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Results for “material stability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Hierarchical microstructures: a potential route to enhanced stability in structural materials for advanced nuclear reactors

The drive to increase efficiency in nuclear energy systems is leading to the need for materials that operate at higher temperatures and stress levels for extended periods, while maintaining stable microstructures to ensure their performance is not compromised. A novel route to producing materials that can perform well in such environments is the creation of hierarchical microstructures. A hierarchical microstructure is a microstructure in which features are present at multiple length scales simultaneously. In this work, a hierarchical microstructure is fabricated in a nickel-base superalloy, featuring nanometer-size gamma precipitates inside larger gamma-prime particles, which are in turn embedded in the gamma matrix phase. The hierarchical features of the microstructure lead to enhanced stability of the gamma-prime precipitates during annealing; the particle size does not follow the expected t^(1/3) growth law predicted by the classic LSW theory. Phase-field simulations are used to understand the unexpected stability of the gamma-prime precipitates.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Hierarchical microstructures: a potential route to enhanced stability in structural materials for advanced nuclear reactors

The drive to increase efficiency in nuclear energy systems is leading to the need for materials that operate at higher temperatures and stress levels for extended periods, while maintaining stable microstructures to ensure their performance is not compromised. A novel route to producing materials that can perform well in such environments is the creation of hierarchical microstructures. A hierarchical microstructure is a microstructure in which features are present at multiple length scales simultaneously. In this work, a hierarchical microstructure is fabricated in a nickel-base superalloy, featuring nanometer-size gamma precipitates inside larger gamma-prime particles, which are in turn embedded in the gamma matrix phase. The hierarchical features of the microstructure lead to enhanced stability of the gamma-prime precipitates during annealing; the particle size does not follow the expected t^(1/3) growth law predicted by the classic LSW theory. Phase-field simulations are used to understand the unexpected stability of the gamma-prime precipitates.

36 - MATERIALS SCIENCE↗
NASA NTRS1985

The thermal and mechanical stability of composite materials for space structures

A continuing research objective of the National Aeronautical and Space Administration (NASA) is to develop advanced composite materials for space structures. The thrust of this research is to gain fundamental understanding of the performance of advanced composites in the space environment. The emphasis has been to identify and model changes in the thermal-physical properties due to induced damage and develop improved materials.

Tompkins, S. S.↗
DOE OSTI2022

Shape-stabilized phase change materials for energy storage based on hierarchically porous calcium magnesium carbonate

A composite phase-change material containing a hierarchically porous Ca 1-x Mg x CO 3 and having pores loaded with a phase change material is described. The heat storage material has a latent heat of melting 123 to 221 J/g, a latent heat of freezing of 107 to 201 J/g, and a thermal conductivity of 0.22 to 0.45 W·m −1 ·K −1 . The phase change material may be polyethylene glycol, and the polyethylene glycol does not leak from the pores of the hierarchically porous Ca 1-x Mg x CO 3 when heating or cooling over phase transitions.

25 ENERGY STORAGE↗
NASA NTRS1991

Characterization of the dimensional stability of advanced metallic materials using an optical test bench structure

The dimensional stability of low-density high specific-strength metal-matrix composites (including 30 vol pct SiC(p)/SXA 24-T6 Al, 25 vol pct SiC(p)/6061-T6 Al, 40 vol pct graphite P100 fiber/6061 Al, 50 vol pct graphite P100 fiber/6061 Al, and 40 vol pct P100 graphite fiber/AZ91D Mg composites) and an Al-Li-Mg metal alloy was evaluated using a specially designed five-strut optical test bench structure. The structure had 30 thermocouple locations, one retroreflector, one linear interferometer multilayer insulation, and various strip heaters. It was placed in a 10 exp -7 torr capability vacuum chamber with a laser head positioned at a window port, and a laser interferometer system for collecting dimensional change data. It was found that composite materials have greater 40-C temporal dimensional stability than the AL-Li-Mg alloy. Aluminum-based composites demonstrated better 40-C temporal stability than Mg-based composites.

Hsieh, Cheng↗
DOE OSTI2023

Stabilized lithium metal oxide electrode material and method of preparation

A stabilized lithium metal oxide cathode material comprises microparticles of lithium metal oxide in which individual particles thereof a core of lithium metal oxide and a coating of a different lithium metal oxide surrounding the core. There is an interface layer between the cores and the coatings in which there are gradients of metal ions in the direction of coating to core. The materials are made by a three stage process involving coprecipitating precursor metal hydroxide core particles at a controlled pH; coprecipitating a different metal hydroxide coating on the particles without controlling the pH; and then calcining the resulting coated precursor particles with lithium hydroxide to form the stabilized lithium metal oxide material.

Lipson, Albert L.↗
DOE OSTI2024

Stabilized lithium metal oxide electrode material and method of preparation

A stabilized lithium metal oxide cathode material comprises microparticles of lithium metal oxide in which individual particles thereof a core of lithium metal oxide and a coating of a different lithium metal oxide surrounding the core. There is an interface layer between the cores and the coatings in which there are gradients of metal ions in the direction of coating to core. The materials are made by a three stage process involving coprecipitating precursor metal hydroxide core particles at a controlled pH; coprecipitating a different metal hydroxide coating on the particles without controlling the pH; and then calcining the resulting coated precursor particles with lithium hydroxide to form the stabilized lithium metal oxide material.

Lipson, Albert L.↗
DOE OSTI2020

Methods for stabilizing biological and soft materials for atom probe tomography

Techniques are disclosed for stabilizing soft specimen traditionally considered too fragile for APT instruments. These specimens include biological samples, polymers and other fragile materials. For this purpose, a protective structure is disclosed that surrounds the sides of the specimen by supporting walls while only exposing the very end or terminus of the specimen to the electrostatic field of the APT instrument. The protective structure may take the form of a nanoscale conical grinder which continually machines the specimen to regenerate the terminus of the specimen in-situ. Alternately, the protective structure may take the form of a nanopipette in which the specimen is first frozen before undergoing field evaporation together with the tip of the nanopipette. Heretofore only routinely possible for rigid and hard materials, the design thus extends APT analysis to produce three-dimensional atomic-scale maps of soft specimens.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Material, Phase, and Interface Stability of Photovoltaic Perovskite: A Perspective

The past decade has witnessed the unprecedented boost of power conversion efficiency (PCE) of photovoltaics based on halide perovskite materials since its early discovery. Despite its remarkably good performance, long-term stability is yet one of the last barriers before commercializing halide perovskite photovoltaics is possible. In this perspective, we discuss the challenges and concurrently the strategies regarding the stability of the perovskite materials, photoactive crystal phases, and the performance as well as stability limiting interfaces. Future perspectives of stable halide perovskite and perovskite solar cells are also proposed to shine light on letting perovskite technology satisfy long-term operation warranty.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Related Studies in Long Term Lithium Battery Stability

The continuing growth of the use of lithium electrochemical systems in a wide variety of both military and industrial applications is primarily a result of the significant benefits associated with the technology such as high energy density, wide temperature operation and long term stability. The stability or long term storage capability of a battery is a function of several factors, each important to the overall storage life and, therefore, each potentially a problem area if not addressed during the design, development and evaluation phases of the product cycle. Design (e.g., reserve vs active), inherent material thermal stability, material compatibility and self-discharge characteristics are examples of factors key to the storability of a power source.

Horning, R. J.↗
NASA NTRS1983

Spacecraft material applications: Long-term stability questions

An examination of the materials concerns for a variety of spacecraft components shows that long-term stability within the space environments is a major issue in the design of large space antenna systems. This survey paper will review some of the more recent work on the effect of space environment on (1) thin films, (2) structural composites, and (3) thermal control materials. Degradation in thermal-mechanical and optical properties associated with atmospheric and trapped particles and ultraviolet light will be highlighted. Finally, the dimensional instability associated with microcracking during thermal cycling will be examined and a methodology for estimating thermal fatigue effects from results of mechanical fatigue tests will be presented.

Crossman, F. W.↗
NASA NTRS1992

Polygenetic origin of Hrad Vallis region of Mars

A variety of apparently genetically related landforms in the Hrad Vallis region of Mars is examined. It is found that the outer valley of Hrad and the neighboring valley are composite features formed by karst or thermokarst processes and the growth and coalescence of smaller fault-aligned depressions. The materials in the vicinity may be soluble carbonates or sulfates or clay-rich sediment subject to thixotropic collapse. Water circulating within fault and fissure systems removed materials or altered the stability of materials to allow formation of steep-sided depressions. After the emplacement of surface materials in early Amazonian time, water was probably discharged to the surface. Isolate topographic depressions probably formed synchronously with the early release of water. Open lakes may have existed for a time.

De Hon, Rene A.↗
DOE OSTI2024

Enhancing the Performance of Plasma-facing Materials Through Solute-stabilized Nanostructured Tungsten Alloys

This report is a summary of the work completed under the auspices of the Department of Energy Early Career Award DE-SC0017899 entitled “Enhancing the Performance of Plasma-facing Materials Through Solute-stabilized Nanostructured Tungsten Alloys”. Summaries of initiatives on computational thermodynamics modeling, experimental alloy synthesis including traditional and additive manufacturing routes, several ion irradiation studies, and plasma exposures are reported.

36 MATERIALS SCIENCE↗
DOE OSTI2021

A General Strategy for Batch Development of High-Performance and Cost-Effective Sodium Layered Cathodes

High-performance and low-cost transition metal (TM) layered oxides using earth abundant elements are promising cathodes for Na-ion batteries. However, it is challenging to obtain desired materials because the large Na size, different Na occupations and various layer stacking sequences multiply the complication in determining the structure of a given composition and exacerbate uncertainty to the structure-property correlation. In this work, we use the attainment of desired NaxMnyNiZTM1-y-zO2-based cathode materials as an example to demonstrate a general roadmap for batch development of sodium layered cathodes towards practical applications. A synthesis phase diagram of NaxMnyNi1-yO2 was created for pre-screening and rational selection of the platform material of P2/O3-structured Na0.85Mn0.6Ni0.4O2. Cationic potential was leveraged in elemental substitution to further promote the material structural stability and electrochemical performance. Several cost-effective O3 and P2/O3 hybrid cathode materials have been obtained, all of which demonstrate excellent performance. In particular, the Na0.85Mn0.5Ni0.4Ti0.1O2 delivers a high specific capacity of ~130 mAh/g between 2-4 V and 91% retention after 500 cycles. The work discovers multiple materials as high-performance and cost-effective Na-ion battery cathodes and offers critical guidance to the rational design of future layered cathode materials.

Xiao, Biwei↗
DOE OSTI2024

Solid breeder material crystal structure evolution due to Li burn up–Loss of crystal stability

Solid breeder materials for fusion power plants are subjected to extreme conditions of radiation damage, high temperature and designed component burn-up. Here, the loss of lattice stability of Li 2 TiO 3 due to Li burn-up was investigated using first principles-based approaches to aid evaluation of upper limit of component lifetime. The lattice stability is analyzed using calculated phonon dispersion in the Li 2 TiO 3 supercell, while Li burn-up is modeled by the introduction of Li-vacancies. It has been determined that the studied ceramic can be structurally stable up to ~40% of Li atoms burn-up. At 50% burn-up, the negative frequency branch in the phonon dispersion spectrum appears indicating the loss of lattice dynamical stability. Moreover, the structure obtained by introduction of unstable frozen phonons with minima energy amplitude also results in a phonon dispersion with negative branches in the structure obtained. Therefore, the system completely loses stability when approximately half of Li atoms are consumed.

36 MATERIALS SCIENCE↗