. Aligned silicate grains make a very good fit to the smooth featureless UV polarization curves that comprise most of the observed sample. The lines of sight showing a UV polarization feature require something different, perhaps a second population of grains as do the fits to the extinction curve. The polarization wavelength dependence of HD 197770 can be fit by a MRN-like mixture of aligned bare silicate and graphite grains. However, none of the popular grain models including MRN envisaged an aligned bump grain population. It has been suggested that the extinction bump is not due to graphite but rather to a population of polycyclic aromatic hydrocarbons (PAHs). If the observed UV polarization features could be associated with the 2175 A bump then it would strengthen the argument that the bump must be due to grains rather than PAHs which are not likely to be aligned to the Galactic Magnetic field. The reality of ultraviolet polarization features has been confirmed by observations with ASTRO-2. The original detection toward HD 197770 has been confirmed and a new feature has been detected toward HD 147933-4. Both features have centroids lying close to 2175 A the location of the UV extinction bump. Two possibilities are considered for the source of the polarization bump, alignment of graphite grains responsible for the extinction bump or changes in the size distribution of the aligned silicate grains responsible for the continuum polarization. It seems the graphite grains are a more likely source of the polarization.

Clayton, Geoffrey C.↗

NASA NTRS1990

A theoretical model for magnetic field mapping as a means of broken fiber detection in graphite epoxy composites

A technique for location of broken fibers by imaging magnetic fields generated from currents injected in the fibers is presented. It is concluded that the magnetic field pattern drops abruptly near the axis of a hole, or a break in fibers. The magnetic image of a hole gives contours with the shape of an ellipse. By measuring the semimajor and semiminor axis of image it is possible to determine the ratios of the conductivities. These ratios depend on feedthrough at sites where fibers of the different directions of the layup can make electrical contact with other fibers in adjacent layers. The effects of delaminations should alter these values.

Yost, William T.↗

NASA NTRS2016

Influence of Molecular Simulation Model Accuracy on the Interfacial Properties of an Ionic Liquid: Overview of Recommended Practices

Increasing the energy storage capability of ionic liquid supercapacitors will require better understanding of ion-electrode interactions. We have probed the influence of these interactions on the structure and differential capacitance of of an ionic liquid ([EMIM][BF4]) at an ideal graphite interface as a function of model accuracy. Of note, differential capacitance is determined through newly derived and validated fluctuation formulas. In terms of model accuracy, we test electrostatic techniques, electrode charging techniques, and electrolyte interatomic potentials. For electrostatic summations, we employ high cost, high fidelity techniques as well as less expensive, approximate techniques for summation in slab geometry. For electrode charging, uniform, constant-charge and environmentally responsive, constant-potential conditions are employed. For the ionic liquid, constant charge and atomically polarizable models are employed. We comment on the role of model accuracy on the structure and energetics of the electric double layer as well as on the magnitude and shape of differential capacitance.

simulations↗

DOE OSTI2025

Modeling Structured Electrodes and Graded Porosity for Improving Discharge Rate Capability in Ultra-Thick Graphite|LiNi 0.6 Mn 0.2 Co 0.2 O 2 Batteries

Long-range electric vehicles (EVs) require high-energy-density batteries that also meet the power demands of high current charge and discharge. Ultra-thick (>100 μm) Lithium-ion battery electrodes are critical to enable this need, but slow ion transport in conventional uniform electrodes (UEs) reduces battery capacity at increasing charge/discharge rates. We present a 3D computational analysis on the impact of structured electrode (SE) and graded electrode (GE) geometries on the discharge rate capability of ultra-thick graphite|LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC-622) battery cells based on the footprint of a commercial EV pouch cell. SE cathodes with either a “grid” or “line” geometry and GEs with two layers of porosity were modeled. Based on the results of 230 models, we found that the electrolyte volume fraction is a key parameter that impacts capacity improvements in UEs, GEs, and SEs at 2 C–6 C discharge rates. SEs have the greatest discharge rate capability, outperforming GEs and UEs due to reduced Lithium-ion concentration gradients across the electrode thickness, which mitigates electrolyte depletion at high rates. The best SE model has a “grid” geometry with gravimetric and volumetric energy density improvements of 0.9%–4% at C/2–2 C and 18%–24% at 4 C–6 C relative to UEs.

25 ENERGY STORAGE↗

NASA NTRS1988

Fracture analysis of local delaminations in laminated composites

A shear deformation model was developed to analyze local delaminations growing from transverse cracks in 90 degree plies located around the mid plane of symmetric laminates. The predictions of the model agree reasonably with experimental data from T300/934 graphite epoxy laminates. The predicted behavior is such that, in combination with an edge delamination model, the critical loads can be predicted accurately in the range of n from .5 to 8.

Sriram, P.↗

NASA NTRS1989

Fracture analysis of local delaminations in laminated composites

Armanios, E. A.↗

NASA NTRS1989

Continuous infrared emission of proto- and young-planetary nebulae

Evolutionary sequences of planetary nebulae (PNe) were calculated beginning from the moment of shell ejection to its dissipation and IR spectra of the outgoing radiation were obtained for different stages of the evolution. To solve the coupled hydrodynamical and radiation transfer problem a computer code was used in which gas and dust are treated as two separate hydrodynamical components. The models, which are calculated for two grain materials (graphite and silicate) have a size distribution of particles based on that found for the interstellar medium. In the computations, the recent optical properties of graphite and astronomical silicate grains tabulated by Draine (1987) were employed. It was assumed that silicate of graphite grains exist below some critical temperature equal to 1300 or to 1700 K, respectively. Infrared model spectra are compared with the IR radiation emitted by some proto- and some young-planetary nebulae. The observed IR continua can be quite well matched with our models with grains having a reasonable size range.

Szczerba, Ryszard↗

DOE OSTI2025

Species Transport Framework Development in SAM for System-Level Tritium Source Term Analysis

The SAM code is under development as a modern system-level modeling and simulation tool for advanced non–light water reactor safety analyses, with recent efforts to add capabilities to evaluate radiological source term risks in these novel reactor concepts. By leveraging the established system-level multiphysics thermal-hydraulic models in SAM, a framework for tightly coupled species transport modeling has been integrated into the code for engineering-scale source term evaluation. This species transport framework was first applied to the simulation of tritium, which is a well-known source term in conventional light water reactors. Tritium poses a unique risk in salt-cooled reactors, especially those with lithium-bearing salts such as the fluoride salt–cooled high-temperature reactor (FHR) concept, as tritium is generated in the salt coolant in significant quantities due to neutron interactions. A compounding factor is the increased mobility of tritium at high temperatures, which is able to permeate through metals while also potentially being retained in graphite pebbles and structures. Engineering-scale models for the tritium transport pathways in a FHR have been developed using the new species transport framework in SAM. The capabilities are assessed through analytical verification problems and validated with data from a graphite retention experiment. In conclusion, the system-level model is demonstrated by performing an initial estimate of baseline tritium generation and flows in a generic reference SAM FHR model, setting a foundation for future studies of source term transient analysis with the potential for further multiscale and multiphysics integration.

SAM↗

NASA NTRS1993

Thermal-mechanical behavior of high precision composite mirrors

Composite mirror panels were designed, constructed, analyzed, and tested in the framework of a NASA precision segmented reflector task. The deformations of the reflector surface during the exposure to space enviroments were predicted using a finite element model. The composite mirror panels have graphite-epoxy or graphite-cyanate facesheets, separated by an aluminum or a composite honeycomb core. It is pointed out that in order to carry out detailed modeling of composite mirrors with high accuracy, it is necessary to have temperature dependent properties of the materials involved and the type and magnitude of manufacturing errors and material nonuniformities. The structural modeling and analysis efforts addressed the impact of key design and materials parameters on the performance of mirrors.

Kuo, C. P.↗