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SeaWiFS technical report series. Volume 20: The SeaWiFS bio-optical archive and storage system (SeaBASS), part 1

This document provides an overview of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Bio-Optical Archive and Storage System (SeaBASS), which will serve as a repository for numerous data sets of interest to the SeaWiFS Science Team and other approved investigators in the oceanographic community. The data collected will be those data sets suitable for the development and evaluation of bio-optical algorithms which include results from SeaWiFS Intercalibration Round-Robin Experiments (SIRREXs), prelaunch characterization of the SeaWiFS instrument by its manufacturer -- Hughes/Santa Barbara Research Center (SBRC), Marine Optical Characterization Experiment (MOCE) cruises, Marine Optical Buoy (MOBY) deployments and refurbishments, and field studies of other scientists outside of NASA. The primary goal of the data system is to provide a simple mechanism for querying the available archive and requesting specific items, while assuring that the data is made available only to authorized users. The design, construction, and maintenance of SeaBASS is the responsibility of the SeaWiFS Calibration and Validation Team (CVT). This report is concerned with documenting the execution of this task by the CVT and consists of a series of chapters detailing the various data sets involved. The topics presented are as follows: 1) overview of the SeaBASS file architecture, 2) the bio-optical data system, 3) the historical pigment database, 4) the SIRREX database, and 5) the SBRC database.

Hooker, Stanford B.

SeaWiFS technical report series. Volume 19: Case studies for SeaWiFS calibration and validation, part 2

This document provides brief reports, or case studies, on a number of investigations and data set development activities sponsored by the Calibration and Validation Team (CVT) within the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project. Chapter 1 is a comparison with the atmospheric correction of Coastal Zone Color Scanner (CZCS) data using two independent radiative transfer formulations. Chapter 2 is a study on lunar reflectance at the SeaWiFS wavelengths which was useful in establishing the SeaWiFS lunar gain. Chapter 3 reports the results of the first ground-based solar calibration of the SeaWiFS instrument. The experiment was repeated in the fall of 1993 after the instrument was modified to reduce stray light; the results from the second experiment will be provided in the next case studies volume. Chapter 4 is a laboratory experiment using trap detectors which may be useful tools in the calibration round-robin program. Chapter 5 is the original data format evaluation study conducted in 1992 which outlines the technical criteria used in considering three candidate formats, the hierarchical data format (HDF), the common data format (CDF), and the network CDF (netCDF). Chapter 6 summarizes the meteorological data sets accumulated during the first three years of CZCS operation which are being used for initial testing of the operational SeaWiFS algorithms and systems and would be used during a second global processing of the CZCS data set. Chapter 7 describes how near-real time surface meteorological and total ozone data required for the atmospheric correction algorithm will be retrieved and processed. Finally, Chapter 8 is a comparison of surface wind products from various operational meteorological centers and field observations. Surface winds are used in the atmospheric correction scheme to estimate glint and foam radiances.

Hooker, Stanford B.

An artifical corrosion protocol for lap-splices in aircraft skin

This paper reviews the progress to date to formulate an artificial corrosion protocol for the Tinker AFB C/KC-135 Corrosion Fatigue Round Robin Test Program. The project has provided new test methods to faithfully reproduce the corrosion damage within a lap-splice by accelerated means, the rationale for a new laboratory test environment, and a means for corrosion damage quantification. The approach is pragmatic and the resulting artificial corrosion protocol lays the foundation for future research in the assessment of aerospace alloys. The general means for quantification of corrosion damage has been presented in a form which can be directly applied to structural integrity calculations.

Shaw, Bevil J.

Offgassing test methodology for composite materials

A significant increase in the use of composite materials has occurred during the past 20 years. Associated with this increased use is the potential for employees to be exposed to offgassing components from composite systems. Various components in composite systems, particularly residual solvents, offgas under various conditions. The potential for offgassing to occur increases as a composite material is heated either during cure or during lay-up operations. Various techniques can be employed to evaluate the offgassing characteristics of a composite system. A joint effort between AIA and SACMA resulted in the drafting of a proposed test method for evaluating the offgassing potential of composite materials. The purpose of testing composite materials for offgassing is to provide the industrial hygienist with information which can be used to assess the safety of the workplace. This paper outlines the proposed test method and presents round robin testing data associated with the test method. Also in this presentation is a discussion of classes of compounds which require specialized sampling techniques.

Scheer, Dale A.

Metrology: Measurement Assurance Program Guidelines

The 5300.4 series of NASA Handbooks for Reliability and Quality Assurance Programs have provisions for the establishment and utilization of a documented metrology system to control measurement processes and to provide objective evidence of quality conformance. The intent of these provisions is to assure consistency and conformance to specifications and tolerances of equipment, systems, materials, and processes procured and/or used by NASA, its international partners, contractors, subcontractors, and suppliers. This Measurement Assurance Program (MAP) guideline has the specific objectives to: (1) ensure the quality of measurements made within NASA programs; (2) establish realistic measurement process uncertainties; (3) maintain continuous control over the measurement processes; and (4) ensure measurement compatibility among NASA facilities. The publication addresses MAP methods as applied within and among NASA installations and serves as a guide to: control measurement processes at the local level (one facility); conduct measurement assurance programs in which a number of field installations are joint participants; and conduct measurement integrity (round robin) experiments in which a number of field installations participate to assess the overall quality of particular measurement processes at a point in time.

Eicke, W. G.

Environmentally safe aviation fuels

In response to the Air Force directive to remove Ozone Depleting Chemicals (ODC's) from military specifications and Defense Logistics Agency's Hazardous Waste Minimization Program, we are faced with how to ensure a quality aviation fuel without using such chemicals. Many of these chemicals are found throughout the fuel and fuel related military specifications and are part of test methods that help qualify the properties and quality of the fuels before they are procured. Many years ago there was a directive for military specifications to use commercially standard test methods in order to provide standard testing in private industry and government. As a result the test methods used in military specifications are governed by the American Society of Testing and Materials (ASTM). The Air Force has been very proactive in the removal or replacement of the ODC's and hazardous materials in these test methods. For example, ASTM D3703 (Standard Test Method for Peroxide Number of Aviation Turbine Fuels), requires the use of Freon 113, a known ODC. A new rapid, portable hydroperoxide test for jet fuels similar to ASTM D3703 that does not require the use of ODC's has been developed. This test has proved, in limited testing, to be a viable substitute method for ASTM D3703. The Air Force is currently conducting a round robin to allow the method to be accepted by ASTM and therefore replace the current method. This paper will describe the Air Force's initiatives to remove ODC's and hazardous materials from the fuel and fuel related military specifications that the Air Force Wright Laboratory.

Liberio, Patricia D.

A Statistical Simulation Approach to Safe Life Fatigue Analysis of Redundant Metallic Components

This paper introduces a dual active load path fail-safe fatigue design concept analyzed by Monte Carlo simulation. The concept utilizes the inherent fatigue life differences between selected pairs of components for an active dual path system, enhanced by a stress level bias in one component. The design is applied to a baseline design; a safe life fatigue problem studied in an American Helicopter Society (AHS) round robin. The dual active path design is compared with a two-element standby fail-safe system and the baseline design for life at specified reliability levels and weight. The sensitivity of life estimates for both the baseline and fail-safe designs was examined by considering normal and Weibull distribution laws and coefficient of variation levels. Results showed that the biased dual path system lifetimes, for both the first element failure and residual life, were much greater than for standby systems. The sensitivity of the residual life-weight relationship was not excessive at reliability levels up to R = 0.9999 and the weight penalty was small. The sensitivity of life estimates increases dramatically at higher reliability levels.

Matthews, William T.

Solar Cell Calibration and Measurement Techniques

The increasing complexity of space solar cells and the increasing international markets for both cells and arrays has resulted in workshops jointly sponsored by NASDA, ESA and NASA. These workshops are designed to obtain international agreement on standardized values for the AMO spectrum and constant, recommend laboratory measurement practices and establish a set of protocols for international comparison of laboratory measurements. A working draft of an ISO standard, WDI 5387, 'Requirements for Measurement and Calibration Procedures for Space Solar Cells' was discussed with a focus on the scope of the document, a definition of primary standard cell, and required error analysis for all measurement techniques. Working groups addressed the issues of Air Mass Zero (AMO) solar constant and spectrum, laboratory measurement techniques, and the international round robin methodology. A summary is presented of the current state of each area and the formulation of the ISO document.

Bailey, Sheila

SeaWiFS Postlaunch Technical Report Series: The SeaWiFS Transfer Radiometer (SXR) - Volume 1

The SeaWiFS Transfer Radiometer (SXR) was built for the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project as part of an Interagency Agreement with the National Aeronautics and Space Administration (NASA). The SXR is a multichannel radiometer designed to verify and compare measurements of spectral radiance at six discrete wavelengths in the visible and near infrared for various calibration sources in the SeaWiFS Project. In addition, the SXR is used to compare these sources to standards of spectral radiance maintained at the National Institute of Standards and Technology (NIST). The SXR was designed, built, and thoroughly characterized in the Optical Technology Division at NIST. A unique optical design provides six independent optical paths, each equipped with a temperature stabilized interference filter and silicon photodiode. A separate beam path through the input lens is used to visually align the SXR. The entrance windows for each channel overlap at the source, with each channel sampling a unique solid angle within the field of view of the SXR; this allows for simultaneous sampling of all channels. The combined standard relative uncertainty of spectral radiance measurements with the SXR is estimated to be between 0.6% and 1.3%. This report describes the design and construction of the SXR in detail, and gives the results of the optical characterization and calibrations done at NIST. The SXR has been used for several intercomparisons which include several SeaWiFS Intercalibration Round-Robin Experiments (SIRREXs); those done at the Marine Optical Buoy (MOBY) laboratories in Honolulu, Hawaii; at the NEC Corporation in Yokohama, Japan; and Orbital Sciences Corporation (OSC) in Germantown, Maryland. Thorough optical characterization and calibration of the SXR was essential to the successful application of the radiometer for these measurements.

Johnson, B. Carol

SeaWiFS Postlaunch Technical Report Series: The SeaWiFS Transfer Radiometer (SXR) - Volume 1

The SeaWiFS Transfer Radiometer (SXR) was built for the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project as part of an Interagency Agreement with the National Aeronautics and Space Administration (NASA). The SXR is a multichannel radiometer designed to verify and compare measurements of spectral radiance at six discrete wavelengths in the visible and near infrared for various calibration sources in the SeaWiFS Project. In addition, the SXR is used to compare these sources to standards of spectral radiance maintained at the National Institute of Standards and Technology (NIST). The SXR was designed, built, and thoroughly characterized in the Optical Technology Division at NIST. A unique optical design provides six independent optical paths, each equipped with a temperature stabilized interference filter and silicon photodiode. A separate beam path through the input lens is used to visually align the SXR. The entrance windows for each channel overlap at the source, with each channel sampling a unique solid angle within the field of view of the SXR; this allows for simultaneous sampling of all channels. The combined standard relative uncertainty of spectral radiance measurements with the SXR is estimated to be between 0.6% and 1.3%. This report describes the design and construction of the SXR in detail, and gives the results of the optical characterization and calibrations done at NIST. The SXR has been used for several intercomparisons which include several SeaWiFS Intercalibration Round-Robin Experiments (SIRREXs); those done at the Marine Optical Buoy (MOBY) laboratories in Honolulu, Hawaii; at the NEC Corporation in Yokohama, Japan; and Orbital Sciences Corporation (OSC) in Germantown, Maryland. Thorough optical characterization and calibration of the SXR was essential to the successful application of the radiometer for these measurements.

Hooker, Stanford B.

SeaWiFS Postlaunch Technical Report Series: The SeaBOARR-98 Field Campaign - Volume 3

This report documents the scientific activities during the first Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Bio-Optical Algorithm Round-Robin (SeaBOARR-98) experiment, which took place from 5-17 July 1998, at the Acqua Alta Oceanographic Tower (AAOT) in the northern Adriatic Sea off the coast of Italy. The ultimate objective of the SeaBOARR activity is to evaluate the effect of different measurement protocols on bio-optical algorithms using data from a variety of field campaigns. The SeaBOARR-98 field campaign was concerned with collecting a high quality data set of simultaneous in-water and above-water radiometric measurements. The deployment goals documented in this report were to: a) use four different surface glint correction methods to compute water-leaving radiances, L W (lambda), from above-water data; b) use two different in-water profiling systems and three different methods to compute L W (lambda) from in-water data (one making measurements at a fixed distance from the tower, 7.5 m, and the other at variable distances up to 29 m away); c) use instruments with a common calibration history to minimize intercalibration uncertainties; d) monitor the calibration drift of the instruments in the field with a second generation SeaWiFS Quality Monitor (SQM-II), to separate differences in methods from changes in instrument performance; and e) compare the L W (lambda) values estimated from the above-water and in-water measurements. In addition to describing the instruments deployed and the data collected, a preliminary analysis of the data is presented, and the kind of follow-on work that is needed to completely assess the estimation of L W (lambda) from above-water and in-water measurements is discussed.

Zibordi, Giuseppe

Sea WiFS Postlaunch Technical Report Series: The SeaBOARR-99 Field Campaign - Volume 8

This report documents the scientific activities during the second Sea-viewing Wide Field-of-view Sensor (Sea- WIFS) Bio-Optical Algorithm Round-Robin (SeaBOARR-99) field campaign, which took place from 2 May to 7 June 1999 on board the Royal Research Ship James Clark Ross during the eighth Atlantic Meridional Transect cruise (AMT-8). The ultimate objective of the SeaBOARR activity is to evaluate the effect of different measurement protocols on bio-optical algorithms using data from a variety of field campaigns. The SeaBOARR-99 field campaign was concerned with collecting a high quality data set of simultaneous in-water and above-water radiometric measurements. The deployment goals documented in this report were to: a) use four different surface glint correction methods to compute water-leaving radiances, Lw(lambda), from above-water data; b) use two different in-water profiling systems and three different methods to compute Lw(lambda) from in-water data; c) use instruments with a common calibration history to minimize intercalibration uncertainties; d) monitor the calibration stability of the instruments in the field with the original SeaWiFS Quality Monitor (SQM) and a commercial, second-generation device called the SQM-II, thereby allowing a distinction between differences in methods from changes in instrument performance; and e) compare the Lw(lambda) values estimated from the above- water and in- water measurements. In addition to describing the instruments deployed and the data collected, a preliminary analysis of part of the SeaBOARR-99 data set is presented (using only the data collected during clear sky, calm sea, and Case-I waters).

Hooker, Stanford B.

Distributed Parallel Processing and Dynamic Load Balancing Techniques for Multidisciplinary High Speed Aircraft Design

Multidisciplinary design optimization (MDO) for large-scale engineering problems poses many challenges (e.g., the design of an efficient concurrent paradigm for global optimization based on disciplinary analyses, expensive computations over vast data sets, etc.) This work focuses on the application of distributed schemes for massively parallel architectures to MDO problems, as a tool for reducing computation time and solving larger problems. The specific problem considered here is configuration optimization of a high speed civil transport (HSCT), and the efficient parallelization of the embedded paradigm for reasonable design space identification. Two distributed dynamic load balancing techniques (random polling and global round robin with message combining) and two necessary termination detection schemes (global task count and token passing) were implemented and evaluated in terms of effectiveness and scalability to large problem sizes and a thousand processors. The effect of certain parameters on execution time was also inspected. Empirical results demonstrated stable performance and effectiveness for all schemes, and the parametric study showed that the selected algorithmic parameters have a negligible effect on performance.

Krasteva, Denitza T.

SIMBIOS Project Data Processing and Analysis Results

The Sensor Intercomparison and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) Project is concerned with ocean color satellite sensor data intercomparison and merger for biological and interdisciplinary studies of the global oceans. Imagery from different ocean color sensors can now be processed by a single software package using the same algorithms, adjusted by different sensor spectral characteristics, and the same ancillary meteorological and environmental data. This enables cross-comparison and validation of the data derived from satellite sensors and, consequently, creates continuity in ocean color information on both the temporal and spatial scale. The next step in this process is the integration of in situ ocean and atmospheric parameters to enable cross-validation and further refinement of the ocean color methodology. The SIMBIOS Project Office accomplishments during 2000 year are summarized under satellite data processing, data product validation, SeaWiFS Bio-Optical Archive and Storage System (SeaBASS) database, supporting services, sun photometers and calibration activities, and calibration round robins. These accomplishments are described.

Ainsworth, Ewa

Sources of Variability in Chlorophyll Analysis by Fluorometry and by High Performance Liquid Chromatography

The need for accurate determination of chlorophyll a (chl a) is of interest for numerous reasons. From the need for ground-truth data for remote sensing to pigment detection for laboratory experimentation, it is essential to know the accuracy of the analyses and the factors potentially contributing to variability and error. Numerous methods and instrument techniques are currently employed in the analyses of chl a. These methods range from spectrophotometric quantification, to fluorometric analysis and determination by high performance liquid chromatography. Even within the application of HPLC techniques, methods vary. Here we provide the results of a comparison among methods and provide some guidance for improving the accuracy of these analyses. These results are based on a round-robin conducted among numerous investigators, including several in the Sensor Intercomparison and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) and HyCODE Programs. Our purpose here is not to present the full results of the laboratory intercalibration; those results will be presented elsewhere. Rather, here we highlight some of the major factors that may contribute to the variability observed. Specifically, we aim to assess the comparability of chl a analyses performed by fluorometry and HPLC, and we identify several factors in the analyses which may contribute disproportionately to this variability.

VanHeukelem, Laurie

Reproducibility and Repeatability of Tensile and Low-Cycle Fatigue Properties in Propulsion Grade Hydrogen

Hydrogen has the potential of increased use in the future as an environmentally friendly fuel. It has, however, shown a tendency to embrittle some materials. To be used in a safe manner and to exploit its full potential, it will be necessary to develop a database of material properties in hydrogen environment. The tests needed to produce this data are costly to perform (tensile test cost 25 times more and low cycle fatigue test are 55 times as expensive). Moreover, there is presently a lack of universal test methods to ensure standardized data within the hydrogen community. Each of the industries that work with hydrogen (aerospace, petroleum, fuel cells, etc.) performs tests by their own laboratory-developed methods, thus rendering cross- comparisons of material property data highly questionable. It is extremely important that data generated in a hydrogen environment be done to a standard that reduces variance to a minimum and allows direct comparison of test results from different laboratories. Doing so will assure that all data generated can be used to further our understanding of the hydrogen effects and to make sure components/products designed for hydrogen are the safest and most reliable possible. This paper reviews the results of two 'round-robin' programs conducted by NASA-MSFC. These two programs examined the reproducibility and repeatability of tensile and low-cycle fatigue test results in high-pressure hydrogen environments. The studies indicated that even with the tightest controls available from current commercial standards, the reproducibility (between different laboratories) and repeatability (within a laboratory) results of the tensile tests exhibited five times the variance as in standard ambient air tests. The variance with the LCF tests were on the same order as with air tests, but that was due to the large variation present in the last Interlaboratory air program. The paper concludes with a recommendation for a program that would allow the development of improved test methods, leading to lower variance in the generation of mechanical property data in the future.

Vesely, E. J.

BENCAL Cruise Report

This report documents the scientific activities on board the South African Fisheries Research Ship (FRS) Africana during an ocean color calibration and validation cruise in the Benguela upwelling ecosystem (BEN-CAL), 4-17 October 2002. The cruise, denoted Afncana voyage 170, was staged in the southern Benguela between Cape Town and the Orange River within the region 14-18.5 deg E,29-34 deg S, with 15 scientists participat- ing from seven different international organizations. Uniquely in October 2002, four high-precision ocean color sensors were operational, and these included the Moderate Resolution Imaging Spectroradiometer (MODIS) instruments on the Aqua and Terra spacecraft, the Medium Resolution Imaging Spectrometer (MERIS), and the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). SeaWiFS imagery was transmitted daily to the ship to assist in choosing the vessel's course and selecting stations for bio-optical deployments. There were four primary objectives of the cruise. The first was to conduct bio-optical measurements with above- and in-water optical instruments to vicariously calibrate the satellite sensors. The second was to interrelate diverse measurements of the apparent optical properties (AOPs) at satellite sensor wavelengths with inherent optical properties (IOPs) and bio-optically active constituents of seawater such as particles, pigments, and dissolved compounds. The third was to determine the interrelationships between optical properties, phytoplankton pigment composition, photosynthetic rates, and primary production, while the fourth objective was to collect samples for a second pigment round-robin intercalibration experiment. Weather conditions were generally very favorable, and a range of hyperspectral and fixed wavelength AOP instruments were deployed during daylight hours. Various IOP instruments were used to determine the absorption, attenuation, scattering, and backscattering properties of particulate matter and dissolved substances, while a Fast Repetition Rate Fluorometer (FRRF) was deployed to acquire data on phytoplankton photosynthetic activity. Hydrographic profiling was conducted routinely during the cruise, and seawater samples were collected for measurements of salinity, oxygen, inorganic nutrients, pigments, particulate organic carbon, suspended particulate material, and primary production. Location of stations and times of optical deployments were selected to coincide with satellite overpasses whenever possible, and to cover a large range in trophic conditions.

Hooker, Stanford B.

New Laboratory Methods for Characterizing the Immersion Factors for Irradiance

The experimental determination of the immersion factor, I(sub f)(lambda), of irradiance collectors is a requirement of any in-water radiometer. The eighth SeaWiFS Intercalibration Round-Robin Experiment (SIRREX-8) showed different implementations, at different laboratories, of the same I(sub f)(lambda) measurement protocol. The different implementations make use of different setups, volumes, and water types. Consequently, they exhibit different accuracies and require different execution times for characterizing an irradiance sensor. In view of standardizing the characterization of I(sub f)(lambda) values for in-water radiometers, together with an increase in the accuracy of methods and a decrease in the execution time, alternative methods are presented, and assessed versus the traditional method. The proposed new laboratory methods include: a) the continuous method, in which optical measurements taken with discrete water depths are substituted by continuous profiles created by removing the water from the water vessel at a constant flow rate (which significantly reduces the time required for the characterization of a single radiometer); and b) the Compact Portable Advanced Characterization Tank (ComPACT) method, in which the commonly used large tanks are replaced by a small water vessel, thereby allowing the determination of I(sub f)(lambda) values with a small water volume, and more importantly, permitting I(sub f)(lambda) characterizations with pure water. Intercomparisons between the continuous and the traditional method showed results within the variance of I(sub f) (lambda) determinations. The use of the continuous method, however, showed a much shorter realization time. Intercomparisons between the ComPACT and the traditional method showed generally higher I(sub f)(lambda) values for the former. This is in agreement with the generalized expectations of a reduction in scattering effects, because of the use of pure water with the ComPACT method versus the use of tap water with the traditional method.

Hooker, Stanford B.