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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

High-speed laser anemometry based on spectrally resolved Rayleigh scattering

Laser anemometry in unseeded flows based on the measurement of the spectrum of Rayleigh scattered laser light is reviewed. The use of molecular scattering avoids the well known problems (particle lag, biasing effects, seed generation, seed injection) of seeded flows. The fundamental limits on velocity measurement accuracy are determined using maximum likelihood methods. Measurement of the Rayleigh spectrum with scanning Fabry-Perot interferometers is analyzed and accuracy limits are established for both single pass and multipass configurations. Multipass configurations have much higher selectivity and are needed for measurements where there is a large amount of excess noise caused by stray laser light. It is shown that Rayleigh scattering is particularly useful for supersonic and hypersonic flows. The results of the analysis are compared with measurements obtained with a Rayleigh scattering diagnostic developed for study of the exhaust plume of a small hydrogen-oxygen rocket, where the velocities are in the range of 1000 to 5000 m/sec.

Seasholtz, Richard G.↗
NASA NTRS1991

High-speed laser anemometry based on spectrally resolved Rayleigh scattering

Laser anemometry in unseeded flows based on the measurement of the spectrum of Rayleigh scattered laser light is reviewed. The use of molecular scattering avoids the well-known problems (particle lag, biasing effects, seed generation, seed injection) of seeded flows. The fundamental limits on velocity measurement accuracy are determined using maximum likelihood methods. Measurement of the Rayleigh spectrum with scanning Fabry-Perot interferometers is analyzed and accuracy limits are established for both single pass and multi-pass configurations. Multi-pass configurations have much higher selectivity and are needed for measurements where there is a large amount of excess noise caused by stray laser light. It is shown that Rayleigh scattering is particularly useful for supersonic and hypersonic flows. The results of the analysis are compared with measurements obtained with a Rayleigh scattering diagnostic developed for study of the exhaust plume of a small hydrogen-oxygen rocket, where the velocities are in the range 1000 to 5000 m/sec.

Seasholtz, R. G.↗
NASA NTRS1996

Investigation of Condensation/Clustering Effects on Rayleigh Scattering Measurements in a Hypersonic Wind Tunnel

Rayleigh scattering, a nonintrusive measurement technique for the measurement of density in a hypersonic wind tunnel, is under investigation at Wright Laboratory's Mach 6 wind tunnel. Several adverse effects, i.e., extraneous scatter off walls and windows, hinder Rayleigh scattering measurements. Condensation and clustering of flow constituents also present formidable obstacles. Overcoming some of these difficulties, measurements have been achieved while the Mach 6 test section was pumped down to a vacuum, as well as for actual tunnel operation for various stagnation pressures at fixed stagnation temperatures. Stagnation pressures ranged from 0.69 MPa to 6.9 MPa at fixed stagnation temperatures of 511, 556, and 611 K. Rayleigh scatter results show signal levels much higher than expected for molecular scattering in the wind tunnel. Even with higher than expected signals, scattering measurements have been made in the flowfield of an 8-degree half-angle blunt nose cone with a nose radius of 1.5 cm.

Tyler, Charles↗
NASA NTRS1980

Effects of the Shuttle Orbiter fuselage and elevon on the molecular distribution of water vapor from the flash evaporator system

A concern has arisen regarding the emissive distribution of water molecules from the shuttle orbiter flash evaporator system (FES). The role of the orbiter fuselage and elevon in affecting molecular scattering distributions was nuclear. The effect of these components were evaluated. Molecular distributions of the water vapor effluents from the FE were measured. These data were compared with analytically predicted values and the resulting implications were calculated.

Richmond, R. G.↗
NASA NTRS1979

On the Angular Variation of Solar Reflectance of Snow

Spectral and integrated solar reflectance of nonhomogeneous snowpacks were derived assuming surface reflection of direct radiation and subsurface multiple scattering. For surface reflection, a bidirectional reflectance distribution function derived for an isotropic Gaussian faceted surface was considered and for subsurface multiple scattering, an approximate solution of the radiative transfer equation was studied. Solar radiation incident on the snowpack was decomposed into direct and atmospherically scattered radiation. Spectral attenuation coefficients of ozone, carbon dioxide, water vapor, aerosol and molecular scattering were included in the calculation of incident solar radiation. Illustrative numerical results were given for a case of North American winter atmospheric conditions. The calculated dependence of spectrally integrated directional reflectance (or albedo) on solar elevation was in qualitative agreement with available observations.

Chang, A. T. C.↗
NASA NTRS1981

On the angular variation of solar reflectance of snow

Spectral and integrated solar reflectance of nonhomogeneous snowpacks are derived assuming surface reflection of direct radiation and subsurface multiple scattering. For surface reflection, a bidirectional reflectance distribution function derived for an isotropic Gaussian faceted surface is considered, and for subsurface multiple scattering an approximate solution of the radiative transfer equation is studied. Solar radiation incident on the snowpack is decomposed into direct and atmospherically scattered radiation. Spectral attenuation coefficients of ozone, carbon dioxide, water vapor, aerosol, and molecular scattering are included in the calculation of incident solar radiation. Illustrative numerical results are given for a case of North American winter atmospheric condition. The calculated dependence of spectrally integrated directional reflectance (or albedo) on solar elevation is in qualitative agreement with available observations.

Choudhury, B. J.↗
DOE OSTI2021

Computing inelastic neutron scattering spectra from molecular dynamics trajectories

Abstract Inelastic neutron scattering (INS) provides a weighted density of phonon modes. Currently, INS spectra can only be interpreted for perfectly crystalline materials because of high computational cost for electronic simulations. INS has the potential to provide detailed morphological information if sufficiently large volumes and appropriate structural variety are simulated. Here, we propose a method that allows direct comparison between INS data with molecular dynamics simulations, a simulation method that is frequently used to simulate semicrystalline/amorphous materials. We illustrate the technique by analyzing spectra of a well-studied conjugated polymer, poly(3-hexylthiophene-2,5-diyl) (P3HT) and conclude that our technique provides improved volume and structural variety, but that the classical force field requires improvement before the morphology can be accurately interpreted.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Subvisual Cirrus cloud properties derived from a FIRE IFO case study

From the central Wisconsin IFO field at Wausau, the Mobile Polarization Lidar and a surface radiation station from the Lamont-Doherty Geological Observatory observed two very tenuous cirrus clouds on 21 October 1986. The clouds were present just below the height of the tropopause, between -60 to -70 C. The first cloud was not detected visually, and is classified as subvisual cirrus. The second, a relatively narrow cloud band that was probably the remnants of an aircraft contrail, can be termed zenith-subvisual since, although it was invisible in the zenith direction, it could be discerned when viewed at lower elevation angles and also due to strong solar forward-scattering and corona effects. The observations provide an opportunity to assess the threshold cloud optical thickness associated with cirrus cloud visibility. Ruby lidar backscattered signals were converted to isotropic volume backscatter coefficients by applying the pure-molecular scattering assumption just below the cloud base. The backscattering coefficient due to the cloud is then obtained and expressed in relation to the molecular backscattering coefficient in terms of the scattering ratio R. The linear depolarization ratio for the cloud is computed after removing the essentially parallel-polarized scattering contribution from air molecules. The values are also applied to determine the cloud optical thickness through the use of backscatter-to-extinction ratio, and the concentration of cloud particles using the backscattering gain, and the effective diameter of the particles obtained from the analysis of solar corona photographs. The sizes of the particles generating the corona are related to the angular separations between the centers of the red bands and the sun, yielding diameters of approximately 25 microns. The direct and diffuse components of shortwave radiation fluxes, measured by full hemispheric pyranometers, were used to compute the nadir optical thickness of the total atmosphere.

Sassen, Kenneth↗
NASA NTRS1998

Calculations of multiple scattering-induced errors in the GLAS mission

The Geoscience Lidar Altimeter System (GLAS) is a laser altimeter designed to measure temporal changes in the topography and mass balance of the Earth's ice sheets. GLAS is scheduled to be launched as part of the Earth Observing System (EOS) in 2001. Due to the large pulse width of GLAS and the slope (and roughness) of the ice sheets, the mean elevation of the laser's surface spot will be estimated from the centroid of the return pulse. While the accuracy of individual altimetry measurements is expected to be 15 cm, a cross-over technique that averages the elevation differences at selected points on the ice sheets will allow GLAS to detect mean ice elevation changes as small as 2 cm per year. One factor that may degrade the proposed accuracy of the altimeter measurements is the effect of multiple scattering by thin clouds and aerosols over the ice sheets. In the return pulse, some photons from the lidar are slightly deflected by cloud particles but still return to the instrument detector. Since these photons travel a longer path than photons that pass directly to and from the surface, the mean travel time of the pulse is lengthened and the centroid of the return pulse is shifted toward a later time . This study intends to determine the importance of this source of altimetry error in the GLAS measurements. Two methods will be used to estimate path delays in the GLAS lidar for a range of cloud conditions. An analytic expression of a doubly scattered return signal (Eloranta, 1972) will be compared to Monte Carlo simulations that estimate path delays by cloud, aerosol and molecular scattering. The results from both methods will be discussed in relationship to current knowledge of Arctic cloud climatology, and the impact of multiple scattering on GLAS altimeter measurements will be evaluated.

Duda, David P.↗
NASA NTRS1976

A scenario on polarization in a planetary atmosphere

A great deal of information can be obtained about aerosol and Rayleigh scattering by observing the polarization state for both reflected and transmitted radiation. Results of neutral point behavior are presented for (1) a Rayleigh or molecular scattering atmosphere; (2) a haze L distribution of aerosols typical of those found in the earth's atmosphere; and (3) two actual models of the earth's atmosphere which combine Rayleigh scattering with a normal aerosol content and with a one-third normal aerosol content.

Kattawar, G. W.↗
NASA NTRS2014

Extending 3D Near-Cloud Corrections from Shorter to Longer Wavelengths

Satellite observations have shown a positive correlation between cloud amount and aerosol optical thickness (AOT) that can be explained by the humidification of aerosols near clouds, and/or by cloud contamination by sub-pixel size clouds and the cloud adjacency effect. The last effect may substantially increase reflected radiation in cloud-free columns, leading to overestimates in the retrieved AOT. For clear-sky areas near boundary layer clouds the main contribution to the enhancement of clear sky reflectance at shorter wavelengths comes from the radiation scattered into clear areas by clouds and then scattered to the sensor by air molecules. Because of the wavelength dependence of air molecule scattering, this process leads to a larger reflectance increase at shorter wavelengths, and can be corrected using a simple two-layer model. However, correcting only for molecular scattering skews spectral properties of the retrieved AOT. Kassianov and Ovtchinnikov proposed a technique that uses spectral reflectance ratios to retrieve AOT in the vicinity of clouds; they assumed that the cloud adjacency effect influences the spectral ratio between reflectances at two wavelengths less than it influences the reflectances themselves. This paper combines the two approaches: It assumes that the 3D correction for the shortest wavelength is known with some uncertainties, and then it estimates the 3D correction for longer wavelengths using a modified ratio method. The new approach is tested with 3D radiances simulated for 26 cumulus fields from Large-Eddy Simulations, supplemented with 40 aerosol profiles. The results showed that (i) for a variety of cumulus cloud scenes and aerosol profiles over ocean the 3D correction due to cloud adjacency effect can be extended from shorter to longer wavelengths and (ii) the 3D corrections for longer wavelengths are not very sensitive to unbiased random uncertainties in the 3D corrections at shorter wavelengths.

aerosol optical depth↗
NASA NTRS1974

Optical polarization measurements of the Jupiter atmosphere at 103 deg phase angle

The first measurements have been made of the linear polarization of sunlight scattered by the Jupiter atmosphere at phase angles greater than 12 deg, using the imaging photopolarimeter on Pioneer 10. The data are of high accuracy, in spite of several problems in the instrument. The polarization is positive at 440 nm. There is no direct evidence for spherical particles in the Jupiter clouds. Using a simple model of Rayleigh scattering above a Lambertian cloud layer, a unique fit is found to the observed intensity and polarization at each point on the planet. The resulting Rayleigh optical depths, if they are attributed to molecular scattering alone (i.e., no aerosols above the cloud tops), can be converted into physical altitudes of the cloud tops. The first results suggest that the north tropical zone, parts of the equatorial zone, and the red spot are all elevated regions.

Coffeen, D. L.↗
NASA NTRS1988

Cloud and aerosol optical depths

An airborne Sun photometer was used to measure optical depths in clear atmospheres between the appearances of broken stratus clouds, and the optical depths in the vicinity of smokes. Results show that (human) activities can alter the chemical and optical properties of background atmospheres to affect their spectral optical depths. Effects of water vapor adsorption on aerosol optical depths are apparent, based on data of the water vapor absorption band centered around 940 nm. Smoke optical depths show increases above the background atmosphere by up to two orders of magnitude. When the total optical depths measured through clouds were corrected for molecular scattering and gaseous absorption by subtracting the total optical depths measured through the background atmosphere, the resultant values are lower than those of the background aerosol at short wavelengths. The spectral dependence of these cloud optical depths is neutral, however, in contrast to that of the background aerosol or the molecular atmosphere.

Pueschel, R. F.↗
NASA NTRS1990

Theoretical line shapes for rotational spectra of HCl in Ar

An interaction potential for HCl-Ar recently derived from spectra of van der Waals complexes (Hutson,1988) has been used to obtain converged close-coupling scattering S matrices from which pressure broadening (linewidth, line shift, and line coupling) cross sections have been computed within the Fano-Ben-Reuven formalism. Linewidths agree well with experimental data with the exception of the 0-1 line at low temperatures (an error of about 15 percent at 125 K). Line shifts, especially the largest, for the 0-1 line, are also in reasonable accord with experimental data. Line coupling is predicted to be quite small. The coupled-states molecular scattering approximation is found to be accurate except at very low collision energies. The infinite-order sudden approximations, on the other hand, is not reliable for this system. Inelastic scattering out of the spectroscopic levels accounts for only a fraction of the linewidth at thermal energies, especially in the lower rotational levels.

Green, Sheldon↗
DOE OSTI2024

Rovibrationally resolved Rayleigh and Raman scattering cross sections for molecular hydrogen

Accurate Rayleigh and Raman scattering cross sections, tensor components, depolarization ratios, and reversal coefficients for all rovibrational transitions within the X1Σg+ ground electronic state of H2 have been calculated. Raman spectra have been generated using these data. A method for calculating Raman scattering cross sections is formulated that is valid below the ionization threshold and in the region containing resonances, which explicitly accounts for all bound and dissociative vibrational levels of the bound intermediate electronic states and approximately accounts for the ionization continuum. A representative set of cross sections is presented for incident photon energies below 15 eV and compared with existing results in the literature where possible. Convergence of our results with an increasing number of bound intermediate electronic states is demonstrated. The accuracy of the Placzek–Teller approximation is discussed. The effect of accounting for the intermediate ionization continuum is investigated. Local thermal equilibrium cross sections are calculated for Rayleigh and Raman scattering. This work represents the most accurate and complete treatment of Raman scattering for molecular hydrogen to date. A total of 9582 Rayleigh and Raman scattering cross sections have been generated and are openly available on Zenodo under an open-source Creative Commons Attribution license at https://zenodo.org/doi/10.5281/zenodo.13441471.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1979

Wavelength dependence of polarization. XXXV - Vertical structure of scattering layers above the visible Venus clouds

Results of multiple-scattering computations based on whole-disk and Digicon polarization observations are presented which indicate vertical inhomogeneity in the upper atmosphere of Venus. It is shown that the whole-disk observations support a thin upper haze layer of 0.18-micron particles and that the low polarization observed near the limb and terminator requires a haze of slightly larger particles. The Digicon polar regions are found to exhibit increased polarization, which is compatible with CO2 absorption measurements and is explained by increased molecular scattering above the clouds. The decrease in cloud-top height for latitudes greater than 45 deg is estimated to be approximately 1.4 km.

Lane, W. A.↗
NASA NTRS1999

Current Status of Aerosol Retrievals from TOMS

Properties of atmospheric aerosols over all land and water surfaces are retrieved from TOMS measurements of backscattered radiances. The TOMS technique, uses observations at two wavelengths. In the near ultraviolet (330-380 nm) range, where the effects of gaseous absorption are negligible. The retrieved properties are optical depth and a measure of aerosol absorptivity, generally expressed as single scattering albedo. The main sources of error of the TOMS aerosol products are sub-pixel cloud contamination and uncertainty on the height above the surface of UV-absorbing aerosol layers. The first error source is related to the large footprint (50 x 50 km at nadir) of the sensor, and the lack of detection capability of sub-pixel size clouds. The uncertainty associated with the height of the absorbing aerosol layers, on the other hand, is related to the pressure dependence of the molecular scattering process, which is the basis of the near-UV method of absorbing aerosol detection. The detection of non-absorbing aerosols is not sensitive to aerosol layer height. We will report on the ongoing work to overcome both of these difficulties. Coincident measurements of high spatial resolution thermal infrared radiances are used to address the cloud contamination issue. Mostly clear scenes for aerosol retrieval are selected by examining the spatial homogeneity of the IR radiance measurements within a TOMS pixel. The approach to reduce the uncertainty associated with the height of the aerosol layer by making use of a chemical transport model will also be discussed.

Torres, O.↗