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At least 109 records · Page 6

Synthesis, Structure, and Characterization of Cu4S10(4-methylpyridine)4

The title compound, Cu4S10(4-methylpyridine)(sub 4) (dot) 4-methylpyridine was prepared by three different reactions: the oxidation of copper powder by sulfur and the reaction of copper (I) sulfide (or CuBr (dot) SMe2) with excess sulfur, both in the coordinating solvent, 4-methylpyridine. Red crystals of the compound obtained by layering with hexanes were subjected to single crystal X-ray diffraction. The structure was refined to R = 0.026 and R(sub w) = 0.036 in a space group P1bar (No. 2), with Z = 2, a = 13.983 (2) A, b = 15.384 (2) A, c = 9.660 (1) A, alpha = 93.87 (1)deg., beta = 93.38 (1)deg., gamma = 99.78 (1)deg., V = 2037.9 (9) A(exp 3). The compound has approximate S(sub 4) symmetry and consists of two pentasulfide chains linking four Cu(I) ions, each with a corrdinating 2-methylpyridine. The infrared spectrum was dominated by absorption due to coordinated 4-methylpyridine with several low-energy peaks attributable to S-S stretches, which were also observed by Raman spectroscopy. A featureless electronic absorption spectrum yielded a single peak in the near ultraviolet upon computer enhancement (lambda = 334 nm, epsilon = 10,000), most likely an intraligand transition. Cyclic voltammetry indicates that the polysulfide complex undergoes irrversible oxidation and reduction at +0.04 and -0.34 V vs. SCE, respectively, at 298 K in 4-methylpyridine when swept at 20 mV/sec. The electrochemical behavior was unvaried even at sweep rates as high as 100 V/sec.

Hepp, Aloysius F.↗

Cosmogenic Cl-36 production rates in meteorites and the lunar surface

Activity vs. depth profiles of cosmic ray produced Cl-36 were measured in metal from two cores each in the St. Severin and Jilin chondrites and in lunar core 15008. Production of Cl-36 in these samples range from high-energy reactions with Fe and Ni to low-energy reactions with Ca and K and possibly neutron-capture reactions with Cl-36. The cross sections used in the Reedy-Arnold model for neutron-induced reactions were adjusted to get production rates that fit the measured Cl-36 activities in St. Severin metal and in the lunar soil of core 15008. The Cl-36 in metal from St. Severin has a fairly flat activity-vs-depth profile, unlike most other cosmogenic nuclides in bulk samples from St. Severin, which increase in concentration with depth. In metal from Jilin, a decrease in Cl-36 was observed near its center. The length of Jilin's most recent cosmic-ray exposure was approximately 0.5 My. Lunar core 15008 has an excess in Cl-36 of about 4 dpm/kg near its surface that was produced by solar-proton-induced reactions. The calculated production rates are consistent with these measured trends in 15008.

Nishiizumi, K.↗

Feasibility and Utility of a Cryogenic Integrated RCS

Traditional in-space propulsion systems use storable propellants, such as MMH/NTO, for applications beyond Low Earth Orbit (LEO). Modern advancements in Cryogenic Fluid Management (CFM) technologies opens the door for use of more efficient cryogenic propellants, such as LOX/LCH4 or LOX/LH2, in these long-duration missions beyond LEO. As these Main Propulsion Systems (MPS) transition to cryogenic propellants, a cryogenic solution for Reaction Control Systems (RCS) becomes attractive for several reasons. A mixed-fluid vehicle solution with cryogenic (cool) MPS and storable (warm) RCS complicates thermal management. Additionally, a vehicle with common cryogenic propellant across the MPS and RCS could take advantage of shared hardware such as tanks, thermal management equipment, and pressurization system, reducing mass and development time. The fluid system design proposed in this presentation features shared hardware, leading to the designation of Cryogenic Integrated Reaction Control System (iRCS). The iRCS design stores cryogenic propellant in the low-pressure (10’s psia) MPS tanks, creates steady high-pressure (100’s psia) flow through an electric pump (e-pump), feeds pulse-firing RCS thrusters, and returns any excess flow to the tank through a pressure control device on a recirculation line. This iRCS design is inspired by the automotive fuel-rail, where similar elevated-pressure and pulse-firing requirements are levied. This design has several inherent advantages. Because this design is pump-fed rather than pressure-fed, heavy, high-pressure propellant storage is not required. The RCS propellant can therefore be stored by increasing MPS tank volume. Furthermore, by increasing the pressure of the circulated fluid through an e-pump, the propellant quality moves further into the sub-cooled regime. Sub-cooled liquid is desirable for accurate pressure and flow control at the thruster inlet. Lastly, the iRCS allows the distribution system hardware to maintain cryogenic temperatures by slowly recirculating liquid in a low-energy “Idle Mode”. Altogether, the iRCS concept enables a more efficient cryogenic vehicle design.

Integrated Reaction Control System↗

Feasibility and Utility of a Cryogenic Integrated RCS

Traditional in-space propulsion systems use storable propellants, such as MMH/NTO, for applications beyond Low Earth Orbit (LEO). Modern advancements in Cryogenic Fluid Management (CFM) technologies opens the door for use of more efficient cryogenic propellants, such as LOX/LCH4 or LOX/LH2, in these long-duration missions beyond LEO. As these Main Propulsion Systems (MPS) transition to cryogenic propellants, a cryogenic solution for Reaction Control Systems (RCS) becomes attractive for several reasons. A mixed-fluid vehicle solution with cryogenic (cool) MPS and storable (warm) RCS complicates thermal management. Additionally, a vehicle with common cryogenic propellant across the MPS and RCS could take advantage of shared hardware such as tanks, thermal management equipment, and pressurization system, reducing mass and development time. The fluid system design proposed in this presentation features shared hardware, leading to the designation of Cryogenic Integrated Reaction Control System (iRCS). The iRCS design stores cryogenic propellant in the low-pressure (10’s psia) MPS tanks, creates steady high-pressure (100’s psia) flow through an electric pump (e-pump), feeds pulse-firing RCS thrusters, and returns any excess flow to the tank through a pressure control device on a recirculation line. This iRCS design is inspired by the automotive fuel-rail, where similar elevated-pressure and pulse-firing requirements are levied. This design has several inherent advantages. Because this design is pump-fed rather than pressure-fed, heavy, high-pressure propellant storage is not required. The RCS propellant can therefore be stored by increasing MPS tank volume. Furthermore, by increasing the pressure of the circulated fluid through an e-pump, the propellant quality moves further into the sub-cooled regime. Sub-cooled liquid is desirable for accurate pressure and flow control at the thruster inlet. Lastly, the iRCS allows the distribution system hardware to maintain cryogenic temperatures by slowly recirculating liquid in a low-energy “Idle Mode”. Altogether, the iRCS concept enables a more efficient cryogenic vehicle design.

Integrated↗

Ultrafast Formation of Jahn–Teller Polarons Revealed by State-Selective Excitation in Correlated Spinel Co 3 O 4

Jahn–Teller polarons are quasiparticles that stem from symmetry breaking and strong local electron–phonon coupling. They originate from an excess charge carrier being dressed by a local lattice distortion, caused by the Jahn–Teller effect, and they critically impact electrical, structural, and magnetic properties in transition metal oxides. The observation of the microscopic steps involved in their formation is essential for enabling control over material properties through the targeted activation of local, site-specific modifications with light pulses. While Jahn–Teller distortion associated with polaron formation was predicted to contribute significantly to changes in electronic band gap and optical properties in Co 3 O 4 , its experimental observation remains elusive, requiring signatures of local symmetry reduction. In this work, we demonstrate Jahn–Teller polaron formation in spinel Co 3 O 4 . By exciting electronic transitions at 3.10 eV and 1.55 eV, we target either the Oh Cobalt(III) or the Td Cobalt(II) ions, and drive the subsequent coherent responses of the system through two different pathways. For the former, we demonstrate that ligand-to-metal charge transfer leads to Jahn–Teller polaron formation, which is linked to the deformation potential and magnetoelastic coupling. For the latter, we identify the coherent excitation of a T 2g phonon mode launched by on-site d-d electronic transitions. Key to our observations is the ability to target site-specific electronic excitations in spinel Co 3 O 4 using ultrafast optical pulses, while monitoring the ensuing low-energy collective modes through the coherent time-domain response of the material. Our approach, which combines the comparative analysis of experimental fingerprints with the support from density functional theory calculations, is broadly applicable to systems in which Jahn–Teller polaron physics has been theoretically predicted but remains experimentally unverified, and it underscores the potential of electronic-state targeting as a route to selectively excite and probe quasiparticle dynamics in solids.

Lattices↗

Photoinitiator Selection and Concentration in Photopolymer Formulations towards Large-Format Additive Manufacturing

Photopolymers are an attractive option for large-format additive manufacturing (LFAM), because they can be formulated from structural thermosets and cure rapidly in ambient conditions under low-energy ultraviolet light-emitting diode (UV LED) lamps. Photopolymer cure is strongly influenced by the depth penetration of UV light, which can be limited in the 2–4 mm layer thicknesses typical of LFAM. Photoinitiator (PI) systems that exhibit photobleaching have proven useful in thick-section cure applications, because they generate a photoinitiation wavefront, but this effect is time-dependent. This study investigates the light transmission and through-thickness cure behavior in (meth)acrylate photopolymer formulations with the photobleaching initiator bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide (BAPO). Utilizing an optical model developed by Kenning et al., lower concentrations (0.1 wt% to 0.5 wt%) of BAPO were predicted to yield rapid onset of photoinitiation. In situ cure measurements under continuous UV LED irradiation of 380 mW/cm2 showed that a 0.1 wt% concentration of BAPO achieved peak polymerization rate within 2.5 s at a 3-mm depth. With only 1 s of irradiation at 1.7 W/cm2 intensity, the 0.1 wt% BAPO formulation also achieved the highest level of cure of the formulas tested. For an irradiation dose of 5.5 J/cm2 at a duration of 3.7 s, cured polymer specimens achieved a flexural strength of 108 MPa and a flexural modulus of 3.1 GPa. This study demonstrates the utility of optical modeling as a potential screening tool for new photopolymer formulations, primarily in identifying an upper limit to PI concentration for the desired cure depth. The results also show that photobleaching provides only a limited benefit for LFAM applications with short (1.0 s to 3.7 s) UV irradiation times and indicate that excess PI concentration can inhibit light transmission even under extended irradiation times up to 60 s.

36 MATERIALS SCIENCE↗

Surface Conversion of Single-Crystal Bi 2 Se 3 to β-In 2 Se 3

In this work, we demonstrate that the surface layers of single-crystal layered-2D Bi 2 Se 3 can be converted to layered-2D rhombohedral ß-In 2 Se 3 by annealing under a trimethylindium (TMIn) flux. Samples were prepared in a metalorganic chemical vapor deposition (MOCVD) chamber, then transferred under vacuum to a surface analysis chamber for analysis with low-energy electron diffraction (LEED) and Auger electron spectroscopy. Additional ex situ characterization included x-ray diffraction, transmission-electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDS) elemental mapping, and Raman spectroscopy. The resulting single-crystal ß-In 2 Se 3 adopts the rhombohedral crystal structure (space group R-3m) and orientation of the underlying Bi 2 Se 3 , and the excess Bi atoms generated by this process create an underlying region of Bi-rich Bi x Se y . Due to the difference in bandgap between Bi 2 Se 3 and In 2 Se 3 , this conversion reaction presents a pathway to lateral heterojunctions if only selected regions are converted by masking the surface to spatially define the TMIn exposure. The conversion may also have implications for heteroepitaxy, because the in-plane lattice constants of Bi 2 Se 3 and In 2 Se 3 (0001) surfaces match those of InP and GaAs (111), respectively, and the natural cleavage planes of a layered-2D crystal facilitate substrate removal and reuse.

14 SOLAR ENERGY↗

Tuning the low-energy band structure in twisted bilayer WSe2

Tuning the electronic structures of two-dimensional (2D) material-based heterostructures is of crucial importance for their use in functional next-generation electronics. Here, through angle-resolved photoemission spectroscopy with nanoscale spatial resolution (nano-ARPES), we systematically track the evolution of the near-Fermi-level electronic structure of bilayer WSe2 over a large range of twist angle. While the momentum positioning of the valence-band maxima (VBM) is independent of twist angle, we find that the energetic separation between the hole bands at the K point of the Brillouin zone and the higher binding-energy hole band at Γ can be varied in excess of 100 meV. We explore the mechanisms underpinning this evolution and discuss the implications for tuning both the size of the band gaps, and the efficiency of the spin-dependent electron-phonon coupling channels in homobilayer transition-metal dichalcogenide devices.

Vu, T-H-Y↗

An Indirect Search for Weakly Interacting Massive Particles in the Sun Using Upward-going Muons in NOvA

I present the first Dark Matter search results using the full data set collected with the upward-going muon trigger in NOvA. Weakly Interactive Massive Particles (WIMPs) are a theoretical non-baryonic form of Dark Matter. The nature of Dark Matter is one of the most exciting open questions in modern physics. Though its existence can be inferred by astrophysical evidence, its properties are not yet understood. If we assume that Dark Matter particles can produce Standard Model particles through their interactions, an indirect search can help shed light on this mystery.The NOvA collaboration has built a 14 kton, fine-grained, low-Z, total absorption tracking calorimeter at an off-axis angle to the NuMI neutrino beam. Even though the detector is optimized to observe electron neutrino appearance from a muon neutrino beam, it has a unique potential for more exotic searches given its excellent granularity and energy resolution and relatively low-energy neutrino thresholds. In fact, with an efficient upward-going muon trigger and sufficient background suppression offline, NOvA is capable of a competitive indirect Dark Matter search for low-mass WIMPs.The idea of the upward-going muon trigger is first to select high-quality muon tracks, then use the timing information of all of the hits of each track to estimate directionality. In this way, the background flux is suppressed by more than a factor of 10^5 at trigger level to a rate of approximately 1 Hz. To further optimize this search, we use only upward-going muons that point to the Sun, so our search occurs at night when the Sun is on the other side of the Earth. This strategy also allows us to use the time when the Sun is above the horizon as a control region to estimate the background. Ultimately, implementation of a cut based and maximum likelihood analysis provides a powerful tool for rejecting background and selecting a sample of neutrino-induced upward-going muons. The overall background rejection power achieved by the analysis is substantial and impressive. Starting with approximately 150,000 events per second, we reduced it to 40 events per year. Since no statistically significant excess was found, a 90\% C.L. upper limit on the expected muon flux of upward-going muons has been set using the upper limit on the number of events given the number of observed events in the signal region. Lastly, by assuming the theory behind the upward-going muon flux, a limit on the WIMP-nucleon spin-dependent cross-section in the Sun was estimated. Although the limits on the spin-dependent cross-section do not appear to be competitive with previous indirect Dark Matter searches, the upward-going muon flux limits are promising. The upward-going muon flux limits could extend these results to a broader class of models that are not specific to the dark matter theory but produce upward-going muons, leading to competitive results.

Principato, Cristiana↗

Dark matter searches and energy accumulation and release in materials

Efforts to identify dark matter by detecting nuclear recoils produced by dark matter particles reveal low-energy backgrounds of unknown origin in different types of detectors. In many cases, energy accumulation and delayed burst-like releases of stored energy could provide an explanation. These dynamics follow Prigogine’s ideas on systems with energy flow and the general Self-Organized Criticality scenario. We compare these models with properties of excess backgrounds in cryogenic solid-state detectors, relaxation processes in glasses and crystals, our observations of delayed luminescence in NaI(Tl), and make predictions for more phenomena present in these systems and in superconducting photon detectors and qubits. Experiments to create accurate phenomenological models are needed.

Pereverzev, Sergey↗

Low-energy astrophysics with KamLAND

We present two results of a search for MeV-scale neutrino and anti-neutrino events correlated with gravitational wave events/candidates and large solar flares with KamLAND. The KamLAND detector is a large-volume neutrino detector using liquid scintillator, which is located at 1 km underground under the top of Mt. Ikenoyama in Kamioka, Japan. KamLAND has multiple reaction channels to detect neutrinos. Electron antineutrino can be detected via inverse-beta decay with 1.8 MeV neutrino energy threshold. All flavors of neutrinos can be detected via neutrino-electron scattering without neutrino energy threshold. KamLAND has continued the neutrino observation since 2002 March. We use the data set of 60 gravitational waves provided by the LIGO/Virgo collaboration during their second and third observing runs and search for coincident electron antineutrino events in KamLAND. We find no significant coincident signals within a ±500 s timing window from each gravitational wave and present 90% C.L. upper limits on the electron antineutrino fluence between 10 8 –10 13 cm -2 for neutrino energies of 1.8–111 MeV. For a solar-flare neutrino search at KamLAND, we determine the timing window using the solar X-ray data set provided by the GOES satellite series from 2002 to 2019 and search for the excess of coincident event rate on the all-flavor neutrinos. We find no significant event rate excess in the flare time windows and get 90% C.L. upper limits on the fluence of neutrinos of all flavors (electron anti-neutrinos) between 10 10 –10 13 cm -2 (10 8 –10 13 cm -2 ) for neutrino energies in the energy range of 0.4–35 MeV.

79 ASTRONOMY AND ASTROPHYSICS↗

Low-energy diffuse X-rays

Diffuse low energy cosmic X rays rocket measurements, noting excess over extrapolated power law valid for higher energies

Bunner, A. N.↗

A reinterpretation of the reported energetic particle fluxes in the vicinity of Mercury

During the Mercury flyby of Mariner 10, observations of large fluxes of energetic electrons (energies in excess of 0.3 MeV) and protons (energies between 0.53 and 1.9 MeV) were reported by Simpson et al. (1974). The reported simultaneous enhancements of protons and electrons in the magnetic field of Mercury have raised some perplexing planetology questions. It is shown here that the response of the proton detector in the Mariner 10 experiment is most plausibly attributable to the pileup of low-energy electrons rather than the presence of protons in the vicinity of Mercury. Further, the reported lower-limit electron differential spectrum exponent of at least 9 and the 300-keV electron fluxes are probably in quantitative error, especially where the count rates are highest. It is concluded that no 'new' acceleration mechanism has been identified at Mercury.

Armstrong, T. P.↗

Hard X-ray spectrum of Cygnus X-1

Long-term measurements of the hard X-ray spectrum from 3 keV to 8 MeV of the black-hole candidate Cygnus X-1 in its low state are reported. Observations were made from October 26 to November 18, 1977 with the A2 (Cosmic X-ray) and A4 (Hard X-ray and Low-Energy Gamma-Ray) experiments on board HEAO 1 in the spacecraft's scanning mode. The measured spectrum below 200 keV is found to agree well with previous spectra which have been fit by a model of the Compton scattering of optical or UV photons in a very hot plasma of electron temperature 32.4 keV and optical depth 3.9 or 1.6 for spherical or disk geometry, respectively. At energies above 300 keV, however, flux excess is observed which may be accounted for by a distribution of electron temperatures from 15 to about 100 keV.

Nolan, P. L.↗

Measurement of the 0.3-8.5 MeV Galactic gamma-ray spectrum from the Galactic center direction

The low-energy gamma-ray spectrum from the direction of the Galactic center is determined using data obtained with the SMM Gamma-Ray Spectrometer. It is found that the diffuse gamma-ray spectrum from the Galactic center region can be interpreted in a straightforward way as the sum of five components of a presented equation. The components include a hard power law dominating the continuum at high energies caused principally by cosmic ray electron bremsstrahlung radiation, two narrow lines due to Al-26 decay and positron annihilation, an excess continuum component below 0.511 MeV consistent with the annihilation of positrons by formation of Ps, and a soft power law at low energies which is consistent with an extrapolation upward in energy of known hard X-ray sources in the Galactic center region.

Harris, M. J.↗

Soft X-ray spectra of Seyfert 2 galaxies

The paper presents soft X-ray spectra of three Seyfert 2 galaxies obtained with the ROSAT PSPC. For two of these objects, NGC 5506 and MCG -5-23-16, most of the flux occurs at energies greater than 1 keV and probably represents a low-energy extension of the source seen at higher (greater than 2 keV) energies. The third source, Mrk 348, has very little flux in the ROSAT band, suggesting a photoelectric cutoff at energies above the ROSAT band, in agreement with Ginga observations. In all three galaxies, X-rays are detected at energies below these photoelectric cutoffs with flux above that expected from a model in which the source has the same spectral index as at higher energies (2-10 keV) and is covered by a uniform, cold, photoelectric absorber. This result indicates the presence of an additional component at soft energies, which is referred to as a 'soft excess'. The monochromatic flux of the soft excess measured at 1 keV is about 1-2 percent of the directly viewed hard X-ray continuum in all three galaxies.

Mulchaey, John S.↗

Gamma-ray observations of Ophiuchus with EGRET: The diffuse emission and point sources

Observations of the Ophiuchus region made with the Energetic Gamma-Ray Experiment Telescope (EGRET) on the Compton Gamma Ray Observatory (CGRO) during the first 2 1/2 years of operation show the diffuse emission from the interstellar gas in Ophiuchus as well as variable emission from two point sources. The gamma-ray emission is modeled in terms of cosmic-ray interactions with atomic and molecular hydrogen in Ophiuchus and with low-energy photons along the line of sight. The model also includes the flux from the two point sources and an isotropic diffuse contribution. The cosmic-ray density is assumed to be uniform. The derived ratio of molecular hydrogen column density to integrated CO intensity is (1.1 +/- 0.2) x 10(exp 20) H-mols/sq cm (K km/s)(exp -1). At the sensitivity and resolution of the gamma-ray data, no variation of this ratio over the modeled region is discernible, nor are any regions of enhanced cosmic-ray density apparent. The model was fitted to seven narrow energy bands to obtain the energy depedence of the gamma-ray production function and the spectra of the point sources. The derived production function is in good agreement with theoretical calculations and the local cosmic-ray electron and proton spectra. The positions of the point sources were determined from maximum likelihood analysis of the gamma-ray emission observed in excess of the diffuse model. We identify one point source with the quasar PKS 1622-253, which has an average flux, E greater than 100 MeV, of (2.5 +/- 0.5) x 10(exp -7) photons/sq cm/s and photon spectral index -1.9 +/- 0.3. The other source, denoted GRO J1631-27, has not yet been identified at other wavelengths. Its average flux, E greater than 100 MeV, is (1.1 +/- 0.4) x 10(exp -7) photons/sq cm/s; however, its spectral index is poorly determined. The spectral index and intensity of the isotropic contribution to the model agree well with the extragalactic diffuse emission derived from the SAS 2 data.

Hunter, S. D.↗

The Bess Investigation of the Origin of Cosmic-ray Antiprotons and Search for Cosmological Antimatter

The Balloon-borne Experiment with a Superconducting Spectrometer (BESS) collaboration has made precise measurements of the spectra of cosmic ray antiprotons and light nuclei and conducted a sensitive search for antinuclei. Ten BESS high-latitude flights, eight from Canada and two from Antarctica, span more than a Solar cycle between 1993 and 2007/2008. BESS measurements of low-energy antiprotons constrain candidate models for dark matter including the possible signature of primordial black hole evaporation. The stringent BESS measurements of antiprotons and the elemental and isotopic spectra of H and He provide strong constraints on models of cosmic-ray transport in the Galaxy and Solar System. BESS has also reported the first antideuterium upper limit. BESS employs a superconducting magnetic-rigity spectrometer with time-of-flight and aerogel Cherenkov detectors to identify incident particles by charge, charge sign, mass, and energy. The BESS-Polar long-duration instrument has reduced lower energy limit of 100 MeV (top of the atmosphere) to increase its sensitivity to possible primary antiproton sources. BESS-Polar II was rebuilt with extended magnet lifetime, improved detector and electronic performance, and greater data storage capacity. It was flown fro Antarctica December 2007-January 2008, recording about 4.6 bission events during 24.5 days at float altitude with the magnet on. During the flight the influence of a high-speed stream in the Solar wind was observed. Details of the BESS-Polar II instrument and flight performance are reported elsewhere at this conference. The successful BESS-Polar II flight at Solar minimum is especially important. Most cosmic-ray antiprotons are secondary products of nuclear interactions of primary cosmic-ray nuclei with the interstellar gas, giving a spectrum that peaks at about 2 GeV and falls rapidly to higher and lower energies. However, BESS data taken in the previous Solar minimum show a small excess over secondary expectations at low energies, possibly suggesting the presence of an additional component that may be masked at higher levels of Solar modulation. The high-statistics Solar minimum data obtained by BESS-Polar II will provide a difinitive test of this component. We will review the BESS program and report the latest results including the antiproton and proton spectra measured in the BESS-Polar I flight, the search for cosmic antinuclei, and the status of the BESS-Polar II analysis.

Mitchell, John↗