Current pushing of the oscillation frequency of a 6328-angstrom units He-Ne laser.
Laser oscillation frequency shift dependence on discharge current in 6328 A He-Ne laser
Arrathoon, R.↗
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Linking The Atlantic Gyres: Warm, Saline Intrusions From Subtropical Atlantic to the Nordic Seas
Ocean state estimates from SODA assimilation are analyzed to understand how major shifts in the North Atlantic Current path relate to AMOC, and how these shifts are related to large scale ocean circulation and surface forcing. These complement surface-drifter and altimetry data showing the same events. SODA data indicate that the warm water limb of AMOC, reaching to at least 600m depth, expanded in density/salinity space greatly after 1995, and that Similar events occurred in the late 1960s and around 1980. While there were large changes in the upper limb, there was no immediate response in the dense return flow, at least not in SODA, however one would expect a delayed response of increasing AMOC due to the positive feedback from increased salt transport. These upper limb changes are winddriven, involving changes in the eastern subpolar gyre, visible in the subduction of low potential vorticity waters. The subtropical gyre has been weak during the times of the northward intrusions of the highly saline subtropical waters, while the NAO index has been neutral or in a negative phase. The image of subtropical/subpolar gyre exchange through teleconnections within the AMOC overturning cell will be described.
Hakkinen, Sirpa M.↗
Extracting and Interpreting Electrochemical Impedance Spectra (EIS) from Physics-Based Models of Lithium-Ion Batteries
This paper implements a highly efficient algorithm to extract electrochemical impedance spectra (EIS) from physics-based battery models (e.g., a P2D model). The mathematical approach is different from how EIS is practiced experimentally. Experimentally, the voltage (current) is harmonically perturbed over a wide range of frequencies and the amplitude and phase shift of the corresponding current (voltage) is measured. The experimental approach can be implemented in simulation software, but is computationally expensive. The approach here is to determine locally linear state-space models from the full physical model. The four Jacobian matrices that are the basis of the state-space models can be derived by numerical differentiation of the physical model. The EIS is then extracted from the state-space model using computationally efficient matrix-manipulation techniques. The algorithm can evaluate the full EIS at an instant in time during a transient, independent of whether the battery is in a stationary state. The approach is also able to separate the full-cell impedance to evaluate partial EIS, such as for a battery anode alone. Although such partial EIS is difficult to measure experimentally, the partial EIS provides valuable insights in interpreting the full-cell EIS.
25 ENERGY STORAGE↗
Bridging knowledge gaps in liquid- and vapor-fed CO 2 electrolysis through active electrode area
Increased use of gas diffusion electrodes for CO 2 electroreduction widens the experimental phase space that was previously inaccessible using foil electrodes, raising fundamental questions over the impacts of key variables that translate between liquid- and vapor-fed CO 2 electrolysis systems. This work focuses on studying the interplay of current-potential profiles and electrochemically active surface area (ECSA) by implementing a Cu nanoflower catalyst morphology. The results show decreased overpotentials as much as 460 and 174 mV for foil and gas diffusion electrodes, respectively, while maintaining or improving multi-carbon product current density. Furthermore, these overpotential shifts and product activities normalized by ECSA lead to current-potential relationships akin to those of the Tafel description, which are found through a continuum model to be useful for describing the roughness dependence for both liquid- and vapor-fed systems. This analysis establishes a holistic approach for establishing catalyst design criteria to improve materials development for CO 2 .
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Highly efficient photon detection systems for noble liquid detectors based on perovskite quantum dots
Abstract Wavelength shifting photon detection systems (PDS) are the critical functioning components in noble liquid detectors used for high energy physics (HEP) experiments and dark matter search. The vacuum ultraviolet (VUV) scintillation light emitted by these Liquid argon (LAr) and liquid Xenon (LXe) detectors are shifted to higher wavelengths resulting in its efficient detection using the state-of-the-art photodetectors such as silicon photomultipliers (SiPM). The currently used organic wavelength shifting materials [such as 1,1,4,4 Tetraphenyl Butadiene (TPB)] have several disadvantages and are unreliable for longterm use. In this study, we demonstrate the application of the inorganic perovskite cesium lead bromide (CsPbBr 3 ) quantum dots (QDs) as highly efficient wavelength shifters. The absolute photoluminescence quantum yield of the PDS fabricated using these QDs exceeds 70%. CsPbBr 3 -based PDS demonstrated an enhancement in the SiPM signal enhancement by up to 3 times when compared to a 3 µm-thick TPB-based PDS. The emission spectrum from the QDs was optimized to match the highest quantum efficiency region of the SiPMs. In addition, we have demonstrated the deposition of the QD-based wavelength shifting material on a large area PDS substrate using low capital cost and widely scalable solution-based techniques providing a pathway appropriate for meter-scale PDS fabrication and widespread use for other wavelength shifting applications.
47 OTHER INSTRUMENTATION↗
Electrical Gating of the Charge-Density-Wave Phases in Two-Dimensional h -BN/1T-TaS 2 Devices
Here we report on the electrical gating of the chargedensity- wave phases and current in h-BN-capped three-terminal 1T-TaS 2 heterostructure devices. It is demonstrated that the application of a gate bias can shift the source–drain current– voltage hysteresis associated with the transition between the nearly commensurate and incommensurate charge-density-wave phases. The evolution of the hysteresis and the presence of abrupt spikes in the current while sweeping the gate voltage suggest that the effect is electrical rather than self-heating. We attribute the gating to an electric-field effect on the commensurate charge-density-wave domains in the atomic planes near the gate dielectric. The transition between the nearly commensurate and incommensurate charge-density-wave phases can be induced by both the source– drain current and the electrostatic gate. Since the charge-densitywave phases are persistent in 1T-TaS 2 at room temperature, one can envision memory applications of such devices when scaled down to the dimensions of individual commensurate domains and few-atomic plane thicknesses.
2D van der Waals materials↗
Capsulation Satellite or CapSat: A Low-Cost, Reliable, Rapid-Response Spacecraft Platform
The National Aeronautics and Space Administration (NASA) Goddard's Rideshare Office estimates that between 2013 and 2022, NASA launches of primary satellites will have left unused more than 20,371 kilograms of excess capacity. This equates to hundreds of millions of dollars in launch-vehicle costs going unutilized. To fill this void with a standard CubeSat or SmallSat spacecraft platform, which when required to be more reliable, still will cost in the neighborhood of $1M a kilogram, making it prohibitively expensive. A newly proposed solution, which NASA is pursuing, is called the Capsulation Satellite or CapSat. CapSat is a modularized, pressurized, thermally controlled spacecraft designed to host ruggedized commercially available instrumentation in a terrestrial like environment on orbit. Using a technique that is under review for a patent, CapSat actively manages internal air temperatures in a manner similar to a household thermostat. This gives CapSat high-thermal stability, which, in turn, provides component longevity. CapSat was specifically designed to take advantage of the United States Air Force (USAF) Rideshare Program and the Evolved Expendable Launch Vehicle Secondary Payload Adaptor, or ESPA ring. The ESPA ring comes in two sizes: standard and Grande. CapSat primarily will take advantage of the ESPA Grande to provide a 300-kilogram payload capability per attachment point, with up to four attachment points per ring. This approach combines a high-mass capability with a proven Rideshare mechanical interface and secondary payload management infrastructure. Opportunities for ESPA based co-manifests are continuing to expand. The CapSat program is currently funded to design and build a limited prototype and perform thermal-vacuum testing. CapSat is currently in the concept/study phase for both single missions and constellation of earth- and space-observing missions. One of these studies includes land imaging using state-of-the-art advanced infrared detector technology. This paper will report on the current status of the CapSat hardware design, testing, and results as well as any openly available advanced concept study results. The CapSat solution is intended to be a game-changing paradigm shift. CapSat will repurpose currently available, already-proven technology to reduce spaceflight hardware costs to less than $50,000 per kilogram.
Burt, Joe↗
Managing Complex Airplane System Failures Through a Structured Assessment of Airplane Capabilities
This report describes an analysis of current transport aircraft system-management displays and the initial development of a set of display concepts for providing information about aircraft system status. The new display concepts are motivated by a shift away from the current approach to aircraft system alerting that reports the status of physical components, and towards displaying the implications for mission capability. Specifically, the proposed display concepts describe transport airplane component failures in terms of operational consequences of aircraft system degradations. The research activity described in this report is an effort to examine the utility of different representations of complex systems and operating environments to support real-time decision making during off-nominal situations. A specific focus is to develop display concepts that provide more highly integrated information to allow pilots to more easily reason about the operational consequences of the off-nominal situations. The work can also serve as a foundational element to autonomy-supported decision making since we are developing ideas for integrating information from the airplane and the operational environment to support decision making.
operational decision making↗
NASA Remote Sensing Research as Applied to Archaeology
The use of remotely sensed images is not new to archaeology. Ever since balloons and airplanes first flew cameras over archaeological sites, researchers have taken advantage of the elevated observation platforms to understand sites better. When viewed from above, crop marks, soil anomalies and buried features revealed new information that was not readily visible from ground level. Since 1974 and initially under the leadership of Dr. Tom Sever, NASA's Stennis Space Center, located on the Mississippi Gulf Coast, pioneered and expanded the application of remote sensing to archaeological topics, including cultural resource management. Building on remote sensing activities initiated by the National Park Service, archaeologists increasingly used this technology to study the past in greater depth. By the early 1980s, there were sufficient accomplishments in the application of remote sensing to anthropology and archaeology that a chapter on the subject was included in fundamental remote sensing references. Remote sensing technology and image analysis are currently undergoing a profound shift in emphasis from broad classification to detection, identification and condition of specific materials, both organic and inorganic. In the last few years, remote sensing platforms have grown increasingly capable and sophisticated. Sensors currently in use, or nearing deployment, offer significantly finer spatial and spectral resolutions than were previously available. Paired with new techniques of image analysis, this technology may make the direct detection of archaeological sites a realistic goal.
Giardino, Marco J.↗
NASA Remote Sensing Applications for Archaeology and Cultural Resources Management
NASA's Earth Science Mission Directorate recently completed the deployment of the Earth Observation System (EOS) which is a coordinated series of polar-orbiting and low inclination satellites for long-term global observations of the land surface, biosphere, solid Earth, atmosphere, and oceans. One of the many applications derived from EOS is the advancement of archaeological research and applications. Using satellites, manned and unmanned airborne platform, NASA scientists and their partners have conducted archaeological research using both active and passive sensors. The NASA Stennis Space Center (SSC) located in south Mississippi, near New Orleans, has been a leader in space archaeology since the mid-1970s. Remote sensing is useful in a wide range of archaeological research applications from landscape classification and predictive modeling to site discovery and mapping. Remote sensing technology and image analysis are currently undergoing a profound shift in emphasis from broad classification to detection, identification and condition of specific materials, both organic and inorganic. In the last few years, remote sensing platforms have grown increasingly capable and sophisticated. Sensors currently in use, including commercial instruments, offer significantly improved spatial and spectral resolutions. Paired with new techniques of image analysis, this technology provides for the direct detection of archaeological sites. As in all archaeological research, the application of remote sensing to archaeology requires a priori development of specific research designs and objectives. Initially targeted at broad archaeological issues, NASA space archaeology has progressed toward developing practical applications for cultural resources management (CRM). These efforts culminated with the Biloxi Workshop held by NASA and the University of Mississippi in 2002. The workshop and resulting publication specifically address the requirements of cultural resource managers through the use of remote sensing. In 2007, NASA awarded six competitively chosen projects in Space Archaeology through an open solicitation whose purpose, among several, was to addresses the potential benefits to modern society that can be derived through a better understanding of how past cultures succeeded or failed to adapt to local, regional, and global change. A further objective of NASA's space archaeology is the protection and preservation of cultural heritage sites while planning for the sustainable development of cultural resources. NASA s archaeological approach through remote sensing builds on traditional methods of aerial archaeology (i.e. crop marks) and utilizes advanced technologies for collecting and analyzing archaeological data from digital imagery. NASA s archaeological research and application projects using remote sensing have been conducted throughout the world. In North America, NASA has imaged prehistoric mound sites in Mississippi; prehistoric shell middens in Louisiana, Puebloan sites in New Mexico and more recently the sites associated with the Lewis and Clark Corps of Discovery Expedition (1804-1806). In Central America, NASA archaeologists have researched Mayan sites throughout the region, including the Yucatan and Costa Rica, as well as Olmec localities in Veracruz. Other data has been collected over Angkor, Cambodia, Giza in Egypt, the lost city of Ubar on the Arabian Peninsula.
Giardino, Marco J.↗
The 10 kW power electronics for hydrogen arcjets
A combination of emerging mission considerations such as 'launch on schedule', resource limitations, and the development of higher power spacecraft busses has resulted in renewed interest in high power hydrogen arcjet systems with specific impulses greater than 1000 s for Earth-space orbit transfer and maneuver applications. Solar electric propulsion systems with about 10 kW of power appear to offer payload benefits at acceptable trip times. This work outlines the design and development of 10 kW hydrogen arcjet power electronics and results of arcjet integration testing. The power electronics incorporated a full bridge switching topology similar to that employed in state of the art 5 kW power electronics, and the output filter included an output current averaging inductor with an integral pulse generation winding for arcjet ignition. Phase shifted, pulse width modulation with current mode control was used to regulate the current delivered to arcjet, and a low inductance power stage minimized switching transients. Hybrid power Metal Oxide Semiconductor Field Effect Transistors were used to minimize conduction losses. Switching losses were minimized using a fast response, optically isolated, totem-pole gate drive circuit. The input bus voltage for the unit was 150 V, with a maximum output voltage of 225 V. The switching frequency of 20 kHz was a compromise between mass savings and higher efficiency. Power conversion efficiencies in excess of 0.94 were demonstrated, along with steady state load current regulation of 1 percent. The power electronics were successfully integrated with a 10 kW laboratory hydrogen arcjet, and reliable, nondestructive starts and transitions to steady state operation were demonstrated. The estimated specific mass for a flight packaged unit was 2 kg/kW.
Hamley, John A.↗
Effect of choked flow on terminal characteristics of MPD thrusters
A one-dimensional steady real gas MPD accelerator model based on data for various electrode lengths and anode orifice radii is presented. The model relates the electric field to the boundary conditions in a form that agrees with experiment over parametric variations in current and mass flow. The electric field is sensitive to the formulations and assumptions bound into the analysis, and is useful in the modeling of outflow properties. It is shown that the location of the sonic point in the arc chamber shifts upstream for high current operation, and the relation between terminal voltage and current is demonstrated. Experiments using an anode suggested by the theory yield a thrust efficiency 1.5 times that of the unmodified thruster.
King, D. Q.↗
Ring currents modulate optoelectronic properties of aromatic chromophores at 25 T
The properties of organic molecules can be influenced by magnetic fields, and these magnetic field effects are diverse. They range from inducing nuclear Zeeman splitting for structural determination in NMR spectroscopy to polaron Zeeman splitting organic spintronics and organic magnetoresistance. A pervasive magnetic field effect on an aromatic molecule is the aromatic ring current, which can be thought of as an induction of a circular current of π-electrons upon the application of a magnetic field perpendicular to the π-system of the molecule. While in NMR spectroscopy the effects of ring currents on the chemical shifts of nearby protons are relatively well understood, and even predictable, the consequences of these modified electronic states on the spectroscopy of molecules has remained unknown. In this work, we find that photophysical properties of model phthalocyanine compounds and their aggregates display clear magnetic field dependences up to 25 T, with the aggregates showing more drastic magnetic field sensitivities depending on the intermolecular interactions with the amplification of ring currents in stacked aggregates. These observations are consistent with ring currents measured in NMR spectroscopy and simulated in time-dependent density functional theory calculations of magnetic field-dependent phthalocyanine monomer and dimer absorption spectra. Here, we propose that ring currents in organic semiconductors, which commonly comprise aromatic moieties, may present new opportunities for the understanding and exploitation of combined optical, electronic, and magnetic properties.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Computational Validation of a Two-Dimensional Semi-Empirical Model for Inductive Coupling in a Conical Pulsed Inductive Plasma Thruster
A two-dimensional semi-empirical model of pulsed inductive thrust efficiency is developed to predict the effect of such a geometry on thrust efficiency. The model includes electromagnetic and gas-dynamic forces but excludes energy conversion from radial motion to axial motion, with the intention of characterizing thrust efficiency loss mechanisms that result from a conical versus a at inductive coil geometry. The range of conical pulsed inductive thruster geometries to which this model can be applied is explored with the use of finite element analysis. A semi-empirical relation for inductance as a function of current sheet radial and axial position is the limiting feature of the model, restricting the applicability as a function of half cone angle to a range from ten degrees to about 60 degrees. The model is nondimensionalized, yielding a set of dimensionless performance scaling parameters. Results of the model indicate that radial current sheet motion changes the axial dynamic impedance parameter at which thrust efficiency is maximized. This shift indicates that when radial current sheet motion is permitted in the model longer characteristic circuit timescales are more efficient, which can be attributed to a lower current sheet axial velocity as the plasma more rapidly decouples from the coil through radial motion. Thrust efficiency is shown to increase monotonically for decreasing values of the radial dynamic impedance parameter. This trend indicates that to maximize the radial decoupling timescale should be long compared to the characteristic circuit timescale.
Hallock, Ashley K.↗
Designer Metasurfaces for Antireflective Applications Enabled by Advanced Nanoparticle Technology
Optic processing advances have shifted system limitations, with current constraints consisting of antireflective (AR) coatings applied to optics and the inability to reduce size, weight, and price. Metasurfaces, and more broadly metaoptics, provide an avenue to overcome these limitations. The ability to generate substrate-engraved metasurfaces that can be tailored is demonstrated within a broad design space to satisfy large-area AR applications for bandpass or broadband needs, demonstrating an optically equivalent surface roughness standard deviation of only 5 Å. Using an advanced nanoparticle masking approach, two metasurfaces are fabricated: 1) vertical sidewall nanofeature metasurface (MS) for AR applications at 351 nm, and 2) sloped sidewall MS designed for broadband AR applications. For the 351 nm MS, the reflectance is measured to be 0.127%. In the case of the sloped sidewall MS, the reflectance is measured to be <0.25% over 400–700 nm and <1% over 400–1100 nm. To the best of the authors’ knowledge, this is the first demonstration of a broadband AR capable of this performance. The tunability of these structures, with a parameter space spanning even more remarkable designs such as broader bands and acceptance angles, coupled with high laser-induced damage durability and mechanical robustness, displays the strength of metasurfaces for AR applications.
36 MATERIALS SCIENCE↗
Electronic Structure of the Complete Series of Gas-Phase Manganese Acetylacetonates by X-ray Absorption Spectroscopy
Metal centers in transition metal–ligand complexes occur in a variety of oxidation states causing their redox activity and therefore making them relevant for applications in physics and chemistry. The electronic state of these complexes can be studied by X-ray absorption spectroscopy, which is, however, due to the complex spectral signature not always straightforward. Here, we study the electronic structure of gas-phase cationic manganese acetylacetonate complexes Mn(acac) 1–3 + using X-ray absorption spectroscopy at the metal center and ligand constituents. The spectra are well reproduced by multiconfigurational wave function theory, time-dependent density functional theory as well as parameterized crystal field and charge transfer multiplet simulations. This enables us to get detailed insights into the electronic structure of ground-state Mn(acac) 1–3 + and extract empirical parameters such as crystal field strength and exchange coupling from X-ray excitation at both the metal and ligand sites. By comparison to X-ray absorption spectra of neutral, solvated Mn(acac) 2,3 complexes, we also show that the effect of coordination on the L 3 excitation energy, routinely used to identify oxidation states, can contribute about 40–50% to the observed shift, which for the current study is 1.9 eV per oxidation state.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Electrical manipulation of skyrmions in a chiral magnet
Writing, erasing and computing are three fundamental operations required by any working electronic device. Magnetic skyrmions could be essential bits in promising in emerging topological spintronic devices. In particular, skyrmions in chiral magnets have outstanding properties like compact texture, uniform size, and high mobility. However, creating, deleting, and driving isolated skyrmions, as prototypes of aforementioned basic operations, have been a grand challenge in chiral magnets ever since the discovery of skyrmions, and achieving all these three operations in a single device is even more challenging. Here, by engineering chiral magnet Co 8 Zn 10 Mn 2 into the customized micro-devices for in-situ Lorentz transmission electron microscopy observations, we implement these three operations of skyrmions using nanosecond current pulses with a low current density of about 10 10 A·m -2 at room temperature. A notched structure can create or delete magnetic skyrmions depending on the direction and magnitude of current pulses. We further show that the magnetic skyrmions can be deterministically shifted step-by-step by current pulses, allowing the establishment of the universal current-velocity relationship. These experimental results have immediate significance towards the skyrmion-based memory or logic devices.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Analysis of the Fe 2p XPS for hematite α Fe2O3: Consequences of covalent bonding and orbital splittings on multiplet splittings
The origins of the complex Fe 2p X-Ray Photoelectron Spectra (XPS) of hematite (α-Fe2O3) are analyzed and related to the character of the bonding in this compound. This analysis provides a new and novel view of the reasons for XPS binding energies (BEs) and BE shifts, which deepens the current understanding and interpretation of the physical and chemical significance of the XPS. In particular, many-body effects are considered for the initial and the final, 2p-hole configuration wavefunctions. It is shown that a one-body or one-configuration analysis is not sufficient and that the many-body, many-determinantal, and many-configurational character of the wavefunctions must be taken into account to describe and understand why the XPS intensity is spread over an extremely large number of final 2p-hole multiplets. The focus is on the consequences of angular momentum coupling of the core and valence open shell electrons, the ligand field splittings of the valence shell orbitals, and the degree of covalent mixing of the Fe(3d) electrons with the O(2p) electrons. Novel theoretical methods are used to estimate the importance of these various terms. An important consequence of covalency is a reduction in the energy separation of the multiplets. Although shake satellites are not considered explicitly, the total losses of intensity from the angular momentum multiplets to shake satellites is determined and related to the covalent character of the Fe-O interaction. The losses are found to be the same for Fe 2p1/2 and 2p3/2 ionization.
Bagus, Paul S. (ORCID:0000000349315217)↗