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At least 109 records · Page 6

Sink-float ferrofluid separator applicable to full scale nonferrous scrap separation

Design and performance of a ferrofluid levitation separator for recovering nonferrous metals from shredded automobiles are reported. The scrap separator uses an electromagnet to generate a region of constant density within a pool of ferrofluid held between the magnetic poles; a saturated kerosene base ferrofluid as able to float all common industrial metals of interest. Conveyors move the scrap into the ferrofluid for separation according to density. Results of scrap mixture separation studies establish the technical feasibility of relatively pure aluminum alloy and zinc alloy fractions from shredded automobile scrap by this ferrofluid levitation process. Economic projections indicate profitable operation for shredders handling more than 300 cars per day.

Source record↗

Near-Earth asteroids: Metals occurrence, extraction, and fabrication

Near-earth asteroids occur in three principle types of orbits: Amor, Apollo, and Aten. Amor asteroids make relatively close (within 0.3 AU) approaches to the earth's orbit, but do not actually overlap it. Apollo asteroids spend most of their time outside the earth's orbital path, but at some point of close approach to the sun, they cross the orbit of the earth. Aten asteroids are those whose orbits remain inside the earth's path for the majority of their time, with semi-major axes less than 0.1 AU. Near-earth orbit asteroids include: stones, stony-irons, irons, carbonaceous, and super-carbonaceous. Metals within these asteroids include: iron, nickel, cobalt, the platinum group, aluminum, titanium, and others. Focus is on the extraction of ferrous and platinum group metals from the stony-iron asteroids, and the iron asteroids. Extraction of the metal fraction can be accomplished through the use of tunnel-boring-machines (TBM) in the case of the stony-irons. The metals within the story-iron asteroids occur as dispersed granules, which can be separated from the stony fraction through magnetic and gaseous digestion separation techniques. The metal asteroids are processes by drilling and gaseous digestion or by gaseous digestion alone. Manufacturing of structures, housings, framing networks, pressure vessels, mirrors, and other products is accomplished through the chemical vapor deposition (CVD) of metal coating on advanced composites and on the inside of contour-defining inflatables (CDI). Metal coatings on advanced composites provide: resistance to degradation in the hostile environments of space; superior optical properties; superior heat dissipation; service as wear coatings; and service as evidential coatings. Metal coatings on the inside of CDI produce metal load-bearing products. Fibers such as graphite, kevlar, glass, ceramic, metal, etc., can be incorporated in the metal coatings on the inside of CDI producing metal matrix products which exhibit high strength and resist crack propagation.

Westfall, Richard↗

Magnetic Susceptibility Measurements for in Situ Characterization of Lunar Soil

Magnetic separation is a viable method for concentration of components of lunar soils and rocks for use as feedstocks for manufacture of metals, oxygen, and for recovery of volatiles such as He-3. Work with lunar materials indicates that immature soils are the best candidates for magnetic beneficiation. The magnetic susceptibility at which selected soil components such as anorthite, ilmenite, or metallic iron are separated is not affected by soil maturity, but the recovery of the concentrated components is. Increasing soil maturity lowers recovery. Mature soils contain significant amounts of glass-encased metallic iron. Magnetic susceptibility, which is sensitive to metallic iron content, can be used to measure soil maturity. The relationship between the ratio of magnetic susceptibility and iron oxide and the conventional maturity parameter, I(sub s)/FeO, ferromagnetic resonant intensity divided by iron oxide content is given. The magnetic susceptibilities were determined using apparatus designed for magnetic separation of the lunar soils.

Oder, R. R.↗

Size distributions and aerodynamic equivalence of metal chondrules and silicate chondrules in Acfer 059

The CR2 chondrite Acfer 059 is unusual in that the original droplet shapes of metal chondrules are well preserved. We determined separate size distributions for metal chondrules and silicate chondrules; the two types are well sorted and have similar size distributions about their respective mean diameters of 0.74 mm and 1.44 mm. These mean values are aerodynamically equivalent for the contrasting densities, as shown by calculated terminal settling velocities in a model solar nebula. Aerodynamic equivalence and similarity of size distributions suggest that metal and silicate fractions experienced the same sorting process before they were accreted onto the parent body. These characteristics, together with depletion of iron in Acfer 059 and essentially all other chondrites relative to primitive CI compositions, strongly suggest that sorting in the solar nebula involved a radial aerodynamic component and that sorting and siderophile depletion in chondrites are closely related.

Skinner, William R.↗

Rubber and alumina gaskets retain vacuum seal in high temperature EMF cell

Silicone rubber gasket and an alumina gasket retain a vacuum inside a high temperature EMF cell in which higher and lower density liquid metal electrodes are separated by an intermediate density fused salt electrolyte. This innovation is in use on a sodium bismuth regenerable EMF cell in which the fused salts and metals are at about 500 deg to 600 deg C.

Hesson, J. C.↗

Electronic modules easily separated from heat sink

Metal heat sink and electronic modules bonded to a thermal bridge can be easily cleaved for removal of the modules for replacement or repair. A thin film of grease between a fluorocarbon polymer film on the metal heat sink and an adhesive film on the modules acts as the cleavage plane.

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Oxygen recombination in individual pressure vessel nickel-hydrogen batteries

A metal-hydrogen cell is described which avoids damage and retards flooding of the hydrogen electrodes by providing for chemical recombination of oxygen and hydrogen in areas or sites remote from the hydrogen electrodes. In the metal-hydrogen cell, a plurality of electrical cell units are place in a back to back relationship. The cells may be lined with a wick, having one or more catalyzed sites on the inner surface of the cell. Separators disposed between the respective metal and hydrogen electrodes of each cell unit are provided with gas directing notches around their peripheries to facilitate the desired movement of gasses within the metal-hydrogen cell. Any two metal electrodes separated by a gas screen are provided with gas tight sealing means between the electrodes at each aperature. The sealing means may be a fing of rubber or elastomeric material which is somewhat compressible but nonreactive with other materials in the cell.

Smithrick, J. J.↗

Transient processes in combustion of single submillimeter metal droplets

A laser was used to ignite Al, Zr, Ti and Hf droplets in separate trials to study metal droplet combustion in air. The burning was recorded with high speed film at high magnification. Al was found to flash vaporize, melt, surface oxidize, revaporize, then combust. All species burned with a vapor diffusion flame surrounded by an oxide condensation front. The Zr, Ti and Hf droplets grew by condensation, coalesced, then convected toward the perimeter of the condensation zone. It is expected that the data will serve as bases for a theoretical vapor diffusion model. Finally, the introduction of a transverse acoustic field was observed to have no effect on either the luminosity or combustion zone geometry.

Pellett, G. L.↗

Technology utilization program report

The application of aerospace technology to the solution of public health and industrial problems is reported. Data cover: (1) development of an externally rechargeable cardiac pacemaker, (2) utilization of ferrofluids-colloidal suspensions of ferrite particles - in the efficient separation of nonferrous metals as Ni, Zn, Cu, and Al from shredded automobile scrap, and (3) development of a breathing system for fire fighters.

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Superfluid helium 2 liquid-vapor phase separation: Technology assessment

A literature survey of helium 2 liquid vapor phase separation is presented. Currently, two types of He 2 phase separators are being investigated: porous, sintered metal plugs and the active phase separator. The permeability K(P) shows consistency in porous plug geometric characterization. Both the heat and mass fluxes increase with K(P). Downstream pressure regulation to adjust for varying heat loads and both temperatures is possible. For large dynamic heat loads, the active phase separator shows a maximum heat rejection rate of up to 2 W and bath temperature stability of 0.1 mK. Porous plug phase separation performance should be investigated for application to SIRTF and, in particular, that plugs of from 10 to the minus ninth square centimeters to 10 to the minus eighth square centimeters in conjunction with downstream pressure regulation be studied.

Lee, J. M.↗

Statistical mechanics of light elements at high pressure. VI - Liquid-state calculations with Thomas-Fermi-Dirac theory

A model free energy is developed for hydrogen-helium mixtures based on solid-state Thomas-Fermi-Dirac calculations at pressures relevant to the interiors of giant planets. Using a model potential similar to that for a two-component plasma, effective charges for the nuclei (which are in general smaller than the actual charges because of screening effects) are parameterized, being constrained by calculations at a number of densities, compositions, and lattice structures. These model potentials are then used to compute the equilibrium properties of H-He fluids using a charged hard-sphere model. The results find critical temperatures of about 0 K, 500 K, and 1500 K, for pressures of 10, 100, and 1000 Mbar, respectively. These phase separation temperatures are considerably lower (approximately 6,000-10,000 K) than those found from calculations using free electron perturbation theory, and suggest that H-He solutions should be stable against phase separation in the metallic zones of Jupiter and Saturn.

Macfarlane, J. J.↗

Model studies in catalysis with uhv-deposited metal particles and clusters

Small supported metal particles have become a popular area of intense research interest, and important contributions to the considered problems are being made from the fields of uhv technology, thin film physics surface science, and surface and thin film instrumentation. Attention is given to insulating supports, particulate metal deposits and their properties, metal/support interactions and gas exposures, and integrated experimental approaches. It is concluded that major contributions to the field of model catalysis should be forthcoming in the near future from uhv-based methods of research. Catalysis and catalysis-related problem areas expected to benefit from advanced model studies include catalyst preparation processing, sintering mechanisms for metals and alloys, separation of initial and final state effects for supported clusters, and the influence of particle and/or support morphologies.

Poppa, H.↗

A study of surface tension driven segregation in monotectic alloy systems

The compatibilities of various monotectic alloy systems with several different crucible materials were evaluated. The study was carried out using small candidate alloy samples of compositions that produced fifty volume percent of each liquid phase at the monotectic temperature. Compatibility was based on the evaluation of the wetting tendency of the two immiscible phases with the crucible material in a one-g solidified sample. Three types of wetting phenomena were observed during the evaluation. Type 1 indicates an alloy-crucible combination where the L2 phase preferentially wets the crucible material. Since L2 is usually the minority phase in desirable alloys, this material combination would be difficult to process and is therefore considered incompatible. Type 2 behavior indicates an alloy-crucible combination where the L1 phase preferentially wets the crucible material. This type of combination is considered compatible since surface tension effects should aid in processing the alloy to a useful form. Type 3 indicates any combination that leads to major reactions between the alloy and crucible material, gas entrapment, or separation of the metal from the crucible wall. Additional compatibility evaluations would have to be carried out on combinations of this category. The five alloy systems studied included aluminum-bismuth, copper-lead, aluminum-indium, aluminum-lead and cadmium-gallium. The systems were combined with crucibles of alumina, boron nitride, mullite, quartz, silicon carbide and zirconia.

Andrews, J. Barry↗

Non-noble electrocatalysts for alkaline fuel cells

Carbons activated with macrocyclics have attracted increasing attention as alternative electrocatalysts for oxygen reduction. Initial activity of these catalysts is good, but performance declines rapidly. Pyrolyzing the macrocyclic on the carbon support leads to enhanced stability and the catalysts retain good activity. The approach described is designed to develop bulk doped catalysts with similar structures to pyrolyzed macrocyclic catalysts. The transition metal and coordinated ligands are dispersed throughout the bulk of the conductive carbon skeleton. Two approaches to realizing this concept are being pursued, both involving the doping of carbon precursors. In one approach, the precursor is a solid phase carbon-containing ion-exchange resin. The precursor is doped with a transition metal and/or nitrogen, and the resulting mixture is pyrolyzed. In the other approach, the precursor is a gas-phase hydrocarbon. This is introduced with a transition metal species and nitrogen species into a reactor and pyrolyzed. Several studies have been conducted to determine if there is a synergistic effect between the transition metal and nitrogen and the effect of different methods of introducing the metal-nitrogen (M-N) coordination on performance. One approach was to introduce the metal and nitrogen separately, for example, by sequentially doping FeCl3 and NH4OH into the resin. Catalysts were prepared from an undoped ion-exchange resin, a resin doped only with N, a resin doped only with Fe, and a resin doped with both Fe and N. Introduction of nitrogen alone has no beneficial effect on the performance of the catalysts. The introduction of the Fe alone significantly improves the performance in both the high and low current density regions. When both Fe and N are introduced, the performance at lower current densities (catalytic activity) is increased beyond that of the Fe-doped carbon, but the performance at higher current densities is similar to the carbon containing only Fe. Catalysts prepared from resins-Fe(bipy)3SO4 precursors have performance that is only slightly less then CoTMPP adsorbed and pyroloyzed on Vulcan XC-72. Their performance is much better than carbons which have had the N and Fe introduced separately.

Sarangapani, S.↗

Theoretical studies of the first- and second-row transition-metal mono- and dicarbonyl positive ions

Ab initio calculations have been carried out on the first- and second-row transition-metal mono- and dicarbonyl positive ions. The bonding in these systems is discussed in detail. Trends in the series of mono- and dicarbonyl ions and between the first- and second-row transition metals are explained in terms of a dominantly electrostatic bonding interaction and differences in metal ion state separations, ionization potentials, and s and d orbital sizes. Dissociation energies are presented and a detailed comparison is made with experimental data. Where reliable experimental data exists, agreement with the theoretical results is generally good.

Barnes, Leslie A.↗

Experimental partitioning studies near the Fe-FeS eutectic, with an emphasis on elements important to iron meteorite chronologies (Pb, Ag, Pd, and Tl)

Partitioning coefficients for metal/sulfide liquid, troilite/sulfide liquid, and schreibersite/sulfide liquid were determined for Ag, Au, Mo, Ni, Pd, and Tl (using EMPA and proton-induced X-ray microprobe and ion microprobe analyses) in order to understand the chronometer systems of iron meteorites. In general, the obtained schreibersite/metal and troilite/metal partition coefficients for 'compatible' elements were quite similar to those inferred from natural assemblages, reinforcing an earlier made conclusion that there is a class of elements for which experimental troilite/metal and schreibersite/metal partition coefficients approximate those inferred from natural samples. The consistency between experimental and natural assemblages, however, was not observed for Ag, Pb, and Tl, indicating that the abundances of these elements determined in 'metal' and 'troilite' separates from iron meteorites are influenced by trace minerals that concentrate incompatible elements.

Jones, J. H.↗

Analysis Of Performance Of A Thick Dichroic Microwave Panel

Report describes theoretical and experimental studies of performance of thick dichroic microwave panel comprising honeycomblike planar array of cross-shaped, waveguidelike apertures separated by thin metal walls. Except for small changes in dimensions, design of panel identical to one of designs described in "Two Thick Microwave Dichroic Panels" (NPO-18887).

Epp, Larry W.↗