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At least 109 records · Page 6

Low-frequency fluctuations in the magnetosheath near the magnetopause

There are four low-frequency modes which may propagate in a high-beta nearly bi-Maxwellian plasma. These are the magnetosonic, Alfven, ion acoustic, and mirror modes. This manuscript defines a procedure based on linear Vlasov theory for the unique identification of these modes by use of transport ratios, dimensionless ratios of the fluctuating field and plasma quantities. A single parameter, the mode deviation is calculated using the plasma and magnetic field data gathered by the Active Magnetospheric Particle Tracer Explorers/Ion Release Module (AMPTE/IRM) spacecraft to identify the modes observed in the terrestial magnetosheath near the magnetopause. As well as determining the mode which best describes the observed fluctuations, it gives us a measure of whether or not the resulting identification is unique. Using 17 time periods temporally close to a magnetopause crossing, and confining our study to the frequency range from 0.01 to 0.04 Hz, we find that the only clearly identified mode in this frequency range is the mirror mode. Most commonly, the quasi-perpendicular mirror mode (with wave vector k roughly perpendicular to the background magnetic field B(sub zero) is observed. In two events the quasi-parallel mirror mode k parallel B(sub zero) was identified.

Denton, Richard E.↗

Emergent actin flows explain distinct modes of gliding motility

During host infection, Toxoplasma gondii and related unicellular parasites move using gliding, which differs fundamentally from other known mechanisms of eukaryotic cell motility. Gliding is thought to be powered by a thin layer of flowing filamentous (F)-actin sandwiched between the plasma membrane and a myosin-covered inner membrane complex. How this surface actin layer drives the various gliding modes observed in experiments—helical, circular, twirling and patch, pendulum or rolling—is unclear. Here we suggest that F-actin flows arise through self-organization and develop a continuum model of emergent F-actin flow within the confines provided by Toxoplasma geometry. In the presence of F-actin turnover, our model predicts the emergence of a steady-state mode in which actin transport is largely directed rearward. Removing F-actin turnover leads to actin patches that recirculate up and down the cell, which we observe experimentally for drug-stabilized actin bundles in live Toxoplasma gondii parasites. These distinct self-organized actin states can account for observed gliding modes, illustrating how different forms of gliding motility can emerge as an intrinsic consequence of the self-organizing properties of F-actin flow in a confined geometry.

59 BASIC BIOLOGICAL SCIENCES↗

Structures of glasses created by multiple kinetic arrests

X-ray scattering has been used to characterize glassy itraconazole (ITZ) prepared by cooling at different rates. Faster cooling produces ITZ glasses with lower (or zero) smectic order with more sinusoidal density modulation, larger molecular spacing, and shorter lateral correlation between the rod-like molecules. We find that each glass is characterized by not one, but two fictive temperatures T f (the temperature at which a chosen order parameter is frozen in the equilibrium liquid). The higher T f is associated with the regularity of smectic layers and lateral packing, while the lower T f with the molecular spacings between and within smectic layers. This indicates that different structural features are frozen on different timescales. The two timescales for ITZ correspond to its two relaxation modes observed by dielectric spectroscopy: the slower δ mode (end-over-end rotation) is associated with the freezing of the regularity of molecular packing and the faster α mode (rotation about the long axis) with the freezing of the spacing between molecules. Finally, our finding suggests a way to selectively control the structural features of glasses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A STUDY OF FUNDAMENTAL LIMITATIONS TO STATISTICAL DETECTION OF REDSHIFTED H I FROM THE EPOCH OF REIONIZATION

In this paper, we explore for the first time the relative magnitudes of three fundamental sources of uncertainty, namely, foreground contamination, thermal noise, and sample variance, in detecting the H I power spectrum from the epoch of reionization (EoR). We derive limits on the sensitivity of a Fourier synthesis telescope to detect EoR based on its array configuration and a statistical representation of images made by the instrument. We use the Murchison Widefield Array (MWA) configuration for our studies. Using a unified framework for estimating signal and noise components in the H I power spectrum, we derive an expression for and estimate the contamination from extragalactic point-like sources in three-dimensional k-space. Sensitivity for EoR H I power spectrum detection is estimated for different observing modes with MWA. With 1000 hr of observing on a single field using the 128 tile MWA, EoR detection is feasible (S/N >1 for k ∼< 0.8 Mpc{sup –1}). Bandpass shaping and refinements to the EoR window are found to be effective in containing foreground contamination, which makes the instrument tolerant to imaging errors. We find that for a given observing time, observing many independent fields of view does not offer an advantage over a single field observation when thermal noise dominates over other uncertainties in the derived power spectrum.

79 ASTRONOMY AND ASTROPHYSICS↗

A Physical Model-based Correction for Charge Traps in the Hubble Space Telescope ’s Wide Field Camera 3 Near-IR Detector and Its Applications to Transiting Exoplanets and Brown Dwarfs

The Hubble Space Telescope Wide Field Camera 3 (WFC3) near-IR channel is extensively used in time-resolved observations, especially for transiting exoplanet spectroscopy as well as brown dwarf and directly imaged exoplanet rotational phase mapping. The ramp effect is the dominant source of systematics in the WFC3 for time-resolved observations, which limits its photometric precision. Current mitigation strategies are based on empirical fits and require additional orbits to help the telescope reach a thermal equilibrium . We show that the ramp-effect profiles can be explained and corrected with high fidelity using charge trapping theories. We also present a model for this process that can be used to predict and to correct charge trap systematics. Our model is based on a very small number of parameters that are intrinsic to the detector. We find that these parameters are very stable between the different data sets, and we provide best-fit values. Our model is tested with more than 120 orbits (∼40 visits) of WFC3 observations and is proved to be able to provide near photon noise limited corrections for observations made with both staring and scanning modes of transiting exoplanets as well as for starting-mode observations of brown dwarfs. After our model correction, the light curve of the first orbit in each visit has the same photometric precision as subsequent orbits, so data from the first orbit no longer need to be discarded. Near-IR arrays with the same physical characteristics (e.g., JWST/NIRCam ) may also benefit from the extension of this model if similar systematic profiles are observed.

79 ASTRONOMY AND ASTROPHYSICS↗

Quantifying the agreement between observed and simulated extratropical modes of interannual variability

Using historical simulations of the Coupled Model Intercomparison Project-5 (CMIP5) and multiple observationally-based datasets, we employ skill metrics to analyze the fidelity of the simulated Northern Annular Mode, the North Atlantic Oscillation, the Pacific North America pattern, the Southern Annular Mode, the Pacific Decadal Oscillation, the North Pacific Oscillation, and the North Pacific Gyre Oscillation. We assess the benefits of a unified approach to evaluate these modes of variability, which we call the common basis function (CBF) approach, based on projecting model anomalies onto observed empirical orthogonal functions (EOFs). The CBF approach circumvents issues with conventional EOF analysis, eliminating, for example, corrections of arbitrarily assigned, but inconsistent, signs of the EOF’s/PC’s being compared. It also avoids the problem that sometimes the first observed EOF is more similar to a higher order model EOF, particularly if the simulated EOFs are not well separated. Compared to conventional EOF analysis of models, the CBF approach indicates that models compare significantly better with observations in terms of pattern correlation and root-mean-squared-error (RMSE) than heretofore suggested. In many cases, models are doing a credible job at capturing the observationally-based estimates of patterns; however, errors in simulated amplitudes can be large and more egregious than pattern errors. In the context of the broad distribution of errors in the CMIP5 ensemble, sensitivity tests demonstrate that our results are relatively insensitive to methodological considerations (CBF vs. conventional approach), observational uncertainties in pattern (as determined by using multiple datasets), and internal variability (when multiple realizations from the same model are compared). The skill metrics proposed in this study can provide a useful summary of the ability of models to reproduce the observed EOF patterns and amplitudes. Additionally, the skill metrics can be used as a tool to objectively highlight where potential model improvements might be made. Finally, we advocate more systematic and objective testing of simulated extratropical variability, especially during the non-dominant seasons of each mode, when many models are performing relatively poorly.

58 GEOSCIENCES↗

Evaluation of Leading Modes of Climate Variability in the CMIP Archives

The adequate simulation of internal climate variability is key for our understanding of climate as it underpins efforts to attribute historical events, predict on seasonal and decadal time scales, and isolate the effects of climate change. Here the skill of models in reproducing observed modes of climate variability is assessed, both across and within the CMIP3, CMIP5, and CMIP6 archives, in order to document model capabilities, progress across ensembles, and persisting biases. A focus is given to the well-observed tropical and extratropical modes that exhibit small intrinsic variability relative to model structural uncertainty. These include El Niño–Southern Oscillation (ENSO), the Pacific decadal oscillation (PDO), the North Atlantic Oscillation (NAO), and the northern and southern annular modes (NAM and SAM). Significant improvements are identified in models’ representation of many modes. Canonical biases, which involve both amplitudes and patterns, are generally reduced across model generations. For example, biases in ENSO-related equatorial Pacific sea surface temperature, which extend too far westward, and associated atmospheric teleconnections, which are too weak, are reduced. Stronger tropical expression of the PDO in successive CMIP generations has characterized their improvement, with some CMIP6 models generating patterns that lie within the range of observed estimates. For the NAO, NAM, and SAM, pattern correlations with observations are generally higher than for other modes and slight improvements are identified across successive model generations. Finally, for ENSO and PDO spectra and extratropical modes, changes are small compared to internal variability, precluding definitive statements regarding improvement.

54 ENVIRONMENTAL SCIENCES↗

Plasma confinement regimes and collective modes characterizing them

A unified theory is presented for the modes that are excited at the edge of the plasma column and are important signatures of the advanced confinement regimes into which magnetically confined plasmas can be driven. In particular, the so-called EDA H-Regime, the Elmy H-Regime, and the I-Regime are considered. The modes that are identified theoretically have characteristics that are consistent with or have anticipated those of the modes observed experimentally for each of the investigated regimes. The phase velocities, the produced transport processes, the frequencies, the wavelengths, and the consistency with the direction of spontaneous rotation are the factors considered for comparison with the relevant experiments. The quasi-coherent mode [I. Cziegler, Ph.D. dissertation, Massachusetts Institute of Technology, Cambridge, MA, 2011] that is present in the EDA H-Regime has a phase velocity in the direction of the ion diamagnetic velocity in the plasma reference frame. Consequently, this is identified as a ballooning mode near finite Larmor radius marginal stability involving the effects of transverse ion viscosity and other dissipative effects. In this regime, impurities are driven outward by the combined effects of the local temperature gradients of the impurities and their thermal conductivity, while in the Elmy H-Regime impurities are driven toward the center of the plasma column. In the I-Regimes, the excited 'Heavy Particle' modes [B. Coppi and T. Zhou, Phys. Plasmas 19, 012302 (2012); Phys. Lett. A 375, 2916 (2011)] are not of the ballooning kind and are shown to expel the impurities toward the plasma edge in the presence of significant fluctuations. These modes can have a finite frequency of oscillation with a phase velocity in the direction of the electron diamagnetic velocity or they can be nearly purely growing, explaining why there are I-Regimes where fluctuations are not observed. Instead, the modes considered for the Elmy H-Regime are of the ballooning kind. They are driven by the combined effects of the plasma pressure gradient and the magnetic field curvature, are close to conditions under which the acquired growth rates are proportional to half power of the relevant dissipation parameters, involve the effects of finite magnetic diffusivity and finite electron thermal conductivity, and can have phase velocities in either direction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Deposition of stress free c-axis oriented LiNbO{sub 3} thin film grown on (002) ZnO coated Si substrate

C-axis oriented lithium niobate thin films have been deposited on Si substrate using RF sputtering technique. A thin buffer layer of c-axis (002) oriented ZnO on Si substrate has been used as a nucleating layer to promote the growth of (006) oriented LiNbO{sub 3} film. The processing gas composition and pressure are found to be very critical in obtaining stress free LiNbO{sub 3} film having desired (006) orientation. The LiNbO{sub 3} films deposited under unique combination of sputtering pressure (10 mTorr) and argon percentage (80%) in reactive gas (Ar + O{sub 2}) composition become almost stress free having lattice parameter (1.3867 A) close to the bulk value. The observed variation in the structural properties and optical phonon modes observed by Raman spectroscopic studies of the oriented LiNbO{sub 3} thin film with stress has been correlated with growth kinetics.

36 MATERIALS SCIENCE↗

Alfvén mode induced particle loss in LHD

Herein losses of beam ions due to Alfvén modes are simulated for discharges in the Large Helical Device at Toki, Japan, using a guiding center code. High frequency beam particle resonances are found for the equilibria for passing particles, providing locations for the destablization of Alfvén modes observed in the device. Losses due to even small modes due to these resonances are significant.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Design and performance of Soft Gamma-ray Detector onboard the Hitomi (ASTRO-H) satellite

Hitomi (ASTRO-H) was the sixth Japanese x-ray satellite that carried instruments with exquisite energy resolution of <7 eV and broad energy coverage of 0.3 to 600 keV. The Soft Gamma-ray Detector (SGD) was the Hitomi instrument that observed the highest energy band (60 to 600 keV). The SGD design achieves a low background level by combining active shields and Compton cameras where Compton kinematics is utilized to reject backgrounds coming from outside of the field of view. A compact and highly efficient Compton camera is realized using a combination of silicon and cadmium telluride semiconductor sensors with a good energy resolution. Compton kinematics also carries information for gamma-ray polarization, making the SGD an excellent polarimeter. Following several years of development, the satellite was successfully launched on February 17, 2016. After proper functionality of the SGD components were verified, the nominal observation mode was initiated on March 24, 2016. The SGD observed the Crab Nebula for approximately two hours before the spacecraft ceased to function on March 26, 2016. We present concepts of the SGD design followed by detailed description of the instrument and its performance measured on ground and in orbit.

79 ASTRONOMY AND ASTROPHYSICS↗

Infrared laser spectroscopy of the n -propyl and i -propyl radicals: Stretch-bend Fermi coupling in the alkyl CH stretch region

The n -propyl and i -propyl radicals were generated in the gas phase via pyrolysis of n -butyl nitrite [CH 3 (CH 2 ) 3 ONO] and i -butyl nitrite [(CH 3 ) 2 CHCH 2 ONO], respectively. Nascent radicals were promptly solvated by a beam of He nanodroplets, and the infrared spectra of the radicals were recorded in the CH stretching region. Several previously unreported bands are observed between 2800 and 3150 cm –1 . The CH stretching modes observed above 3000 cm –1 are in excellent agreement with CCSD(T) anharmonic frequencies computed using second-order vibrational perturbation theory. However, between 2800 and 3000 cm –1 , the spectra of n - and i -propyl radicals become congested and difficult to assign due to the presence of multiple anharmonic resonance polyads. To model the spectrally congested region, Fermi and Darling-Dennison resonances are treated explicitly using “dressed” Hamiltonians and CCSD(T) quartic force fields in the normal mode representation, and the agreement with experiment is less than satisfactory. Computations employing local mode effective Hamiltonians reveal the origin of the spectral congestion to be strong coupling between the high frequency CH stretching modes and the lower frequency CH n bending/scissoring motions. The most significant coupling is between stretches and bends localized on the same CH 2 /CH 3 group. As a result, spectral simulations using the local mode approach are in excellent agreement with experiment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Temperature-dependent structural studies of mullite-type Bi{sub 2}Fe{sub 4}O{sub 9}

We report on the temperature-dependent structural studies on the mullite-type Bi{sub 2}Fe{sub 4}O{sub 9} compound. The crystal structures were determined using both powder X-ray diffraction and single crystal neutron diffraction. The thermal expansion of the cell parameters from smallest to largest occurred in the order a<c<b; their expansion behavior was fit using either linear or nonlinear regression according to the region of choice. The anisotropic thermal expansion was monitored with respect to the expansion coefficients, anisotropy factor, and polyhedral geometry. At 900 K an abrupt change of the anisotropy factor is observed which correlates with a slope in the BiO{sub 6} polyhedral volume. At the same temperature the FeO{sub 4} tetrahedral distortion starts to increase. The temperature-dependent stereochemically activity of the Bi{sup 3+} 6s{sup 2} lone electron pair was probed by the absolute value of eccentricity parameter. This parameter shows a significant drop at around 773 K. Additionally, the average crystal size and micro-strain of the powder samples were studied. A healing of intrinsic defects is observed with respect to a decreasing micro-strain followed by crystal growth above about 900 K. The temperature-dependent infrared spectra were described in three distinct zones. Deconvolution of the absorption features between 370 cm{sup -1} and 1000 cm{sup -1} required nine fitted bands, and the decomposed Pseudo-Voigt elements were assigned to Fe-O stretching, Fe-O-Fe bending and O-Fe-O bending vibrations. The shift of the observed modes was described with respect to temperature. An effective linewidth parameter {Delta}corr was determined by autocorrelation analysis between 740 cm{sup -1} and 900 cm{sup -1} for each temperature-dependent spectrum. The break of the slope of {Delta}corr at about 773 K was interpreted as the change of some vibrational modes of the FeO{sub 4} tetrahedra. The intrinsic effects observed around 773 K are responsible for extrinsic parameter changes found around 900 K. - Graphical abstract: Temperature-dependent stereochemical activity (eccentricity |{Phi}{sub i}|) of the Bi{sup 3+} 6s{sup 2} lone electron pair directing in the non-bonded region of the Bi-O coordination in the Bi{sub 2}Fe{sub 4}O{sub 9} iron framework (given as polyhedra). Highlights: Black-Right-Pointing-Pointer Complex expansion-contraction mechanism explains anisotropic thermal expansion. Black-Right-Pointing-Pointer Bi 6s{sup 2} lone electron pair sphericity influences analyses by FTIR autocorrelation. Black-Right-Pointing-Pointer Intrinsic effects at 773 K are responsible for extrinsic parameter changes at 900 K.

36 MATERIALS SCIENCE↗

Ultrafast Three-Dimensional Integrated Imaging of Strain in Core/Shell Semiconductor/Metal Nanostructures

Visualizing the dynamical response of material heterointerfaces is increasingly important for the design of hybrid materials and structures with tailored properties for use in functional devices. In situ characterization of nanoscale heterointerfaces such as metal-semiconductor interfaces, which exhibit a complex interplay between lattice strain, electric potential, and heat transport at subnanosecond time scales, is particularly challenging. Here in this work, we use a laser pump/X-ray probe form of Bragg coherent diffraction imaging (BCDI) to visualize in three-dimension the deformation of the core of a model core/shell semiconductor-metal (ZnO/Ni) nanorod following laser heating of the shell. We observe a rich interplay of radial, axial, and shear deformation modes acting at different time scales that are induced by the strain from the Ni shell. We construct experimentally informed models by directly importing the reconstructed crystal from the ultrafast experiment into a thermo-electromechanical continuum model. The model elucidates the origin of the deformation modes observed experimentally. Our integrated imaging approach represents an invaluable tool to probe strain dynamics across mixed interfaces under operando conditions.

36 MATERIALS SCIENCE↗

The excitation and damping of solar oscillations

The status of understanding of the excitation and damping of solar p-mode oscillations is reviewed. While a few simple statements can be made about the expected properties of p-modes, there is currently no complete theory which explains the observed mode amplitudes and linewidths. Evidence suggests that the p-modes cannot be overstable and therefore self-excited, but are instead probably stochastically excited by turbulent convection. The status of the latter model for exciting p-modes, and possible future directions are discussed.

Libbrecht, Ken G.↗

The photometric properties of the HST astrometer Fine Guidance Sensor

This paper presents the results of the photometric calibration of the F583W filter in the astrometer Fine Guidance Sensor on the Hubble Space Telescope. Dozens of observations of the 9.58 mag Fine Guidance Sensor (FGS) transfer mode reference star Upgren 69 (in the cluster NGC 188) have been utilized to verify the consistency and demonstrate the temporal stability of the photomultipliers. The measurements which provided the material for a transformation from the FGS instrumental system to the Johnson V magnitude consisted of the extensive position mode observations performed during the Optical Field Angle Distortion calibration. A total of 588 measurements of 92 stars in the galactic cluster M35 were performed. Johnson V band photometry with a precision (i.e., random errors) of plus or minus 0.05 mag is available with an accuracy (i.e., systematic errors) of 0.05 mag over 2 yr.

Bucciarelli, B.↗

Development of a Two-Wheel Contingency Mode for the MAP Spacecraft

In the event of a failure of one of MAP's three reaction wheel assemblies (RWAs), it is not possible to achieve three-axis, full-state attitude control using the remaining two wheels. Hence, two of the attitude control algorithms implemented on the MAP spacecraft will no longer be usable in their current forms: Inertial Mode, used for slewing to and holding inertial attitudes, and Observing Mode, which implements the nominal dual-spin science mode. This paper describes the effort to create a complete strategy for using software algorithms to cope with a RWA failure. The discussion of the design process will be divided into three main subtopics: performing orbit maneuvers to reach and maintain an orbit about the second Earth-Sun libration point in the event of a RWA failure, completing the mission using a momentum-bias two-wheel science mode, and developing a new thruster-based mode for adjusting the inertially fixed momentum bias. In this summary, the philosophies used in designing these changes is shown; the full paper will supplement these with algorithm descriptions and testing results.

Starin, Scott R.↗

Raman Fingerprints of Phase Transitions and Ferroic Couplings in van der Waals Multiferroic CuCrP 2 S 6

CuCrP 2 S 6 (CCPS), a type-II multiferroic material, exhibits unique phase transitions involving ferroelectric, antiferroelectric, and antiferromagnetic ordering. Here, in this study, we conduct a comprehensive investigation on the intricate phase transitions and their multiferroic couplings in CCPS across a wide temperature range from 4 to 345 K through Raman spectroscopic measurements down to 5 cm –1 . We first assign the observed Raman modes with the support of theoretical calculations and angle-resolved polarized Raman measurements. We further present clear signatures of phase transitions from the analyses of temperature-dependent Raman spectral parameters. Particularly, two low-frequency soft modes are observed at 36.1 cm –1 and 70.5 cm –1 below 145 K, indicating the antiferroelectric to quasi-antiferroelectric transition. Moreover, phonon mode hardening is observed when the temperature increases from 4 to 65 K, suggesting negative thermal expansion (NTE) and strong magnetoelastic coupling below 65 K. These findings advance the understanding of vdW multiferroic CCPS, paving the way for future design and engineering of multiferroicity in cutting-edge technologies, such as spintronics and quantum devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗