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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Come for predictions, stay for complexity: synthesis and experimental probing of ionic conductivity in Li 9 B 19 S 33

Lithium thioborates, despite their potential cost-effectiveness and low density, have received considerably less attention as solid electrolytes compared to their thiophosphate counterparts. A primary obstacle to their widespread investigation has been the inherent challenge in synthesizing single-phase materials. Computational studies have predicted several lithium thioborate phases exhibiting high ionic conductivity, with Li 9 B 19 S 33 notably predicted to reach 80 mS cm −1 . However, experimental validation of these theoretical predictions remains absent. This work addresses this gap by detailing a successful synthesis of the previously elusive Li 9 B 19 S 33 phase, facilitated by in situ temperature dependent powder X-ray diffraction. Our findings reveal the peritectic nature of phase formation, necessitating an excess of boron sulfide in the reaction mixture. We further present a comprehensive structural characterization of Li 9 B 19 S 33 utilizing spectroscopic techniques like NMR, FT-IR, and diffuse reflectance and report on its ionic conductivity. Solid-state 6 Li NMR line narrowing experiments revealed an ion mobility activation energy of 0.26 eV whereas activation energies derived from impedance spectroscopy measurements were significantly higher, resulting in lower than theoretically predicted ionic conductivity.

Oppong, Richeal A. [Iowa State Univ., Ames, IA (Un↗
NASA NTRS2016

NuSTAR AND Swift Observations of the Very High State in GX 339-4: Weighing the Black Hole With X-Rays

We present results from spectral fitting of the very high state of GX339-4 with Nuclear Spectroscopic Telescope Array (NuSTAR) and Swift. We use relativistic reflection modeling to measure the spin of the black hole and inclination of the inner disk and find a spin of a = 0.95+0.08/-0.02 and inclination of 30deg +/- 1deg (statistical errors). These values agree well with previous results from reflection modeling. With the exceptional sensitivity of NuSTAR at the high-energy side of the disk spectrum, we are able to constrain multiple physical parameters simultaneously using continuum fitting. By using the constraints from reflection as input for the continuum fitting method, we invert the conventional fitting procedure to estimate the mass and distance of GX 339-4 using just the X-ray spectrum, finding a mass of 9.0+1.6/-1.2 Stellar Mass and distance of 8.4 +/- 0.9 kpc (statistical errors).

accretion↗
NASA NTRS1980

Spectroscopic studies of water and water/regolith mixtures on planetary surfaces at low temperatures

New reflectance spectra of Ganymede, Europe, Callisto, Io, Saturn's rings, and Mars were obtained. The new data is combined with data covering other spectral regions for compositional interpretation. The spectral properties of water and mixtures of water plus other minerals were studied in the laboratory at the low temperatures typical of Mars, the Galilean satellites, and Saturn's rings. High precision reflectance spectra of water ice were studied.

Clark, R. N.↗
DOE OSTI2022

Spin-phonon resonances in nearly polar metals with spin-orbit coupling

In metals in the vicinity of a polar transition, interactions between electrons and soft phonon modes remain to be determined. Here we explore the consequences of spin-orbit assisted electron-phonon coupling on the collective modes of such nearly polar metals in the presence of magnetic field. We find that the soft polar phonon hybridizes with spin-flip electronic excitations of the Zeeman-split bands leading to an anticrossing. The associated energy splitting allows for an unambiguous determination of the strength of the spin-orbit mediated coupling to soft modes in polar metals by spectroscopic experiments. Here, the approach to the polar transition is reflected by the softening of the effective g factor of the hybridized spin-flip mode. Analyzing the static limit, we find that the polar order parameter can be oriented by magnetic field. This provides possibilities for alternative switching protocols in polar metallic materials. We demonstrate that the effects we predict can be observed with current experimental techniques and discuss promising material candidates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1972

Relative transition probabilities for krypton.

First experimental line strength data for the visible Kr II lines and for several of the more prominent Kr I lines are given. The spectroscopic light source used is the thermal plasma behind the reflected shock wave in a gas-driven shock tube. A 3/4-m spectrograph and a 1-m spectrograph were employed simultaneously to provide redundant photometry. The data are compared with other measurements and with theoretical calculations.

Miller, M. H.↗
NASA NTRS1984

Hot subdwarfs in detached binary systems and thick-disk cataclysmic variables from the Palomar-Green survey

A total of 19 stars from the Palomar Green (PG) survey which were found to show composite spectra, generally with a hot subdwarf primary and a cool main-sequence secondary star, are discussed. The primary components have Teff values between 27,000 and 38,000 K (Mv = +5 to +7) and log g = about 6.5, while the secondaries generally show spectral types G8 to K4.5; however, these ranges are undoubtedly limited by selection effects, and extremely helium-rich subdwarfs were excluded as well. Aproximately half of all the PG subdwarfs could be in undetected binaries. Only two thick-disk cataclysmic variables with predominantly absorption-line spectra were found in the PG survey, which provides strong evidence that this kind of cataclysmic variable is luminous and confined to the Galactic plane (Population I). On the other hand, a few of the detached binaries show evidence for spectroscopic variations. Those which are close enough for a significant reflection effect on the secondary star may be progenitors to cataclysmic variable systems.

Ferguson, D. H.↗
NASA NTRS1984

The application of thermodynamic and spectroscopic techniques to adhesion in the polyimide/Ti 6-4 and polyphenylquinoxaline/Ti 6-4 systems

The results of calorimetric measurements of Ti adherend surfaces are presented. The measurements were carried out after several chemical pretreatments and after fracture of several lap shear samples aged at high temperature. The exact composition of the Ti samples was Ti(6 percent Al-4 percent V). The adhesives used were polyimides and polyphenylquinoxalines (PPQ). Each chemical pretreatment was accompanied by a unique spectroscopic feature which was characterized by XPS, SEM, and specular reflectance infrared spectroscopy. The energetics of the interaction between primer solutions and the Ti adherend were evaluated by microcalorimetry. Changes in the structure of the surface oxide layer upon heating of the adherend were deduced from immersion temperatures of the PI and PPQ solutions. The XPS and SEM data are given is a table.

Dias, S.↗
NASA NTRS2026

X-Ray Polarization From the Atoll 4U 1735−44 Suggests a Low Inclination

X-ray polarimetry is a new tool capable of probing the geometry of accretion onto weakly magnetized neutron stars. Here we present the first X-ray spectro-polarimetric results from coordinated observations of the atoll source 4U 1735−44, conducted with the Imaging X-ray Polarimetry Explorer (IXPE), NICER, and NuSTAR . Over the 2–8 keV energy range, we obtained a marginal detection of polarization with the polarization degree of 1.4% ± 0.7% and polarization angle of −29◦ ± 14◦, corresponding to a 3σ upper limit on the polarization degree of 3.5%. The best-fit model to describe the spectrum comprises a thermal component associated with the accretion disk, a Comptonized black body component, and a relativistic reflection component. From the reflection model, we infer a disk inclination of ∼40◦. The spectroscopic and polarimetric properties of 4U 1735−44 are consistent with those observed in other atoll sources studied by IXPE, with its low polarization likely due to its low inclination

X-rays: binaries↗
NASA NTRS2019

Implications of the Warm Corona and Relativistic Reflection Models for the Soft Excess in Mrk 509

We present the analysis of the first Nuclear Spectroscopic Telescope Array observations (∼220 ks), simultaneous with the last Suzaku observations (∼50 ks), of the active galactic nucleus of the bright Seyfert 1 galaxy Mrk 509. The time-averaged spectrum in the 1–79 keV X-ray band is dominated by a power-law continuum (Γ ∼ 1.8–1.9), a strong soft excess around 1 keV, and signatures of X-ray reflection in the form of Fe K emission (∼6.4 keV), an Fe K absorption edge (∼7.1 keV), and a Compton hump due to electron scattering (∼20–30 keV). We show that these data can be described by two very different prescriptions for the soft excess: a warm (kT ∼ 0.5–1 keV) and optically thick (τ ∼ 10–20) Comptonizing corona or a relativistically blurred ionized reflection spectrum from the inner regions of the accretion disk. While these two scenarios cannot be distinguished based on their fit statistics, we argue that the parameters required by the warm corona model are physically incompatible with the conditions of standard coronae. Detailed photoionization calculations show that even in the most favorable conditions, the warm corona should produce strong absorption in the observed spectrum. On the other hand, while the relativistic reflection model provides a satisfactory description of the data, it also requires extreme parameters, such as maximum black hole spin, a very low and compact hot corona, and a very high density for the inner accretion disk. Deeper observations of this source are thus necessary to confirm the presence of relativistic reflection and further understand the nature of its soft excess.

Javier Garcia↗
NASA NTRS2010

Biosensors for EVA: Improved Instrumentation for Ground-based Studies

During lunar excursions in the EVA suit, real-time measurement of metabolic rate is required to manage consumables and guide activities to ensure safe return to the base. Metabolic rate, or oxygen consumption (VO2), is normally measured from pulmonary parameters but cannot be determined with standard techniques in the oxygen-rich environment of a spacesuit. Our group has developed novel near infrared spectroscopic (NIRS) methods to calculate muscle oxygen saturation (SmO 2), hematocrit, and pH, and we recently demonstrated that we can use our NIRS sensor to measure VO 2 on the leg during cycling. Our NSBRI project has 4 objectives: (1) increase the accuracy of the metabolic rate calculation through improved prediction of stroke volume; (2) investigate the relative contributions of calf and thigh oxygen consumption to metabolic rate calculation for walking and running; (3) demonstrate that the NIRS-based noninvasive metabolic rate methodology is sensitive enough to detect decrement in VO 2 in a space analog; and (4) improve instrumentation to allow testing within a spacesuit. Over the past year we have made progress on all four objectives, but the most significant progress was made in improving the instrumentation. The NIRS system currently in use at JSC is based on fiber optics technology. Optical fiber bundles are used to deliver light from a light source in the monitor to the patient, and light reflected back from the patient s muscle to the monitor for spectroscopic analysis. The fiber optic cables are large and fragile, and there is no way to get them in and out of the test spacesuit used for ground-based studies. With complimentary funding from the US Army, we undertook a complete redesign of the sensor and control electronics to build a novel system small enough to be used within the spacesuit and portable enough to be used by a combat medic. In the new system the filament lamp used in the fiber optic system was replaced with a novel broadband near infrared LED light source. The compact grating spectrometer was replaced with a chip-scale spectrometer. With this new design, the sensor is 4 in 2 in 0.5 in, weighs 60 g, and no fiber optic cables are needed. The sensor, which contains the light source and the spectrometer, is adhered directly to the skin with medical grade adhesive. The sensor can be powered via the USB port of the laptop computer that controls the sensor operation. Alternatively, for studies in the spacesuit, the sensor can be powered by a small battery pack and operated by an ultra-portable hand-held computer. Both the handheld computer and battery pack will easily fit within the PLSS of the test spacesuit. System automation was significantly improved, to add features suggested by our colleagues in the Cardiovascular Laboratory and the NASA JSC Exercise Physiology and Countermeasures Project. The functionality and portability of this system were demonstrated in our UMass laboratory.

Soller, B.↗
DOE OSTI2021

The influence of tillage and fertilizer on the flux and source of nitrous oxide with reference to atmospheric variation using laser spectroscopy

Nitrous oxide (N 2 O) is the third most important long-lived greenhouse gas and agriculture is the largest source of N 2 O emissions. Curbing N 2 O emissions requires understanding influences on the flux and sources of N 2 O. We measured flux and evaluated microbial sources of N 2 O using site preference ( S P ; the intramolecular distribution of 15 N in N 2 O) in flux chambers from a grassland tilling and agricultural fertilization experiments and atmosphere. We identified values greater than that of the average atmosphere to reflect nitrification and/or fungal denitrification and those lower than atmosphere as increased denitrification. Our spectroscopic approach was based on an extensive calibration with 18 standards that yielded S P accuracy and reproducibility of 0.7 ‰ and 1.0 ‰, respectively, without preconcentration. Chamber samples from the tilling experiment taken ~ monthly over a year showed a wide range in N 2 O flux (0–1.9 g N 2 O-N ha -1 d -1 ) and S P (- 1.8 to 25.1 ‰). Flux and S P were not influenced by tilling but responded to sampling date. Large fluxes occurred in October and May in no-till when soils were warm and moist and during a spring thaw, an event likely representing release of N 2 O accumulated under snow cover. These high fluxes could not be ascribed to a single microbial process as S P differed among chambers. However, the year-long S P and flux data for no-till showed a slight direct relationship suggesting that nitrification increased with flux. The comparative data in till showed an inverse relationship indicating that high flux events are driven by denitrification. Corn ( Zea mays ) showed high fluxes and S P values indicative of nitrification ~ 4 wk after fertilization with subsequent declines in S P indicating denitrification. Although there was no effect of fertilizer treatment on flux or S P in switchgrass ( Panicum virgatum) , high fluxes occurred ~1 month after fertilization. In both treatments, S P was indicative of denitrification in many instances, but evidence of nitrification/fungal denitrification also prevailed. At 2 m atmospheric N 2 O S P had a range of 31.1 ‰ and 14.6 ‰ in the grassland tilling and agricultural fertilization experiments, respectively. These data suggest the influence of soil microbial processes on atmospheric N 2 O and argue against the use of the global average atmospheric S P in isotopic modeling approaches.

Environmental Sciences & Ecology↗
NASA NTRS2021

Reflection Modeling of the Black Hole Binary 4U 1630–47: The Disk Density and Returning Radiation

We present the analysis of X-ray observations of the black hole binary 4U 1630−47 using relativistic reflection spectroscopy. We use archival data from the Rossi X-ray Timing Explorer, Neil Gehrels Swift Observatory, and Nuclear Spectroscopic Telescope Array observatories, taken during different outbursts of the source between 1998 and 2015. Our modeling includes two relatively new advances in modern reflection codes: high-density disks, and returning thermal disk radiation. Accretion disks around stellar-mass black holes are expected to have densities well above the standard value assumed in traditional reflection models (i.e., n(e) ∼ 10^(15) per cu. cm). New high-density reflection models have important implications in the determination of disk truncation (i.e., the disk inner radius). This is because one must retain self-consistency in the irradiating flux and corresponding disk ionization state, which is a function of disk density and system geometry. We find that the disk density is n(e) ≥ 10^(20) per cu. cm across all spectral states. This density, combined with our constraints on the ionization state of the material, implies an irradiating flux impinging on the disk that is consistent with the expected theoretical estimates. Returning thermal disk radiation—the fraction of disk photons that bend back to the disk producing additional reflection components—is expected predominantly in the soft state. We show that returning radiation models indeed provide a better fit to the soft-state data, reinforcing previous results that show that in the soft state, the irradiating continuum may be blackbody emission from the disk itself.

Riley M. T. Connors↗
DOE OSTI2024

Spectral and Temperature-Dependent Optical Metrology: Towards More Robust, Effective and Durable Materials for Concentrated Solar Power

The primary objective of this project is to develop reliable and standardized spectroscopic measurement techniques to determine radiative properties, specifically the emittance and reflectance, of materials relevant for the next generation (Gen3) concentrated solar power (CSP) technologies. Experimental measurements will span near- and mid-infrared wavelengths (1–20 µm) with emphasis on quantifying the influences of: (1) operating temperatures of 25–1000 °C, (2) thermal cycling, and (3) environmental exposure of materials during operation (vacuum/air). A secondary goal is to develop open-access and digitized databases to host and share experimental data, together with standardized measurement protocols and operating procedures to determine optical properties of materials. This project will also include reasonable emphasis on developing predictive modeling tools to augment experimental data to extract more fundamental and material-specific radiative properties.

14 SOLAR ENERGY↗
NASA NTRS1991

Fourier transform infrared and Raman spectroscopic characterization of homogeneous solution concentration gradients near a container wall at different temperatures

Fourier transform infrared (FTIR) and Raman spectroscopic techniques were used to study the solution concentration gradient in succino nitrile-rich and water-rich homogeneous solutions. The spectroscopic data shows significant concentration dependency. Although FTIR-attenuated total reflectance could not yield surface spectra since the evanescent infrared wave penetrated deep into the bulk solution, it showed that water-rich clusters were decreased at higher temperatures. This result is consistent with the calorimetric results reported earlier.

Loo, B. H.↗
NASA NTRS1981

Spectroscopic evidence for aqueous alteration products on the surfaces of low-albedo asteroids

The spectral reflectances of primary components of the carbonaceous chondrite matrix materials (CCMM) and their secondary alteration products are compared with new observations of low-albedo asteroids. It is shown that the spectral differences between C-type asteroids and carbonaceous chondrites are consistent with differing degrees of aqueous alteration of CCMM.

Feierberg, M. A.↗
NASA NTRS1973

Opportunities for space surveys of moisture anomalies

Review of a combination of infrared scanning, unsupervised spectroscopic classification, change detection, and perturbation spectroscopy for monitoring anomalous moisture exchange from space. Infrared sensors have been developed which can monitor the solar reflectance from droplet distributions in vegetation and clouds, the absorption of thermal radiation by water vapor, and the microwave attenuation by atmospheric water. Unsupervised spectroscopic classification techniques are emerging which have the potential to subdivide strip maps from infrared scanners into different moisture targets. Intersecting and parallel spacecraft orbits provide opportunities to study the change of recognized targets between two scans and to recognize anomalous moisture exchange from those changes which significantly exceed the statistical uncertainty of the spectroscopic target signature. The new concept of perturbation spectroscopy shows a potential to quantitatively determine the change of integrated water vapor pressure with a minimum of 'atmospheric truth' and with low spectroscopic resolution that is typical of simple interference filters.

Krause, F. R.↗
NASA NTRS1993

An infrared study of the remarkable dusty M star HR 3126

HR 3126 is a unique M giant star embedded in the bipolar reflection nebula IC 2220. In this paper we present new photometric and spectroscopic observations of HR 3126 and combine them with existing data from the literature in an extensive reappraisal of the star's properties at infrared wavelengths. The spectral energy distribution is consistent with an optical classification of M0-3 II with infrared excess. The dust shell cannot be fitted by a single-temperature blackbody: at least three components are required, with temperatures in the range 35-1300 K. On the basis of spectroscopy at 1-4 and 7-25 microns, combined with an assessment of various color-color diagrams, we are able to reject the hypothesis that HR 3126 is carbon-rich. Weak silicate emission features are detected at 10 and 19 microns, and a previous report of silicon carbide emission at 11.2 microns is not substantiated. It seems likely that HR 2136 is in a phase of advanced and rapid postmain-sequence evolution, possibly beginning its ascent of the asymptotic giant branch.

Chiar, J. E.↗