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Hydrogen and He ion irradiation retention coefficients, saturation concentrations and temperature-gas release curves for olivine and estatite
Here, a comparison of Computational Fluid Dynamics (CFD) predictions with measurements is presented for cryo-compressed hydrogen vertical jets. The stagnation conditions of the experiments are characteristic of unintended leaks from pipe systems that connect cryogenic hydrogen storage tanks and could be encountered at a fuel cell refueling station. Jets with pressure up to 5 bar and temperatures just above the saturation liquid temperature were examined. Comparisons are made to the centerline mass fraction and temperature decay rates, the radial profiles of mass fraction and the contours of volume fraction. Two notional nozzle approaches are tested to model the under-expanded jet that was formed in the tests with pressures above 2 bar. In both approaches the mass and momentum balance from the throat to the notional nozzle are solved, while the temperature at the notional nozzle was assumed equal to the nozzle temperature in the first approach and was calculated by an energy balance in the second approach. The two approaches gave identical results. Satisfactory agreement with the measurements was found in terms of centerline mass fraction and temperature. However, for test with 3 and 4 bar release the concentration was overpredicted. Furthermore, a wider radial spread was observed in the predictions possibly revealing higher degree of diffusion using the k-ε turbulence model. An integral model for cryogenic jets was also developed and provided good results. Finally, a test simulation was performed with an ambient temperature jet and compared to the cold jet showing that warm jets decay faster than cold jets.
Here, this study investigates the warm-season extreme precipitation–temperature scaling relationship in CONUS404, a convection-permitting (4 km) Weather Research and Forecasting (WRF) Model simulation over the conterminous United States for the past four decades, and compares it with the WRF-Thermodynamic Global Warming (WRF-TGW) historical simulation at a coarser resolution (12 km) using parameterized convection. We also analyze the NCEP stage IV and NASA Integrated Multi-satellitE Retrievals for the Global Precipitation Measurement (IMERG) datasets as observational benchmarks. We examine how extreme precipitation intensity (EPI) varies with temperature and saturation deficit over representative regions based on hourly data. The stage IV and IMERG data show a similar pattern of EPI variation with temperature and saturation deficit, except that the EPI peak is lower in IMERG than in stage IV. Under dry and hot conditions, EPI decreases too rapidly with elevated saturation deficit in both CONUS404 and WRF-TGW compared to observations, but the performance of CONUS404 is superior to WRF-TGW. When the near-surface atmosphere is saturated or close to saturated, both CONUS404 and WRF-TGW produce higher peak values of EPI relative to the observational references; IMERG exhibits scaling rates close to the Clausius–Clapeyron (C–C) relationship, while CONUS404, WRF-TGW, and stage IV all demonstrate super-C–C scaling behaviors. Despite marked warming over the past four decades, in both CONUS404 and WRF-TGW, the scaling relationship between EPI and temperature in a saturated atmosphere remains stable and robust. This indicates a strong potential for the EPI–temperature scaling rate under saturation to be used as an emergent constraint in reducing uncertainties of future extreme precipitation projection.
Integration of heat transfer coefficients, modified to account for local vapor quality, into the 45 mm bearing model has been completed. The model has been evaluated with two flow rates and subcooled and saturated coolant. The evaluation showed that by increasing the flow from 3.6 to 7.0 lbs/sec the average ball temperature was decreased by 102 F, using a coolant temperature of -230 F. The average ball temperature was decreased by 63 F by decreasing the inlet coolant temperature from saturated to -230 F at a flow rate of 7.0 lbs/sec. Since other factors such as friction, cage heating, etc., affect bearing temperatures, the above bearing temperature effects should be considered as trends and not absolute values. The two phase heat transfer modification has been installed in the 57 mm bearing model and the effects on bearing temperatures have been evaluated. The average ball temperature was decreased by 60 F by increasing the flow rate from 4.6 to 9.0 lbs/sec for the subcooled case. By decreasing the inlet coolant temperature from saturation to -24 F, the average ball temperature was decreased 57 F for a flow rate of 9.0 lbs/sec. The technique of relating the two phase heat transfer coefficient to local vapor quality will be applied to the tester model and compared with test data.
High saturation core material magnetic behavior, noting structural instability accompanied by deteriorating magnetic properties at high temperatures
Sonochemically-synthesized atomically-dispersed titanium-aluminum-boron nanopowder (TiAlB NP) exhibits a remarkable low-temperature catalytic activation of aliphatic C-H bonds at 750 K followed by C-C bond activation thus emerging as a potent low-cost alternative to expensive platinum group metals. Here, the model saturated hydrocarbon, exo-tetrahydrodicyclopentadiene (C10H16), undergoes catalytic decomposition on TiAlB NPs in a chemical microreactor to produce 1,3-cyclopentadiene (c-C5H6), cyclopentene (c-C5H8), and molecular hydrogen (H2) as detected in situ via isomer-selective, single-photon ionization time-of-flight mass spectrometry. Extensive electronic structure theory calculations on model clusters of the catalyst decode a unique synergy among the atomic constituents of the catalyst and chemical bonding in this stepwise, retro Diels Alder reaction: Ti, although insensitive to C-H activation in its metallic state, initiates the catalysis via chemisorption of the hydrocarbon, adjacent B centers readily abstract hydrogen atoms and store them during the catalytic cycle, while Al stabilizes the catalyst structure yet providing space for critical docking sites for the departing hydrocarbons.
A new ReaxFF reactive force field has been developed for metal carbonate systems including Na + , Ca 2+ , and Mg 2+ cations and the CO 3 2– anion. This force field is fully transferable with previous ReaxFF water and water/electrolyte descriptions. The Me–O–C (Me = metal) three-body valence angle parameters and Me–C non-reactive parameters of the force field have been optimized against quantum mechanical calculations including equations of state, heats of formation, heats of reaction, angle distortions and vibrational frequencies. The new metal carbonate force field has been validated using molecular dynamics simulations to study the solvation and reactivity of metal and carbonate ions in water at 300 K and 700 K. The coordination radius and self-diffusion coefficient show good consistency with existing experimental and simulation results. The angular distribution analysis explains the structural preference of carbonate ions to form carbonates and bicarbonates, where Na + predominantly forms carbonates due to weaker angular strain, while Ca 2+ and Mg 2+ prefer to form bicarbonate monodentate in nature. Residence time distribution analyses on different systems reveal the role of ions in accelerating and decelerating the dynamics of water and carbonate ions under different thermodynamic conditions. The formation and dissolution of bicarbonates and carbonates in solution were explored on the basis of the protonation capability in different systems. Here, the nucleation phenomenon of metal carbonates at ambient and supercritical conditions is explained from the perspective of cluster formation over time: Ca 2+ ions can form prenucleation clusters at ambient temperature but show saturation with increasing temperature, whereas Na + and Mg 2+ ions show a rapid increase in cluster size and amount upon increasing time and temperature.
The resistance of a conventional insulator diverges as temperature approaches zero. The peculiar low-temperature resistivity saturation in the 4f Kondo insulator (KI) SmB 6 has spurred proposals of a correlation-driven topological Kondo insulator (TKI) with exotic ground states. However, the scarcity of model TKI material families leaves difficulties in disentangling key ingredients from irrelevant details. Here we use angle-resolved photoemission spectroscopy (ARPES) to study FeSb 2 , a correlated d-electron KI candidate that also exhibits a low-temperature resistivity saturation. On the (010) surface, we find a rich assemblage of metallic states with two-dimensional dispersion. Measurements of the bulk band structure reveal band renormalization, a large temperature-dependent band shift, and flat spectral features along certain high-symmetry directions, providing spectroscopic evidence for strong correlations. Our observations suggest that exotic insulating states resembling those in SmB 6 and YbB 12 may also exist in systems with d instead of f electrons.
The effectiveness of a thermal energy storage (TES) system is typically characterized with the help of thermal stratification or temperature gradients along the direction of heat injection, which is typically the flow direction of heat transfer fluid. The steepness of temperature gradients are a direct indicator of the effectiveness or efficiency of the heat storage or dispatch process. The temperature gradient evolution along the packed bed of ceramic particles upon saturated steam injection is presented in this work. Distributed temperature sensing based on optical frequency domain reflectometry was deployed in a packed bed of ceramic particles to capture the thermal front evolution in the axial direction. The physical processes accompanying steam injection in packed beds are complex due to phase change, transitioning two-phase flow, and changes in condensate accumulation. Therefore, the variation of thermal response of the TES system for various steam injection flow rates was experimentally studied using a high-resolution distributed temperature sensing system in a chemically inert alumina particle-packed bed. Distinct zones of different heat transfer modes were observed during the steam injection experiments. A distinct conduction zone, evident from diffuse thermal fronts, was observed at low flow rates, and these thermal gradients became sharper as the flow rate increased. The diffuse thermal fronts in the heat storage media suggest a low exergy efficiency of the TES system, as energy losses started initiating before a significant fraction of the bed was saturated with steam.
Data reduction techniques are developed to compensate for water vapor path delay, a limiting error source in geodetic measurements made with very long baseline interferometry and in radio ranging to spacecraft. It is shown that water vapor path delay is proportional to a linear combination of saturation-corrected sky brightness temperatures, measured on and off the water vapor line. The effects of emission from liquid water droplets in clouds as well as most of the oxygen emission are removed by the off-line channel. Sky brightness temperatures are saturation-corrected or 'linearized' using estimates of effective sky temperatures made from surface temperature. Tipping curves are used to remove instrumental error. Coefficients are found by two methods: from a regression analysis of measured brightness temperatures versus radiosonde measured delay, and from a regression analysis of theoretical brightness temperatures versus radiosonde measured delay. In each case the coefficients are adjusted for differing climatic conditions by measurements of surface temperature, pressure, and relative humidity. Regression solutions are constrained to remove liquid water contributions and to give the correct slope for radiometer versus radiosonde path delay.
Expanding upon our prior experimental work, we constructed a three-dimensional model of a polymer electrolyte membrane water electrolyzer using computational fluid dynamics. We applied the assumption of pseudo-two-phase flow, the flow of two phases with equal velocity. Experimental data were used to obtain parameters and to determine the conditions under which this model was valid. Anodic distributions of current density, temperature, liquid saturation, and relative humidity were obtained at various flow rates. The overall current density and temperature difference from inlet to outlet at the anode agreed strongly with experimental measurements under most circumstances. This verification allowed us to further examine the apparent gas coverage calculated from experimental and model temperature data. Results suggested a low liquid saturation and low relative humidity at the anode due to the consumption of liquid water and water vapor. However, we questioned the accuracy of the pseudo-two-phase assumption at low water feed rates. We concluded that the model was applicable to systems with liquid water feed rates greater than 0.6 ml min -1 cm -2 . Therefore, it is a fair screening method that can advise which operating conditions lead to excessive temperatures or drying at the anode, thereby promoting the longevity of the membrane and catalyst.
With our limited knowledge of the relationship between changes in the state of an aquifer or reservoir and the corresponding changes in the elastic moduli, that is the rock physics model, hampers the effective use of time-lapse seismic observations for estimating flow properties within the Earth. A central problem is the complicated dependence of the magnitude of time-lapse changes on the saturation, pressure, and temperature changes within an aquifer or reservoir. We describe an inversion methodology for reservoir characterization that uses onset times, the calendar time of the change in seismic attributes, rather than the magnitude of the changes. We find that onset times are much less sensitive than magnitudes to the rock physics model used to relate time-lapse observations to changes in saturation, temperature and fluid pressure. We apply the inversion scheme to observations from daily monitoring of enhanced oil recovery at the Peace River field in Canada. An array of 1492 buried hydrophones record seismic signals from 49 buried sources. Time-shifts for elastic waves traversing the reservoir are extracted from the daily time-lapse cubes. In our analysis 175 images of time-shifts are transformed into a single map of onset times, leading to a substantial reduction in the volume of data. These observations are used in conjunction with bottom hole pressure data to infer the initial conditions prior to the injection, and to update the reservoir permeability model. The combination of a global and local inversion scheme produces a collection of reservoir models that are best described by three clusters. The updated model leads to a nearly 70 percent reduction in seismic data misfit. The final set of solutions successfully predict the observed normalized pressure history during the soak and flow-back into the wells between 82 and 175 days into the cyclic steaming operation.
Six entropy diagrams for parahydrogen in or near the saturated liquid state cover the temperature range from 29.16 degrees to 42.48 degrees R with pressures to 100 psia and mixtures of the liquid and vapor phases to 0.003 quality. The diagrams are printed in color, are 19 by 30 inches in size, and are suitable for wall mounting.
Conditional instability and the buoyancy of plumes drive moist convection but have a variety of representations in model convective schemes. Vertical thermodynamic structure information from Atmospheric Radiation Measurement (ARM) sites and reanalysis (ERA5), satellite-derived precipitation (TRMM3b42), and diagnostics relevant for plume buoyancy are used to assess climate models. Previous work has shown that CMIP6 models represent moist convective processes more accurately than their CMIP5 counterparts. However, certain biases in convective onset remain pervasive among generations of CMIP modeling efforts. Here we diagnose these biases in a cohort of nine CMIP6 models with sub-daily output, assessing conditional instability in profiles of equivalent potential temperature θ e and saturation equivalent potential temperature θ es in comparison to a plume model with different mixing assumptions. Most models capture qualitative aspects of the θ es vertical structure, including a substantial decrease with height in the lower free troposphere associated with the entrainment of subsaturated air. We define a “pseudo-entrainment” diagnostic that combines subsaturation and a θ es measure of conditional instability similar to what entrainment would produce under the small-buoyancy approximation. This captures the trade-off between larger θ es lapse rates (entrainment of dry air) and small subsaturation (permits positive buoyancy despite high entrainment). This pseudo-entrainment diagnostic is also a reasonable indicator of the critical value of integrated buoyancy for precipitation onset. Models with poor θ e /θ es structure (those using variants of the Tiedtke Scheme) or low entrainment runs of CAM5, and models with low subsaturation, such as NASA-GISS, lie outside the observational range in this diagnostic.
To support development of a zero-gravity pressure control capability for liquid hydrogen (LH2), a series of thermodynamic venting system (TVS) tests was conducted in 1996 and 1998 using the Marshall Space Flight Center (MSFC) multipurpose hydrogen test bed (MHTB). These tests were performed with ambient heat leaks =20 and 50 W for tank fill levels of 90%, 50%, and 25%. TVS performance testing revealed that the spray bar was highly effective in providing tank pressure control within a 7-kPa band (131-138 Wa), and complete destratification of the liquid and the ullage was achieved with all test conditions. Seven of the MHTB tests were correlated with the TVS performance analytical model. The tests were selected to encompass the range of tank fill levels, ambient heat leaks, operational modes, and ullage pressurants. The TVS model predicted ullage pressure and temperature and bulk liquid saturation pressure and temperature obtained from the TVS model were compared with the test data. During extended self-pressurization periods, following tank lockup, the model predicted faster pressure rise rates than were measured. However, once the system entered the cyclic mixing/venting operational mode, the modeled and measured data were quite similar.
In designing systems for the long-term storage of cryogens in low gravity space environments, one must consider the effects of thermal stratification on excessive tank pressure that will occur due to environmental heat leakage. During low gravity operations, a Thermodynamic Venting System (TVS) concept is expected to maintain tank pressure without propellant resettling. The TVS consists of a recirculation pump, Joule-Thomson (J-T) expansion valve, and a parallel flow concentric tube heat exchanger combined with a longitudinal spray bar. Using a small amount of liquid extracted by the pump and passing it though the J-T valve, then through the heat exchanger, the bulk liquid and ullage are cooled, resulting in lower tank pressure. A series of TVS tests were conducted at the Marshall Space Flight Center using liquid nitrogen as a liquid oxygen simulant. The tests were performed at fill levels of 90%, 50%, and 25% with gaseous nitrogen and helium pressurants, and with a tank pressure control band of 7 kPa. A transient one-dimensional model of the TVS is used to analyze the data. The code is comprised of four models for the heat exchanger, the spray manifold and injector tubes, the recirculation pump, and the tank. The TVS model predicted ullage pressure and temperature and bulk liquid saturation pressure and temperature are compared with data. Details of predictions and comparisons with test data regarding pressure rise and collapse rates will be presented in the final paper.
In designing systems for the long-term storage of cryogens in low-gravity (space) environments, one must consider the effects of thermal stratification on tank pressure that will occur due to environmental heat leaks. During low-gravity operations, a Thermodynamic Vent System (TVS) concept is expected to maintain tank pressure without propellant resettling. A series of TVS tests was conducted at NASA Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a liquid oxygen (LO2) simulant. The tests were performed at tank til1 levels of 90%, 50%, and 25%, and with a specified tank pressure control band. A transient one-dimensional TVS performance program is used to analyze and correlate the test data for all three fill levels. Predictions and comparisons of ullage pressure and temperature and bulk liquid saturation pressure and temperature with test data are presented.