SEARCH · Search NASA

Results for “kinetic distributions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

All sources NASA NTRS DOE OSTI

NASA NTRS1989

The cooling rate dependence of cation distributions in CoFe2O4

The room-temperature cation distributions in bulk CoFe2O4 samples, cooled at rates between less than 0.01 and about 1000 C/sec, have been determined using Mossbauer spectroscopy in an 80-kOe magnetic field. With increasing cooling rate, the quenched structure departs increasingly from the mostly ordered cation distribution ordinarily observed at room temperature. However, the cation disorder appears to saturate just short of a random distribution at very high cooling rates. These results are interpreted in terms of a simple relaxation model of cation redistribution kinetics. The disordered cation distributions should lead to increased magnetization and decreased coercivity in CoFe2O4.

De Guire, Mark R.↗

NASA NTRS1979

Spatial and time domain spectral energetics in the GLAS circulation model

Zonally averaged eddy kinetic energies and time domain energetics spectra were calculated for the GLAS general circulation model. The spatial results show significant improvements in the magnitude and distribution of the eddy kinetic energy. The spectral results provide a technique for tracing when and where the model predictions diverge from observations.

Tenenbaum, J.↗

NASA NTRS1998

Ion Energy Distributions and their Relative Abundance in Inductively Coupled Plasmas

Study of kinetics of ions and neutrals produced in high density inductively coupled plasma (ICP) discharges is of great importance for achieving a high degree of plasma assisted deposition and etching. In this paper, we present the ion energy distributions (IEDs) of various ions arriving at the grounded lower electrode. The ions were energy as well as mass analyzed by a combination of electrostatic analyzer-quadrupole mass spectrometer for pure Ar and CF4/Ar mixtures. The measurements have been made at gas pressures ranging from 30 to 100 mTorr. In addition, the IEDs were measured when the wafer-supporting electrode was also rf-powered and the effect of the self-bias was observed in the energy distributions of ions. The shapes of the IEDs are discussed an related to the sheath properties and measured electrical waveforms, as a function of pressure and applied power. Relative ion intensities were obtained by integration of each ion kinetic energy distribution function over its energy range.

Kim, J. S.↗

NASA NTRS1994

Kinetic aspects of reconnection at the magnetopause

Observations presented here support the kinetic (or single particle) description of reconnection where ions interacting with the magnetopause conserve their pitch angles or change them by equal amounts as in adiabatic motion. These observations include ion reflection and transmission at the magnetopause and time of flight effects associated with the magnetopause layers, with an emphasis here on ion reflection. Velocities of the reflected distributions predicted from this kinetic description are in good agreement with observed velocities. However, predicted velocities for the transmitted distributions are often higher than observed ones. Reflected distributions are also heated at the magnetopause; however, this heating is less important than the large scale ion motion. Reflection coefficients at the magnetopause are high (averaging 30%), appear to be the same on either side of the magnetopause, and have little or no dependence on ion mass. Time of flight effects result from the finite extent of the reconnection layers and are best observed at the edges of the layers.

Fuselier, Stephen A.↗

NASA NTRS1988

Growth of electron plasma waves above and below f(p) in the electron foreshock

This paper investigates the conditions required for electron beams to drive wave growth significantly above and below the electron plasma frequency, f(p), by numerically solving the linear dispersion equation. It is shown that kinetic growth well below f(p) may occur over a broad range of frequencies due to the beam instability, when the electron beam is slow, dilute, and relatively cold. Alternatively, a cold or sharp feature at low parallel velocities in the distribution function may drive kinetic growth significantly below f(p). Kinetic broadband growth significantly above f(p) is explained in terms of faster warmer beams. A unified qualitative theory for the narrow-band and broad-band waves is proposed.

Cairns, Iver H.↗

NASA NTRS1993

A multi-dimensional kinetic-based upwind solver for the Euler equations

A multidimensional kinetic fluctuation-splitting scheme has been developed for the Euler equations. The scheme is based on an N-scheme discretization of the Boltzmann equation at the kinetic level for triangulated Cartesian meshes with a diagonal-adaptive strategy. The resulting Euler scheme is a cell-vertex fluctuation-splitting scheme where fluctuations in the conserved-variable vector Q are obtained as moments of the fluctuation in the Maxwellian velocity distribution function at the kinetic level. Encouraging preliminary results have been obtained for perfect gases on Cartesian meshes with first-order spatial accuracy. The present approach represents an improvement to the well-established dimensionally-split upwind schemes.

Eppard, W. M.↗

NASA NTRS1990

Stratosphere chemistry in a 2-D model with residual circulation

The objective of this research was to examine the effects of chemical perturbations on the stratosphere using models which can incorporate fully interactive radiative, chemical, and dynamical responses, in the context of a zonally averaged model. Model runs for the unperturbed, chlorine-perturbed and simultaneously chlorine-and CO2-perturbed cases were completed using the JPL-87 chemical kinetics data. The base case was analyzed and submitted for publication. The perturbed cases show substantial sensitivity of the predicted column ozone depletion to the perturbations affecting lower stratosphere temperature, but less to far dynamical perturbations. The column ozone distribution changed substantially when the kinetics data was changed. This implies a greater-than-expected uncertainty in predicted latitude distributions of ozone depletion, due to uncertainty about the accuracy and completeness of the chemical kinetics data set.

Guthrie, Paul D.↗

NASA NTRS1994

Shock propagation and the generation of magnetohydrodynamic wave fields in inhomogeneous molecular clouds

We develop a simple one-dimensional model for the interaction of a steady, thin, planar shock wave with a nonrigid cloud which may be in motion relative to the surrounding medium, and we apply the model to shocks impinging on, and propagating through, molecular clouds. Both 'adiabatic' (gamma = 5/3) and radiative (gamma = 1) shocks are considered and we allow for the presence of a uniform magnetic field directed either parallel or perpendicular to the shock normal. The former field orientation is equivalent to the hydrodynamic case, and the latter involves only fast MHD shocks. We focus on the manner in which such shocks can generate internal kinetic motions in the cloud on a range of size and density scales through the direct acceleration of cores and clumps by shocks transmitted into them and through the generation of an MHD wavefield via the reflection of the incident shock at clump boundaries. We find that stronger incident Mach numbers and smaller density contrasts lead to more efficient cloud acceleration, as do isothermal intercloud shocks and small intercloud magnetic field strengths. The acceleration efficiency is insensitive to the adiabatic index and the magnetic field strength in the cloud itself. For typical parameter choices, the direct acceleration of clouds and clumps by strong shocks is found to be substantial and could at least in part account for their observed velocity dispersions. If the shocks are moderately weak, the final velocity of the cloud is linearly related to its initial velocity, with higher acceleration giving shallower slopes (i.e., final velocity distributions which are less sensitive to the initial distribution). Compared to the kinetic energy of the postshock cloud, the energy given to the wavefield at each encounter is small, and the heating of the interclump medium by the dissipation of this wavefield is found to be insufficient to balance the cooling rate in the cloud as a whole (although it may be important in particular regions), even if this medium is warm, unless it is also extremely tenuous (n approximately less than 0.1/cu cm). Nevertheless, the correction for the velocity imparted to the cloud leads to a substantial increase in the critical incident Mach numner for wave emission over that reported by Spitzer for the rigid case. The implications of our model for shock-induced star formation are discussed briefly.

Miesch, Mark S.↗

NASA NTRS1986

A kinetic model for the thermal nitridation of SiO2/Si

To explain the observed nitrogen distributions in thermally nitridated SiO2 films, a kinetic model is proposed in which the nitridation process is simulated, using the first-order chemical kinetics and Arrhenius dependence of the diffusion and reaction rates on temperature. The calculations show that initially, as the substrate reacts with diffusing nitrogen, a nitrogen-rich oxynitride forms at the SiO2-Si interface, while at nitridation temperatures above 1000 C, an oxygen-rich oxynitride subsequently forms at the interface, due to reaction of the substrate with an increasingly concentrated oxygen displaced by the slower nitridation of the SiO2. This sequence of events results in a nitrogen distribution in which the peak of the interfacial nitrogen concentration occurs away from the interface. The results are compared with the observed nitrogen distribution. The calculated results have correctly predicted the positions of the interfacial nitrogen peaks at the temperatures of 800, 1000, and 1150 C. To account for the observed width of the interfacial nitrogen distribution, it was found necessary to include in the simulations the effect of interfacial strain.

Vasquez, R. P.↗

NASA NTRS1982

Modulation of energetic particle fluxes by a mixed mode of transverse and compressional waves

Modulation characteristics of particle fluxes in the presence of a mixed mode of compressional and transverse magnetic waves at hydromagnetic frequencies are investigated through kinetic perturbation of the distribution function. The magnetospheric medium where the particles are modulated contains both the magnetic and pressure gradients. The modulation features are found to be strongly dependent on the energy and pitch angle of the particles. Drifting particles can resonate with waves whose phase velocities are close to their drift velocities. When this occurs, the modulation amplitudes become significantly large and large phase shifts will occur. It is pointed out that resonance is important for particles with mid pitch angles (40-70 deg). The phase shift between the particle modulations and the magnetic field oscillations are strongly controlled by the combined effects of transverse and compressional wave components and/or the occurrence of drift resonance. Numerical calculations are performed using the dispersion relation of drift mirror Alfven waves as an example of waves with both compressional and transverse components.

Lin, C. S.↗

NASA NTRS1982

Conference on Complex Turbulent Flows: Comparison of Computation and Experiment, Stanford University, Stanford, CA, September 14-18, 1981, Proceedings. Volume 2 - Taxonomies, reporters' summaries, evaluation, and conclusions

Computational techniques for simulating turbulent flows were explored, together with the results of experimental investigations. Particular attention was devoted to the possibility of defining a universal closure model, applicable for all turbulence situations; however, conclusions were drawn that zonal models, describing localized structures, were the most promising techniques to date. The taxonomy of turbulent flows was summarized, as were algebraic, differential, integral, and partial differential methods for numerical depiction of turbulent flows. Numerous comparisons of theoretically predicted and experimentally obtained data for wall pressure distributions, velocity profiles, turbulent kinetic energy profiles, Reynolds shear stress profiles, and flows around transonic airfoils were presented. Simplifying techniques for reducing the necessary computational time for modeling complex flowfields were surveyed, together with the industrial requirements and applications of computational fluid dynamics techniques.

Kline, S. J.↗

NASA NTRS1983

Kinetic effects on trace element partitioning

A potential difficulty regarding the application of trace element abundance data to problems in igneous petrogenesis is related to the possibility that partitioning of trace elements among minerals and melt may not be an equilibrium process. It may rather be controlled by kinetic processes, specifically the interplay between crystal growth and diffusion of the trace elements in crystals and melt. The present investigation has the objective to quantify kinetic effects on trace element partitioning. Crystals of olivine, pyroxene, and plagioclase were grown rapidly from synthetic melts resembling naturally-occurring mafic melts and doped with La, Sm, and Lu to quantify the magnitude of the effect of crystal growth rate on concentration of excluded trace elements. Olivine melt partitioning failed to show any appreciable kinetic effects, while diopside/melt distribution coefficients increased by 70 percent when the crystals grew very rapidly.

Lindstrom, D. J.↗

NASA NTRS1984

A study of the variability of ocean currents in the northwestern Atlantic using satellite altimetry

Altimeter data obtained from GEOS-3 during the three year period 1975-78 for a region of the western North Atlantic which includes a portion of the Gulf Stream system and part of the open ocean area of the subtropical gyre are analyzed by a new technique which utilizes all the points along the satellite tracks. The physical phenomenon studied are the time-variable but almost geostrophic currents, or mesoscale eddies, so that geoid errors contaminate the scientific signal minimally and the dynamical interpretation is direct. Results presented include the spatial distribution of geostrophic eddy kinetic energy and examples of a synoptic map of the eddy field (April 1977) and of a time series at a point. These results are compared to and synthesized with a diverse and select set of existing measurements and observations obtained in situ by a variety of instrumental techniques. The agreement is generally good, and the altimeter data analyzed provides new information on features in the map of mean eddy kinetic energy. The implications are that satellite altimetry will serve as a powerful quantitative tool in eddy current research and that even presently archived data contains further useful scientific information.

Robinson, A. R.↗

NASA NTRS1986

Grain boundary oxidation and fatigue crack growth at elevated temperatures

Fatigue crack growth rate at elevated temperatures can be accelerated by grain boundary oxidation. Grain boundary oxidation kinetics and the statistical distribution of grain boundary oxide penetration depth were studied. At a constant delta K-level and at a constant test temperature, fatigue crack growth rate, da/dN, is a function of cyclic frequency, nu. A fatigue crack growth model of intermittent micro-ruptures of grain boundary oxide is constructed. The model is consistent with the experimental observations that, in the low frequency region, da/dN is inversely proportional to nu, and fatigue crack growth is intergranular.

Liu, H. W.↗

NASA NTRS1986

Grain boundary oxidation and fatigue crack growth at elevated temperatures

Liu, H. W.↗

NASA NTRS1993

Plasma heating by collisionless magnetic reconnection - Analysis and computation

Analytic and numerical results on particle acceleration in 2D collisionless magnetic reconnection are presented. The particles are followed until they reach an outgoing flux surface at the same distance from the origin as the starting surface. The magnetic moment is not conserved for particles passing through the unmagnetized region around the X line at the origin. Other particles cross the separatrix without passing near the X line. The magnetic moment of the first class of outgoing particles is randomized, whereas it can be considered for the second class. The analytic model is based upon the observation of the final kinetic energy as a function of the initial conditions. Analytic results are shown to predict a Maxwellian tail for the distribution function in the perpendicular kinetic energy, with this energy much greater than the parallel kinetic energy. Numerical results showing that the predicted tail temperature agrees with the numerically computed temperature to within 10 percent over 4 orders of magnitude in the electric field are presented.

Moses, R. W.↗

NASA NTRS1993

Solar wind composition measurements by the Ulysses SWICS experiment during transient solar wind flows

For the March/April 1991 time period, the alpha/proton abundance ratio, the proton kinetic temperature and speed distributions, and the relative abundance of O(+7) to O(+6) is determined over each 13-minute duty cycle of the Solar Wind Ion Composition Spectrometer (SWICs) experiment on Ulysses. The ratio O(+7)/O(+6) (as a relative measure of ionization temperature) is shown to be useful in identifying possible coronal mass ejection (CME) events. We report measurements of silicon/oxygen abundance ratios and silicon and oxygen charge state distributions in the solar wind during a CME event and compare these compositions to a 'normal' solar wind time period.

Galvin, A. B.↗

NASA NTRS1994

Convective flow effects on protein crystal growth

A high-resolution microscopic interferometric setup for the monitoring of protein morphologies has been developed. Growth or dissolution of a crystal can be resolved with a long-term depth resolution of 200 A and a lateral resolution of 2 microns. This capability of simultaneously monitoring the interfacial displacement with high local depth resolution has yielded several novel results. We have found with lysozyme that (1) the normal growth rate is oscillatory, and (2) depending on the impurity content of the solution, the growth step density is either greater or lower at the periphery of a facet than in its center. The repartitioning of Na plus and Cl minus ions between lysozyme solutions and crystals was studied for a wide range of crystallization conditions. A nucleation-growth-repartitioning model was developed, to interpret the large body of data in unified way. The results strongly suggest that (1) the ion to lysozyne ratio in the crystal depends mostly on kinetic rather than crystallographic parameters, and (2) lysozyme crystals possess a salt-rich core with a diameter electron microscopy results appear to confirm this finding, which could have far-reaching consequences for x-ray diffraction studies. A computational model for diffusive-convective transport in protein crystallization has been applied to a realistic growth cell geometry, taking into account the findings of the above repartitioning studies and our kinetics data for the growth of lysozyme. The results show that even in the small cell employed, protein concentration nonuniformities and gravity-driven solutal convection can be significant. The calculated convection velocities are of the same order to magnitude as those found in earlier experiments. As expected, convective transport, i.e., at Og, lysozyme crystal growth remains kinetically limited. The salt distribution in the crystal is predicted to be non-uniform at both 1g and 0g, as a consequence of protein depletion in the solution. Static and dynamic light scattering studies in undersaturated and supersaturated solutions have been performed. Diffusivities in undersaturated solutions, were found to vary with lysozyme concentrations. Depending on the salt concentration, the diffusivities either increase or decrease. Interestingly, the corresponding static scattering intensities behave oppositely, Our current analysis indicates that these changes are inconsistent with aggregation in undersaturated solutions. However, the data are compatible with concentration-dependent changes of the interactions between protein and salt.

Rosenberger, Franz↗