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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Chemical models of the deep atmospheres of Jupiter and Saturn

New and updated chemical kinetic data, elemental abundances, and thermodynamic data are used for thermochemical equilibrium and, where relevant, thermochemical kinetic calculations of gas abundances and condensate stability in the hot, deep atmospheres of Jupiter and Saturn. Over 2000 compounds of all naturally occurring elements in the periodic table are considered. The calculations range from 298 to 2000 K and are done for adiabatic models of the two planetary atmospheres. The results predict the abundances of many gases which are potentially observable by the Galileo probe to Jupiter, by the Cassini mission to Saturn, and by Earth-based and Earth-orbital telescopes. In addition, the results also predict many new species which are potentially observable by a new generation of entry probes capable of penetrating deeper into the atmospheres of Jupiter and Saturn.

Fegley, Bruce, Jr.↗
NASA NTRS1988

Trapped noble gases in meteorites

The trapped noble gases in meteorites come in two main varieties, usually referred to as solar and planetary. The solar noble gases are implanted solar-wind or solar-flare materials, and thus their relative elemental abundances provide a good estimate of those of the sun. The planetary noble gases have relative elemental abundances similar to those in the terrestrial atmosphere, but there are also important distinctions. At least one other elemental pattern (subsolar) and several isotopic patterns have also been identified.

Swindle, Timothy D.↗
NASA NTRS2024

The D/H Ratio in Titan’s Acetylene from High Spectral Resolution IRTF/TEXES Observations

We report observations of deuterated acetylene (C 2 HD) at 19.3 μm (519 cm −1 ) with the Texas Echelon Cross Echelle Spectrograph on the NASA Infrared Telescope Facility in July 2017. Six individual lines from the Q-branch of the 𝜈 4 band were clearly detected with a S/N ratio up to 10. Spectral intervals around 8.0 μm (745 cm −1 ) and 13.4 μm (1247 cm −1 ) containing acetylene (C 2 H 2 ) and methane (CH 4 ) lines respectively, were observed during the same run to constrain the disk-averaged C 2 H 2 abundance profile and temperature profile. Cassini observations with the Composite Infrared Spectrometer (CIRS) were used to improve the flux calibration and help to constrain the atmospheric model. The measured D/H ratio in acetylene, derived from the C 2 HD/C 2 H 2 abundance ratio, is (1.22 +0.27 −0.21 )× 10 −4 , consistent with that in methane obtained in previous studies. Possible sources of fractionation at different steps of the acetylene photochemistry are investigated.

Planetary atmospheres↗
NASA NTRS1981

The abundance of carbon in HU 2-1

A logarithmic carbon abundance of 8.61 + or - 0.3 is derived for the planetary nebula Hu 2-1 using data taken with the International Ultraviolet Explorer satellite. This value is close to the logarithmic carbon abundance of 8.67 + or - 0.1, found for the sun by other investigators. The carbon abundance of Hu 2-1 is compared to those of other planetary nebulae and to the predictions of stellar evolution calculations.

Lutz, J. H.↗
NASA NTRS1987

Physical parameters for 12 planetary nebulae and their central stars in the Magellanic Clouds

Nebular and central star parameters and elemental abundances of C, N, O, Ne, S, and Ar are presented for the planetary nebulae N2, N5, N43, N54, and N67 in the SMC and P2, P7, P9, P25, P33, and P40 in the LMC. The nebular chemical compositions are affected by nuclear processes in the precursor stars, which may not have been sufficiently massive to synthesize Ne, S, or Ar, which appear to be deficient with respect to their solar abundances by factors of roughly four and five for the LMC and SMC, respectively. Even after excluding nebulae formed by stars in which O apparently was destroyed by nuclear processes, O depletion in the LMC and SMC nebulae is significantly greater than in galactic planetaries. The estimated masses of the 12 remnant central stars range from 0.58 to 0.71 solar mass.

Aller, Lawrence H.↗
NASA NTRS2022

The Lithophile Element Budget of Earth’s Core

The relative composition of Earth’s core and mantle were set during core formation. By determining how elements partition between metal and silicate at high pressures and temperatures, measurements of the mantle composition and geophysical observations of the core can be used to understand the mechanisms by which Earth formed. Here we present the results of metal–silicate partitioning experiments for a range of nominally lithophile elements (Al, Ca, K, Mg, O, S, Si, Th, U) and S to 85 GPa and up to 5400 K. With our results and a compilation of literature data, we developed a parameterization for partitioning that accounts for compositional dependencies in both the metal and silicate phases. Using this parameterization in a range of planetary growth models, we find that, in general, lithophile element partitioning into the metallic phase is enhanced at high temperatures. The relative abundances of FeO, SiO2 and MgO in the mantle vary significantly between planetary growth models, and the mantle abundances of these elements can be used to provide important constraints on Earth’s accretion. To match Earth’s core mass and mantle composition, Earth’s building blocks must have been enriched in Fe and depleted in Si compared with CI chondrites. Finally, too little Mg, Si and O are partitioned into the core for precipitation of oxides to be a major source of energy for the geodynamo. In contrast, several ppb of U can be partitioned into the core at high temperatures, and this energy source must be accounted for in thermal evolution models.

dynamo↗
NASA NTRS2003

Mid-Infrared Spectroscopy of Polycyclic Aromatic Nitrogen Heterocycles (PANHS) and their Ions

In recent years, polycyclic aromatic nitrogen heterocycles (PANHs) have attracted a good deal of attention because of their potent carcinogenic and mutagenic properties, and their prevalence in our environment. Such species also play a prominent role in the chemistry of life up to and including the very nucleobases from which our DNA is constructed. Surprisingly, these compounds may even be common outside of our terrestrial environment. To wit, it is now widely accepted that polycyclic aromatic materials are abundant in space and represent a major reservoir of organic carbon in the interstellar medium and developing planetary systems. Given that nitrogen is the fourth most abundant chemically reactive element in space (surpassed only by hydrogen, carbon, and oxygen), it is entirely reasonable to suspect that PANHs may represent an important component of that organic reservoir. Motivated by their intrinsic merit and with special attention toward evaluating their exobiological significance, we have initiated a program to study the spectroscopic and chemical properties of P A " s under conditions relevant to extraterrestrial environments. Here we present the first results of that program-infrared spectroscopic measurements on a series of PANH"s in neutral and cationic forms, isolated in inert matrices at cryogenic temperatures.temperatures. The species studied include: 1 -, and 2-azabenz[a]anthracene, 1-, 2-, and 4- azachrysene, dibenz[a,h]acridine, and dibenz[a,J)acridine. The experimental measurements are also compared with theoretical spectra calculated using density functional theory. General spectroscopic trends observed in this series of compounds are discussed and the implications of these results for Astrophysics and Exobiology are considered.

Mattioda, Andrew L.↗
NASA NTRS1983

Effects of dust formation on chemical abundances

Gas-phase abundances of C, Mg, Si, Ca, and Fe have been measured for a number of planetary nebulae on the basis of optical, ultraviolet, and infrared emission-line intensities. The abundances of Si, Ca, and Fe show characteristic depletions of one to two orders-of-magnitude as a result of grain formation. Magnesium shows a similar depletion in the outer parts of several planetary nebulae, but it is undepleted in their inner parts. Carbon is not detectably depleted by grain formation. Efficient condensation of refractory elements can easily occur during the early stages of formation of a planetary nebula; but the observed, residual gas-phase abundances are not understood. Observations of molecules in the envelopes of late-type stars may provide useful clues.

Shields, G. A.↗
NASA NTRS1976

Absolute measurement of the photoionization cross section of atomic hydrogen with a shock tube for the extreme ultraviolet

The paper reports an experiment which is part of a program to measure the absolute values of the atomic photoionization cross sections of astrophysically abundant elements, particularly in stars and planetary atmospheres. An aerodynamic pressure-driven shock tube constructed from stainless steel with a quadratic cross section was used to measure the photoionization cross section of H I at 19 wavelength points from 910 to 609 A with experimental uncertainties between 7 and 20%. The shock tube was used to produce fully dissociated hydrogen and neon mixtures for the photoabsorption measurements.

Palenius, H. P.↗
NASA NTRS1977

Ancient carbon and noble gas fractionation

Noble gases in ancient terrestrial kerogen and meteoritic carbonaceous residues are compared in terms of their elemental fractionation with respect to atmospheric and the cosmic reservoirs, respectively. Fractionation factors for the heavy noble gases are almost identical in both types of samples. Therefore, some features of the interaction between carbon phases and noble gases in very different environments of origin appear to be similar. These findings underscore the plausibility of the meteoritic carbonaceous residues as a noble gas carrier and as a novel vehicle for achieving the elemental fractionation required to derive the planetary noble gas pattern from cosmic abundances.

Frick, U.↗
NASA NTRS1981

Infrared experiments for spaceborne planetary atmospheres research. Full report

The role of infrared sensing in atmospheric science is discussed and existing infrared measurement techniques are reviewed. Proposed techniques for measuring planetary atmospheres are criticized and recommended instrument developments for spaceborne investigations are summarized for the following phenomena: global and local radiative budget; radiative flux profiles; winds; temperature; pressure; transient and marginal atmospheres; planetary rotation and global atmospheric activity; abundances of stable constituents; vertical, lateral, and temporal distribution of abundances; composition of clouds and aerosols; radiative properties of clouds and aerosols; cloud microstructure; cloud macrostructure; and non-LTE phenomena.

Source record↗
NASA NTRS1981

An analysis of the planetary nebula NGC 2867

Spectroscopic observations made with the Anglo-Australian Telescope are combined with IUE data to provide material for a theoretical analysis of NGC 2867. Except for the S II forbidden line, line intensities in the optical region can be represented reasonably well by a simple theoretical model based on Balick's (1975) work. The model is used to assess temperatures in strata of higher ionization where no good spectroscopic diagnostic criteria are available and to derive ionization correction factors to account for unobserved stages of ionization. The derived chemical composition is compared with that of the sun and other planetaries. NGC 2867 shows no significant abundance peculiarities or abnormalities.

Aller, L. H.↗
NASA NTRS1984

Detection of the Ne III 36 micron forbidden line in the planetary nebula NGC 6543

The first observation of the Ne III 36.02 micron forbidden line in a planetary nebula, NGC 6543, is presented. Since the dominant form of neon in medium-excitation to high-excitation planetary nebulae is Ne III, the abundance of this ion is important in determining the total neon abundance. Use of the 36 micron line for an abundance determination has the advantage of insensitivity to temperature uncertainties. However, current atomic parameters lead to a Ne III abundance in NGC 6543 which is 4.5 times the cosmic neon abundance and 2.6 times the abundance from optical line studies. Although such a high abundance cannot be ruled out immediately, inaccuracies in the infrared level collision strengths are suspected because resonances were neglected in their calculation. The 36 micron line is also useful as a temperature probe when combined with the Ne III 3868-A forbidden line. When compared to Ne III 15.56 micron forbidden line fluxes, a temperature-insensitive density estimate may be obtained. The utility of these line ratios depends upon the actual infrared level collision strengths, which will affect the density range over which they are sensitive.

Shure, M. A.↗
NASA NTRS1985

Scientific objectives for a 1996 Mars Sample Return Mission

The Mars Sample Return Mission, designed to return a variety of surface and subsurface samples as well as atmospheric samples, is described. Primary information about the planet is essential to understanding its place in the evolution of the solar system. The most accurate landing techniques will be used to place the lander near geologically interesting features. A capable rover will be an essential element of the sample collection strategy to maximize the diversity of the samples. The sample collection and return systems will keep the samples at Mars ambient conditions or colder to preserve the abundances and distribution of volatile components. Planetary quarantine is an important consideration for both the Mars lander and the earth return vehicle. Quarantine procedures must be consistent with the primary objectives of the mission and must not compromise the investigations of the returned samples.

Blanchard, D. P.↗
NASA NTRS1995

The abundances of methane and ortho/para hydrogen on Uranus and Neptune: Implications of New Laboratory 4-0 H2 quadrupole line parameters

The tropospheric methane molar fraction (f(sub CH4, t) and the ortho/para hydrogen ratio are derived for Uranus and Neptune based on new determinations of spectroscopic parameters for key hydrogen features as reported by D. W./ Ferguson et al. (1993). For each planet, the relatively weak laboratory linestrengths (approximately 30 and 15% less than the theoretical 4-0 S(0) and S(1) linestrengths, respectively) results, when compared to analyses adopting theroetical values, in a approximately 30% decrease in the tropospheric methane ratio and a comparable increase in the pressure level of the optically thick cloudtop marking the bottom of the visible atmosphere (P(sub c/d)). The increase in the ratio of S(1)/S(0) linestrengths from 4.4 (theoretical) to approximately 5.9 (measured) results in a decrease in the range of viable ortho/para ratios; an equilibrium hydrogen distribution is now the best fit for both planets. The methane mixing ratios reported here are in agreement with the value of 0.023 derived by the Voyager Radio Occultation Experiment (G. F. Lindal, 1992) for Neptune, but slightly lower than the Voyager Uranus measurement of 0.023 reported by G. F. LIndel et al. (1987). The relative carbon-to-hydrogen abundances for Uranus and Neptune support planetary formation mechanisms involving the dissolution of carbon-bearing planetesimals in the atmospheres of both planets during their early stages of formation (e.g., J. B. Pollack et al., 1986).

Baines, Kevin H.↗
NASA NTRS2004

Fullerenes: A New Carrier Phase for Noble Gases in Meteorites

The major focus of our research effort has been to measure the noble gases encapsulated within fullerenes, a new carbon carrier phase and compare it to the myriad of components found in the bulk meteorite acid residues. We have concentrated on the carbonaceous chondrites (Allende, Murchison and Tagish Lake) since they have abundant noble gases, typically with a planetary signature that dominates the stepped-release of the meteorite bulk acid residue. They also contain an extractable fullerene component that can be isolated and purified from the same bulk material.

Becker, Luann↗
NASA NTRS2010

Abundances of Jupiter's Trace Hydrocarbons from Voyager and Cassini. Data Tables: Cassini CIRS Observations Planetary and Space Science, Forthcoming 2010

The following six tables give the retrieved temperatures and volume mixing ratios of C2H2 and C2H6 and the formal errors on these results from the retrieval, as described in the manuscript. These are in the form of two-dimensional tables, specified on a latitudinal and vertical grid. The first column is the pressure in bar, and the second column gives the altitude in kilometers calculated from hydrostatic equilibrium, and applies to the equatorial profile only. The top row of the table specifies the planetographic latitude.

Cassini CIRS observations↗