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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Aluminum under high pressure. I - Equation of state

A curve of applied pressure versus lattice constant is calculated for single-crystal aluminum. It results from an application of the method of structural expansions for deriving the energies of simple metals, a method known to give reasonable results for the elastic constants even at second order in the effective electron-ion interaction. The latter is taken from Fermi-surface analysis, and it is verified that the extant face-centered cubic structure remains the preferred crystalline phase up to the highest pressures considered. Arguments are given to suggest that the curve should have reasonable a priori accuracy and can admit possible improvement if experimental data in the intermediate-pressure region can be provided to refine the (in principle) energy-dependent pseudopotential. At three megabars, the lattice constant is reduced by only 22 per cent; the ion cores at this pressure are still very well separated.

Friedli, C.↗
NASA NTRS1976

Flexible, FEP-Teflon covered solar cell module development

Techniques and equipment were developed for the large scale, low-cost fabrication of lightweight, roll-up and fold-up, FEP-Teflon encapsulated solar cell modules. Modules were fabricated by interconnecting solderless single-crystal silicon solar cells and heat laminating them at approximately 300 C between layers of optically clear FEP and to a loadbearing Kapton substrate sheet. Modules were fabricated from both conventional and wraparound contact solar cells. A heat seal technique was developed for mechanically interconnecting modules into an array. The electrical interconnections for both roll-up and fold-up arrays were also developed. The use of parallel-gap resistance welding, ultrasonic bonding, and thermocompression bonding processes for attaching interconnects to solar cells were investigated. Parallel-gap welding was found to be best suited for interconnecting the solderless solar cells into modules. Details of the fabrication equipment, fabrication processes, module and interconnect designs, environmental test equipment, and test results are presented.

Rauschenbach, H. S.↗
NASA NTRS1976

Metal-insulator-semi-conductor studies of lead telluride

The capacitance and conductance-voltage characteristics were measured on metal-insulator-semiconductor capacitors fabricated with zirconium dioxide films on single-crystal lead telluride. At 77 K, on both n- and p-type substrates, evidence of surface potential control was obtained. Comparison of the measured capacitance-voltage characteristics with those calculated from the equilibrium solution of the one-dimensional Poisson equation indicated qualitative agreement, although the slope of the measured capacitance in the region near the capacitance minimum was less steep than calculated.

Lilly, D. A.↗
NASA NTRS1976

Adsorption of oxygen on W/100/ - Adsorption kinetics and structure

The adsorption of oxygen on W(100) single-crystal surfaces is studied by Auger electron spectroscopy (AES), flash desorption, low-energy electron diffraction (LEED), and retarding-field work-function measurements. The AES results reveal stepwise changes in the sticking coefficients in the coverage range 0 to 1 and activated adsorption at higher coverages. Upon room-temperature adsorption, a series of complex LEED patterns is observed. In layers adsorbed at 1050 K and cooled to room temperature, the p(2 x 1) structure is the first ordered structure observed. This structure shows a reversible order-disorder transition between 700 and 1000 K and is characterized by a work function which is lower than that of the clean surface. Heating room-temperature adsorbates changes their structure irreversibly. At temperatures below 750 K, some new structures are observed.

Bauer, E.↗
NASA NTRS1976

Moessbauer effect measurement in single crystal iron subjected to cyclic stress

Backscattered Moessbauer spectra were recorded at different fatigue levels in cyclically fatigued high-purity single-crystal iron specimens in the form of rectangular strips with appropriate concentrators in the midplane. The Moessbauer spectra were submitted to a least-squares analysis to determine the isomer shift, quadrupole shift, hyperfine field, and peak spectral widths in each spectrum. It is shown that the quadrupole shift and the isomer shift changed little with fatigue, whereas the effective internal field and the associate line widths exhibit significant variation as a function of fatigue level. It is concluded that the impurity concentration builds up slowly with increasing fatigue level in the region of stress concentration. Since there is a direct correlation between crack initiation and defect concentration level, it is expected that Moessbauer measurements in the test specimen can provide a means of monitoring the impurity buildup presumed to be the eventual cause of fatigue crack initiation and failure.

Singh, J. J.↗
NASA NTRS1976

Mineralogy of the Ibitira eucrite and comparison with other eucrites and lunar samples

The mineralogy of the Ibitira meteorite is studied using single-crystal X-ray and energy-dispersive electron-probe techniques. It is shown that this strongly metamorphosed unbrecciated vesicular eucrite has a primary variolitic and secondary hornfelsic texture dominated by equant grains of pale-brown pyroxene (60%) set in an irregular matrix of plagioclase (30%). Minor phases are detected which indicate igneous crystallization, a prolonged metamorphic history, and vapor deposition. The following sequence of events is suggested as the simplest explanation for the mineralogical features observed: (1) crystallization of the meteorite in a lava flow; (2) prolonged annealing, reduction of primary spinel, and vapor deposition; (3) strong shock sufficient to modify the texture of the plagioclase grains; and (4) sufficient annealing to allow crystallization of the plagioclase as a subparallel mosaic and partial conversion to the low structural state. Evidence for this sequence is examined in detail, particularly in relation to the general features of eucrites, howardites, and mesosiderites

Steele, I. M.↗
NASA NTRS1977

Measurements of the frequency spectrum of transition radiation

We report a measurement of the frequency spectrum of X-ray transition radiation. X rays were generated by electrons of 5 and 9 GeV in radiators of multiple polypropylene foils, and detected in the range 4 to 30 keV with a calibrated single-crystal Bragg spectrometer. The experimental results closely reproduce the features of the theoretically predicted spectrum. In particular, the pronounced interference pattern of multifoil radiators and the expected hardening of the radiation with increasing foil thickness are clearly observed. The overall intensity of the radiation is somewhat lower than predicted by calculations.

Cherry, M. L.↗
NASA NTRS1977

Application of diffusion barriers to high modulus fibers

Barrier layers were coated onto high-modulus fibers, and nickel and titanium layers were overcoated as simulated matrix materials. The objective was to coat the high-strength fibers with unreactive selected materials without degrading the fibers. The fibers were tungsten, niobium, and single-crystal sapphire, while the materials used as barrier coating layers were Al2O3, Y2O3, TiC, ZrC, WC with 14% Co, and HfO2. An ion-plating technique was used to coat the fibers. The fibers were subjected to high-temperature heat treatments to evaluate the effectiveness of the barrier layer in preventing fiber-metal interactions. Results indicate that Al2O3, Y2O3, and HfO2 can be used as barrier layers to minimize the nickel-tungsten interaction. Further investigation, including thermal cycling tests at 1090 C, revealed that HfO2 is probably the best of the three.

Veltri, R. D.↗
NASA NTRS1976

Pyroxene-spinel intergrowths in lunar and terrestrial pyroxenes

The paper describes the oriented intergrowth of spinel and pyroxene in a pigeonite from Luna 20, an augite from Apollo 16 anorthosite 67075, and an orthopyroxene from a spinel lherzolite nodule from the San Quintin volcanic field, Mexico. Using Mo K alpha radiation, photographs were taken of small, hand-picked single-crystals. A mechanism of exsolution is suggested in which the oxygen framework remains intact and spinel nuclei are formed by the migration of cations from interstitial sites and tetrahedral sites in the original non-stoichiometric pyroxene.

Okamura, F. P.↗
NASA NTRS1978

Hydrogen embrittlement of nickel

Report describes comprehensive study of hydrogen embrittlement in high purity single-crystal and polycrystalline nickel at temperatures from -130 degrees C to 20 degrees C.

Kamdar, M. H.↗
NASA NTRS1978

Measurements of the spectrum and energy dependence of X-ray transition radiation

The results of experiments designed to test the theory of X-ray transition radiation and to verify the predicted dependence of the characteristic features of the radiation on the radiator dimensions are presented. The X-ray frequency spectrum produced by 5- to 9-GeV electrons over the range 4 to 30 keV was measured with a calibrated single-crystal Bragg spectrometer, and at frequencies up to 100 keV with an NaI scintillator. The interference pattern in the spectrum and the hardening of the radiation with increasing foil thickness are clearly observed. The energy dependence of the total transition-radiation intensity was studied using a radiator with large dimensions designed to yield energy-dependent signals at very high particle energies, up to E/mc-squared approximately equal to 100,000. The results are in good agreement with the theoretical predictions.

Cherry, M. L.↗
NASA NTRS1977

4.2-4.3 AE anorthositic soil fragments - Equilibrated or unequilibrated polycomponent systems

The petrographies and phase chemistries of five lunar crystalline anorthositic fragments with Ar-40/Ar-39 plateau 'ages' ranging from 4.1 to 4.3 AE are reported. An investigation is conducted to determine whether the individual fragments are monomict or polymict breccias. For polymict breccias it is attempted to establish whether clasts and matrix have equilibrated chemically. On the basis of the results of the investigation it is suggested that sample 73263,1,1 was a breccia (possibly a clast-laden melt) containing old clasts, incorporated in an ejecta blanket that was annealed at about 4.1 AE in a transient high-temperature event. The sample 73263,1,6 studied is an annealed anorthositic breccia containing approximately 20% clasts dominated by single-crystal plagioclase fragments. The obtained data are consistent with a two-component system containing old plagioclase clasts in a young (about 4.0 AE) annealed, matrix. The annealing event at approximately 4.0 AE was insufficient to equilibrate the argon. It is found that four of the breccias having ages of about 4.2 AE or more are polymict. The most striking feature of all of the samples studied is the presence of a significant amount of 4.2-4.3 AE argon.

Delano, J. W.↗
NASA NTRS1975

Relative cooling rates of mare basalts at the Apollo 12 and 15 sites as estimated from pyroxene exsolution data

X-ray single-crystal diffraction studies, supplemented by electron microprobe analyses of core pigeonites and rim augites from rocks 12031, 15085, 15475, and 15495, have been used to suggest cooling rates for these and other Apollo 12 and 15 rocks studied by similar methods. The extent of subsolidus phase separation of pyroxenes is used as a measure of the cooling rate. The results were interpreted in terms of model cooling histories of a lava flow whose thickness was estimated from the absolute cooling rates obtained by cooling rate experiments and by temperature-time variation through an extrusive flow computed by employing simplified theory of Jaeger. All available data on the exsolution and cation distributions of pyroxenes from Apollo 12 and 15 samples at present are consistent with the hypothesis that these rocks were derived from the top and interior of lava flows with thicknesses of 4-10 m. A process for exsolution of augite from a host pigeonite on (100) has been related to its low-calcium content.

Takeda, H.↗
NASA NTRS1978

Solar power satellites - Heat engine or solar cells

A solar power satellite is the energy-converting element of a system that can deliver some 10 GW of power to utilities on the earth's surface. We evaluated heat engines and solar cells for converting sunshine to electric power at the satellite. A potassium Rankine cycle was the best of the heat engines, and 50 microns thick single-crystal silicon cells were the best of the photovoltaic converters. Neither solar cells nor heat engines had a clear advantage when all factors were considered. The potassium-turbine power plant, however, was more difficult to assemble and required a more expensive orbital assembly base. We therefore based our cost analyses on solar-cell energy conversion, concluding that satellite-generated power could be delivered to utilities for around 4 to 5 cents a kWh.

Oman, H.↗
NASA NTRS1978

Advantages of thin silicon solar cells for use in space

A system definition study on the Solar Power Satellite System showed that a thin, 50 micrometers, silicon solar cell has significant advantages. The advantages include a significantly lower performance degradation in a radiation environment and high power-to-mass ratios. The advantages of such cells for an employment in space is further investigated. Basic questions concerning the operation of solar cells are considered along with aspects of radiation induced performance degradation. The question arose in this connection how thin a silicon solar cell had to be to achieve resistance to radiation degradation and still have good initial performance. It was found that single-crystal silicon solar cells could be as thin as 50 micrometers and still develop high conversion efficiencies. It is concluded that the use of 50 micrometer silicon solar cells in space-based photovoltaic power systems would be advantageous.

Denman, O. S.↗
NASA NTRS1978

Solar power satellite

The solar power satellite (SPS) concept, under evaluation by NASA since 1974, is discussed. A typical system providing a total of 10,000 MW of electrical power to the ground receiving stations is considered. Energy conversion systems, including the photovoltaic device category using single-crystal silicon cells, are taken into account, as are the 2.45-GHz microwave power-transmission link and the ground receiver (or rectenna). Concepts involving space construction of the satellite's large structures (5 x 25 km) are described, noting that a process similar to the familiar roll-forming of light sheet metal parts has been adapted to the space environment. Transportation vehicles are discussed, including the Space Shuttle planned to reach 60 flights per year by the mid 1980's. Electrical power forecasts and advanced systems cost projections are analyzed, together with a description of costs estimates. The indirect economics of energy research and development, and the present NASA/DOE SPS program are noted.

Davis, H. P.↗
NASA NTRS1978

Thin silicon solar cell performance characteristics

Refined techniques for surface texturizing, back surface field and back surface reflector formation were evaluated for use with shallow junction, single-crystal silicon solar cells. Each process was characterized individually and collectively as a function of device thickness and bulk resistivity. Among the variables measured and reported are open circuit voltage, short circuit current and spectral response. Substantial improvements were obtained by the utilization of a low cost aluminum paste process to simultaneously remove the unwanted n(+) diffused region, form the back surface field and produce an ohmic contact metallization. The highly effective BSF which results from applying this process has allowed fabrication of cells 0.05 mm thick with initial outputs as high as 79.5 mW/4 sq cm (28 C, AM0) and superior electron radiation tolerance. Cells of 0.02 mm to 0.04 mm thickness have been fabricated with power to mass ratios well in excess of 2 watts per gram.

Gay, C. F.↗