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At least 109 records · Page 6

Mineral mapping at Cuprite, Nevada with a 63-channel imaging spectrometer

Geophysical and Environmental Research Imaging Spectrometer (GERIS) 63-channel scanner data covering the spectral region 0.4 to 2.5 microns were analyzed for the Cuprite mining district, Esmeralda and Nye Counties, Nevada. Individual and spatially averaged spectra extracted from the GERIS data were used to identify the minerals alunite, kaolinite, buddingtonite, and hematite by their spectral characteristics. The images were classified in the spectral domain to produce color-coded image maps of mineral distribution that clearly show the zoned nature of the hydrothermal system. Comparison of the thematic mineral maps with existing geologic and alteration maps demonstrates the utility of imaging spectrometers for producing detailed maps for mineral exploration.

Kruse, F. A.↗

Water resources and hydrology of Mars

The surface of Mars has been extensively modified by a large variety of water erosional and depositional processes. Although liquid water is presently unstable on the planet's surface, in its cold, hyperarid climate, there is abundant geomorphological evidence of past fluvial valley development multiple episodes of catastrophic flooding, periglacial landforms, ice-related permafrost, lake deposits, eroded impact craters and possible glacial landforms throughout much of Mars' geological history. The amount of water required to form such features is estimated to be equivalent to a planet-wide layer approximately 50 meters deep. Some of this water undoubtedly was removed from the planet by atmospheric escape processes, but much probably remains in the subsurface of Mars. Jakosky summarized the present partitioning of water on Mars, expressed as an average global depth, as follows: in the polar caps, 30 meters; in the megaregolith, 500 to 1000 meters; structurally bound in clays, 10 meters; and in high latitude regolith, a few meters. However, most of this water is probably in the form of ice, except in anomalous areas of possible near surface liquid water, and in regions where hydrothermal systems are still active. The best locations for prospecting are those areas where water or ice is sufficiently concentrated at shallow enough depths to make it feasible to pump out or mine.

Baker, V. R.↗

Fluvial valleys in the heavily cratered terrains of Mars: Evidence for paleoclimatic change?

Whether the formation of the Martian valley networks provides unequivocal evidence for drastically different climatic conditions remains debatable. Recent theoretical climate modeling precludes the existence of a temperate climate early in Mars' geological history. An alternative hypothesis suggests that Mars had a globally higher heat flow early in its geological history, bringing water tables to within 350 m of the surface. While a globally higher heat flow would initiate ground water circulation at depth, the valley networks probably required water tables to be even closer to the surface. Additionally, it was previously reported that the clustered distribution of the valley networks within terrain types, particularly in the heavily cratered highlands, suggests regional hydrological processes were important. The case for localized hydrothermal systems is summarized and estimates of both erosion volumes and of the implied water volumes for several Martian valley systems are presented.

Gulick, V. C.↗

The mineralogic evolution of the Martian surface through time: Implications from chemical reaction path modeling studies

Chemical reaction path calculations were used to model the minerals that might have formed at or near the Martian surface as a result of volcano or meteorite impact driven hydrothermal systems; weathering at the Martian surface during an early warm, wet climate; and near-zero or sub-zero C brine-regolith reactions in the current cold climate. Although the chemical reaction path calculations carried out do not define the exact mineralogical evolution of the Martian surface over time, they do place valuable geochemical constraints on the types of minerals that formed from an aqueous phase under various surficial and geochemically complex conditions.

Plumlee, G. S.↗

Exopaleontology and the search for a fossil record on Mars

Although present Martian surface conditions appear unfavorable for life as we know it, there is compelling geological evidence that the climate of early Mars was much more Earth-like, with a denser atmosphere and abundant surface water. The fact that life developed on the Earth within the first billion years of its history makes it quite plausible that life may have also developed on Mars. If life did develop on Mars, it is likely to have left behind a fossil record. This has led to the development of a new subdiscipline of paleontology, herein termed 'exopaleontology', which deals with the exploration for fossils on other planets. The most important factor enhancing microbial fossilization is the rapid entombment of microorganisms by fine-grained, stable mineral phases, such as silica, phosphate, or carbonate. The oldest body fossils on Earth are preserved in this way, occurring as permineralized cells in fine-grained siliceous sediments (cherts) associated with ancient volcanic terranes in Australia and South Africa. Modern terrestrial environments where minerals may precipitate in the presence of microorganisms include subaerial thermal springs and shallow hydrothermal systems, sub-lacustrine springs and evaporitic alkaline lakes, zones of mineralization within soils where 'hardpans' (e.g. calcretes, silcretes) form, and high latitude frozen soils or ground ice.

Farmer, Jack D.↗

Aldehydes in hydrothermal solution - Standard partial molal thermodynamic properties and relative stabilities at high temperatures and pressures

Aldehydes are common in a variety of geologic environments and are derived from a number of sources, both natural and anthropogenic. Experimental data for aqueous aldehydes were taken from the literature and used, along with parameters for the revised Helgeson-Kirkham-Flowers (HKF) equations of state, to estimate standard partial molal thermodynamic data for aqueous straight-chain alkyl aldehydes at high temperatures and pressures. Examples of calculations involving aldehydes in geological environments are given, and the stability of aldehydes relative to carboxylic acids is evaluated. These calculations indicate that aldehydes may be intermediates in the formation of carboxylic acids from hydrocarbons in sedimentary basin brines and hydrothermal systems like they are in the atmosphere. The data and parameters summarized here allow evaluation of the role of aldehydes in the formation of prebiotic precursors, such as amino acids and hydroxy acids on the early Earth and in carbonaceous chondrite parent bodies.

Schulte, Mitchell D.↗

ISSOL Meeting, Barcelona, Spain, 1993

Topics in a conference on the origins of life and the evolution of the biosphere include the origin of chirality, prebiotic chemistry of small biomolecules, primitive polymer formation, RNA regulation and control. Early origins of life and the ecology of hydrothermal systems such as ocean floor vents and their simple organisms are examined. The process of mineral catalysis in Montmorillonite as a model for early metabolism is used. The origin of the genetic code and the development of branching in molecular structures of amino acids is described. Studies are reported of the effects of meteorite impact on early Earth life.

Ferris, James P.↗

Potential Mars Surveyor 2001 Landing Sites Near Apollinaris Patera

Landing sites near Apollinaris Patera are proposed for the Mars Surveyor 2001 lander/rover mission. Regions near the base of Apollinaris Patera provide a unique opportunity within the proposed -15(beta)o 30(beta) latitude belt to sample outcrop lithologies ranging from highland Noachian basement rocks, to Hesperian aged lava flows, channel and flood plain materials, to Amazonian volcanic, ash flow, and channel deposits. Pristine impact craters exhibiting lobate ejecta blankets are found both on the volcano itself and on the surrounding terrain implying a ground water rich environment well into the Amazonian. Therefore its formation likely induced long-lived volcanic-hydrothermal systems, a high priority target for the mission.

Gulick, Virginia C.↗

Environmental Effects on Volcanic Eruptions:From Deep Ocean to Deep Space. Chapter 3. Volcanism and Ice Interactions on Earth and Mars

CONCLUSION Volcano/ice interactions produce meltwater. Meltwater can enter the groundwater cycle and under the influence of hydrothermal systems, it can be later discharged to form channels and valleys or cycled upward to melt permafrost. Water or ice-saturated ground can erupt into phreatic craters when covered by lava. Violent mixing of meltwater and volcanic material and rapid release can generate lahars or jokulhlaups, that have the ability to freight coarse material, great distances downslope from the vent. Eruption into meltwater generate unique appearing edifices, that are definitive indicators of volcano/ice interaction. These features are hyaloclastic ridges or mounds and if capped by lava, tuyas. On Earth, volcano/ice interactions are limited to alpine regions and ice-capped polar and temperate regions. On Mars, where precipitation may be an ancient phenomenon, these interactions may be limited to areas of ground ice accumulation or the northern lowlands where water may have ponded fairly late in martian history. The recognition of features caused by volcano/ice interactions could provide strong constraints for the history of volatiles on Mars.

Chapman, Mary G.↗

Atmospheric Energy Limits on Subsurface Life on Mars

It has been suggested that the terrestrial biomass of subterranean organisms may equal or exceed that at the surface. Taken as a group, these organisms can live in heavily saline conditions at temperatures from 115 C to as low as -20 C. Such conditions might exist on Mars beneath the surface oxidant in an aquifer or hydrothermal system, where the surrounding rock would also protect against the solar ultraviolet radiation. The way that such systems could obtain energy and carbon is not completely clear, although it is believed that on Earth, energy flows from the interaction of highly reduced basalt with groundwater produce H2, while carbon is derived from CO2 dissolved in the groundwater. Another potential source is the Martian atmosphere, acting as a photochemical conduit of solar insolation.

Weiss, B. P.↗

Potential Mars Surveyor 2001 Landing Sites Near Apollinaris Patera

Landing sites near Apollinaris Patera are proposed for the Mars Surveyor 2001 lander/rover mission. Regions near the base of Apollinaris Patera provide a unique opportunity within the proposed -15 deg to 30deg latitude belt to sample outcrop lithologies ranging from highland Noachian basement rocks, to Hesperian aged lava flows, channel and flood plain materials, to Amazonian volcanic, ash flow, and channel deposits. Pristine impact craters exhibiting lobate ejecta blankets are found both on the volcano itself and on the surrounding terrain implying a ground water rich environment well into the Amazonian. Therefore its formation likely induced long-lived volcanic-hydrothermal systems, a high priority target for the mission.

Gulick, Virginia C.↗

Gusev Crater Paleolake: Two-Billion Years of Martian Geologic, (and Biologic?) History

Ancient Martian lakes are sites where the climatological, chemical, and possibly biological history of the planet has been recorded. Their potential to keep this global information in their sedimentary deposits, potential only shared with the polar layered-deposits, designates them as the most promising targets for the ongoing exploration of Mars in terms of science return and global knowledge about Mars evolution. Many of the science priority objectives of the Surveyor Program can be met by exploring ancient Martian lake beds. Among martian paleolakes, lakes in impact craters represent probably the most favorable sites to explore. Though highly destructive events when they occur, impacts may have provided in time a significant energy source for life, by generating heat, and at the contact of water and/or ice, deep hydrothermal systems, which are considered as favorable environments for life. In addition, impact crater lakes are changing environments, from thermally driven systems at the very first stage of their formation, to cold ice-protected potential oases in the more recent Martian geological times. Thus, they are plausible sites to study the progression of diverse microbiologic communities.

Cabrol, N. A.↗

Hopanoid Biomarker Preservation In Coniform (Phormidium) Stromatolites in Siliceous Thermal Springs, Yellowstone National Park

The microbial communities that characterize modem hydrothermal ecosystems serve as modern analogs to those thought to have dominated early environments on Earth and possibly Mars. The importance of such hydrothermal systems as targets in exploring for an early biosphere on Mars is well established. Such work provides an important basis for the analysis of Martian samples associated with such environments. The surviving molecular structure and isotopic signature of diagnostic lipid biomarkers found as chemical fossils can provide a link between modern bacterially dominated ecosystems and their ancient counterparts. We are interested in the processes involved in the deposition and/or degradation of organic material in moderately thermal, silicifying microbial mats, particularly as this relates to the potential for preservation of some biomarker components known to be more highly resistant to microbial degradation. Several excellent biomarker molecules are associated with the cyanobacteria that dominate these mats, particularly the 2-methylbacteriohopanepolyols (2-MeBHP). These compounds are ubiquitous on Earth and are not easily degraded in nature, a fact documented by their detection in ancient Earth rocks dating back as far as 2,700 Ma.

Jahnke, Linda L.↗

Potential Mars Exploration Rover Landing Sites West and South of Apollinaris Patera

Apollinaris provides an exceptional site for astrobiological, geological, and climatalogical purposes. Fluvial (including ground water sapping) and associated processes were likely pervasive from the late Noachian, through the Hesperian, and into the Amazonian. Long-lived and large scale hydrothermal systems were certainly present throughout much if not all of this period. Thermal springs likely persisted for long periods. Water from the highlands via Ma'adim Valles and other smaller valley networks deposited highland-derived material in the area. In short, Apollinaris provides an excellent variety of rock types and ages and may preserve evidence of biologic or pre-biologic processes in associated thermal spring deposits.

Gulick, Virginia C.↗

A Strategy for Mars Exopaleontology

There is compelling geological evidence that the climate of early Mars was much more Earth-like, with a denser atmosphere and abundant surface water. Given that life developed on the Earth very quickly (between 4.2 and 3.5 Ga), it is quite plausible that life may have also developed on Mars during this early clement period. If Martian life developed, it is likely to have left behind a fossil record. Thus, an important focus for upcoming Mars missions is to explore for an ancient biosphere. This presents a set of goals and problems that are quite distinct from Exobiology. I call this new activity "Exopaleontology", whose core principles derive from studies of the Precambrian fossil record on Earth, biosedimentology and microbial fossilization. Such studies reveal that the most important factor favoring the long-term preservation of microbial fossils is rapid entombment of microorganisms by fine-grained, stable mineral phases such as silica, phosphate, carbonate and metal sulfides. Terrestrial environments where such aqueous mineral phases frequently entomb and preserve microorganisms include subaerial and subaqueous springs and shallow hydrothermal systems, evaporitic alkaline lakes, "hardpan" soils (e.g. calcretes, silcretes, ferracretes), and frozen soils or ground ice. With the exception of ice, which has a short crustal residence time, such deposits am known to retain a record of terrestrial life for billions of years. Current activities seek to refine and apply this strategy to the Mars Global Surveyor missions and beyond. Ongoing studies of microbial fossilization in each of the target environments identified above are aimed at improving our understanding of how biological information is incorporated into aqueous mineral deposits and preserved. Viking data is being used to target sites for high resolution orbital imaging and spectroscopy during upcoming Mars missions. Such data will provide a basis for selecting sites for future landed missions and eventually, sample return.

Farmer, Jack D.↗

In Situ Mineralogical Analysis of Planetary Materials Using X-Ray Diffraction and X-Ray Fluorescence

Remote observations of Mars have led scientists to believe that its early climate was similar to that of the early Earth, having had abundant liquid water and a dense atmosphere. One of the most fascinating questions of recent times is whether simple bacterial life developed on Mars (as it did on the Earth) during this early element period. Analyses of SNC meteorites have broadened considerably our knowledge of the chemistry of certain types of Martian rocks, underscoring the tantalizing possibility of early hydrothermal systems and even of ancient bacterial life. Detailed analyses of SNC meteorites in Terrestrial laboratories utilize the most sophisticated organic, isotopic and microscopic techniques in existence. Indeed; it is unlikely that the key biogenic indicators used in McKay et al (ibid) could be identified by a remote instrument on the surface of Mars. As a result, it is probable that any robotic search for evidence of an ancient Martian biosphere will have as its focus the identification of key minerals in likely host rocks rather than the direct detection of organic or isotopic biomarkers. Even on a sample return mission, mineralogical screening will be utilized to choose the most likely candidate rocks. X-ray diffraction (XRD) is the only technique that can provide a direct determination of the crystal structures of the phases present within a sample. When many different crystalline phases are present, quantitative analysis is better constrained if used in conjunction with a determination of elemental composition, obtainable by X-ray fluorescence (XRF) using the same X-ray source as for XRD. For planetary surface analysis, a remote instrument combining XRD and XRF could be used for mineralogical characterization of both soils and rocks. We are designing a remote XRD/XRF instrument with this objective in mind. The instrument concept pays specific attention to constraints in sample preparation, weight, volume, power, etc. Based on the geometry of a pinhole camera (transmission geometry, flat two-dimensional detector perpendicular to the direct beam), the instrument (which we call CHEMIN, for Chemistry and Mineralogy) uses an X-ray sensitive CCD detector which will allow concurrent positional and energy-dispersive analysis of collected photons. Thus XRF (energy) and XRD (geometry) analysis of transmitted X-rays will be performed at the same time. Tests performed with single minerals and simple mixtures give promising results. Refinements of the prototype promise interpretable results on complex samples.

Sarrazin, P.↗

Life in the Ice

The current Martian surface environment is extremely hostile to any known form of life. The combination of subfreezing temperature, low atmospheric pressure and high ultraviolet flux, combined with desiccated and possibly oxidizing soil, could destroy even the hardiest microorganisms. The Viking biology experiments are generally interpreted to indicate that the surface of Mars is currently devoid of life and organic molecules at the part-per-billion level. Speculation on the possibility of extant or preserved microbial life on Mars thus centers on refuges in some manner protected from the current surface environment, either in space or time. Terrestrial analogs include hydrothermal systems, lakes, caves and subsurface aquifers as well as more clement conditions in the distant past. We are examining the evidence for microbiology in Earth's glaciated polar regions as analogs to the polar caps of Mars. This research concerns the detection of microorganisms or their preserved remains at the surface and within polar glacial ice.

C C Allen↗