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The shape of spectral lines: The importance of the far wings

Spectroscopy, the study of the interaction of radiation and matter, provides most of the information we have gleaned about the composition, structure, and evolution of the universe. As is well known, by measuring the frequencies of spectral lines in absorption or emission, one can uniquely infer the presence of atoms or molecules as well as their physical state and environment (e.g., solid or gaseous, neutral or ionized, moving or stationary, etc.). Furthermore, by studying the intensities of these lines, one can determine the abundance (i.e., number of a particular species per unit volume). Although less well known, the shape of the spectral lines, in particular, the structure of the far wings, plays a very important role in many important atmospheric phenomena such as the greenhouse effect or the absorption of harmful ultraviolet radiation. Although first measured more than 50 years ago, the anomalous absorption of radiation by water vapor in the earth's atmosphere was postulated to be due to far wings of allowed lines. However, only within the past few years has a quantitative verification of this hypothesis been possible through the development of an accurate theoretical description of the shape of self-broadened water lines. During the summer, work has been done on improving this theory and in comparing the results to other theories valid near the center of the lines. The relevance of this work to measurements of greenhouse gases, of earth-based measurements of the 3 K cosmic background radiation, of satellite-based measurements of the atmospheres of the earth and other planets, and other similar problems will be discussed briefly.

Tipping, Richard↗

The Need for Earth-Based Experiments to Inform Microbial Evolution on Planetary Surfaces

Introduction: Historically, the focus of planetary protection at NASA has been on unmanned, robotic missions. Such missions have paved the way for understanding how to implement planetary protection in a feasible and cost-sensitive way. However, with the introduction of crewed missions to Mars in the not-sodistant future, there is a need to better define and understand how to implement planetary protection under new circumstances, as well as understand the risk of contaminating Mars. One unavoidable fact is that microbes will go where humans go. Therefore, it is critical to understand how these microbes may (and will) impact our ability to conduct meaningful, reliable astrobiological science. Microorganisms have spent millions of years evolving to survive in extreme environments here on Earth. Already there are indications that microbes aboard the International Space Station evolve and adapt to life in low earth orbit. The microbes that are eventually taken to Mars with humans will also adapt, potentially causing harmful effects to crew and/or the planetary or astrobiological science conducted. Therefore, it is of critical interest that we evaluate and characterize the potential risks of microbial evolution on Mars. It is expected that microbes carried by humans will begin to evolve to new environments even before landing on Mars, during the several month cruise phase. Once landed, microbes will encounter different stressors within the crew habitats on Mars. During extravehicular activities, venting, or other release events, microbes will find their way out onto the Martian surface. The induced environments around crewed systems will create potentially-favorable conditions for microbes to continue evolving on Mars. Eventually, microbes may find their way beyond the close confines of the crewed area and continue evolving so as to fill new or distant niches on the Martian surface. It is challenging to replicate Martian environments here on Earth, making it nearly impossible to predict the evolutionary changes that microbes would undergo on Mars. But this work is critical. Serial passaging experiments performed by Richard Lenski on E. coli show the dramatic changes microbes can undergo even within a laboratory setting. Furthermore, experiments performed by Michael Baym also demonstrate the power of single mutations in microbial development of antibiotic resistance [3]. Long duration experiments should be performed on a suite of microbes exposed to environments likely to be experienced on the Martian surface. While simulating space environments can be challenging, facilities exist that can achieve individual and combinatorial environmental conditions to simulate space and planetary conditions. Such chambers should be employed for microbial studies. Currently, at the Marshall Space Flight Center, we have used various stressors like drying, vacuum, proton radiation, and ultraviolet light both separately and in combination, to evaluate the survival of cleanroom microbes. Shockingly, several non-spore forming isolates have demonstrated the ability to survive many extreme conditions (manuscript in preparation). These short duration exposures must be augmented with larger and more gradual studies to replicate what microbes might experience in the transition from cruise, to surface habitats, to induced surface environments, and finally true Martian environments. While no Earth-based experiment can perfectly replicate the Martian environment, nor could we test every possible microbe in simulation experimental regimes, efforts should be made to examine the evolutionary potential of the “usual suspects” seen on the ISS or in other crewed environments to begin to fill this important knowledge gap.

Chelsi D. Cassilly↗

Monitoring of Observation Errors in the Assimilation of Satellite Ozone Data

The stratospheric ozone layer protects life on Earth from the harmful effects of solar ultravioiet radiation. The ozone layer is currently in a fragile state because of depletion caused by man-made chemicals, especially chlorofluorocarbons. The state of the ozone layer is being monitored and evaluated by scientific experts around the world, in order to help policy makers assess the impacts of international protocols that control the production and release of ozone depleting chemicals. Scientists use a variety ozone measurements and models in order to form a comprehensive picture about the current state of the ozone layer, and to predict the future behavior (expected to be a recovery, as the abundance of the depleting chemicals decreases). Among the data sets used, those from satellite-borne instruments have the advantage of providing a wealth of information about the ozone distribution over most of the globe. Several instruments onboard American and international satellites make measurements of the properties of the atmosphere, from which atmospheric ozone amounts are estimated; long-term measurement programs enable monitoring of trends in ozone. However, the characteristics of satellite instruments change in time. For example, the instrument lenses through which measurements are made may deteriorate over time, or the satellite orbit may drift so that measurements over each location are made later and later in the day. These changes may increase the errors in the retrieved ozone amounts, and degrade the quality of estimated ozone amounts and of their variability. Our work focuses on combining the satellite ozone data with global models that capture atmospheric motion and ozone chemistry, using advanced statistical techniques: this is known as data assimilation. Our method provides a three-dimensional global ozone distribution that is consistent with both the satellite measurements and with our understanding of processes (described in the models) that control ozone distribution. Through the monitoring of statistical properties of the agreement between the data and the model, this approach also enables us to detect changes in the quality of ozone data retrieved from satellite-borne instrument measurements. This paper demonstrates that calculations of the changes in satellite data quality, and the impact these changes on the estimates of the global ozone distribution, can assist in maintaining the uniform quality of the satellite ozone data throughout the lifetime of these instruments, thus contributing to our understanding of long-term ozone change.

Stajner, Ivanka↗

Unlocking the Spacecraft and Human Habitat Microbiome to Enable the Next Generation of Space Exploration

Planetary protection is the discipline that prevents harmful contamination of the solar system during exploration activities. The current international guidelines and NASA policy addressing biological contamination on spacecraft surfaces contains prescriptive guidelines of spore requirements (e.g., 300 spores/m2, 5×105 spores per spacecraft) applicable to spacecraft bound for Mars. To verify these requirements spacecraft engineers sample spacecraft surfaces throughout the assembly, test and launch operations phase of the mission using damp water cotton swabs and polyester wipes. After sampling, the potential biological contamination is enumerated using a series of traditional microbiology techniques to include sonication, heat shocking at 80°C for 15min to select for spores, and growth on tryptic soy agar at 32°C for 72 hours. To enable crewed missions to Mars and robotic exploration of the Ocean Worlds a risk informed decision making / performance-based approach to assess biological contamination offers a promising solution in the trade space. Recognizing the need for a performance-based approach, NASA’s new Planetary Protection policies now incorporate the agility for missions to be able to leverage a performance or prescriptive approach. One of top contenders in the option space is a coupled quantitative, descriptive and functional based approach to be able to assess the quantity, types and capabilities of the biological contamination present on spacecraft surfaces. A tailored, mission by mission assurance case could then be formulated by building an argument around the target body, projected capabilities surrounding the types of organisms their potential for survival and proliferation, and ability to be transported on the target body to contaminate an area of biological interest. A performance-based requirement would then be used to demonstrate the mission’s compliance in protecting the planetary environment safety objectives. This symposium talk will showcase the background and need case for NASA to develop such a capability as well as provide an update on the efforts underway in developing a transparent and responsible performance-based approach to biological contamination assessments on spacecraft surfaces.

Habitat Microbiome↗

Development of an Automated Reader for Analysis and Storage of Personnel Dosimeter Badge Data

The collection and archiving of data from personnel dosimeters has become increasingly important in light of the lowered Threshold Limit Values (TLV) for HydraZine (HZ), MonoMethylHydrazine (MMH), and Unsymmetrical DiMethylHydrazine (UDMH). The American Conference of Government Industrial Hygienists (ACGIH) lowered the TLV from 100 parts per billion (ppb) to IO ppb and has caused increased concern over long term exposures of personnel to trace levels of these hypergols and other potentially harmful chemicals. An automated system of reading the exposure levels of personnel dosimeters and storing exposure data for subsequent evaluation has been developed. The reading of personnel dosimeter badges for exposure to potentially harmful vapor concentrations of hydrazines or other chemicals is performed visually by comparing the color developed by the badge with a calibrated color comparator. The result obtained using visual comparisons of the developed badge color with the comparator may vary widely from user to user. The automated badge reader takes the variability out of the dosimeter reading by accurately comparing the reflectance obtained from a colored spot on the badge with a reading on the same spot prior to any exposure to chemical vapors. The observed difference between the reflectance values is used as part of a calculation of the dose value for the badge based on a stored calibration curve. The badge reader also stores bar-code data unique to each badge, as well as bar-code information on the user, as part of the permanent badge record. The start and stop exposure times for each badge are recorded and can be used as part of the calculated concentration, in ppm, for each badge logged during a recording period. The badge reader is equipped with a number of badge holders, each of which is unique to a specific type of personnel dosimeter badge. This gives the reader maximum flexibility to allow for the reading of several different types of badges. Test results of the badge reader for several different types of personnel dosimeter badges are presented within the body of this paper.

Meneghelli, B. J.↗

Development of an Automated Reader for Analysis and Storage of Personnel Dosimeter Badge Data

The collection and archiving of data from personnel dosimeters has become increasingly important in light of the lowered threshold limit values (TLV) for hydrazine (HZ), monomethylhydrazine (MMH), and unsymmetrical dimethylhydrazine (UDMH). The American Conference of Government Industrial Hygienists (ACGIH) lowered the TLV from 100 parts per billion (ppb) to 10 ppb and has caused increased concern over long term exposures of personnel to trace levels of these hypergols and other potentially harmful chemicals. An automated system of reading the exposure levels of personnel dosimeters and storing exposure data for subsequent evaluation has been developed. The reading of personnel dosimeter badges for exposure lo potentially harmful vapor concentrations of hydrazines or other chemicals is performed visually by comparing the color developed by the badge with a calibrated color comparator. The result obtained using visual comparisons of the developed badge color with the comparator may vary widely from user to user. The automated badge reader takes the variability out of the dosimeter reading by accurately comparing the reflectance obtained from a colored spot on the badge with a reading on the same spot prior to any exposure to chemical vapors. The observed difference between the reflectance values is used as part of a calculation of the dose value for the badge based on a stored calibration curve. The badge reader also stores bar-code data unique to each badge, as well as bar-code information on the user, as part of the permanent badge record. The start and stop exposure times for each badge are recorded and can be used as part of the calculated concentration, in ppm, for each badge logged during a recording period. The badge reader is equipped with a number of badge holders, each of which is unique to a specific type of personnel dosimeter badge. This gives the reader maximum flexibility to allow for the reading of several different types of badges. Test results of the badge reader for several different types of personnel dosimeter badges are presented within the body of this paper.

Meneghelli, B. J.↗

Recovery of postural equilibrium control following spaceflight

Decreased postural stability is observed in most astronauts immediately following spaceflight. Because ataxia may present postflight operational hazards, it is important to determine the incidence of postural instability immediately following landing and the dynamics of recovery of normal postural equilibrium control. It is postulated that postflight postural instability results from in-flight adaptive changes in central nervous system (CNS) processing of sensory information from the visual, vestibular, and proprioceptive systems. The purpose of the present investigation was to determine the magnitude and time course of postflight recovery of postural equilibrium control and, hence, readaptation of CNS processing of sensory information. Thirteen crew members from six spaceflight missions were studied pre- and postflight using a modified commercial posturography system. Postural equilibrium control was found to be seriously disrupted immediately following spaceflight in all subjects. Readaptation to the terrestrial environment began immediately upon landing, proceeded rapidly for the first 10-12 hours, and then proceeded much more slowly for the subsequent 2-4 days until preflight stability levels were reachieved. It is concluded that the overall postflight recovery of postural stability follows a predictable time course.

NASA Discipline Neuroscience↗

Real Data and Rapid Results: Ocean Color Data Analysis with Giovanni (GES DISC Interactive Online Visualization and ANalysis Infrastructure)

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has taken a major step addressing the challenge of using archived Earth Observing System (EOS) data for regional or global studies by developing an infrastructure with a World Wide Web interface which allows online, interactive, data analysis: the GES DISC Interactive Online Visualization and ANalysis Infrastructure, or "Giovanni." Giovanni provides a data analysis environment that is largely independent of underlying data file format. The Ocean Color Time-Series Project has created an initial implementation of Giovanni using monthly Standard Mapped Image (SMI) data products from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) mission. Giovanni users select geophysical parameters, and the geographical region and time period of interest. The system rapidly generates a graphical or ASCII numerical data output. Currently available output options are: Area plot (averaged or accumulated over any available data period for any rectangular area); Time plot (time series averaged over any rectangular area); Hovmeller plots (image view of any longitude-time and latitude-time cross sections); ASCII output for all plot types; and area plot animations. Future plans include correlation plots, output formats compatible with Geographical Information Systems (GIs), and higher temporal resolution data. The Ocean Color Time-Series Project will produce sensor-independent ocean color data beginning with the Coastal Zone Color Scanner (CZCS) mission and extending through SeaWiFS and Moderate Resolution Imaging Spectroradiometer (MODIS) data sets, and will enable incorporation of Visible/lnfrared Imaging Radiometer Suite (VIIRS) data, which will be added to Giovanni. The first phase of Giovanni will also include tutorials demonstrating the use of Giovanni and collaborative assistance in the development of research projects using the SeaWiFS and Ocean Color Time-Series Project data in the online Laboratory for Ocean Color Users (LOCUS). The synergy of Giovanni with high-quality ocean color data provides users with the ability to investigate a variety of important oceanic phenomena, such as coastal primary productivity related to pelagic fisheries, seasonal patterns and interannual variability, interdependence of atmospheric dust aerosols and harmful algal blooms, and the potential effects of climate change on oceanic productivity.

Acker, J. G.↗

Impact of Canadian Wildfires on Mid Atlantic’s Region Air Quality: An Analysis Using ASDC Data

Wildfires pose a growing concern in North America due to their harmful impacts on air quality and public health, with increased wildfire activity in recent years leading to widespread smoke plumes that can transcend borders. The exposure of New York City (NYC), the most populous city in North America, to Canadian wildfire smoke highlights the substantial implications for public health and urban environments. To better understand the impact of Canadian wildfires on air quality in NYC, satellite data from the NASA Atmospheric Science Data Center (ASDC) at Langley Research Center, along with ground-based measurements and atmospheric modeling results, are analyzed. We examine concentrations of atmospheric aerosols—particularly PM2.5 particulate matter originating from Canadian wildfires—their dispersion patterns, and the duration and intensity of smoke events impacting NYC. Data from multiple satellites, such as those from the Earth Polychromatic Imaging Camera (EPIC), are synergistically used to identify regions affected by wildfires and estimate aerosol loading. Ground-based measurements, including data from air quality monitoring stations, provide localized information for validation and calibration purposes. The findings of this study contribute to our understanding of the impact of Canadian wildfires on NYC's air quality and emphasize the importance of monitoring and prediction of transboundary smoke events using data synthesized from multiple sources, such as those provided by the ASDC. This information is crucial for policymakers, public health officials, and residents in affected areas to develop effective strategies for mitigating the health risks associated with wildfire smoke and improving air quality during wildfire seasons. The utilization of ASDC data in this research highlights the critical role of atmospheric remote sensing in addressing the challenges posed by wildfires and their consequences on regional scales.

Ingrid Garcia-Solera↗

Analyzing the Impact of Canadian Wildfires on Air Quality in the U.S. Mid-Atlantic: with Data and Tools from NASA’s Atmospheric Sciences Data Center

Wildfires pose a growing concern in North America due to their harmful impacts on air quality and public health, with increased wildfire activity in recent years leading to widespread smoke plumes that can transcend borders. The exposure of New York City (NYC), the most populous city in North America, to Canadian wildfire smoke highlights the substantial implications for public health and urban environments. To better understand the impact of Canadian wildfires on air quality in NYC, satellite data from the NASA Atmospheric Science Data Center (ASDC) at Langley Research Center, along with ground-based measurements and atmospheric modeling results, are analyzed. We examine concentrations of atmospheric aerosols—particularly PM2.5 particulate matter originating from Canadian wildfires—their dispersion patterns, and the duration and intensity of smoke events impacting NYC. Data from multiple satellites, such as those from the Earth Polychromatic Imaging Camera (EPIC), are synergistically used to identify regions affected by wildfires and estimate aerosol loading. Ground-based measurements, including data from air quality monitoring stations, provide localized information for validation and calibration purposes. The findings of this study contribute to our understanding of the impact of Canadian wildfires on NYC's air quality and emphasize the importance of monitoring and prediction of transboundary smoke events using data synthesized from multiple sources, such as those provided by the ASDC. This information is crucial for policymakers, public health officials, and residents in affected areas to develop effective strategies for mitigating the health risks associated with wildfire smoke and improving air quality during wildfire seasons. The utilization of ASDC data in this research highlights the critical role of atmospheric remote sensing in addressing the challenges posed by wildfires and their consequences on regional scales.

Ingrid Garcia-Solera↗

Applicability of Spectral Decomposition by Varimax-Rotated, Principal Component Analysis to the Surface Biology and Geology (SBG) VNIR Mission Concept

Cyanobacterial and Harmful Algal Blooms (CyanoHABs) are a growing concern in coastal and inland waters. But, spectral interference from multiple constituents in optically complex waters can hamper application of remote sensing using traditional image processing methods. The Kent State University (KSU) spectral decomposition method can be applied to multispectral and hyperspectral remote sensing images (e.g. HICO and the NASA Glenn HSI2) to partition and identify signals related to cyanobacteria, algae, pigment degradation products and suspended sediment in each pixel. Fundamental to the use of remote sensing data is the ability to extract independent signals from correlated hyperspectral VNIR data cubes. The Kent State University varimax-rotated, principal component analysis method (VPCA) is important to integrate into the SBG VNIR mission concept because it provides greater specificity, a software-based SNR boost relative to hardware performance, and can assist with Cal/Val, Modeling and Applications. We present examples of the hyperspectral application of the KSU VPCA method with relevance to SBG. The information extracted by VPCA can be validated spectrally or spatially with laboratory and/or in situ sensors, which capture spatial or time series of information at discrete points within remote sensing images. Comparisons show hyperspectral sensors extract more components than multispectral ones, but more independent information can be extracted from multispectral sensors by VPCA than traditional band ratio approaches. The spectral decomposition method is capable of enhancing the signal to noise ratio (SNR) of the NASA Glenn, second-generation hyperspectral imager by a factor of 7x to 20x, with a spectral reproducibility of ±3%. The spectral decomposition method, when compared against existing remote sensing monitoring methods exhibits both greater specificity and a lower detection limit. The method has been validated with multispectral images in Lake Erie to quantify the Microcystis CyanoHAB and from the Indian River Lagoon, Florida to quantify the Brown Tide resulting from A. lagunesnsis. Field operations in the Western Basin of Lake Erie were conducted using a bbe Fluoroprobe to collect vertical profiles and horizontal tows along a transect from the Toledo to the Detroit Lighthouse during coincident satellite overpasses. Extraction of pixel values from the MODIS Aqua sensor yields agreement between in situ field and lab-based measures of cyanobacterial, cryptophyte, diatoms and green algae, suspended sediment and pigment degradation products with R2>0.8.

hyperspectral↗

Template Matching Approach to Signal Prediction

A new approach to signal prediction and prognostic assessment of spacecraft health resolves an inherent difficulty in fusing sensor data with simulated data. This technique builds upon previous work that demonstrated the importance of physics-based transient models to accurate prediction of signal dynamics and system performance. While models can greatly improve predictive accuracy, they are difficult to apply in general because of variations in model type, accuracy, or intended purpose. However, virtually any flight project will have at least some modeling capability at its disposal, whether a full-blown simulation, partial physics models, dynamic look-up tables, a brassboard analogue system, or simple hand-driven calculation by a team of experts. Many models can be used to develop a predict, or an estimate of the next day s or next cycle s behavior, which is typically used for planning purposes. The fidelity of a predict varies from one project to another, depending on the complexity of the simulation (i.e. linearized or full differential equations) and the level of detail in anticipated system operation, but typically any predict cannot be adapted to changing conditions or adjusted spacecraft command execution. Applying a predict blindly, without adapting the predict to current conditions, produces mixed results at best, primarily due to mismatches between assumed execution of spacecraft activities and actual times of execution. This results in the predict becoming useless during periods of complicated behavior, exactly when the predict would be most valuable. Each spacecraft operation tends to show up as a transient in the data, and if the transients are misaligned, using the predict can actually harm forecasting performance. To address this problem, the approach here expresses the predict in terms of a baseline function superposed with one or more transient functions. These transients serve as signal templates, which can be relocated in time and space against the signal background. One then has the ability to reconstruct a signal regardless of the precise timing of the transients. During operation, one applies the actual start times of spacecraft activities as they occur, and produces a reconstructed, accurate predict in real-time. This general approach is valid under two important conditions. First, the transients themselves must be time-invariant. Second, the transients must be reasonably consistent with respect to different operating points. Both of these assumptions are generally valid, but in the case of a complicated system with numerous types of overlapping transients, this approach may not be effective. Fortunately, there tend to be few transients in spacecraft telemetry of sensor quantities or low-level health and status information because these signals rarely reflect multiple different types of operation. Furthermore, if the predict is at least reasonably close to actual operation, the shift either in time, or in the operating point when the transient occurs - is likely to be small. The proposed approach considers three ways to recognize a transient. The first and most reliable is to use a different signal that identifies operating mode - often the transient will be correlated to a change in operating mode, and this change can usually be detected positively from discrete signals in spacecraft telemetry. If there is no useful mode signal, the second option is to identify the transient template by hand, and detect the onset of the transient using a curve-fitting approach. Finally, if one elects not to choose by hand, there is an option for automatic selection. This technique has been applied to sensor data from several JPL missions and industrial applications, demonstrating an improvement in accurate prediction of future behavior and early detection of system problems. This technique is applicable to practically any time-varying, quantitative sensor measurement.

Mackey, Ryan↗

Principal Component and Machine Learning Approach to Gap Fill Hyperspectral Ocean Color Satellite Retrievals

Retrievals of ocean color properties from space are important for monitoring the health of the ocean ecosystem but such retrievals can be limited spatially due to conditions such as clouds, aerosols, and sun glint. Gap filling of ocean color retrievals is typically performed by combining retrievals from multiple satellites or temporally averaging multiple days of retrievals. Despite these techniques large gaps still exist posing challenges for near real time monitoring of events like harmful algae blooms. To address these limitations, we developed a spatial gap filling approach applying machine learning approach to hyperspectral instruments to learn how to perform an atmospheric correction under challenging retrieval conditions. In this approach a principal component analysis is used to decompose the hyperspectral measurements into spectral components that describe the scattering and absorption of the atmosphere mixed with the surface spectral signatures. The coefficients of the principal components are used to train a neural network to predict ocean color properties derived from a standard MODIS ocean color algorithm. We apply the approach to two hyperspectral UV/VIS sensors, the Ozone Monitoring Instrument (OMI) and TROPOspheric Monitoring Instrument (TROPOMI) to show that it can be used to estimate ocean color properties such as chlorophyll, remote sensing reflectance, and fluorescence line height. This method could be used as a gap-filling technique for the future Ocean Color Instrument (OCI) onboard upcoming NASA's Plankton, Aerosol Cloud, ocean Ecosystem (PACE) satellite to provide additional information for monitoring the health of our global oceans. Additionally, it could be applied to the first NASA and Smithsonian geostationary Tropospheric Emissions: Monitoring of Pollution (TEMPO) spectrometer to better understand diurnal variability in inland and coastal ocean ecology.

Zachary Fasnacht↗

The Planetary Protection Strategy of the Earth Return Orbiter–Capture, Containment & Return System in the Context of the Mars Sample Return Campaign

The Mars Sample Return Campaign aims at bringing back to Earth the rock and atmospheric samples that the rover Perseverance has started to collect on the surface of Mars with the goal of analyzing them in a facility built specifically for this purpose to answer questions about the habitability of Mars. The Campaign consists of several missions, including the Earth Return Orbiter–Capture, Containment & Return System (ERO-CCRS), which will capture the samples previously put in Martian orbit, contain them in redundant containers to ensure that no unsterilized particles are released, and return them to Earth through a parachute-less entry vehicle. Both NASA and ESA policies address the United Nations’ Outer Space Treaty by addressing potential harm from material returned from solar system bodies beyond the Earth-Moon system. In the conduct of Mars Sample Return, the two agencies have agreed to apply approaches consistent with their own standards to campaign elements each provides. This work presents the overall strategy for both forward and backward planetary protection for the ERO-CCRS mission. Specifically, for forward planetary protection, CCRS is not required to meet specific bioburden requirements as a Category III mission provided the ERO (1) meets orbital lifetime requirements during orbiter operations and (2) any elements jettisoned at Mars meet orbital lifetime requirements. CCRS is required to be built in ISO-8 or better cleanrooms and, by agreement with ERO, be compatible with direct bioburden verification methods. For backward planetary protection, the overall approach includes building robust, highly reliable systems to prevent inadvertent release of unsterilized Mars material through redundant containment vessels and particle transport analyses. Ongoing work to define verification approaches and quantify containment assurance levels for specific sample return systems will also be discussed, along with how those data will inform launch approval for ERO-CCRS.

Giuseppe Cataldo↗

Electrochemical Recycling of CO2

Carbon dioxide (CO2) is a molecule that plays multiple roles in our universe. Currently, its impact on global warming has rightfully given CO2 a label as a harmful waste product that must be amply handled. Nonetheless, under other circumstances, and from other perspectives, CO2 could be regarded as a valuable resource. As example, in nature CO2 is an essential building block in photosynthesis ultimately yielding molecules and materials that we harvest for numerous applications ranging from energy storage and construction to medicines and food. In a similar manner, there is a growing interest to utilize atmospheric CO2 to generate renewable fuels and platform chemicals through artificial processes. These processes can replace fossil based industrial processes on earth alleviating climate impact, but they can also find uses far away from our planet. In space, CO2 is an important source of precious oxygen, however, it can also serve as feedstock for carbon-based molecules and materials that are needed to sustain societies at distant planets such as Mars. In this presentation, I will discuss the contemporary understanding of electrochemical reduction of CO2 for selective production of desired molecules. We will zoom in to the very atomic scale to gain mechanistic understanding of how the structure and composition of the cathode electrode affects product distributions. This information is used as guide in the design of new materials that convert CO2 more efficiently and more selectively. On this basis, opportunities for recycling CO2 under different conditions will be discussed, as will remaining challenges for the ultimate application towards the sustainable human living on earth and in space.

electrochemistry↗

Adaptive Changes in Sensorimotor Coordination and Motion Sickness Following Repeated Exposures to Virtual Environments

Virtual environments offer unique training opportunities, particularly for training astronauts and preadapting them to the novel sensory conditions of microgravity. Two unresolved human factors issues in virtual reality (VR) systems are: 1) potential "cybersickness", and 2) maladaptive sensorimotor performance following exposure to VR systems. Interestingly, these aftereffects are often quite similar to adaptive sensorimotor responses observed in astronauts during and/or following space flight. Initial interpretation of novel sensory information may be inappropriate and result in perceptual errors. Active exploratory behavior in a new environment, with resulting feedback and the formation of new associations between sensory inputs and response outputs, promotes appropriate perception and motor control in the new environment. Thus, people adapt to consistent, sustained alterations of sensory input such as those produced by microgravity, unilateral labyrinthectomy and experimentally produced stimulus rearrangements. The purpose of this research was to compare disturbances in sensorimotor coordination produced by dome and head-mounted virtual environment displays and to examine the effects of exposure duration, and repeated exposures to VR systems. The first study examined disturbances in balance control, and the second study examined disturbances in eye-head-hand (EHH) and eye-head coordination.

Harm, D. L.↗

Opportunities for nutritional amelioration of radiation-induced cellular damage

The closed environment and limited evasive capabilities inherent in space flight cause astronauts to be exposed to many potential harmful agents (chemical contaminants in the environment and cosmic radiation exposure). Current power systems used to achieve space flight are prohibitively expensive for supporting the weight requirements to fully shield astronauts from cosmic radiation. Therefore, radiation poses a major, currently unresolvable risk for astronauts, especially for long-duration space flights. The major detrimental radiation effects that are of primary concern for long-duration space flights are damage to the lens of the eye, damage to the immune system, damage to the central nervous system, and cancer. In addition to the direct damage to biological molecules in cells, radiation exposure induces oxidative damage. Many natural antioxidants, whether consumed before or after radiation exposure, are able to confer some level of radioprotection. In addition to achieving beneficial effects from long-known antioxidants such as vitamins E and C and folic acid, some protection is conferred by several recently discovered antioxidant molecules, such as flavonoids, epigallocatechin, and other polyphenols. Somewhat counterintuitive is the protection provided by diets containing elevated levels of omega-3 polyunsaturated fatty acids, considering they are thought to be prone to peroxidation. Even with the information we have at our disposal, it will be difficult to predict the types of dietary modifications that can best reduce the risk of radiation exposure to astronauts, those living on Earth, or those enduring diagnostic or therapeutic radiation exposure. Much more work must be done in humans, whether on Earth or, preferably, in space, before we are able to make concrete recommendations.

Review↗

The Urban Environmental Monitoring/100 Cities Project: Legacy of the First Phase and Next Steps

The Urban Environmental Monitoring (UEM) project, now known as the 100 Cities Project, at Arizona State University (ASU) is a baseline effort to collect and analyze remotely sensed data for 100 urban centers worldwide. Our overarching goal is to use remote sensing technology to better understand the consequences of rapid urbanization through advanced biophysical measurements, classification methods, and modeling, which can then be used to inform public policy and planning. Urbanization represents one of the most significant alterations that humankind has made to the surface of the earth. In the early 20th century, there were less than 20 cities in the world with populations exceeding 1 million; today, there are more than 400. The consequences of urbanization include the transformation of land surfaces from undisturbed natural environments to land that supports different forms of human activity, including agriculture, residential, commercial, industrial, and infrastructure such as roads and other types of transportation. Each of these land transformations has impacted, to varying degrees, the local climatology, hydrology, geology, and biota that predate human settlement. It is essential that we document, to the best of our ability, the nature of land transformations and the consequences to the existing environment. The focus in the UEM project since its inception has been on rapid urbanization. Rapid urbanization is occurring in hundreds of cities worldwide as population increases and people migrate from rural communities to urban centers in search of employment and a better quality of life. The unintended consequences of rapid urbanization have the potential to cause serious harm to the environment, to human life, and to the resulting built environment because rapid development constrains and rushes decision making. Such rapid decision making can result in poor planning, ineffective policies, and decisions that harm the environment and the quality of human life. Slower, more thought-out, decision making could result in more favorable outcomes. The harm to the environment includes poor air quality, soil erosion, polluted rivers and aquifers, and loss of wildlife habitat. Human life is then threatened because of increased potential for disease spreading, human conflict, environmental hazards, and diminished quality of life. The built environment is potentially threatened when cities are built in areas that can be impacted by events such as hurricanes, tsunamis, earthquakes, fires, and landslides. Our goals include assessing the threat of such events on cities and the people living there.

Stefanov, William L.↗