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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

The Measurement of Sulfur Oxidation Products and Their Role in Homogeneous Nucleation

An improved version of a transverse ion source was developed which uses selected ion chemical ionization mass spectrometry techniques inside of a particle nucleation flow tube. These new techniques are very unique, in that the chemical ionization is done inside of the flow tube rather than by having to remove the compounds and clusters of interest which are lost on first contact,with any surfaces. The transverse source is also unique because it allows the ion reaction time to be varied over more than an order of magnitude, which in turn makes possible the separation of ion induced cluster growth from the charging of preexisting molecular clusters. As a result of combining these unique capabilities, the first ever measurements of prenucleation molecular clusters were performed. These clusters are the intermediate stage of growth in the gas-to-particle conversion process. This new technique provides a means of observing clusters containing 2, 3, 4, ... and up to about 8 sulfuric acid molecules, where the critical cluster size under these measurement conditions was about 4 or 5. Thus, the nucleation process can now be directly observed and even growth beyond the critical cluster size can be investigated. The details of this investigation are discussed in a recently submitted paper, which is included as Appendix A. Measurements of the diffusion coefficient of sulfuric acid and sulfuric acid clustered with a water molecule have also been performed. The measurements are also discussed in more detail in another recently submitted paper which is included as Appendix B. The empirical results discussed in both of these papers provide a critical test of present nucleation theories. They also provide new hope for resolving many of the huge discrepancies between field observation and model prediction of particle nucleation. The second part of the research conducted under this project was directed towards the development of new chemical ionization techniques for measuring sulfur oxidation products.

Eisele, F. L.↗
NASA NTRS1975

Criteria for identification of ablation debris from primitive meteoric bodies

Samples of ablated materials are analyzed to determine properties expected to be characteristic of particulates generated by the ablation of primitive meteoric bodies. Analyses of carbonaceous-chondrite fusion crusts and samples artificially ablated in the laboratory indicate that most meteor-ablation debris should consist of assemblages of silicate minerals, principally olivine, and micron-sized magnetic grains. It is expected that ablation debris of at least 10 microns should have abundances of Fe, Mg, Si, Ca, and Ni similar to those found in chondritic meteorites. Volatile species such as S, H2O, and Cl are lost during ablation and normally should not be found in ablated material. The major findings of this study are supported by analysis of spherules collected in the atmosphere which are thought, on separate grounds, to be genuine meteor-ablation products. The majority of meteoric bodies probably have cometary origins, and it is hoped that the ability to collect and identify meteor-ablation debris reliably will provide an opportunity to do laboratory analysis of cometary matter.-

Brownlee, D. E.↗
NASA NTRS1992

Chemical differentiation of a convecting planetary interior: Consequences for a one-plate planet such as Venus

Chemically depleted mantle forming a buoyant, refractory layer at the top of the mantle can have important implications for the evolution of the interior and surface. On Venus, the large apparent depths of compensation for surface topographic features might be explained if surface topography were supported by variations in the thickness of a 100-200 km thick chemically buoyant mantle layer or by partial melting in the mantle at the base of such a layer. Long volcanic flows seen on the surface may be explained by deep melting that generates low-viscosity MgO-rich magmas. The presence of a shallow refractory mantle layer may also explain the lack of volcanism associated with rifting. As the depleted layer thickens and cools, it becomes denser than the convecting interior and the portion of it that is hot enough to flow can mix with the convecting mantle. Time dependence of the thickness of a depleted layer may create episodic resurfacing events as needed to explain the observed distribution of impact craters on the venusian surface. We consider a planetary structure consisting of a crust, depleted mantle layer, and a thermally and chemically well-mixed convecting mantle. The thermal evolution of the convecting spherical planetary interior is calculated using energy conservation: the time rate of change of thermal energy in the interior is equated to the difference in the rate of radioactive heat production and the rate of heat transfer across the thermal boundary layer. Heat transfer across the thermal boundary layer is parameterized using a standard Nusselt number-Rayleigh number relationship. The radioactive heat production decreases with time corresponding to decay times for the U, Th, and K. The planetary interior cools by the advection of hot mantle at temperature T interior into the thermal boundary layer where it cools conductively. The crust and depleted mantle layers do not convect in our model so that a linear conductive equilibrium temperature distribution is assumed. The rate of melt production is calculated as the product of the volume flux of mantle into the thermal boundary layer and the degree of melting that this mantle undergoes. The volume flux of mantle into the thermal boundary layer is simply the heat flux divided by amount of heat lost in cooling mantle to the average temperature in the thermal boundary layer. The degree of melting is calculated as the temperature difference above the solidus, divided by the latent heat of melting. A maximum degree of melting is prescribed corresponding to the maximum amount of basaltic melt that the mantle can initially generate. As the crust thickens, the pressure at the base of the crust becomes high enough and the temperature remains low enough for basalt to transform to dense eclogite.

Parmentier, E. M.↗
NASA NTRS1973

Calculation of energy deposition distributions for simple geometries

When high-energy charged particles pass through a thin detector, the ionization energy loss in that detector is subject to fluctuations or straggling which must be considered in interpreting the data. Under many conditions, which depend upon the charge and energy of the incident particle and the detector geometry, the ionization energy lost by the particle is significantly different from the energy deposited in the detector. This problem divides naturally into a calculation of the energy loss that results in excitation and low-energy secondary electrons which do not travel far from their production points, and a calculation of energy loss that results in high-energy secondary electrons which can escape from the detector. The first calculation is performed using a modification of the Vavilov energy loss distribution. A cutoff energy is introduced above which all electrons are ignored and energy transferred to low energy particles is assumed to be equivalent to the energy deposited by them. For the second calculation, the trajectory of the primary particle is considered as a source of secondary high-energy electrons. The electrons from this source are transported using Monte Carlo techniques and multiple scattering theory, and the energy deposited by them in the detector is calculated. The results of the two calculations are then combined to predict the energy deposition distribution. The results of these calculations are used to predict the charge resolution of parallel-plate pulse ionization chambers that are being designed to measure the charge spectrum of heavy nuclei in the galactic cosmic-ray flux.

Watts, J. W., Jr.↗
NASA NTRS1993

Functional patterns in an annual grassland during an AVIRIS overflight

This study relates Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) imagery to ground measurements of vegetation distribution, physiology, and productivity at Stanford University's Jasper Ridge Biological Preserve. Primary efforts focused on a 9-ha region of annual grassland where we completed a detailed ground-based study in conjunction with a 15 May 1991 AVIRIS overflight. Spectral mixture analysis and the normalized difference vegetation index (NDVI) calculated from AVIRIS data were used to evaluate spatial patterns of vegetation type, productivity, and potential physiological activity. Concurrent ground sampling revealed a high degree of correlation between NDVI and estimates of canopy chemistry, structure, productivity, and CO2 flux, supporting the use of imaging spectrometry to estimate spatial and temporal trends in vegetation physiology and productivity in this relatively simple grassland ecosystem. Geostatistical analyses of both ground and AVIRIS data supported the conclusion that the AVIRIS pixel size was suitable for describing the influence of major landscape features in this grassland and that spatial detail would be lost at slightly larger pixel sizes typical of other imaging spectrometers.

Gamon, John A.↗
NASA NTRS2010

Microwave Plasma Hydrogen Recovery System

A microwave plasma reactor was developed for the recovery of hydrogen contained within waste methane produced by Carbon Dioxide Reduction Assembly (CRA), which reclaims oxygen from CO2. Since half of the H2 reductant used by the CRA is lost as CH4, the ability to reclaim this valuable resource will simplify supply logistics for longterm manned missions. Microwave plasmas provide an extreme thermal environment within a very small and precisely controlled region of space, resulting in very high energy densities at low overall power, and thus can drive high-temperature reactions using equipment that is smaller, lighter, and less power-consuming than traditional fixed-bed and fluidized-bed catalytic reactors. The high energy density provides an economical means to conduct endothermic reactions that become thermodynamically favorable only at very high temperatures. Microwave plasma methods were developed for the effective recovery of H2 using two primary reaction schemes: (1) methane pyrolysis to H2 and solid-phase carbon, and (2) methane oligomerization to H2 and acetylene. While the carbon problem is substantially reduced using plasma methods, it is not completely eliminated. For this reason, advanced methods were developed to promote CH4 oligomerization, which recovers a maximum of 75 percent of the H2 content of methane in a single reactor pass, and virtually eliminates the carbon problem. These methods were embodied in a prototype H2 recovery system capable of sustained high-efficiency operation. NASA can incorporate the innovation into flight hardware systems for deployment in support of future long-duration exploration objectives such as a Space Station retrofit, Lunar outpost, Mars transit, or Mars base. The primary application will be for the recovery of hydrogen lost in the Sabatier process for CO2 reduction to produce water in Exploration Life Support systems. Secondarily, this process may also be used in conjunction with a Sabatier reactor employed to stockpile life-support oxygen as well as propellant and fuel production from Martian atmospheric CO2

Atwater, James↗
NASA NTRS2020

Recovery, Restoration and Archiving of Previously Lost Data and Metadata from the Apollo Lunar Surface Experiments Package (ALSEP)

The Apollo Lunar Surface Experiments Package (ALSEP) is the name used to collectively represent the geophysical instruments deployed on the lunar surface by the astronauts on Apollo 12, 14, 15, 16, and 17. These instruments were active from the times of their deployment (November 1969 – December 1972) to September 1977. During that time, fourteen types of experiments were conducted, and their data were transmitted to Earth. The experiment PIs processed them. At the conclusion of the experiments, some of these data were submitted to the NASA Space Science Data Coordinated Archive (NSSDCA) for archiving, while others were not. The raw instrument data received from the Moon prior to March 1976 were not archived, either. The unarchived data, resided on open-reel magnetic tapes, became lost in the decades since, along with much of the metadata (the information necessary/useful in properly processing/analyzing the data). This article retraces the history of the ALSEP data archiving efforts in the 1970s, the subsequent loss of the data tapes, and the search, recovery, and restoration of the lost data by contemporary researchers in the 21st century. In 2006, NSSDCA began reformatting some of the ALSEP data archived in the 1970s to conform with the current Planetary Data System (PDS). In 2010, 440 of the previously lost magnetic tapes containing the raw ALSEP data were recovered. From these tapes, the data were extracted, re-packaged for individual experiments, and, for those with sufficient metadata, processed into higher order data readily usable by researchers. All of these data products have been recently archived with either PDS or NSSDCA. These newly restored data fill a number of gaps in the previously existing archive of the ALSEP data. In addition, tens of thousands of pages of Apollo era documents have been optically scanned and compiled into an online searchable catalog. This article also describes the content, organization, and usage of the restored raw ALSEP data and metadata.

S Nagihara↗
NASA NTRS1984

LEO atomic oxygen effects on spacecraft materials: STS-5 results

Effects of low Earth orbit (LEO) atomic oxygen were measured on a variety of spacecraft materials which obtained exposure on STS-5. Material degradation dependency on temperature was found in one material. Of the five paints flown, only S13GLO was unaffected. Generally, the glossy paints became Lambertian and the diffuse coatings improved. Scanning electron microscope examinations indicated removal of urethane and epoxy paint binder materials. Reaction products were evident on the surfaces of Z302 paint and Mylar. Thin films showed thickness losses ranging from negligible loss in Teflon to considerable loss in Mylar and Kapton. Glossy films such as black Kapton and white Tedlar became diffused. Kevlar 29 rope lost tensile strength and silver solar cell interconnect material oxidized. Oxidation on the backside of an elevated specimen indicated that reflections of oxygen atoms were occurring and that reflecting surfaces, probably Kapton, were not fully accommodating the incident atoms.

Whitaker, A. F.↗
NASA NTRS2003

Questions Revisited: A Close Examination of Calculus of Inference and Inquiry

In this paper I examine more closely the way in which probability theory, the calculus of inference, is derived from the Boolean lattice structure of logical assertions ordered by implication. I demonstrate how the duality between the logical conjunction and disjunction in Boolean algebra is lost when deriving the probability calculus. In addition, I look more closely at the other lattice identities to verify that they are satisfied by the probability calculus. Last, I look towards developing the calculus of inquiry demonstrating that there is a sum and product rule for the relevance measure as well as a Bayes theorem. Current difficulties in deriving the complete inquiry calculus will also be discussed.

Knuth, Kevin H.↗
NASA NTRS1988

The growth of continents and some consequences since 1.5 Ga

The budget of Earth's oceanic sediment masses was discussed in terms of crustal growth and recycling. Based on estimates of the volume of oceanic sediments and the average age of oceanic crust, a continental denudation rate of 1.65 cu km/yr was computed. This crudely balances estimated crustal production rates of about 1 cu km/yr, but the efficiency of sediment loss via subduction, for example, must be considered. It was argued, on the basis of earthquake focal solutions, imagery of subduction zones, and plate kinematic reconstructions that little, if any, sediment was lost in this way. This yields a present day crustal growth rate of about 1 cu km/yr. The volume of continents to 1.5 Ga ago was discussed, assuming constant continental thickness and freeboard, and a constant hydrosphere volume. It was concluded that ocean ridge length was a factor of about 1.75 greater 1.5 Ga ago, but a major uncertainty is the average spreading rate in the past.

Howell, David G.↗
NASA NTRS2016

Self-Cleaning Boudouard Reactor for Full Oxygen Recovery from Carbon Dioxide

Oxygen recovery from respiratory carbon dioxide is an important aspect of human spaceflight. Methods exist to sequester the carbon dioxide, but production of oxygen needs further development. The current International Space Station Carbon Dioxide Reduction System (CRS) uses the Sabatier reaction to produce water (and ultimately breathing air). Oxygen recovery is limited to 50% because half of the hydrogen used in the Sabatier reactor is lost as methane, which is vented overboard. The Bosch reaction, which converts carbon dioxide to oxygen and solid carbon is capable of recovering all the oxygen from carbon dioxide, and is the only real alternative to the Sabatier reaction. However, the last reaction in the cycle, the Boudouard reaction, produces solid carbon and the resulting carbon buildup will eventually foul the nickel or iron catalyst, reducing reactor life and increasing consumables. To minimize this fouling and increase efficiency, a number of self-cleaning catalyst designs have been created. This paper will describe recent results evaluating one of the designs.

Oxygen recovery↗
NASA NTRS2016

Self-Cleaning Boudouard Reactor for Full Oxygen Recovery from Carbon Dioxide

Oxygen recovery from respiratory carbon dioxide is an important aspect of human spaceflight. Methods exist to sequester the carbon dioxide, but production of oxygen needs further development. The current International Space Station Carbon Dioxide Reduction System (CRS) uses the Sabatier reaction to produce water (and ultimately breathing air). Oxygen recovery is limited to 50% because half of the hydrogen used in the Sabatier reactor is lost as methane which is vented overboard. The Bosch reaction, which converts carbon dioxide to oxygen and solid carbon, is capable of recovering all the oxygen from carbon dioxide, and it is a promising alternative to the Sabatier reaction. However, the last reaction in the cycle, the Boudouard reaction, produces solid carbon, and the resulting carbon buildup eventually fouls the catalyst, reducing reactor life and increasing consumables. To minimize this fouling and increase efficiency, a number of self-cleaning catalyst designs have been created. This paper will describe recent results evaluating one of the designs.

ECLSS↗
NASA NTRS2016

Self-Cleaning Boudouard Reactor for Full Oxygen Recovery from Carbon Dioxide

Oxygen recovery from respiratory carbon dioxide is an important aspect of human spaceflight. Methods exist to sequester the carbon dioxide, but production of oxygen needs further development. The current International Space Station Carbon Dioxide Reduction System (CRS) uses the Sabatier reaction to produce water (and ultimately breathing air). Oxygen recovery is limited to 50 because half of the hydrogen used in the Sabatier reactor is lost as methane, which is vented overboard. The Bosch reaction, which converts carbon dioxide to oxygen and solid carbon is capable of recovering all the oxygen from carbon dioxide, and is the only real alternative to the Sabatier reaction. However, the last reaction in the cycle, the Boudouard reaction, produces solid carbon and the resulting carbon buildup will eventually foul the nickel or iron catalyst, reducing reactor life and increasing consumables. To minimize this fouling and increase efficiency, a number of self-cleaning catalyst designs have been created. This paper will describe recent results evaluating one of the designs.

Oxygen Recovery↗
NASA NTRS1995

Shielding materials for highly penetrating space radiations

Interplanetary travel involves the transfer from an Earth orbit to a solar orbit. Once outside the Earth's magnetosphere, the major sources of particulate radiation are solar cosmic rays (SCR's) and galactic cosmic rays (GCR's). Intense fluxes of SCR's come from solar flares and consist primarily of protons with energies up to 1 GeV. The GCR consists of a low flux of nuclei with energies up to 10(exp 10) GeV. About 70 percent of the GCR are protons, but a small amount (0.6 percent) are nuclei with atomic numbers greater than 10. High energy charged particles (HZE) interact with matter by transferring energy to atomic electrons in a Coulomb process and by reacting with an atomic nucleus. Energy transferred in the first process increases with the square of the atomic number, so particles with high atomic numbers would be expected to lose large amounts of energy by this process. Nuclear reactions produced by (HZE) particles produce high-energy secondary particles which in turn lose energy to the material. The HZE nuclei are a major concern for radiation protection of humans during interplanetary missions because of the very high specific ionization of both primary and secondary particles. Computer codes have been developed to calculate the deposition of energy by very energetic charged particles in various materials. Calculations show that there is a significant buildup of secondary particles from nuclear fragmentation and Coulomb dissociation processes. A large portion of these particles are neutrons. Since neutrons carry no charge, they only lose energy by collision or reaction with a nucleus. Neutrons with high energies transfer large amounts of energy by inelastic collisions with nuclei. However, as the neutron energy decreases, elastic collisions become much more effective for energy loss. The lighter the nucleus, the greater the fraction of the neutron's kinetic energy that can be lost in an elastic collision. Thus, hydrogen-containing materials such as polymers are most effective in reducing the energy of neutrons. Once neutrons are reduced to very low energies, the probability for undergoing a reaction with a nucleus (the cross section) becomes very high. The product of such a reaction is often radioactive and can involve the release of a significant amount of energy. Thus, it is important to provide protection from low energy neutrons during a long duration space flight. Among the light elements, lithium and boron each have an isotope with a large thermal neutron capture cross section, Li-6 and B-10. However, B-10 is more abundant in the naturally-occurring element than Li-6, has a thermal neutron capture cross section four times that of Li-6, and produces the stable products, He-4 and Li-7 in the interaction while Li-6 produces radioactive tritium (H-3). Thus, boron is the best light-weight material for thermal neutron absorption in spacecraft. The work on this project was focused in two areas: computer design where existing computer codes were used, and in some cases modified, to calculate the propagation and interactions of high energy charged particles through various media, and materials development where boron was incorporated into high performance materials.

Kiefer, Richard L.↗
NASA NTRS1987

Exosat observations of 4U/MXB 1636-53 - On the relation between the amount of accreted fuel and the strength of an X-ray burst

During Exosat observations of 4U/MXB 1636-53 in August 1985, three bursts were observed in 6 h and 24 bursts in 79 h of uninterrupted observation. The burst times, burst fluences, peak burst fluxes, burst rise times, decay times, burst intervals, mean persistent fluxes, and the product of the latter two are listed, analyzed, and discussed. The implications of the results for thermonuclear flash models are examined. A model which fits the data well involves bursts which suffer from nuclear energy losses due to stable hydrogen burning between bursts. Thus, the percentage of 'lost' energy increases with increasing burst intervals. For individual bursts, however, there are significant deviations from the approximate linear relationship.

Lewin, W. H. G.↗
NASA NTRS2001

Air Charter - The Business Airline of the Future...But, Does the Business Traveler Know?

Historically, FAR Part 121 commercial carriers have provided efficient, economical and safe air transportation for corporate and business users. Recently, however, corporate and business travelers find their travel plans disrupted by delays, bankruptcies, poor service, lost baggage, fare increases, labor strikes and other systemic difficulties that degrade their travel experience to unsatisfactory levels. This article examines these Part 121 service delivery problems and, utilizing a tripartite investigative methodology, examines an alternative air transport mode: FAR Part 135 on-demand charter travel products. This long extant segment of our national air transportation system is set prime to support increased demand for charter services. Corporate and business travelers are set prime to utilize viable, cost effective alternatives to commercial travel products. Two research questions emerge. First is whether corporate and business travelers are aware of Part 135 travel alternatives. Second is whether Part 135 charter service providers are aware of this latent demand and are effectively targeting this demand segment in their marketing efforts. The three-part surveys employed to investigate these questions examined demand side

Kaps, Robert W.↗
NASA NTRS2008

Land-use and Land-cover Change from 1974 to 2008 around Mobile Bay

This project is a Gulf of Mexico Application Pilot in which NASA Stennis Space Center (SSC) is working within a regional collaboration network of the Gulf of Mexico Alliance. NASA researchers, with support from the NASA SSC Applied Science Program Steering Committee, employed multi-temporal Landsat data to assess land-use and land-cover (LULC) changes in the coastal counties of Mobile and Baldwin, AL, between 1974 and 2008. A multi-decadal time-series, coastal LULC product unique to NASA SSC was produced. The geographic extent and nature of change was quantified for the open water, barren, upland herbaceous, non-woody wetland, upland forest, woody wetland, and urban landscapes. The National Oceanic and Atmospheric Administration (NOAA) National Coastal Development Data Center (NCDDC) will assist with the transition of the final product to the operational end user, which primarily is the Mobile Bay National Estuary Program (MBNEP). We found substantial LULC change over the 34-year study period, much more than is evident when the change occurring in the last years. Between 1974 and 2008, the upland forest landscape lost almost 6% of the total acreage, while urban land cover increased by slightly more than 3%. With exception to open water, upland forest is the dominant landscape, accounting for about 25-30% of the total area.

Ellis, Jean↗
NASA NTRS1976

History of the dust released by comets

The Finson-Brobstein theory is used to examine production and history of dust released from periodic comets and to compare dust size distribution in relation to the Zodiacal cloud. Results eliminate all of the bright new comets from contributors to the Zodiacal cloud. Among the periodic comets, all particles of size much smaller than 10 micrometer are also lost. Only the large particles remain as possible contributors.

Jambor, B. J.↗