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Launch Complex 34, SWMU CC054 2023 DNAPL Source Zone Operations, Maintenance, and Monitoring, Site-Wide Long-Term Monitoring, and Hot Spot 6 Air Sparge System Annual Performance Monitoring and Phase Two Expansion Construction Completion Report Cape Canaveral Space Force Station, Florida

This Annual Performance Monitoring Report (PMR) for the Dense Non-Aqueous Phase Liquid (DNAPL) Source Zone (DSZ), Site-Wide Long-Term Monitoring (LTM), and Hot Spot 6 (HS 6) Air Sparge (AS) System presents the results of Year 14 operations and performance monitoring of the hydraulic containment (HC) Interim Measure (IM), details associated with construction and implementation of the HS 6 AS system expansion (Phase Two), and the results of operations and performance sampling of the HS 6 AS IM at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. The timeframe for activities documented in this PMR extends from April 1, 2023 to March 31, 2024. LC34 has been designated Solid Waste Management Unit CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act Corrective Action Program. The objective of the HC IM at LC34 is to contain the shallow and deep DSZ and surrounding dissolved-phase trichloroethene (TCE) high concentration plume via operation of a hydraulic containment system (HCS). The pre-IM design 300 micrograms per liter (μg/L) TCE groundwater contour was used to establish the deep zone capture area for deep recovery wells, and the shallow zone capture area was defined by the DSZ. The system began operating in 2010, and in 2015, the system was expanded to provide HC for areas within the 300 μg/L TCE groundwater isocontours of HS 3 and 4. In 2018 and 2019, an investigation was conducted to recharacterize the DSZ, which included investigating TCE mass in Layer 7. This data was subsequently used to optimize the pumping rates of the HCS and install additional recovery wells in Layer 7 to more adequately capture residual contaminant mass. The operational period for Year 14 of the HCS was from April 1, 2023 to March 31, 2024. Operational runtime for the system was 94 percent during Year 14, with downtime events attributed to planned maintenance, system repairs, and power outages. As of March 31, 2024, a total of 344,849,634 cumulative gallons of groundwater containing 94,656 pounds of chlorinated volatile organic compounds (CVOCs) have been removed by the HCS. During the reporting period covered under this report, the HCS recovered 31,176,393 gallons and approximately 6,319 pounds of CVOC mass. Total combined influent concentrations of TCE have decreased since startup from approximately 280,000 µg/L (January 2010) to 25,000 µg/L (March 2024). During the reporting period, all effluent concentrations from the HCS (aqueous and vapor) were below regulatory reporting limits, indicating the system continues to operate as intended. Performance monitoring was conducted in January 2024 within the DSZ to evaluate TCE contamination. Groundwater samples were collected via DPT at nine locations, consistent with previous events between 2017 and 2022. Full vertical profile sampling was completed at each DPT from 8 to 98 feet below land surface (bls), at 5-foot intervals. The DPT performance monitoring results are summarized in this PMR. The results revealed TCE remains at concentrations greater than 11,000 µg/L in the DSZ (1-percent solubility, indicative of DNAPL) at eight of the nine DPT locations and at depths ranging from 28 to 98 feet bls. An overall decreasing trend of TCE concentrations was observed in DPT samples during this reporting period, which is a reduction from the previous event (December 2022) and the peak event in December 2021, where TCE percentages appeared to increase in all depth zones because several recovery wells were turned off during the AS pilot study in the DSZ. The maximum TCE concentration in January 2024 was 1,600,000 µg/L in the 53 feet bls depth interval at DPT594 (previous maximum result in 2022 was 1,800,000 µg/L in the 48 feet bls depth interval at DPT599). This maximum concentration in the 53 feet bls depth interval is in the deep capture zone. During the January 2024 DPT event, the largest portion of TCE mass was observed in the 48 feet bls interval above/within Layer 4. This trend remains consistent with previous years and appears to indicate continued mass discharge from Layer 4 (fine-grained unit). In addition to DPT sampling, annual groundwater samples were collected from 11 deep monitoring wells in the DSZ area (Layers 7 and 8) in December 2023 to verify vertical and horizontal delineation. Three of the wells were also sampled biweekly to evaluate operations of recovery well RW21D (screened 86 to 106 feet bls), which was installed in January 2023. Of the Layer 7/8 monitoring sampled only annually, results were non-detect or less than groundwater cleanup target levels GCTLs in December 2023, with the exception of one well, IW45D2, which had a cis-1,2-dichloroethene (cDCE), detection greater than the GCTL. Of the three wells sampled biweekly during the operational period, the well located closest to Layer 7 recovery well RW21D (IW44D2, screened 105 to 115 feet bls) had concentrations of TCE, cDCE and vinyl chloride (VC) greater than GCTLs throughout the operational period, but displayed a decreasing trend since the peak concentrations in September 2023. The maximum TCE concentration during this operational period was 190,000 µg/L at IW44D2 in September 2023, but reduced to 700 µg/L in March 2024, indicating the HCS is still effectively removing mass from the source area. Expansion of the HCS and addition of new recovery wells is ongoing and will continue to be evaluated as the groundwater recovery scheme is optimized. Details of the expansion and optimization will be provided in a future PMR. The HS 6 AS IM was initiated in 2018 with 160 AS wells and expanded in 2019 with another 140 AS wells. An additional expansion of the HS 6 AS IM was completed during the reporting period covered under this report and details of the construction implementation and startup of the expansion are detailed in Section III of this report. The new expansion, referred to as Phase Two, was implemented between August 17, 2022 and August 28, 2023, and included the installation of 190 air sparge wells to treat an additional 11.2 acres. The original configuration (referred to as Phase One) operated until Phase Two came online, then all but 52 AS wells were turned off so the components could be moved and utilized in the Phase Two area. The 52 AS wells that remain on are in a barrier configuration preventing contaminated groundwater from impacting the treated area. The HS 6 AS system (both Phase One and Two) operated normally during the reporting period covered under this report. Semi-annual performance monitoring of the Phase One configuration was conducted in April and November 2023, consistent with previous years. For the Phase Two configuration, 21 new monitoring wells were installed and sampled quarterly, with a baseline event in July 2023, and quarterly events in November 2023 and February 2024 summarized in this report. Semi-annual monitoring results collected in April and October 2023 show concentrations of contaminants of concern (cDCE, trans-1,2-dichloroethene, and VC) have decreased to less than GCTLs in nearly all wells and not impacting the surface water drainage canal, indicating the HS 6 IM continues to meet objectives. The baseline and quarterly sampling for the Phase Two configuration indicate generally decreasing concentrations in wells within and around the perimeter of the treatment area. At least two more quarters of monitoring will be conducted and once those results are evaluated a reduced the sampling frequency may be considered. Overall, the tasks associated with Year 14 operation of the HC IM and operation of the HS 6 AS IM were performed in accordance with recommendations included in the previous 2022 LC34 (Year 13) PMR. Evaluation of results from the HC IM and HS 6 IM show that these systems are operating as designed and meeting performance objectives.

groundwater remediation↗

Nondestructive ultrasonic characterization of two-phase materials

The development of ultrasonic methods for the nondestructive characterization of mechanical properties of two phase engineering materials are described. The primary goal was to establish relationships between the nonlinearity parameter and the percentage of solid solution phase in two phase systems such as heat treatable aluminum alloys. The acoustoelastic constant was also measured on these alloys. A major advantage of the nonlinearity parameter over that of the acoustoelastic constant is that it may be determined without the application of stress on the material, which makes the method more applicable to inservice nondestructive characterization. The results obtained on the heat treatable 7075 and the work hardenable 5086 and 5456 aluminum alloys show that both the acoustoelastic constant and the acoustic nonlinearity parameter change considerable with the volume fraction of second phase precipitates in these aluminum alloys. A mathematical model was also developed to relate the effective acoustic nonlinearity parameter to volume fraction of second phase precipitates in an alloy. The equation is approximated to within experimental error by a linear expression for volume fractions up to approx. 10%.

Salama, Kamel↗

A two-phase three-field modeling framework for heat pipe application in nuclear reactors

Heat pipes and two-phase thermosyphons are highly efficient heat transfer devices utilizing continuous evaporation and condensation of working fluid for two-phase heat transport in closed systems. Because of the nearly isothermal and fully passive phase-change heat transfer mechanism, heat pipes and thermosyphons have found many applications in nuclear engineering, space technologies, and other energy systems. High-temperature heat pipes are used in nuclear microreactors to remove fission power from the primary system and are coupled with power conversion systems or process heat applications. Modeling of the two-phase flow phenomena inside a heat pipe is essential to its design and safety analysis. In this study, a comprehensive one-dimensional two-phase three-field flow model has been developed for the analysis of heat pipes in normal operation conditions and transients. The conservation or field equations of mass, momentum, and energy were developed for the liquid film, vapor, and droplet. In addition, constitutive models or correlations were reviewed thoroughly and provided for the closure of the three-field equations. Specific constitutive equations regarding interfacial mass and heat transfer at two interfaces, namely film-gas interface and gas-droplet interface, were reviewed for droplet entrainment and deposition rates as well as film and droplet evaporation rates. Furthermore, mechanistic correlations of annular flow film thickness were recommended for the modeling of the thermosyphons without a wick as a critical constitutive correlation. Furthermore, experimental data needs from new experiments using a prototype working fluid or surrogate fluids for the model validation of high-temperature heat pipes in microreactors were recommended for future research.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A two phase Mach number description of the equilibrium flow of nitrogen in ducts

Some additional thermodynamic properties of the usual two-phase form which is linear in the moisture fraction are derived which are useful in the analysis of many kinds of duct flow. The method used is based on knowledge of the vapor pressure and Gibbs function as functions of temperature. With these, additional two-phase functions linear in moisture fraction are generated, which ultimately reveal that the squared ratio of mixture specific volume to mixture sound speed depends on liquid mass fraction and temperature in the same manner as do many weighted mean two-phase properties. This leads to a simple method of calculating two-phase Mach numbers for various duct flows. The matching of one- and two-phase flows at a saturated vapor point with discontinuous Mach number is also discussed.

Bursik, J. W.↗

Modeling of a Two-Phase Jet Pump with Phase Change, Shocks and Temperature-Dependent Properties

One of the primary motivations behind this work is the attempt to understand the physics of a two-phase jet pump which constitutes part of a flow boiling test facility at NASA-Marshall. The flow boiling apparatus is intended to provide data necessary to design highly efficient two-phase thermal control systems for aerospace applications. The facility will also be capable of testing alternative refrigerants and evaluate their performance using various heat exchangers with enhanced surfaces. The test facility is also intended for use in evaluating single-phase performance of systems currently using CFC refrigerants. Literature dealing with jet pumps is abundant and covers a very wide array of application areas. Example application areas include vacuum pumps which are used in the food industry, power station work, and the chemical industry; ejector systems which have applications in the aircraft industry as cabin ventilators and for purposes of jet thrust augmentation; jet pumps which are used in the oil industry for oil well pumping; and steam-jet ejector refrigeration, to just name a few. Examples of work relevant to this investigation includes those of Fairuzov and Bredikhin (1995). While past researchers have been able to model the two-phase flow jet pump using the one-dimensional assumption with no shock waves and no phase change, there is no research known to the author apart from that of Anand (1992) who was able to account for condensation shocks. Thus, one of the objectives of this work is to model the dynamics of fluid interaction between a two-phase primary fluid and a subcooled liquid secondary fluid which is being injected employing atomizing spray injectors. The model developed accounts for phase transformations due to expansion, compression, and mixing. It also accounts for shock waves developing in the different parts of the jet pump as well as temperature and pressure dependencies of the fluid properties for both the primary two-phase mixture and the secondary subcooled liquid. The research effort on which this document partly reports described a relatively simple model capable of describing the performance of a two-phase flow jet pump. The model is based on the isentropic homogeneous expansion/compression hypothesis and is capable of fully incorporating the effects of shocks in both the mixing chamber and the throat/diffuser parts of the pump. The physical system chosen is identical to that experimentally tested by Fairuzov and Bredikhin (1995) and should therefore be relatively easy to validate.

Sherif, S. A.↗

Method for driving two-phase turbines with enhanced efficiency

A method for driving a two phase turbine characterized by an output shaft having at least one stage including a bladed rotor connected in driving relation with the shaft is described. A two phase fluid is introduced into one stage at a known flow velocity and caused to pass through the rotor for imparing angular velocity thereto. The angular velocity of the rotor is maintained at a value such that the angular velocity of the tips of the blades of the rotor is a velocity equal to at least 50% of the velocity of the flow of the two phase fluid.

Elliott, D. G.↗

Analysis of Two-Phase Flow in Damper Seals for Cryogenic Turbopumps

Cryogenic damper seals operating close to the liquid-vapor region (near the critical point or slightly su-cooled) are likely to present two-phase flow conditions. Under single phase flow conditions the mechanical energy conveyed to the fluid increases its temperature and causes a phase change when the fluid temperature reaches the saturation value. A bulk-flow analysis for the prediction of the dynamic force response of damper seals operating under two-phase conditions is presented as: all-liquid, liquid-vapor, and all-vapor, i.e. a 'continuous vaporization' model. The two phase region is considered as a homogeneous saturated mixture in thermodynamic equilibrium. Th flow in each region is described by continuity, momentum and energy transport equations. The interdependency of fluid temperatures and pressure in the two-phase region (saturated mixture) does not allow the use of an energy equation in terms of fluid temperature. Instead, the energy transport is expressed in terms of fluid enthalpy. Temperature in the single phase regions, or mixture composition in the two phase region are determined based on the fluid enthalpy. The flow is also regarded as adiabatic since the large axial velocities typical of the seal application determine small levels of heat conduction to the walls as compared to the heat carried by fluid advection. Static and dynamic force characteristics for the seal are obtained from a perturbation analysis of the governing equations. The solution expressed in terms of zeroth and first order fields provide the static (leakage, torque, velocity, pressure, temperature, and mixture composition fields) and dynamic (rotordynamic force coefficients) seal parameters. Theoretical predictions show good agreement with experimental leakage pressure profiles, available from a Nitrogen at cryogenic temperatures. Force coefficient predictions for two phase flow conditions show significant fluid compressibility effects, particularly for mixtures with low mass content of vapor. Under these conditions, an increase on direct stiffness and reduction of whirl frequency ratio are shown to occur. Prediction of such important effects will motivate experimental studies as well as a more judicious selection of the operating conditions for seals used in cryogenic turbomachinery.

Arauz, Grigory L.↗

Scaling of two-phase water-steam relative permeability and thermal fluxes in porous media

Two-phase water-steam flow conditions are frequently encountered in many engineering applications, including geothermal reservoirs. Although routine calculations are based on the multiphase Darcy’s law, the role of the topology of the flowing phases at the pore-scale is usually neglected in the estimation of relative permeabilities. Instead, the latter are frequently computed using empirical models like the Corey correlation. In this work, we first apply the model for relative permeabilities based on pore-scale flow regimes developed by Picchi and Battiato (2019), Relative permeability scaling from pore-scale flow regimes, Water Resour. Res. 55, 3215–3233, to scenarios typical of geothermal reservoirs and then extend it by deriving the scaling laws for the transmissibilities and the thermal properties as a function of temperature. First, we discuss the scaling behavior of normalized relative permeabilities in terms of viscosity ratio and capillary number of water-steam systems and, then, we provide a validation of the model against experimental data available in the literature. The model captures well the data trends collected in real 3D porous media. These results suggest that water-steam relative permeabilities follow the same scaling behavior of gas-liquid systems where the non-wetting phase is much less viscous than the wetting phase. Finally, we investigate the impact that relative permeabilities have on heat transfer rates at two-phase flow conditions and the scaling of mass and energy transmissibility and thermal properties of the mixture. An estimation of the exergy carried by the two-phase water-steam mixture is also included.

42 ENGINEERING↗

Two-phase choked flow of subcooled nitrogen through a slit

Two-phase choked flow rate and pressure distribution data are reported for subcooled nitrogen flowing through a slit. The slip was a narrow rectangular passage of equal length and width. The inlet stagnation pressure ranged from slightly above saturation to twice the thermodynamic critical pressure. Four stagnation isotherms were investigated covering a range which spanned the critical temperature. The results suggested a uniform two-phase flow pattern with vaporization occurring at or near the exit in most cases. The results compared favorably with the theory of Henry for nonequilibrium subcooled two-phase choked flow in long tubes.

Simoneau, R. J.↗

Development and Validation of Two-Phase Flow Models in MOOSE and Application to Molten Salt Reactors

Two-phase flow in Molten Salt Reactors (MSRs) is important as it impacts reactivity evolution, reactor transient response, and the removal of species dissolved in the molten salt through gas phase transfer. Therefore, accurately predicting the gas distribution and the associated liquid-gas interface area in MSRs is essential for their design and operation. Recently, we integrated two new models into Idaho National Laboratory (INL)’s Multiphysics Object-Oriented Simulation Environment (MOOSE): a multi-D generalization of a mixture drift-flux model and a Euler-Euler model. The Euler-Euler model offers higher fidelity, while the mixture drift-flux model provides greater computational efficiency, which is typically preferred for modeling reactor transients. However, the mixture model's accuracy in capturing void distribution and interfacial area in MSRs still needs to be assessed. This article begins with a description of the mathematical framework for the two-phase models implemented in MOOSE. It then presents validation of these models against relevant experimental data. Finally, both models are applied to the Molten Salt Reactor Experiment case study, analyzing various operational conditions such as different rates of fission product volatilization and diverse cover gas entrainment scenarios at the reactor pump. The article concludes by assessing the suitability of both models for capturing the two-phase flow dynamics critical to MSR operations.

42 - ENGINEERING↗

Two-phase choked flow of subcooled nitrogen through a slit

Two-phase choked flow rate and pressure distribution data are reported for subcooled nitrogen flowing through a slit. The slit was a narrow rectangular passage of equal length and width. The inlet stagnation pressure ranged from slightly above saturation to twice the thermodynamic critical pressure. Four stagnation isotherms were investigated, covering a range which spanned the critical temperature. The results suggested a uniform two-phase flow pattern with vaporization occurring at or near the exit in most cases. The results compared favorably with the theory of Henry (1970) for nonequilibrium subcooled two-phase choked flow in long tubes.

Simoneau, R. J.↗

Numerical simulation of compressible, turbulent, two-phase flow

A computer program for numerically simulating compressible, turbulent, two-phase flows is described and applied. Special attention is given to flows in which dust is ingested into the turbulent boundary layer behind shock waves moving over the earth's surface. it is assumed that the two phases are interpenetrating continua which are coupled by drag forces and heat transfer. The particle phase is assumed to be dilute, and turbulent effects are modeled by zero- and two-equation eddy viscosity models. An important feature of the turbulence modeling is the treatment of surface boundary conditions which control the ingestion of particles into the boundary layer by turbulent friction and diffusion. The numerical method uses second-order implicit upwind differencing of the inviscid terms of the equations and second-order central differencing of the viscous terms. A diagonal form of the implicit algorithm is used to improve efficiency, and the transformation to a curvilinear coordinate system is accomplished by the finite volume techniques. Applications to a series of representative flows include a two-phase nozzle flow, the steady flow of air over a sand bed, and the air flow behind a normal shock wave in uniform motion over a sand bed. Results of the latter two applications are compared with experimental results.

Coakley, t. J.↗

A combined Eulerian-Lagrangian analysis for computation of two-phase flows

A combined Eulerian-Lagrangian analysis, which combines a linearized block implicit Navier-Stokes analysis for the continuous phase with a Lagrangian analysis for the motion of the droplet phase to simulate evaporating two-phase flows, has been developed. A unique aspect of this analysis is that the Lagrangian equations for the droplet motion have been transformed into the Eulerian computational space using coordinate transformation resulting in better computational efficiency. Use of the present implicit procedure for the continuous phase makes it possible to efficiently use a locally highly refined mesh. The coupling of the continuous phase and the droplet phase analyses is such that it allows the use of convergence acceleration techniques for steady-state problems, as well as making it possible to simulate transient flows. A rapidly evaporating two-phase flow caused by spray of liquid nitrogen in gaseous nitrogen has been used as a test problem to demonstrate the computer code using this analysis.

Sabnis, J. S.↗

DEMONSTRATION OF A DATA-DRIVEN PHYSICS-BASED APPROACH FOR COMPUTATIONALLY EFFICIENT CFD PREDICTION OF TWO-PHASE BUBBLY FLOW

To realize efficient computational fluid dynamics (CFD) prediction of two-phase flow, a multi-scale physics-guided data-driven approach, Feature Similarity Measurement (FSM) technique was developed for error estimation in two-phase flow simulation using coarse-mesh CFD, to achieve a comparable accuracy as fine-mesh simulations with fast-running feature. By defining physics-guided parameters and variable gradients as physical features, FSM has the capability to capture the underlying local patterns in the coarse-mesh CFD simulation. Massive low-fidelity data and respective high-fidelity data are used to explore the underlying information relevant to the main simulation errors and the effects of phenomenological scaling. By learning from previous simulation data, a surrogate model using deep feedforward neural network (DFNN) can be developed and trained to estimate the simulation error of coarse-mesh CFD. In a demonstration case of two-phase bubbly flow, the DFNN model well captured and corrected the unphysical “peaks” in the velocity and void fraction profiles near the wall in the coarse-mesh configuration, even for extrapolative predictions. The research documented supports the feasibility of the physics-guided deep learning methods for coarse mesh CFD simulations which has a potential for the efficient industrial design.

42 ENGINEERING↗

Enhanced Models for the Simulation of Two-Phase Boiling Flow and Critical Heat Flux with the STAR-CCM+ and NEK-2P CFD Codes: Executive Summary (Final Report)

The goal of the project was to develop, verify and validate an advanced two-phase boiling flow modeling capability that enhances the existing two-phase flow modeling of the STAR-CCM+ Computational Fluid Dynamics (CFD) code. The project focused on the simulation of two phase flow and heat transfer phenomena that occur in Boiling Water Reactor (BWR) and Pressurized Water Reactor (PWR) fuel bundles under various operating conditions. The extended STAR-CCM+ two-phase flow models implemented during the project follow the approach similar to the Extended Boiling Framework [1-6] previously developed at Argonne but include more fundamental physical models of boiling phenomena. The development and validation of the extended two-phase models is supported by the U.S. DOE GAIN program and performed in collaboration with Framatome U.S. Inc.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Review of heat transfer enhancement techniques in two-phase flows for highly efficient and sustainable cooling

We show that two-phase internal flow is ubiquitous to many systems due to its ability to transfer large amounts of heat effectively. Recent advances motivated by sustainability have pushed towards augmenting the heat transfer between the tube and the two-phase working fluid. Augmenting heat transfer in two-phase flows enables process intensification, and compactness leading to reduced cost and material consumption. This review investigates the effect of heat transfer enhancement techniques on different fluids including R134a, R407C, R22, etc … The techniques are categorized into passive and active and focus on durable enhancement methods which do not include surface structuring or coating. Passive techniques utilize geometrical and surface modifications to induce better mixing. Several passive techniques are analyzed including fins, inserts, and more. In analyzing these techniques, the effect of changing geometric parameters is studied, and the limitations are highlighted. Further, active techniques that enable heat transfer enhancement through applying power are also investigated. Electrohydrodynamic approaches are analyzed and compared to passive techniques. Additionally, the implications of heat exchange enhancement in the context of global energy are discussed. An energy analysis discretized by the use sector is conducted, with an emphasis on predicting the future potential for renewable and sustainable development. Moreover, although active approaches provide the highest heat transfer enhancement, due to implementation difficulties, passive techniques are more frequently adopted. The review ends with discussion of next-generation heat exchangers which will rely more on additive manufacturing due to its flexibility and reduced cost per part as the technology matures.

Nusselt number↗

Scaling of Two-Phase Flows to Partial-Earth Gravity

A report presents a method of scaling, to partial-Earth gravity, of parameters that describe pressure drops and other characteristics of two-phase (liquid/ vapor) flows. The development of the method was prompted by the need for a means of designing two-phase flow systems to operate on the Moon and on Mars, using fluid-properties and flow data from terrestrial two-phase-flow experiments, thus eliminating the need for partial-gravity testing. The report presents an explicit procedure for designing an Earth-based test bed that can provide hydrodynamic similarity with two-phase fluids flowing in partial-gravity systems. The procedure does not require prior knowledge of the flow regime (i.e., the spatial orientation of the phases). The method also provides for determination of pressure drops in two-phase partial-gravity flows by use of a generalization of the classical Moody chart (previously applicable to single-phase flow only). The report presents experimental data from Mars- and Moon-activity experiments that appear to demonstrate the validity of this method.

Hurlbert, Kathryn M.↗

The Dynamic of Complex Two-Phase Mixtures During Coarsening: From Dendritic to Bicontinuous Mixtures

Dendrites are tree-like crystals that frequently form during the solidification of castings. In systems with nearly isotropic interfacial energy, these dendrites possess secondary and sometimes even tertiary arms, and lead to morphologically complex two-phase mixtures. Dealloying, in which one component is selectively leached, leads to nanoporous structures that have proven useful for many technological applications. These bicontinuous two-phase mixtures are topologically and morphologically complex with spatially varying mean and Gaussian curvatures. The evolution of these structures during coarsening is of considerable technological importance since the morphology of the dendrites and nanoporous structure sets the properties of the resulting material. During coarsening, the total surface area per volume of the mixture decreases, thus resulting in an increase in the size-scale of the two-phase mixture. The evolution of interfacial morphology of these interconnected two-phase mixtures is being studied using large-scale computer simulations. The simulations are used to develop a theory of coarsening in these systems that will elucidate the impact of the complicated morphology found in dendritic and nanoporous systems on the coarsening process. The experiments employ four-dimensional X-ray microtomography, which enables the morphology of the two-phase mixture to be followed in three dimensions and time (an additional dimension). The experiments also serve as a test of simulations and theory of the coarsening process, as well as to provide initial conditions for the simulations. Through these experiments and theory, we aim to develop a comprehensive description of coarsening in these complex and technologically important two-phase mixtures.

36 MATERIALS SCIENCE↗