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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

The Incidence and Fate of Volatile Methyl Siloxanes in a Crewed Spacecraft Cabin

Volatile methyl siloxanes (VMS) arise from diverse, pervasive sources aboard crewed spacecraft ranging from materials offgassing to volatilization from personal care products. These sources lead to a persistent VMS compound presence in the cabin environment that must be considered for robust life support system design. Volatile methyl siloxane compound stability in the cabin environment presents an additional technical issue because degradation products such as dimethylsilanediol (DMSD) are highly soluble in water leading to a unique load challenge for water purification processes. The incidence and fate of VMS compounds as observed in the terrestrial atmosphere, water, and surface (soil) environmental compartments have been evaluated as an analogy for a crewed cabin environment. Volatile methyl siloxane removal pathways aboard crewed spacecraft are discussed and a material balance accounting for a DMSD production mechanism consistent with in-flight observations is presented.

Perry, Jay L.↗
NASA NTRS2022

The Ozone–Climate Penalty Over South America and Africa By 2100

Climate change has the potential to increase surface ozone (O3) concentrations, known as the “ozone–climate penalty”, through changes to atmospheric chemistry, transport and dry deposition. In the tropics, the response of surface O3 to changing climate is relatively understudied but has important consequences for air pollution and human and ecosystem health. In this study, we evaluate the change in surface O3 due to climate change over South America and Africa using three state-of-the-art Earth system models that follow the Shared Socioeconomic Pathway 3-7.0 emission scenario from CMIP6. In order to quantify changes due to climate change alone, we evaluate the difference between simulations including climate change and simulations with a fixed present-day climate. We find that by 2100, models predict an ozone–climate penalty in areas where O3 is already predicted to be high due to the impacts of precursor emissions, namely urban and biomass burning areas, although on average, models predict a decrease in surface O3 due to climate change. We identify a small but robust positive trend in annual mean surface O3 over polluted areas. Additionally, during biomass burning seasons, seasonal mean O3 concentrations increase by 15 ppb (model range 12 to 18 ppb) in areas with substantial biomass burning such as the arc of deforestation in the Amazon. The ozone–climate penalty in polluted areas is shown to be driven by an increased rate of O3 chemical production, which is strongly influenced by NOx concentrations and is therefore specific to the emission pathway chosen. Multiple linear regression finds the change in NOx concentration to be a strong predictor of the change in O3 production, whereas increased isoprene emission rate is positively correlated with increased O3 destruction, suggesting NOx-limited conditions over the majority of tropical Africa and South America. However, models disagree on the role of climate change in remote, low-NOx regions, partly because of significant differences in NOx concentrations produced by each model. We also find that the magnitude and location of the ozone–climate penalty in the Congo Basin has greater inter-model variation than that in the Amazon, so further model development and validation are needed to constrain the response in central Africa. We conclude that if the climate were to change according to the emission scenario used here, models predict that forested areas in biomass burning locations and urban populations will be at increasing risk of high O3 exposure, irrespective of any direct impacts on O3 via the prescribed emission scenario.

Surface ozone↗
NASA NTRS1994

Signal transduction pathways mediating parathyroid hormone regulation of osteoblastic gene expression

Parathyroid hormone (PTH) plays a central role in regulation of calcium metabolism. For example, excessive or inappropriate production of PTH or the related hormone, parathyroid hormone related protein (PTHrP), accounts for the majority of the causes of hypercalcemia. Both hormones act through the same receptor on the osteoblast to elicit enhanced bone resorption by the osteoclast. Thus, the osteoblast mediates the effect of PTH in the resorption process. In this process, PTH causes a change in the function and phenotype of the osteoblast from a cell involved in bone formation to one directing the process of bone resorption. In response to PTH, the osteoblast decreases collagen, alkaline phosphatase, and osteopontin expression and increases production of osteocalcin, cytokines, and neutral proteases. Many of these changes have been shown to be due to effects on mRNA abundance through either transcriptional or post-transcriptional mechanisms. However, the signal transduction pathway for the hormone to cause these changes is not completely elucidated in any case. Binding of PTH and PTHrP to their common receptor has been shown to result in activation of protein kinases A and C and increases in intracellular calcium. The latter has not been implicated in any changes in mRNA of osteoblastic genes. On the other hand activation of PKA can mimic all the effects of PTH; protein kinase C may be involved in some responses. We will discuss possible mechanisms linking PKA and PKC activation to changes in gene expression, particularly at the nuclear level.

Review↗
NASA NTRS2019

Soy expansion in Brazil's Cerrado

The Cerrado biome is Brazil's breadbasket and a major provider of ecosystem services, though these dual roles are increasingly at odds, in part because there are few mechanisms to protect remaining vegetation from large‐scale agricultural expansion. We assessed Cerrado conversion to soy using over 580,000 property boundaries, covering 77% of the biome that is eligible for commercial land use, and using microwatersheds, to cover 100% of eligible areas. Soy expansion accounted for 22% of conversion during 2003–14. Only 15% of clearing exceeded restrictions on private properties under the Forest Code (FC). However, 51% of soy farms have violated the FC, five times the rate of other farms. As a leading cause of both Cerrado conversion and FC violations, the soy sector has environmental and economic incentives to shift production to already cleared land. We used suitability maps to identify potential pathways for soy expansion across both old and new cropland frontiers.

Brazil↗
NASA NTRS2022

Observations of Particle Number Size Distributions and New Particle Formation in Six Indian Locations

Atmospheric new particle formation (NPF) is a crucial process driving aerosol number concentrations in the atmosphere; it can significantly impact the evolution of atmospheric aerosol and cloud processes. This study analyses at least 1 year of asynchronous particle number size distributions from six different locations in India. We also analyze the frequency of NPF and its contribution to cloud condensation nuclei (CCN) concentrations. We found that the NPF frequency has a considerable seasonal variability. At the measurement sites analyzed in this study, NPF frequently occurs in March–May (pre-monsoon, about 21 % of the days) and is the least common in October–November (post-monsoon, about 7 % of the days). Considering the NPF events in all locations, the particle formation rate (J_(SDS)) varied by more than 2 orders of magnitude (0.001–0.6 /cu.cm s) and the growth rate between the smallest detectable size and 25 nm (GR_(SDS-25 nm)) by about 3 orders of magnitude (0.2–17.2 nm/h). We found that JSDS was higher by nearly 1 order of magnitude during NPF events in urban areas than mountain sites. GRSDS did not show a systematic difference. Our results showed that NPF events could significantly modulate the shape of particle number size distributions and CCN concentrations in India. The contribution of a given NPF event to CCN concentrations was the highest in urban locations (4.3 × 10^(3) /cu.cm per event and 1.2 × 10^(3)/cu.cm per event for 50 and 100 nm, respectively) as compared to mountain background sites (2.7 × 10^(3)/cu.cm per event and 1.0 × 10^(3)/cu.cm per event, respectively). We emphasize that the physical and chemical pathways responsible for NPF and factors that control its contribution to CCN production require in situ field observations using recent advances in aerosol and its precursor gaseous measurement techniques.

particle number size distributions↗
NASA NTRS2022

The Mass Change Designated Observable Study: Overview and Results

The 2017–2027 United States National Academy of Sciences Decadal Survey (DS) for Earth Science and Applications from Space identified Mass Change (MC) as one of five Designated Observables (DOs) having the highest priority in terms of Earth observations required to advance Earth system science over the next decade. In response to this designation, NASA initiated several multi-center studies, with the goal of recommending observing system architectures for each DO for implementation within this decade. This paper provides an overview of the Mass Change Designated Observable (MCDO) Study along with key findings. The study process included: (a) generation of a Science and Applications Traceability Matrix (SATM) that maps required measurement parameters to the DS Science and Applications Objectives; (b) identification of three architecture classes relevant for measuring mass change: Precise Orbit Determination (POD), Satellite-Satellite-Tracking (SST) and Gravity Gradiometry (GG), along with variants within each architecture class; and (c) creation of a Value Framework process that considers science value, cost, risk, schedule, and partnership opportunities, to identify and recommend high value observing systems for further in-depth study. The study team recommended the implementation of an SST architecture, and identified variants that simultaneously (a) satisfy the baseline measurement parameters of the SATM; (b) maximize the probability of providing overlap with the Gravity Recovery and Climate Experiment Follow-On (GRACE-FO) mission currently in operation, accelerating science return from both missions; and (c) provide a pathway towards substantial improvements in resolution and accuracy of mass change data products relative to the program of record.

D N Wiese↗
NASA NTRS2005

Strawman Philosophical Guide for Developing International Network of GPM GV Sites

The creation of an international network of ground validation (GV) sites that will support the Global Precipitation Measurement (GPM) Mission's international science programme will require detailed planning of mechanisms for exchanging technical information, GV data products, and scientific results. An important component of the planning will be the philosophical guide under which the network will grow and emerge as a successful element of the GPM Mission. This philosophical guide should be able to serve the mission in developing scientific pathways for ground validation research which will ensure the highest possible quality measurement record of global precipitation products. The philosophical issues, in this regard, partly stem from the financial architecture under which the GV network will be developed, i.e., each participating country will provide its own financial support through committed institutions -- regardless of whether a national or international space agency is involved.At the 1st International GPM Ground Validation Workshop held in Abingdon, UK in November-2003, most of the basic tenants behind the development of the international GV network were identified and discussed. Therefore, with this progress in mind, this presentation is intended to put forth a strawman philosophical guide supporting the development of the international network of GPM GV sites, noting that the initial progress has been reported in the Proceedings of the 1st International GPM GV Workshop -- available online. The central philosophical issues themselves, all flow from the fact that each participating institution can only bring to the table, GV facilities and scientific personnel that are affordable to the sanctioning (funding) national agency (be that a research, research-support, or operational agency). This situation imposes on the network, heterogeneity in the measuring sensors, data collection periods, data collection procedures, data latencies, and data reporting capabilities. Therefore, in order for the network to be effective in supporting the central scientific goals of the GPM mission, there must be a basic agreed upon doctrine under which the network participants function vis-a-vis: (1) an overriding set of general scientific requirements, (2) a minimal set of policies governing the free flow of GV data between the scientific participants, (3) a few basic definitions concerning the prioritization of measurements and their respective value to the mission, (4) a few basic procedures concerning data formats, data reporting procedures, data access, and data archiving, and (5) a simple means to differentiate GV sites according to their level of effort and ability to perform near real-time data acquisition - data reporting tasks. Most important, in case they choose to operate as a near real-time data collection-data distribution site, they would be expected to operate under a fairly narrowly defined protocol needed to ensure smooth GV support operations. This presentation will suggest measures responsive to items (1) - (5) from which to proceed,. In addition, this presentation will seek to stimulate discussion and debate concerning how much heterogeneity is tolerable within the eventual GV site network, given that the any individual GV site can only be considered scientifically useful if it supports the achievement of the central GPM Mission goals. Only ground validation research that has a direct connection to the space mission should be considered justifiable given the overarching scientific goals of the mission. Therefore each site will have to seek some level of accommodation to what the GPM Mission requires in the way of retrieval error characterization, retrieval error detection and reporting, and generation of GV data products that support assessment and improvement of the mission's standard precipitation retrieval algorithms. These are all important scientific issues that will be best resolved in open scientific debate.

Smith, Eric A.↗
NASA NTRS2000

Regulation of sucrose metabolism in higher plants: localization and regulation of activity of key enzymes

Sucrose (Suc) plays a central role in plant growth and development. It is a major end product of photosynthesis and functions as a primary transport sugar and in some cases as a direct or indirect regulator of gene expression. Research during the last 2 decades has identified the pathways involved and which enzymes contribute to the control of flux. Availability of metabolites for Suc synthesis and 'demand' for products of sucrose degradation are important factors, but this review specifically focuses on the biosynthetic enzyme sucrose-phosphate synthase (SPS), and the degradative enzymes, sucrose synthase (SuSy), and the invertases. Recent progress has included the cloning of genes encoding these enzymes and the elucidation of posttranslational regulatory mechanisms. Protein phosphorylation is emerging as an important mechanism controlling SPS activity in response to various environmental and endogenous signals. In terms of Suc degradation, invertase-catalyzed hydrolysis generally has been associated with cell expansion, whereas SuSy-catalyzed metabolism has been linked with biosynthetic processes (e.g., cell wall or storage products). Recent results indicate that SuSy may be localized in multiple cellular compartments: (1) as a soluble enzyme in the cytosol (as traditionally assumed); (2) associated with the plasma membrane; and (3) associated with the actin cytoskeleton. Phosphorylation of SuSy has been shown to occur and may be one of the factors controlling localization of the enzyme. The purpose of this review is to summarize some of the recent developments relating to regulation of activity and localization of key enzymes involved in sucrose metabolism in plants.

NASA Discipline Plant Biology↗
NASA NTRS1999

Steady and transient fluid shear stress stimulate NO release in osteoblasts through distinct biochemical pathways

Fluid flow has been shown to be a potent stimulus in osteoblasts and osteocytes and may therefore play an important role in load-induced bone remodeling. The objective of this study was to investigate the characteristics of flow-activated pathways. Previously we reported that fluid flow stimulates rapid and continuous release of nitric oxide (NO) in primary rat calvarial osteoblasts. Here we demonstrate that flow-induced NO release is mediated by shear stress and that this response is distinctly biphasic. Transients in shear stress associated with the onset of flow stimulated a burst in NO production (8.2 nmol/mg of protein/h), while steady flow stimulated sustained NO production (2.2 nmol/mg of protein/h). Both G-protein inhibition and calcium chelation abolished the burst phase but had no effect on sustained production. Activation of G-proteins stimulated dose-dependent NO release in static cultures of both calvarial osteoblasts and UMR-106 osteoblast-like cells. Pertussis toxin had no effect on NO release. Calcium ionophore stimulated low levels of NO production within 15 minutes but had no effect on sustained production. Taken together, these data suggest that fluid shear stress stimulates NO release by two distinct pathways: a G-protein and calcium-dependent phase sensitive to flow transients, and a G-protein and calcium-independent pathway stimulated by sustained flow.

Non-NASA Center↗
NASA NTRS2016

Combining Livestock Production Information in a Process-Based Vegetation Model to Reconstruct the History of Grassland Management

Grassland management type (grazed or mown) and intensity (intensive or extensive) play a crucial role in the greenhouse gas balance and surface energy budget of this biome, both at field scale and at large spatial scale. However, global gridded historical information on grassland management intensity is not available. Combining modelled grass-biomass productivity with statistics of the grass-biomass demand by livestock, we reconstruct gridded maps of grassland management intensity from 1901 to 2012. These maps include the minimum area of managed vs. maximum area of unmanaged grasslands and the fraction of mown vs. grazed area at a resolution of 0.5deg by 0.5deg. The grass-biomass demand is derived from a livestock dataset for 2000, extended to cover the period 19012012. The grass-biomass supply (i.e. forage grass from mown grassland and biomass grazed) is simulated by the process-based model ORCHIDEE-GM driven by historical climate change, risingCO2 concentration, and changes in nitrogen fertilization. The global area of managed grassland obtained in this study increases from 6.1 x 10(exp 6) km(exp 2) in 1901 to 12.3 x 10(exp 6) kmI(exp 2) in 2000, although the expansion pathway varies between different regions. ORCHIDEE-GM also simulated augmentation in global mean productivity and herbage-use efficiency over managed grassland during the 20th century, indicating a general intensification of grassland management at global scale but with regional differences. The gridded grassland management intensity maps are model dependent because they depend on modelled productivity. Thus specific attention was given to the evaluation of modelled productivity against a series of observations from site-level net primary productivity (NPP) measurements to two global satellite products of gross primary productivity (GPP) (MODIS-GPP and SIF data). Generally, ORCHIDEE-GM captures the spatial pattern, seasonal cycle, and inter-annual variability of grassland productivity at global scale well and thus is appropriate for global applications presented here.

Livestock dataset↗
NASA NTRS2018

Stable Isotope Fractionation in Titan Aerosol Formation

Stable isotope ratio measurements are a powerful tool used to understand both ancient and modern planetary processes. Instruments on the Cassini- Huygens spacecraft along with ground-based observations have measured several isotope pairs, including C-13/C-12 and N-15/N-14, in Titan's atmosphere. This includes isotopic measurements of the major atmospheric species, CH4 and N2, along with HCN, HC3N, C2H2. C2H6 and C4H2. However, the isotopic fractionation of Titan's organic aerosol has not conclusively been measured and therefore the effect of aerosol formation as an isotopic fractionation pathway in Titan's atmosphere has not been considered. Laboratory studies have measured the carbon and/or nitrogen isotopic fractionation of Titan aerosol analogs. [18] found that the carbon fractionation of photochemical organic aerosol analogs are more enriched in C-13. This enrichment in the aerosol analogs is opposite of what is predicted for photochemical products by the kinetic isotope effect. Additionally, both [16] and [18] found that the nitrogen fractionation in the organic aerosol analogs are opposite of what is observed in Titan's atmospheric N2 and HCN, with the aerosol analogs being a light nitrogen sink. Here we monitor the gas phase during photochemical aerosol analog production as a function of reaction time. In a recirculation experiment, the isotopic fractionation of carbon within the gas-phase products is measured as the CH4 reservoir is depleted. This allows us to monitor the isotopic fractionation pathway during photochemical aerosol analog formation.

Ugelow, M. S.↗
NASA NTRSDate not supplied

Mitochondria Dysfunction Central in Driving Health Risks Associated with Spaceflight

Background: Determining the biological impact of spaceflight through novel approaches is essential to reduce the health risks to astronauts for long-term space missions. The current established health risks due to spaceflight are only reflecting known symptomatic and physiologic responses and do not reflect early onset of other potential diseases. There are many unknown variables which still need to be identified to fully understand the health impacts due to the environmental factors in space. Materials and Methods: One method to uncover potential novel biological mechanisms responsible for health risks in astronauts is by utilizing NASA’s GeneLab platform (genelab.nasa.gov). GeneLab is public repository that hosts multiple omics datasets generated from space biology experiments that include experiments flown in space, simulated cosmic radiation experiments, and simulated microgravity experiments. This presentation will provide an example of analysis and novel hypothesis generation that is being produced with GeneLab datasets. A comprehensive multi-omics approach was implemented correlating transcriptomics, proteomics, metabolomics, and methylation analysis. Results: We found that cells have stronger overall biological response than the tissues to spaceflight, with mitochondrial activity and innate immunity pathways being heavily impacted. NASA Twin Study results are consistent with a specific alteration in mitochondrial ATP production. Our results indicate that the space environment can directly induce mitochondrial damage, with mitochondrial dysfunctions being a cause for chronic inflammation and both being involved in the development of metabolic disorders that cause changes in lipid metabolism. We also found biological changes occurring during spaceflight with cell cycle, circadian rhythm and olfactory activity pathways can also influence and be influenced by alterations on mitochondrial activity

Afshin Beheshti↗
NASA NTRSDate not supplied

Design of a Jettison System For Space Transit Vehicles

Many options to re-use waste are currently being developed by NASA. These include combustion, compaction, torrefaction, and converting waste materials to an easily stored base polymer for future use. Human exploration missions require large amounts of supplies such as food, clothing and spare parts. A many-month journey to Mars will result in the generation of a substantial amount of problematic waste products. It is thought that this waste must be discarded to enable a Mars transit mission. The most cost-effective, reliable, and safest method to address this problem may be to simply jettison these materials from the spacecraft. The ability to jettison requires a multi-component integrated system design. Major components include a launcher, airlocks, trash bags, and tracking system. Depending upon mission requirements, a jettison dedicated airlock may be necessary. In other cases, the crew airlock might be all that’s needed. Examples of what to jettison include food waste, fecal containers, broken equipment, foam, expendables, hygiene products, health items, wipes, and clothing. The most important design factor is always crew safety. Other features to consider are loss of air due to the inefficiencies of vacuum pumps in the airlock, outgassing from the bags, and liquids condensing on the airlock that result in unwanted coatings. The launching system design must consider many different features: while in planetary orbit, a minimum exit velocity is necessary so the jettisoned material will not complete an orbit only to return and strike the ship. Also, for planetary protection issues, enabling waste to be sent to distant non-critical locations is highly desirable. When the space craft is in planetary transit to say, Mars, the jettison exit velocity should be low if the material is not released along the direction of travel. This is to minimize trajectory perturbations due to jettison-imposed torque on the spacecraft. Design considerations for the launcher include exit velocity, power consumption, volume and mass of material jettisoned, and frequency of jettison. Finally, the launcher must be able to handle many different types and shapes of waste products. This paper will discuss these design issues and give guidance to a pathway forward.

Steve Sepka↗
NASA NTRS1990

Possible atmospheric lifetimes and chemical reaction mechanisms for selected HCFCs, HFCs, CH3CCl3, and their degradation products against dissolution and/or degradation in seawater and cloudwater

For a wide variety of atmospheric species including CO2, HNO3, and SO2, dissolution in seawater or cloudwater followed by hydrolysis or chemical reaction represents a primary pathway for removal from the atmosphere. In order to determine if this mechanism can also remove significant amounts of atmospheric chlorofluorocarbons (HCFC's), fluorocarbons (HFC's), and their degradation products, an investigation was undertaken as part of the Alternative Fluorocarbons Environmental Acceptability Study (AFEAS). In this investigation, the rates at which CHCl2CF3 (HCFC-123), CCl2FCH3 (HCFC-141b), CClF2CH3 (HCFC-142b), CHClF2 (HCFC-22), CHClFCF3 (HCFC-124) CH2FCF3 (HFC-134a) CHF2CH3 (HFC-152a), CHF2CF3 (HFC-125), and CH3CCl3 can be dissolved in the oceans and in cloudwater were estimated from the species' thermodynamic and chemical properties using simple mathematical formulations to simulate the transfer of gases from the atmosphere to the ocean or cloudwater. The ability of cloudwater and rainwater to remove gas phase degradation products of these compounds was also considered as was the aqueous phase chemistry of the degradation products. The results of this investigation are described.

Wine, P. H.↗
NASA NTRS2016

Directional and Spectral Irradiance in Ocean Models: Effects on Simulated Global Phytoplankton, Nutrients, and Primary Production

The importance of including directional and spectral light in simulations of ocean radiative transfer was investigated using a coupled biogeochemical-circulation-radiative model of the global oceans. The effort focused on phytoplankton abundances, nutrient concentrations and vertically-integrated net primary production. The importance was approached by sequentially removing directional (i.e., direct vs. diffuse) and spectral irradiance and comparing results of the above variables to a fully directionally and spectrally-resolved model. In each case the total irradiance was kept constant; it was only the pathways and spectral nature that were changed. Assuming all irradiance was diffuse had negligible effect on global ocean primary production. Global nitrate and total chlorophyll concentrations declined by about 20% each. The largest changes occurred in the tropics and sub-tropics rather than the high latitudes, where most of the irradiance is already diffuse. Disregarding spectral irradiance had effects that depended upon the choice of attenuation wavelength. The wavelength closest to the spectrally-resolved model, 500 nm, produced lower nitrate (19%) and chlorophyll (8%) and higher primary production (2%) than the spectral model. Phytoplankton relative abundances were very sensitive to the choice of non-spectral wavelength transmittance. The combined effects of neglecting both directional and spectral irradiance exacerbated the differences, despite using attenuation at 500 nm. Global nitrate decreased 33% and chlorophyll decreased 24%. Changes in phytoplankton community structure were considerable, representing a change from chlorophytes to cyanobacteria and coccolithophores. This suggested a shift in community function, from light-limitation to nutrient limitation: lower demands for nutrients from cyanobacteria and coccolithophores favored them over the more nutrient-demanding chlorophytes. Although diatoms have the highest nutrient demands in the model, their relative abundances were generally unaffected because they only prosper in nutrient-rich regions, such as the high latitudes and upwelling regions, which showed the fewest effects from the changes in radiative simulations. The results showed that including directional and spectral irradiance when simulating the ocean light field can be important for ocean biology, but the magnitude varies with variables and regions. The quantitative results are intended to assist ocean modelers when considering improved irradiance representations relative to other processes or variables associated with the issues of interest.

Phytoplankton↗
NASA NTRS1994

Computed Potential Energy Surfaces and Minimum Energy Pathways for Chemical Reactions

Computed potential energy surfaces are often required for computation of such parameters as rate constants as a function of temperature, product branching ratios, and other detailed properties. For some dynamics methods, global potential energy surfaces are required. In this case, it is necessary to obtain the energy at a complete sampling of all the possible arrangements of the nuclei, which are energetically accessible, and then a fitting function must be obtained to interpolate between the computed points. In other cases, characterization of the stationary points and the reaction pathway connecting them is sufficient. These properties may be readily obtained using analytical derivative methods. We have found that computation of the stationary points/reaction pathways using CASSCF/derivative methods, followed by use of the internally contracted CI method to obtain accurate energetics, gives usefull results for a number of chemically important systems. The talk will focus on a number of applications including global potential energy surfaces, H + O2, H + N2, O(3p) + H2, and reaction pathways for complex reactions, including reactions leading to NO and soot formation in hydrocarbon combustion.

Walch, Stephen P.↗
NASA NTRS1994

Tartarus Colles: A sampling of the Martian highlands

Several of the most fundamental issues about the geology of Mars can be addressed using information on composition and structure of the plateau plains ('highlands') that cover approximately half the planet. The units that compose the highlands are interpreted as a mixture of volcanic, fluvial, lacustrine, and impact ejecta deposits. A more precise inventory of differing of igneous and sedimentary lithologies in highland rock units would not only lead to a better understanding of how the plateau plains formed, but would also clarify the nature of the surface environment during the first 800 m.y. of martian history. Structural features including bedforms, joints, and small faults that are unresolved from orbit record a history of the emplacement and deformation of the highlands. In addition, weathering products present in this very ancient terrain represent a mineralogic record of past climate and of the pathways by which bedrock is altered chemically. Their similarity or dissimilarity to bright soils observed spectroscopically and in situ at the Viking Lander sites will be evidence for the relative roles of regional sources and global eolian transport in producing the widespread cover of 'dust.' Unfortunately, these issues are difficult to address in the plateau plains proper, because bedrock is covered by mobile sand and weathering products, which dominate both surface composition and remotely measurable spectral properties. However, the 'Tartarus Colles' site, located at 11.41 deg N, 197.69 deg W at an elevation of -1 km, provides an excellent opportunity to address the highland geology within the mission constraints of Mars Pathfinder. The site is mapped as unit HNu, and consists of knobby remnants of deeply eroded highlands. It contains rolling hills, but lacks steep escarpments and massifs common in most highland remnants, and is free of large channels that would have removed colluvium from eroded upper portions of the stratigraphic column. These characteristics indicate that variety of bedrock types from throughout the Noachian-Hesperian stratigraphic column may remain at the site.

Murchie, Scott↗
NASA NTRS2021

Extreme Lows of Wheat Production in Brazil

Wheat production in Brazil is insufficient to meet domestic demand and falls drastically in response to adverse climate events. Multiple, agro-climate-specific regression models, quantifying regional production variability, were combined to estimate national production based on past climate, cropping area, trend-corrected yield, and national commodity prices. Projections with five CMIP6 climate change models suggest extremes of low wheat production historically occurring once every 20 years would become up to 90% frequent by the end of this century, depending on representative concentration pathway, magnified by wheat and in some cases by maize price fluctuations. Similar impacts can be expected for other crops and in other countries. This drastic increase in frequency in extreme low crop production with climate change will threaten Brazil's and many other countries progress toward food security and abolishing hunger.

Brazil↗