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Measurements of the absolute photoionization cross section from the 6s5d 3D metastable level of barium are presented. The 3D levels were selectively populated with a high-power tuneable dye laser. The number density was determined by observing the resulting depopulation of the ground state when pumping occurred.
The high resolution of the photoionization mass spectrophotometer was utilized to resolve some doubts about the participating species in the reaction of metastable oxygen molecular ions with oxygen molecules to yield ozone ions and oxygen radicals. It is found from inspection of the appearance potential of the ozone ion that an a4 Pi-excited state is responsible for the formation of ozone near the appearance potential of these lines.
This paper deals with the details of the absorption spectrum of the 3D metastable term in barium. The 3D term was selectively populated with a tuneable dye laser. The fundamental triplet series (6s5d 3D-6snf 3F) is identified and extended out to n = 32. In addition, the absolute photoionization cross section was measured at 303 nm. The relative cross section from 303 to 250 nm was also measured with the absolute scale set by the measurement at 303 nm and was found to be nearly constant in the wavelength region measured.
Photoionization from metastable levels of atomic xenon has been studied in the wavelength range from the threshold at 4622 A to 2700 A. Structure in the photoionization signal, due to autoionization, is analyzed to provide term values, lifetimes, and line-shape parameters of the autoionizing states. These parameters, together with the estimated absolute cross sections, are used to derive discrete and continuum oscillator strengths.
The paper reports on differential and integral cross sections for scattering of 4.5 eV electrons by ground state (x 3 Sigma g minus) and metastable (a 1 Delta g) oxygen molecules in the -2.0 eV to plus 2.0 eV energy loss range. The cross section for the (a 1 Delta g to b 1 Sigma g plus) transition was found to be more than an order of magnitude larger than that of the excitation of the b state from the ground state. It was found that the principle of detailed balance can be applied to the rotationally unresolved inelastic and superelastic electronic transitions between the (x 3 Sigma g minus) and (a 1 Delta g) states, which indicates that for this transition one may neglect the very different rotational level structure of the two states in estimating superelastic cross section from inelastic data to an accuracy of about 15 per cent.
Methods previously described for calculating rigorous upper and lower bounds to dynamic dipole polarizabilities are applied to the metastable 2(1S) and 2(2S) excited states of He and Li(+), using highly correlated variational trial functions. For each of these species, the bounds rigorously establish the values of the frequency-dependent dipole polarizability to within about 1% and appear to represent the first determination of this property at frequencies above the first excitation threshold.
A new method of calculating speed of sound for two-phase flow is presented. The new equation assumes no phase change during the propagation of an acoustic disturbance and assumes that only the total entropy of the mixture remains constant during the process. The new equation predicts single-phase values for the speed of sound in the limit of all gas or all liquid and agrees with available two-phase, air-water sound speed data. Other expressions used in the two-phase flow literature for calculating two-phase, metastable sound speed are reviewed and discussed. Comparisons are made between the new expression and several of the previous expressions -- most notably a triply isentropic equation as used, a triply isentropic equation as used, among others, by Karplus and by Wallis. Appropriate differences are pointed out and a thermodynamic criterion is derived which must be satisfied in order for the triply isentropic expression to be thermodynamically consistent. This criterion is not satisfied for the cases examined, which included two-phase nitrogen, air-water, two-phase parahydrogen, and steam-water. Consequently, the new equation derived is found to be superior to the other equations reviewed.
The concentration and altitude distribution of metastable N(2P) atoms was measured in a diffuse IBC II(+) auroral arc. The dominant N(2P) source is shown to be the dissociative excitation of N2 by electron impact with a minor contribution from the dissociative recombination of N2(+) ions. The possibility that an ion-molecule process involving atomic oxygen and vibrationally excited N2(+) ions is a significant N(2P) source is examined. Values for the proportional yield of N(+), N(2P), N(2D), and N(4S) atoms from electron-impact dissociation of N2 under optically thick conditions are given.
A theory is developed for isentropic metastable sound propagation in high pressure gas-liquid mixtures. Without simplification, it also correctly predicts the minimum speed for low pressure air-water measurements where other authors are forced to postulate isothermal propagation. This is accomplished by a mixture heat capacity ratio which automatically adjusts from its single phase values to approximately the isothermal value of unity needed for the minimum speed. Computations are made for the pure components parahydrogen and nitrogen, with emphasis on the latter. With simplifying assumptions, the theory reduces to a well known approximate formula limited to low pressure.
The radiative lifetime of metastable N(+)(5S2) has been measured to be 4.2 + or - 0.6 msec, a value generally in agreement with theory, by direct monitoring of the spontaneous emission from approximately 1,000,000 ions stored in a radio-frequency ion trap. Additional measurements were made of the quenching rate coefficient (2.5 x 10 to the -9th cu cm/sec) and the production cross section (greater than or equal to 10 to the -18th sq cm) of N(+)(5S2) in N2. This work supports the interpretation of the 2145-A feature in the spectrum of aurorae as being due to N(+)(5S2) emission.
The general field of preparation and study of metastable and modulated semiconductor structures has progressed rapidly in recent years. This short overview offers an assessment of the progress and current understanding in the areas of fabrication, characterization, and utilization of these new material systems. The discussion includes the more prominent growth techniques, theoretical and experimental analysis of growth kinetics, and an overview of structural, chemical, electronic, and optical characterization. The probable application of these structures for the technological development of new device structures and concepts is considered. The discussion particularly emphasizes the prospects for future studies in view of the specific current understanding.
The stability of HOC(+) ions under conditions in interstellar molecular clouds is considered. In particular, the possibility that collisions with helium or hydrogen will induce isomerization to the stable HCO(+) form is examined theoretically. Portions of the electronic potential energy surfaces for interaction with He and H atoms are obtained from standard quantum mechanical calculations. Collisions with He atoms are found to be totally ineffective for inducing isomerization. Collisions with H atoms are found to be ineffective at low interstellar temperatures owing to a small (about 500 K) barrier in the entrance channel; at higher temperatures where this barrier can be overcome, however, collisions with hydrogen atoms do result in conversion to the stable HCO(+) form. Although detailed calculations are not presented, it is argued that low-energy collisions with H2 molecules are also ineffective in destroying the metastable ion.
The present investigation is concerned with a miniature metastable ionization detector featuring an unconventional electrode configuration, whose performance characteristics parallel those of traditional design. The ionization detector is to be incorporated in a flight gas chromatograph (GC) for use in the Space Shuttle. The design of the detector is discussed, taking into account studies which verified the sensitivity of the detector. The triaxial design of the detector is compared with a flat-plate style. The obtained results show that the principal goal of developing a miniature, highly sensitive ionization detector for flight applications was achieved. Improved fabrication techniques will utilize glass-to-metal seals and brazing procedures.
The Metastable Ionization Detector (MID) is three orders of magnitude more sensitive than the thermal conductivity detectors used on previous flight instruments. The miniature MID provides scientists with a much smaller and highly sensitive detector for flight gas chromatographs. A miniature MID featuring an unconventional triaxial electrode configuration was developed and used routinely in the laboratory. Although much smaller and lighter than the commercial MID, its performance characteristics parallel those of the traditional design. The detector is compatible with the modulated voltage circuitry, also developed here, and thus can perform over an expanded response range of more than 7 orders magnitude. A micro volume version of a miniature MID, with an internal volume of less than 8 microliter, was recently designed is now being tested. The micro volume MID uses carrier gas flow rates of approx. 2cc/min thus eliminating the need for makeup gas when capillary columns are used.
An analysis of the possible dissociation of metastable oxygen molecules subject ot constraints imposed by selection rules for molecular transitions, airglow observations, and atmospheric chemistry leads to the following conclusions. Dissociation of O2(b1Sigma g +) must produce a negligible number of oxygen atoms at all altitudes in the earth's atmosphere. However, if the dissociation cross section of O2(a1Delta g) has a maximum value in the range 10 to the -20th to 10 to the -19th/sq cm, then the process O2(a1Delta g) + h(nu) yields O2(C3Delta u) yields O(3P) + O(3P) will constitute a significant, and potentially the major, source of odd oxygen in the uppermost stratosphere and mesosphere.
The discovery of cyclopropenylidene in space suggests that other C3H2 isomers may be present, and a tentative detection of one such isomer, propargylene (HCCCH), has been reported. Ab initio molecular orbital theory has been used to characterize five low-lying, metastable isomers of cyclopropenylidene. Extended calculations including the electron correlation energy, show that the lowest in energy is singlet propadienylidene, followed by propargylene; the singlet and triplet of the latter are too close in energy to allow an assignment of the ground state; triplet propadienylidene is at a significantly higher energy. Rotational frequencies computed to an expected accuracy of + or - 1 -2 percent do not confirm the tentative detection of propargylene in space, although the discrepancy between theory and the observation is not so great as to unequivocally rule out this possibility.
Laboratory investigations have been conducted on the effects of variations in sulfur sample histories on their solid-state transformation rate and the corresponding spectral variation of freshly frozen sulfur. The temporal variations in question may be due to differences in the amount and type of metastable allotropes present in the sulfur after solidification, as well as to the physics of the phase-transformation process itself. The results obtained are pertinent to the physical behavior and spectral variation of such freshly solidified sulfur as may exist on the Jupiter moon Io; this would initially solidify into a glassy solid or monoclinic crystalline lattice, then approach ambient dayside temperatures. Laboratory results imply that the monoclinic or polymeric allotropes can in these circumstances be maintained, and will take years to convert to the stable orthorhombic crystalline form.
Velocity models of subducting slabs with a kinetically-depressed olivine to beta- and gamma-spinel transition are constructed, and the effect that such structures would have on teleseismic P waveforms are examined using a full-wave finite-difference method. These 2D calculations yielded waveforms at a range of distances in the downdip direction. The slab models included a wedge-shaped, low-velocity metastable olivine tongue (MOTO) to a depth of 670 km, as well as a plausible thermal anomaly; one model further included a 10-km-thick fast layer on the surface of the slab. The principal effect of MOTO is to produce grazing reflections at wide angles off the phase boundary, generating a secondary arrival 0 to 4 seconds after the initial arrival depending on the take-off angle. The amplitude and timing of this feature vary with the lateral location of the seismic source within the slab cross-section.