Search NASA⌕ Search

SEARCH · Search NASA

Results for “particulate composites”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

Thermal infrared (2.5-13.5-micron) spectroscopic remote sensing of igneous rock types on particulate planetary surfaces

The compositional significance of outstanding spectral features in the reflectance spectra of particulate igneous rocks was investigated by analyzing directional reflectance spectra, obtained with an FTIR spectrophotometer at 2.17-13.5 microns, of a suite of well-characterized igneous rocks ground to fine particle size. It was found that, using spectral features associated with the principal Christiansen frequency and with a region of relative transparency between the Si-O stretching and bending bands, it is possible to identify general rock type using the Walter and Salisbury (1989) SCFM chemical index, SCFM, defined as SCFM = SiO2/(SiO2 + CaO + FeO + MgO). It is emphasized, however, that the appearance and the wavelength of these features may be affected by environmental factors.

Salisbury, John W.↗

Morphology and elemental composition analysis by size of rocket particulate effluent

Particulate samples collected on six stages of a quartz crystal microbalance cascade impactor mounted in an aircraft traversing the plume of a large solid-fueled rocket are analyzed, postflight, by scanning electron microscopy (SEM) and energy dispersed X-ray (EDXRA). The results indicate the morphology and elemental composition of the particles fall into several distinct groups. Those larger than about 0.5 micron in diameter and nearly spherical in shape contain, among elements with atomic numbers of 11 and higher, only aluminum, suggesting they are aluminum oxide formed in the solid rocket fuel combustion. Still larger but less symmetrical particles contain only sodium and chlorine. Particles much smaller than 0.5 micron seem to end up as agglomerates after impaction (or during the impaction process), and show a complex elemental make-up of Na, Al, S, Cl, K, Ca, Fe and Zn. The unagglomerated single particles smaller than 0.2 micron, on the other hand, show no evidence of elements above atomic number 11 at all, suggesting they may be carbon or hydrocarbon particles.

Chuan, R. L.↗

NiAl-base composite containing high volume fraction of AlN for advanced engines

A particulate reinforced NiAl-AlN composite alloy has a NiAl matrix and greater than about 13 volume percent fine particles of AlN within the matrix. The particles preferably have a diameter from about 15 nanometers to about 50 nanometers. The particulate reinforced NiAl-AlN composite alloy may be prepared by cryomilling prealloyed NiAl in liquid nitrogen using grinding media having a diameter of from about 2 to 6 mm at an impeller speed of from about 450 RPM to about 800 RPM. The cryomilling may be done for a duration of from about 4 hours to about 20 hours to obtain a cryomilled powder. The cryomilled powder may be consolidated to form the particulate reinforced NiAl-AlN composite alloy. The particulate reinforced alloy can further include a toughening alloy. The toughening alloy may include NiCrAlY, FeCrAlY, and FeAl.

Hebsur, Mohan↗

Nial-base composite containing high volume fraction of AlN for advanced engines

A particulate reinforced NiAl-AlN composite alloy has a NiAl matrix and greater than about 13 volume percent fine particles of AlN within the matrix. The particles preferably have a diameter from about 15 nanometers to about 50 nanometers. The particulate reinforced NiAl-AlN composite alloy may be prepared by cryomilling prealloyed NiAl in liquid nitrogen using grinding media having a diameter of from about 2 mm to about 6 mm at an impeller speed of from about 450 RPM to about 800 RPM. The cryomilling may be done for a duration of from about 4 hours to about 20 hours to obtain a cryomilled powder. The cryomilled powder may be consolidated to form the particulate reinforced NiAl-AlN composite alloy. The particulate reinforced alloy can further include a toughening alloy. The toughening alloy may include NiCrAlY, FeCrAY and FeAl.

Hebsur, Mohan G.↗

Mechanics of composite materials: Recent advances; Proceedings of the Symposium, Virginia Polytechnic Institute and State University, Blacksburg, VA, August 16-19, 1982

The present conference on the mechanics of composites discusses microstructure's influence on particulate and short fiber composites' thermoelastic and transport properties, the elastoplastic deformation of composites, constitutive equations for viscoplastic composites, the plasticity and fatigue of metal matrix composites, laminate damping mechanisms, the micromechanical modeling of Kevlar/epoxy composites' time-dependent failure, the variational characterization of waves in composites, and computational methods for eigenvalue problems in composite design. Also discussed are the elastic response of laminates, elastic coupling nonlinear effects in unsymmetrical laminates, elasticity solutions for laminate problems having stress singularities, the mechanics of bimodular composite structures, the optimization of laminated plates and shells, NDE for laminates, the role of matrix cracking in the continuum constitutive behavior of a damaged composite ply, and the energy release rates of various microcracks in short fiber composites.

Hashin, Z.↗

An ICME Modeling Framework for Metal Matrix Composites Focusing on Ultrahigh Temperature Matrix Material and Tungsten Carbide Reinforcement Particulate (Final CRADA Report)

Ultra High Temperature Metal Matrix Composites (UHT-MMCs) are of interest to the due to their potential defense and aerospace applications. These materials consist of a metal matrix reinforced with a stiff ceramic or cermet. Based on a preliminary literature survey, this project will focused on a pure titanium (Ti) matrix reinforced with tungsten carbide-cobalt (WC-Co). UHT-MMC technology is still at a nascent stage of development and requires extensive experimental work to optimize the structure and resulting material properties of a particular UHT-MMC material system. An accurate and complete high-performance computing (HPC) model of the Ti/WC-Co material system could greatly accelerate the development and deployment Ti/WC-Co materials by connecting processing parameters to material properties. This type of model could then be used in an integrated computational materials engineering approach to optimize the material structure to achieve a targeted level of performance.

36 MATERIALS SCIENCE↗

Kinetics of gas-to-liquid and liquid-to-solid transfer of particles in metal-matrix composites

Analytical models for transfer of particles from gas to liquid and from liquid to solid are introduced. The model for calculation of the pushing/engulfment transition in directionally solidified particulate metal matrix composites, considers process thermodynamics, process kinetics, thermophysical properties and buoyant forces. Based on processing variables (solidification velocity and direction) and on material variables (interface energies, particle size, particle and liquid density, volume fraction of particles and particle/liquid thermal conductivity ratio) four types of behavior were predicted. Also, two numerical models for liquid-to-solid transfer are discussed, as well as the limitations of presently available models.

Stefanescu, D. M.↗

Investigation of Lubricant Additive Interactions on Gasoline Particulate Filters

To understand how the composition of novel lubricant additives and their ash interact with gasoline particulate filters (GPFs), an accelerated aging protocol was conducted using three lubricant additive formulations and two GPF types. The additive packages (adpaks) consisted of Ca+Mg detergent in a 3:1 or 0:1 ratio and an anti-wear component—either zinc dialkyl dithiophosphate (ZDDP) or a novel phosphonium-phosphinate ionic liquid (IL) substitute. The particulate sampling captured amount/compositions of particulate matter (PM) generated, total particulate number, and size distribution. Five ash loadings were completed. GPF position and adpak composition affected the backpressure, ash composition, ash morphology, and captured mass. The particulate sampling indicated that the ash component consisted primarily of particles less than 50 nm in size and that the Mg-only adpak resulted in more particulate of 50–400 nm in size. Postmortem materials characterization indicated GPFs in the underfloor position had deeper penetration of ash into the walls compared to the close-coupled position. Additionally, the Mg-only adpak had a higher filter collection efficiency (>90%) and the ash particles consisted of a higher concentration of dense ash material. In contrast, four of the 3:1 Ca:Mg lubricant adpaks resulted in a collection efficiency of only 40–50%. Although the collection efficiency was higher with the Mg-only adpak, the ash layer in the GPF was not thicker, nor was the penetration into the wall more significant, and surprisingly the full useful life (FUL) backpressure was lower than with Ca:Mg adpaks. The higher density of the Mg-derived ash was the only detectable difference. A possible explanation of this observation is that Mg ash has a lower melting point and is more susceptible to densification during combustion or GPF regeneration. The substitution of IL in place of the ZDDP did not lead to any notable changes in collection efficiency or location of the ash.

42 ENGINEERING↗

Remote monitoring of environmental particulate pollution - A problem in inversion of first-kind integral equations

The determination of the microstructure, chemical nature, and dynamical evolution of scattering particulates in the atmosphere is considered. A description is given of indirect sampling techniques which can circumvent most of the difficulties associated with direct sampling techniques, taking into account methods based on scattering, extinction, and diffraction of an incident light beam. Approaches for reconstructing the particulate size distribution from the direct and the scattered radiation are discussed. A new method is proposed for determining the chemical composition of the particulates and attention is given to the relevance of methods of solution involving first kind Fredholm integral equations.

Fymat, A. L.↗

Effect of Pigmentation in Particulate Formation from Fluoropolymer Thermodegradation in Microgravity

Fires aboard spacecraft have occurred as a result of overheated electrical wires and thermodegradation of their insulation, which is composed of fluoropolymers. The particulate products of polymer thermodegradation are only 20-50 run in diameter and are thought to play a role in "polymer fume fever". Therefore an experimental study of the particulates produced by intense ohmic heating of various fluoropolymer-insulated 20 AWG copper wire (representative of spacecraft materials) was undertaken in normal gravity and in microgravity. The 2.2 s drop facility at NASA LeRC and 1.5 s drop facility at the Colorado School of Mines were used to achieve low gravity conditions. Thermophoretic sampling was used for particulate collection. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) were used to characterize the smoke particulates. It was found that the color of PTFE (Polytetrafluoroethylene) insulation has an overwhelming effect on the size, shape, morphology and, composition of the particulates. Size distributions and shape analyses using computerized image analysis showed that particle size distributions were also dependent on the pigment of the fluoropolymer insulation. The influence of pigment was observed in experiments under both normal and microgravity. Under microgravity conditions, owing to the lack of natural convective transport of particulates, much more particle aggregation was observed, and the nature of the aggregates was dependent on the color of the insulation.

Srivastava, Rajiv↗

Methods for providing ceramic matrix composite components with increased thermal capacity

A method for enhancing the cooling capability of a turbine component made from a ceramic matrix composite. The method improves the thermal performance of the component by producing a surface having increased cooling capacity, thereby allowing the component to operate at a higher temperature. The method tailors the available surface area on the cooling surface of the composite component by depositing a particulate layer of coarse grained ceramic powders of preselected size onto the surface of the ceramic matrix composite component. The size of the particulate is selectively tailored to match the desired surface finish or surface roughness of the article. The article may be designed to have different surface finishes for different locations, so that the application of different sized powders can provide different cooling capabilities at different locations, if desired. The compositions of the particulates are chemically compatible with the ceramic material comprising the outer surface or portion of the ceramic matrix composite. The particulates are applied using a slurry and incorporated into the article by heating to an elevated temperature without melting the matrix, the particulates or the fiber reinforcement.

Steibel, James Dale↗

Compositional Variation Tests on DuraMelter 100 with LAW Sub-Envelope A1 Feed (LAWA44 Glass) in Support of the LAW Pilot Melter, VSL-02R62N0-4, Rev. 0 (Nov 2002)

The two tests described in this report utilized blended feed (glass formers plus waste simulant) prepared by Optima Chemicals according to VSL specifications generating about 1. 7 metric tons of glass. Sugar was added (at VSL) to the nominal feed at a "sugar ratio" of 0.5 for each of the two variation tests1; however, since the sugar addition is assumed to be "blind" to the variations, the actual sugar ratios were 0.57 and 0.44. The DMl00-WV melter was used in order to provide a direct comparison with the LAW tests previously conducted on the same melter. Two 100-hour melter tests were conducted: one with a 15% deficiency in simulant and one with 15% excess in simulant. Key operating parameters including cold cap coverage, feed rate, and glass pool temperature were held constant to investigate the effects of the glass compositional changes on processing characteristics (including salt formation) and the product glass. The bubbling rate was adjusted to provide the desired glass production rate with a near complete cold cap (90-100% of melt surface covered with feed). Quantitative measurements of glass production rates, melter operating conditions (temperatures, pressures, power, flows, etc.), and off-gas characteristics (NOx, SO 2, CO, particulate load and composition, and acid gases) were made for each test.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Detection techniques for tenuous planetary atmospheres

Electrostatic charging of dust and its effect on planetary atmospheres is discussed, along with its applications to Martian atmosphere. Laboratory and field experiments in dust storms indicate that the major atmospheric parameters on Mars include: (1) pressure, temperature, and relative humidity; (2) wind velocity and direction; (3) particulate size and composition; and (4) electrostatic charge and field gradient. Various instrumentation techniques adapted for a Mars Lander are briefly reviewed. The effect of exoelectron emission on surface catalysis is studied.

Hoenig, S. A.↗

Particle Engulfment and Pushing by Solidifying Interfaces

The scientific objectives of the work on Particle Engulfment and Pushing by Solidifying Interfaces (PEP) include: (1) to enhance the fundamental understanding of the physics of interaction between inert particles and the solidification interface, and (2) to investigate aspects of melt processing of particulate metal matrix composites in the unique microgravity environment that will yield some vital information for terrestrial applications. The proposal itself calls for a long-term effort on the Space Station. This paper reports on ground experiments performed to date, as well as on the results obtained from two flight opportunities, the LMS mission (1996) and the USMP-4 mission (1997).

Stefanescu, Doru M.↗

Total Optical Depth Analysis for NO2, O3 and Aerosols by a Multi-Filter Shadowband Radiometer

The main focus of this research is the retrieval of tropospheric aerosol information using a Multi-filter Rotating Shadowband Radiometer, Model MFR-7, placed on the roof of the Science Building at Medgar Evers College. This instrument makes precise measurements of atmospheric extinction of the direct solar beam simultaneously at six wavelengths (475, 500, 615, 670, 840 and 940 nm) at one minute intervals throughout the day. We are interested in measuring the changes in the optical depth of ambient aerosols, mass, effective particle size, aerosol size distribution, and chemical composition of ambient particulate matter in the Greater New York City Area. Results will be compared with data obtained by A. Lacis, B. Carlson and B. Cairns at the NASA Goddard Institute for Space Studies.

Williamson, Lorenzo↗

PHALANX: Expendable Projectile Sensor Networks for Planetary Exploration

Technologies enabling long-term, wide-ranging measurement in hard-to-reach areas are a critical need for planetary science inquiry. Phenomena of interest include flows or variations in volatiles, gas composition or concentration, particulate density, or even simply temperature. Improved measurement of these processes enables understanding of exotic geologies and distributions or correlating indicators of trapped water or biological activity. However, such data is often needed in unsafe areas such as caves, lava tubes, or steep ravines not easily reached by current spacecraft and planetary robots. To address this capability gap, we have developed miniaturized, expendable sensors which can be ballistically lobbed from a robotic rover or static lander - or even dropped during a flyover. These projectiles can perform sensing during flight and after anchoring to terrain features. By augmenting exploration systems with these sensors, we can extend situational awareness, perform long-duration monitoring, and reduce utilization of primary mobility resources, all of which are crucial in surface missions. We call the integrated payload that includes a cold gas launcher, smart projectiles, planning software, network discovery, and science sensing: PHALANX. In this paper, we introduce the mission architecture for PHALANX and describe an exploration concept that pairs projectile sensors with a rover “mothership.” Science use cases explored include reconnaissance using ballistic cameras, volatiles detection, and building timelapse maps of temperature and illumination conditions. Strategies to autonomously coordinate constellations of deployed sensors to self-discover and localize with peer ranging (i.e. a “local GPS”) are summarized, thus providing communications infrastructure beyond-line-of-sight (BLOS) of the rover. Capabilities were demonstrated through both simulation and physical testing with a terrestrial prototype. The approach to developing a terrestrial prototype is discussed, including design of the launching mechanism, projectile optimization, micro-electronics fabrication, and sensor selection. Results from early testing and characterization of commercial-off-the-shelf (COTS) components are reported. Nodes were subjected to successful burn-in tests over 48 hours at full logging duty cycle. Integrated field tests were conducted in the Roverscape, a half-acre planetary analog environment at NASA Ames, where we tested up to 10 sensor nodes simultaneously coordinating with an exploration rover. Ranging accuracy has been demonstrated to be within +/-10cm over 20m using commodity radios when compared to high-resolution laser scanner ground truthing. Evolution of the design, including progressive miniaturization of the electronics and iterated modifications of the enclosure housing for streamlining and optimized radio performance are described. Finally, lessons learned to date, gaps toward eventual flight mission implementation, and continuing future development plans are discussed.

Dille, Michael↗