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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Moisture ingress in commercial steel drums: Water content determination, diffusion modelling and predicted permeation rates

Commercial steel drums underpin the global economy, playing a pivotal role in the storage and transportation of critical materials. Transported and stored materials, such as food, chemical and nuclear waste, can be sensitive to ambient conditions, particularly moisture that can enhance negative effects such as corrosion and material degradation. Although international standards and regulations are in place for the qualification of steel drums, there are no current testing requirements, established limits or boundaries for the permeation of moisture into the drums during transportation or storage. This work aims to provide insights into the moisture ingress over time into properly sealed steel drums and provides estimated moisture ingress rates over time through extrapolation. Water vapour transmission rate (WVTR) measurements through the gasket material at 10–40°C were 0.11–2.1 g/m 2 /day resulting in a permeation activation energy of 30.2 kJ/mol. Water sorption measurements and Karl Fischer titration (KFT) on ethylene propylene diene monomer (EPDM) gasket material revealed a decrease in equilibrium moisture saturation with increasing temperature. KFT measurements also revealed the presence of moisture within the adhesive and drum wall after exposure to ambient conditions. KFT and Fourier transform infrared spectroscopy (FTIR) show that moisture will desorb from the EPDM and drum wall after exposure to desiccating conditions, although a minimal amount of moisture will remain present. When sealed to the manufacturer's recommendations, the steel drums are effective in minimizing moisture ingress. In conclusion, in sealed empty drums, moisture ingress rates for 19-L drums were 0.4–1.5 mg/day at 25°C 15% relative humidity (RH) and increased to 7.1–8.8 mg/day at 40°C 90% RH, and moisture ingress rates for 210-L drums were 2.5 and 3.5 mg/day at field deployment conditions of 15.5°C 51.5% RH and 23°C 40% RH, respectively.

42 ENGINEERING↗

Determining circuit model parameters from operation data for PV system degradation analysis: $\mathrm{PVPRO}$

Physics-based circuit parameters like series and shunt resistance are essential to provide insights into the degradation status of photovoltaic (PV) arrays. However, calculating these parameters typically requires a full current-voltage characteristic (I-V curve), the acquisition of which involves specific measurement devices and costly methods. Thus, I-V curves of the PV system level are often not available. Here this paper proposes a methodology (PVPRO) to estimate these I-V curve parameters using only operation (string-level DC voltage and current) and weather data (irradiance and temperature). PVPRO first performs multi-stage data pre-processing to remove noisy data. Next, the time-series DC data are used to fit an equivalent circuit single-diode model (SDM) to estimate the circuit parameters by minimizing the differences between the measured and estimated values. In this way, the time evolutions of the SDM parameters are obtained. We evaluate PVPRO on synthetic datasets and find an excellent estimation of both SDM and the key I-V parameters (e.g., open-circuit voltage, short-circuit current, maximum power, etc.) with an average relative error of 0.55%. The performance, especially the extracted degradation rate of parameters, is robust to various measurement noises and the presence of faults. In addition, PVPRO is applied to a 271 kW PV field system. The relative error between the real and estimated operation voltage and current is less than 1%, suggesting that degradation trends are well captured. PVPRO represents a promising open-source tool to extract the time-series degradation trends of key PV parameters from routine operation data.

14 SOLAR ENERGY↗

CO 2 Sorption in Moisture Swing Anion Exchange Resins for Direct Air Capture: Experimental Isotherm Determination and Modeling

Moisture swing (MS) sorption is a promising direct air capture (DAC) technology to achieve negative CO 2 emissions and counter global warming. Here, in this study, MS CO 2 sorption in a model MS sorbent, IRA900, was investigated. IRA900 is a macroporous commercial strong-base anion exchange resin (AER) with quaternary ammonium functional groups. A rigorous CO 2 desorption process was developed to desorb all CO 2 from the sample and obtain CO 2 sorption isotherms as a function of relative humidity, CO 2 partial pressure, and temperature. CO 2 sorption increased with decreasing relative humidity, decreasing temperature, and increasing CO 2 partial pressure. Remarkably, the total CO 2 uptake from the sorption isotherms matched the ion exchange capacity (IEC) of the material, suggesting a stoichiometry of one CO 2 molecule reacting per active site. An isotherm model for CO 2 sorption starting with empty sorption sites (i.e., with the AER in the OH – form) described the experimental data well, supporting the hypothesis that the bicarbonate-loaded AER fully unloaded to the OH – state following rigorous CO 2 desorption. CO 2 sorption kinetics were studied, and carbon diffusion coefficients were estimated as a function of %RH and CO 2 partial pressure. Overall, this study provides a roadmap for the systematic evaluation of MS CO 2 DAC materials.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Model-independent determination of the strong-phase difference between D 0 and D ¯ 0 → π + π − π + π − decays

Measurements of the strong-phase difference between D 0 and D ¯ 0 → π + π − π + π − are performed in bins of phase space. The study exploits a sample of quantum-correlated D D ¯ mesons collected by the BESIII experiment in e + e − collisions at a center-of-mass energy of 3.773 GeV, corresponding to an integrated luminosity of 2.93 fb − 1 . Here, D denotes a neutral charm meson in a superposition of flavor eigenstates. The reported results are valuable for measurements of the C P -violating phase γ (also denoted ϕ 3 ) in B ± → D K ± , D → π + π − π + π − decays, and the binning schemes are designed to provide good statistical sensitivity to this parameter. The expected uncertainty on γ arising from the precision of the strong-phase measurements, when applied to very large samples of B -meson decays, is around 1.5° or 2°, depending on the binning scheme. The binned strong-phase parameters are combined to give a value of F + 4 π = 0.746 ± 0.010 ± 0.004 for the C P -even fraction of D 0 → π + π − π + π − decays, which is around 30% more precise than the previous best measurement of this quantity. Published by the American Physical Society 2024

Ablikim, M.↗

An extended model for determining dynamic loads in spur gearing

In this study a large scale digitized approach is used for an uninterrupted static and dynamic analysis of spur gearing. An interactive method was developed to calculate directly the variable gear mesh stiffness as a function of transmitted load, gear profile errors, gear tooth deflections and gear hub torsional deformation, and position of contacting profile points. The developed methods are applicable to both the normal and high contact ratio gearing. Certain types of simulated sinusoidal profile errors and pitting can cause interruptions of the normal gear mesh stiffness function and, thus, increase the dynamic loads in gearing.

Kasuba, R.↗

Effect of Fuselage and Tail Surfaces on Low-speed Yawing Characteristics of a Swept-wing Model as Determined in Curved-flow Test Section of Langley Stability Tunnel

Results are presented of a wind-tunnel investigation made to determine the influence of the fuselage and tail surfaces on the rotary derivatives in yawing flight of a transonic-airplane configuration having 45 degrees sweptback wing and tail surfaces. The tests were run in the curved-flow test section of the Langley stability tunnel at a Reynolds number of 1.07 X 10 to the sixth power and consisted of balance measurements throughout the angle-of-attack range for several flight-path radii of curvature. The results are compared with data from forced-oscillation and free-oscillation tests, and a description of testing techniques used is included.

WIND TUNNELS↗