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NASA NTRS1976

Enhanced effects of starlight on the interstellar medium

The photodesorption of molecules and atoms from the surfaces of interstellar grains can be an important source of heating for the interstellar medium and the origin of instabilities which may separate grains and gas. For low densities, the force exerted on the grains is proportional to the gas density and independent of the radiation intensity; for high densities, it is proportional to the radiative flux and independent of the gas density. This force may act differently on grains of different sizes. The photoelectric effect may also be an efficient mechanism for the separation of gas and dust in diffuse clouds.

Gerola, H.↗

NASA NTRS1987

The local interstellar medium

The structure of the local interstellar medium is reviewed with emphasis on the new observations of the cold neutral component. The properties of the high latitude molecular clouds are discussed as well as their relationship to the 'infrared cirrus' and atomic gas. The molecular clouds are shown to lie preferentially along the loops and filaments of local H I gas, but a detailed examination shows the CO and H I peaks are offset from one another. An expansion velocity of 7 km/s is derived for one of the shells, suggesting an expansion energy of about 8 x 10 to the 47th ergs, which is somewhat smaller than that expected for a supernova explosion. If the pressure in the clumps of the high latitude clouds is in equilibrium with the surrounding gas, the pressure in the shells is 10,000-100,000/cu cm K, an order of magnitude higher than what is generally argued to exist in the interstellar medium.

Blitz, Leo↗

NASA NTRS1995

Interstellar Grain Surface Chemistry

Chemistry on grain surfaces plays an Important role in the formation of interstellar Ices, It can also influence the composition of the gas phase through outgassing near luminous, newly formed stars. This paper reviews the chemical processes taking place on Interstellar grain surfaces with the emphasis on those transforming CO into other hydrocarbons. At low, molecular cloud temperatures (approximately equal to 10K), physisorption processes dominate interstellar grain surface chemistry and GO is largely hydrogenated through reactions with atomic H and oxidized through reactions with atomic O. The former will lead to the formation of H2CO and CH3OH ices, while the latter results in CO2 ice. The observational evidence for these ices in molecular clouds will be discussed. Very close to protostars, the gas and grain temperatures are much higher (approximately equal to 500K) and chemisorption processes, including catalytic surface reactions, becomes important. This will be illustrated based upon our studies of the Fischer-Tropsch Synthesis of CH4 from CO on metallic surfaces. Likely, this process has played an important role in the early solar nebula. Observational consequences will be pointed out.

Tielens, Alexander G. G. M.↗

NASA NTRS1994

Gamma-ray observations of Ophiuchus with EGRET: The diffuse emission and point sources

Observations of the Ophiuchus region made with the Energetic Gamma-Ray Experiment Telescope (EGRET) on the Compton Gamma Ray Observatory (CGRO) during the first 2 1/2 years of operation show the diffuse emission from the interstellar gas in Ophiuchus as well as variable emission from two point sources. The gamma-ray emission is modeled in terms of cosmic-ray interactions with atomic and molecular hydrogen in Ophiuchus and with low-energy photons along the line of sight. The model also includes the flux from the two point sources and an isotropic diffuse contribution. The cosmic-ray density is assumed to be uniform. The derived ratio of molecular hydrogen column density to integrated CO intensity is (1.1 +/- 0.2) x 10(exp 20) H-mols/sq cm (K km/s)(exp -1). At the sensitivity and resolution of the gamma-ray data, no variation of this ratio over the modeled region is discernible, nor are any regions of enhanced cosmic-ray density apparent. The model was fitted to seven narrow energy bands to obtain the energy depedence of the gamma-ray production function and the spectra of the point sources. The derived production function is in good agreement with theoretical calculations and the local cosmic-ray electron and proton spectra. The positions of the point sources were determined from maximum likelihood analysis of the gamma-ray emission observed in excess of the diffuse model. We identify one point source with the quasar PKS 1622-253, which has an average flux, E greater than 100 MeV, of (2.5 +/- 0.5) x 10(exp -7) photons/sq cm/s and photon spectral index -1.9 +/- 0.3. The other source, denoted GRO J1631-27, has not yet been identified at other wavelengths. Its average flux, E greater than 100 MeV, is (1.1 +/- 0.4) x 10(exp -7) photons/sq cm/s; however, its spectral index is poorly determined. The spectral index and intensity of the isotropic contribution to the model agree well with the extragalactic diffuse emission derived from the SAS 2 data.

Hunter, S. D.↗

NASA NTRS1975

Hot hydrogen in prebiological and interstellar chemistry

Two articles discuss the recent experimental work of Hong et al. on the production of amino acids and gas-phase organic compounds from the ultraviolet irradiation of simple gases, with hot hydrogen atoms used as the principal energy conversion agent. The reaction possibilities involving frozen ices are mentioned in both articles, as well as the significance of three-body collisions in this situation.

Sagan, C.↗

NASA NTRS1987

Collisional excitation of interstellar sulfur dioxide

State-to-state rotational excitation rates for the asymmetric top molecule SO2 in collisions with low-energy He atoms have been computed. The intermolecular forces were obtained from an electron gas model, and collision dynamics were treated with the finite-order sudden approximation. The total excitation rate is probably accurate to better than 50 percent; however, individual state-to-state rates may be in error by factors of 2 or 3, and some smaller rates may be accurate only to an order of magnitude. Present results are expected to reflect within the same level of accuracy rates for excitation by collisions with H2 molecules.

Palma, Amedeo↗

NASA NTRS1985

Ultraviolet absorption by highly ionized halo gas near the Galactic center

Initial results are presented for a program to survey highly ionized gas in the Milky Way disk and halo. High-resolution IUE (International Ultraviolet Explorer) far-UV spectra were obtained for 12 stars at galactocentric distances less than 6 kpc. The stars are 0.7-2.2 kpc away from the plane. Most of the spectra contain exceedingly strong and broad interstellar absorption lines of weakly and highly ionized atoms. In addition to the normally strong lines of Si IV and C IV, strong interstellar NV lines have been detected in the spectra of eight stars. The detection of NV absorption (amounting to more than 10 times the predicted NV) provides an important new constraint on models for the origin of Galactic halo gas. A Galactic fountain operating in the presence of known UV and EUV radiation might explain the observations.

Savage, B. D.↗

NASA NTRS1980

Chemical and isotopic fractionation by grain size separates

Fractionation of refractory elements according to grain size is argued to occur during their growth. Two major modes should exist: (1) during thermal condensation sequences whenever the condensing phase (e.g. Mg2SiO4) does not alloy with the precondensed phase (e.g. MgAl2O4); (2) during accretion of gaseous atoms in the nonequilibrated interstellar medium. Processes dynamically sorting grains according to size (e.g. sedimentation) therefore are potentially capable of achieving fractionations normally attributed to separations of dust and gas. This paper considers the first mode during supernova condensation; however, it also can occur in an equilibrium solar condensation sequence owing to an overlooked freedom in that simplified description.

Clayton, D. D.↗

NASA NTRS1992

Heating the warm ionized medium

If photoelectric heating by grains within the diffuse ionized component of the interstellar medium is 10 exp -25 ergs/s per H atom, the average value within diffuse H I regions, then grain heating equals or exceeds photoionization heating of the ionized gas. This supplemental heat source would obviate the need for energetic ionizing photons to balance the observed forbidden-line cooling and could be responsible in part for enhanced intensities of some of the forbidden lines.

Reynolds, R. J.↗

NASA NTRS1978

The formation of molecules in interstellar clouds from singly and multiply ionized atoms

The suggestion is considered that multiply ionized atoms produced by K- and L-shell X-ray ionization and cosmic-ray ionization can undergo ion-molecule reactions and also initiate molecule production. The role of X-rays in molecule production in general is discussed, and the contribution to molecule production of the C(+) radiative association with hydrogen is examined. Such gas-phase reactions of singly and multiply ionized atoms are used to calculate molecular abundances of carbon-, nitrogen-, and oxygen-bearing species. The column densities of the molecules are evaluated on the basis of a modified version of previously developed isobaric cloud models. It is found that reactions of multiply ionized carbon with H2 can contribute a significant fraction of the observed CH in diffuse interstellar clouds in the presence of diffuse X-ray structures or discrete X-ray sources and that substantial amounts of CH(+) can be produced under certain conditions.

Langer, W. D.↗

NASA NTRS1979

Analysis of ultraviolet spectrophotometric data from Copernicus

Ultraviolet spectral data from the OAO 3 satellite are being used to study interstellar absorption lines and stellar and circumstellar lines in hot stars. The interstellar data are beneficial in analyzing the depletions of heavy elements from the gas phase and in elucidating how these depletions depend on physical conditions. Abundances in separate velocity components were determined from line profiles. Observations were carried out for interstellar abundances, both atomic and molecular, towards a number of stars. The better quality data are being analyzed for profile information and the lesser data are being used in curve-of-growth analyses. Molecular observations were carried out as well, N2 was sought; interstellar C2 was detected and its rotational excitation utilized to establish limits in interstellar cloud temperatures. An extensive search for H2O resulted in a tentative identification which will produce new information on chemical reaction rates. Interstellar depletions and grain properties in the rho Ophiuchi cloud, stellar wind variability, and circumstellar lines are also under study.

Snow, T. P., Jr.↗

NASA NTRS1987

Large scale dissociation of molecular gas in the sprial arms of M51

The distribution of the atomic and ionized hydrogen along the inner spiral arms of M51 are compared. As is the case in M83, the location of both these phases of the interstellar medium with respect to the major dust lanes suggests that molecular hydrogen is dissociated on kpc scales in active star-forming regions, and that this dissociation process may strongly affect the observed morphology of atomic hydrogen in spiral arms.

Tilanus, R. P. J.↗

NASA NTRS2009

Theoretical Modeling of Interstellar Chemistry

The chemistry of complex interstellar organic molecules will be described. Gas phase processes that may build large carbon-chain species in cold molecular clouds will be summarized. Catalytic reactions on grain surfaces can lead to a large variety of organic species, and models of molecule formation by atom additions to multiply-bonded molecules will be presented. The subsequent desorption of these mixed molecular ices can initiate a distinctive organic chemistry in hot molecular cores. The general ion-molecule pathways leading to even larger organics will be outlined. The predictions of this theory will be compared with observations to show how possible organic formation pathways in the interstellar medium may be constrained. In particular, the success of the theory in explaining trends in the known interstellar organics, in predicting recently-detected interstellar molecules, and, just as importantly, non-detections, will be discussed.

Charnley, Steven↗

NASA NTRS1991

Collisional excitation of formaldehyde in 'hot' interstellar molecular regions

Earlier calculations for rotational excitation of formaldehyde by collisions with He atoms are extended to include the lowest 81 rotational levels and kinetic temperatures to 300 K. Calculations are generally based on Green et al. (1978) but coupled differential equations are solved via a modified log-derivative propagator at low energies (Manolopoulos, 1986) and an R-matrix propagator at higher energies (Stechel, Walker, and Light, 1978). Consideration is given to the expected accuracy of the rates for excitation of formaldehyde by collisions with He atoms which are calculated in the present paper and to the expected differences between these rates and those for excitation by H2 molecules which comprise a larger fraction of the interstellar gas. The comparisons performed indicate that, for excitation by He, calculated state-to-state rates are likely to be 50 percent accurate, and total excitation rates, better than 20 percent. For excitation by H2, the rates should be increased by a factor of 2.2.

Green, Sheldon↗

NASA NTRS1980

Interstellar sulfur chemistry

The results of a chemical model of SO, CS, and OCS chemistry in dense clouds are summarized. The results are obtained from a theoretical study of sulfur chemistry in dense interstellar clouds using a large-scale time-dependent model of gas-phase chemistry. Among the results are the following: (1) owing to activation energy, the reaction of CS with O atoms is efficient as a loss mechanism of CS during the early phases of cloud evolution or in hot and oxygen-rich sources such as the KL nebula; (2) if sulfur is not abnormally depleted in dense clouds, then the observed abundances of SO, SO2, H2S, CS, OCS, H2CS, and SiS indicate that sulfur is mostly atomic in dense clouds; and (3) OCS is stable against reactions with neutral atoms and radicals in dense clouds.

Prasad, S. S.↗

NASA NTRS1993

Solar wind latitude variations and multiple scattering from Galileo interplanetary Lyman-alpha observations

The Galileo Ultraviolet Spectrometer Experiment (UVS) obtained a map of the celestial sphere from interplanetary Lyman-alpha (IPLA) on 13, 14 December 1990 during the Earth1 encounter. The Galileo spacecraft was near the downwind interstellar axis during the encounter and the map view directions filled the downwind hemisphere. The ratio between the observation and a single scattering model is attributed to a direct measurement of the multiple scattering correction required to model IPLA in the inner solar system. Analysis of this data set, referred to as an antisun map, shows that the solar wind charge exchange rate with interplanetary gas is 25 percent less over the solar poles than in the ecliptic at solar maximum. A model of the interstellar wind based on the antisun map observation exhibits a number density of atomic hydrogen far from the solar system, inside the heliosphere, of 0.16 +/- 0.05/cu cm.

Ajello, Joseph M.↗

NASA NTRS1995

A far-infrared spectral line survey of 23 infrared-bright Galaxy nuclei

We present results from a KAO survey of fine-structure lines observed in 23 infrared-luminous galaxies. One or more of the following lines was observed and/or detected in each galaxy: (S III) 19, 33 microns, (Ne V) 24 microns, (O IV) 26 microns, (Fe II) 26 microns, (Si II) 35 microns, (O III) 52, 88 microns, (0 I) 63, 146 microns, (N III) 57 micro ns, (N II) 122, 205 microns, (C II) 158 microns. The galaxies span a wide range of morphologies (irregular to grand design), have varying metallicities, and include mergers, AGN's, and starburst systems. The observations were made beginning in 1988 using the facility Cryogenic Grating Spectrometer onboard the KAO at a typical resolution of approximately 60-140 km/s and with a 30-44 deg beam. We interpret the (C II) and (O I) fluxes, along with previous measurements of the IR continuum fluxes, in the context of photo dissociation region (PDR) models (Tielens & Hollenbach 1985; Wolfire et al. 1990). With these models, we obtain estimates of the typical interstellar UV fields incident on the line emitting regions (102-104 times the local interstellar radiation field) and the total masses (10(exp 7)-10(exp 8) Solar Mass), densities (10(exp 3)-10(exp 4)/cu cm), and temperatures (100-250 K) of the warm atomic gas. The (O III) (52/88) and (S III) (33/19) line flux ratios constrain the range of electron densities and pressures found within the ionized regions. The (O III) and (S III) lines also provide estimates of the effective temperature of the ionizing stars and elemental abundances within the ionized regions of these galactic nuclei. Our measurements imply typical gas pressures of nT approximately 5 x 10(exp 6)/cu cm K and typical upper mass cutoffs of 25-35 Solar Mass. The low-metallicity systems show high (C II)/CO and (O I)/CO flux ratios, 3-5 times the Milky Way value, indicating that they contain a larger fraction of photodissociated gas relative to the molecular material.

Lord, Steven D.↗

NASA NTRS1994

The interstellar medium in the starburst regions of NGC 253 and NGC 3256

We discuss observations of the (C II) 158 micrometers, (O I) 63 micrometers, (Si II) 35 micrometers, (O III) 52,88 micrometers, and (S III) 33 micrometers fine-structure transitions toward the central 45 seconds of the starburst galaxies NGC 253 and NGC 3256. The (C II) and (O I) emission probably originates in photodissociated gas at the surfaces of molecular clouds, although a small (less than or approximately 30%) contribution to the (C II) flux from H II regions cannot be ruled out. The (O III) and (S III) lines originate in H II regions and the (Si II) flux is best explained as originating in H II regions with some contribution from photodissociation regions (PDRs). The gas phase silicon abundance is nearly solar in NGC 253, which we interpret as evidence for grain destruction in the starburst region. We find that the photodissociated atomic gas has densities approximately 10(exp 4)/cu cm and temperature 200-300 K. About 2% of the gas is in this phase. The thermal gas pressure in the PDRs, P(PDR)/k approximately 1-3 x 10(exp 6) K/cu cm, might represent the 'typical' interstellar gas pressure in starburst systems. The Far Ultraviolet (FUV) radiation fields illuminating the clouds are 10(exp 3)-10(exp 4) stronger than the local Galactic FUV field and come from the contribution of many closely packed O and B stars. For the central 250 pc of NGC 253, we find that the H II gas has an average density n(sub e) is approximately 400/cu cm. This corresponds to a thermal pressure P(H II)/k approximately 7 x 10(exp 6) K/cu cm which is approximately P(PDR)/k, suggesting that the ionized gas is in pressure equilibrium with the photodissociated gas at the surfaces of molecular clouds. The H II gas fills a significant fraction, approximately 0.01-0.3, of the volume between the clouds. The effective temperature of the ionizing stars in NGC 253 is greater than or approximately 34,500 K; 2 x 10(exp 5) O7.5 stars would produce the observed Lyman countinuum photon luminosity. The average separation between the stars is approximately 3 pc. Applying the simple model for the interstellar medium in galactic nuclei of Wolfire, Tielens, & Hollenbach (1990), we find the molecular gas in the central regions of NGC 253 and NGC 3256 to be distributed in a large number (5 x 10(exp 3) to 5 x 10(exp 5)) of small (0.5-2 pc), dense (approximately 10(exp 4)/cu cm) clouds (or alternatively 'thin-flattened' structures) with volume filling factors 10(exp -3) to 10(exp -2), very different from the local Interstellar Medium (ISM) of the Galaxy. We suggest a self-consistent scenario for the ISM in NGC 253 in which clouds and H II gas are in pressure balance with a supernova-shocked, hot 1-3 x 10(exp 6) K, low-density (approximately 10(exp 4)/cu cm), all pervasive medium. A feedback mechanism may be indicated in which the pressure generated by the supernovae compresses the molecular clouds and triggers further massive star formation. The similarity of ISM parameters deduced for NGC 253, NGC 3256, and M82 (Lord et al. 1993) suggests that the ISM properties are independent of the luminosity of the starburst or the triggering mechanism, but are rather endemic to starburst systems. The starburst in NGC 3256 appears to be a scaled-up version of the NGC 253 and M82 starbursts.

Carral, P.↗